JPS63242610A - Manufacture of polytetrafluoroethylene sealing part - Google Patents

Manufacture of polytetrafluoroethylene sealing part

Info

Publication number
JPS63242610A
JPS63242610A JP7834787A JP7834787A JPS63242610A JP S63242610 A JPS63242610 A JP S63242610A JP 7834787 A JP7834787 A JP 7834787A JP 7834787 A JP7834787 A JP 7834787A JP S63242610 A JPS63242610 A JP S63242610A
Authority
JP
Japan
Prior art keywords
mold
ptfe
molding material
molding stock
heated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP7834787A
Other languages
Japanese (ja)
Other versions
JPH0450166B2 (en
Inventor
Shigetake Hashida
茂壮 橋田
Toshiyuki Yamaguchi
寿之 山口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Valqua Industries Ltd
Nihon Valqua Kogyo KK
Original Assignee
Nippon Valqua Industries Ltd
Nihon Valqua Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Valqua Industries Ltd, Nihon Valqua Kogyo KK filed Critical Nippon Valqua Industries Ltd
Priority to JP7834787A priority Critical patent/JPS63242610A/en
Publication of JPS63242610A publication Critical patent/JPS63242610A/en
Publication of JPH0450166B2 publication Critical patent/JPH0450166B2/ja
Granted legal-status Critical Current

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  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To obtain a polytetrafluoroethylene (PTFE) sealing part, which has uniform density and smooth sealing surface and in which no filler is exposed, by a method wherein molding stock, which mainly consists of PTFE, is put in a mold under the state being heated up to a specified temperature or higher and, after that, pressed by moving a moving mold so as to form into a desired shape. CONSTITUTION:Molding stock, which mainly consists of calcined PTFE and has a simple annular shape, is heated up to 200 deg.C or higher and put in a cavity 4 formed in a mold 3. Next, without shifting mixed molds 5, 6 and 7, which constitute the mold 3, a moving mold 8 is brought close towards the fixed mold 7 so as to compress the molding stock 2 by pressurizing in order to plastically flow and deform it along the inner form of the cavity 4 into a desired form. Through the plastical flow and deformation of the molding stock 2 along the inner form of the cavity 4, the surface of the PTFE molding stock 2 is oriented and becomes be draped to the surfaces of the molds 5, 6, 7 and 8, resulting in smoothly and hardening the surface. In addition, no ununiform density of the PTFE molding stock 2 results.

Description

【発明の詳細な説明】 及五例五■尖夏 本発明は、ポリテトラフルオロエチレン樹脂製シール部
品の製造方法に係り、ざらに詳しくは、なめらかなシー
ル面を有するポリテトラフルオロエチレン樹脂製シール
部品を簡単に製造する方法に関する。
Detailed Description of the Invention The present invention relates to a method for manufacturing a polytetrafluoroethylene resin seal component, and more specifically, a polytetrafluoroethylene resin seal having a smooth sealing surface. Concerning a method for easily manufacturing parts.

Cの技術的背景ならびにその問題11、ポリテトラフル
オロエチレン樹脂(以下、rPTFEJとも略称する)
は、耐熱性および耐薬品性に優れるとともに、摩擦係数
が小さく自己潤滑性を有しているので、パツキン、Oリ
ング、バルブ、コックなどのシール部品として広く使用
されている。
Technical background of C and its problems 11, polytetrafluoroethylene resin (hereinafter also abbreviated as rPTFEJ)
has excellent heat resistance and chemical resistance, low coefficient of friction, and self-lubricating properties, so it is widely used as sealing parts such as gaskets, O-rings, valves, and cocks.

ところでPTFEは、耐摩耗性が必ずしも良好ではなく
しかも圧縮強さも必ずしも充分ではないため、PTFE
に種々の充填剤を添加して耐摩耗性ならびに機械的強度
を改良することもある。このようなPTFE中□に添加
される充填剤としては、ガラス繊維、炭素i!維、グラ
ファイト、二硫化モリブデン、ブロンズ粉末などの無機
充填剤が知られている。
By the way, PTFE does not necessarily have good abrasion resistance and also does not necessarily have sufficient compressive strength.
Various fillers may be added to improve wear resistance and mechanical strength. Fillers added to such PTFE medium □ include glass fiber, carbon i! Inorganic fillers such as fiber, graphite, molybdenum disulfide, and bronze powder are known.

このようなPTFEをシール部品として使用するために
種々の形状に成形するには、PTFE樹脂が他の熱可塑
性樹脂とは異なり加熱による流動性が小さいため、従来
では、次に示す特殊な成形方法が用いられている。
In order to mold such PTFE into various shapes for use as seal parts, PTFE resin, unlike other thermoplastic resins, has low fluidity when heated, so conventionally the following special molding method has been used. is used.

(イ)PTFE樹脂粉末を、1qようとする形状と略同
−のキャビティ形状を有する金型内に充填した後、加圧
圧縮してPTFE製予備成形品を作成し、次いでこの予
備成形品をPTFEの融点温度(327℃)以上の温度
で焼成して所定形状のシール部品を得る方法。
(b) Fill a mold with a cavity shape that is approximately the same as that of the desired 1q PTFE resin powder, pressurize and compress it to create a PTFE preform, and then process this preform. A method of obtaining a seal component of a predetermined shape by firing at a temperature higher than the melting point temperature of PTFE (327°C).

(ロ)PTFE樹脂粉末を、得ようとする形状より大き
なキャビティ形状を有する金型内に充填した後加圧圧縮
して削り代を有するブロック状の予備成形品を作成し、
次いで該ブロックを327℃以上の温度で焼成した後、
このブロックを切削して所定形状のシール部品を得る方
法。
(b) PTFE resin powder is filled into a mold having a cavity shape larger than the shape to be obtained, and then compressed under pressure to create a block-shaped preformed product with a machining allowance;
Then, after firing the block at a temperature of 327°C or higher,
A method of cutting this block to obtain seal parts of a predetermined shape.

ところが、このような従来例に係る(イ)の方法にあっ
ては、特に複雑な形状のシール部品を得ようとする場合
に、金型に形成された所定形状のキャビティ内にPTF
E樹脂粉末を均一にむらなく充填することは難しく、こ
のため得られるシール部品の密度が不均一になりやすい
という問題点があった。もし金型内にPTFE樹脂粉末
の充填むらがある場合には、加圧圧縮時に充填密度の高
い部分では過大な圧力が加わってクラックが発生しやす
く、一方充填密度の低い部分では加圧力が不足してポー
ラス状となってしまう。また、充填むらに起因するシー
ル部品の密度の不均一さがあると、焼成冷却の際に不均
一な膨張および収縮が起こり、寸法安定性が悪くしかも
機械的強度も一定しないという問題点もあった。
However, in the method (a) according to such a conventional example, when trying to obtain a seal part with a particularly complicated shape, PTF is used in a cavity of a predetermined shape formed in a mold.
It is difficult to uniformly and evenly fill the E-resin powder, and as a result, there is a problem in that the density of the obtained sealing part tends to be non-uniform. If there is uneven filling of PTFE resin powder in the mold, excessive pressure is applied during pressure compression in areas with high packing density, which tends to cause cracks, while in areas with low packing density, there is insufficient pressure. This results in a porous shape. In addition, if there is uneven density in the sealing part due to uneven filling, uneven expansion and contraction will occur during firing and cooling, resulting in poor dimensional stability and inconsistent mechanical strength. Ta.

一方、前記(ロ)の方法にあっては、(イ)の方法にお
ける諸欠点は比較的少ないが、所定の形状に切削する際
にシール部品におけるシール面が粗くなり、シール性が
低下する虞れがあった。また、特にガラス等の充填剤が
添加されたPTFEを前記(ロ)の方法によってシール
部品として成形した場合には、切削によってシール面に
ガラス等の充填剤が露呈し、相手部材を傷付ける虞れが
あった。ざらに、(ロ)の方法にあっては、切削代をつ
けて予備成形するため、材料費が嵩むと共に、切削加工
が煩雑になるという不都合を有していた。
On the other hand, the method (b) has relatively few drawbacks compared to the method (a), but there is a risk that the sealing surface of the seal part may become rough when cutting into a predetermined shape, resulting in a decrease in sealing performance. There was that. In addition, especially when PTFE to which a filler such as glass is added is molded as a seal part by the method (b) above, the filler such as glass may be exposed on the sealing surface by cutting and may damage the mating member. was there. Generally speaking, the method (b) involves preforming with a cutting allowance, which has the disadvantages of increasing material costs and making the cutting process complicated.

発明の目的 本発明は、このような不都合を解消するためになされた
ものであり、均一な密度を有すると共に充填剤が露呈せ
ずなめらかなシール面を有するPTFEWaシール部品
を、切削加工することなく低コストで簡単に成形するP
TFE製シール部品の成形方法を提供することを目的と
する。
Purpose of the Invention The present invention was made in order to eliminate such inconveniences, and it is possible to produce a PTFE Wa seal component having a uniform density and a smooth sealing surface without exposing the filler without cutting it. Easy to mold at low cost
The purpose of the present invention is to provide a method for molding a TFE seal component.

1団り旦工 かかる目的を達成するために、本発明に係るポリテトラ
フルオロエチレン樹脂製シール部品の製造方法は、前工
程で加熱焼成したポリテトラフルオロエチレン樹脂を主
成分とする単純形状の成形素材を約200℃以上に加熱
した状態で金型内に入れ、その後、前記金型における移
動型を移動して前記成形素材を加圧して塑性流動変形さ
せ当該成形素材を希望形状に成形することを特徴とじて
いる。
In order to achieve the objective of requiring only one batch of labor, the method for manufacturing polytetrafluoroethylene resin seal parts according to the present invention involves molding into a simple shape whose main component is polytetrafluoroethylene resin that has been heated and fired in the previous step. The material is heated to about 200° C. or more and then placed in a mold, and then a movable die in the mold is moved to pressurize and plastically deform the molding material to form the molding material into a desired shape. It is characterized by

このような本発明に係る方法によれば、ポリテトラフル
オロエチレン樹脂(PTFE)を主成分とする成形素材
を金型内で加圧して塑性流動変形させるため、その際に
表面のPTFEの結晶が配向すると共に金型の表面に馴
み、シール面である表面が滑らかになると共に硬くなる
。しかも、成形素材の密度が不均一になることもない。
According to such a method according to the present invention, a molding material mainly composed of polytetrafluoroethylene resin (PTFE) is pressurized in a mold to cause plastic flow deformation, so that the PTFE crystals on the surface are As it becomes oriented, it conforms to the surface of the mold, and the sealing surface becomes smooth and hard. Furthermore, the density of the molded material does not become non-uniform.

PTFE製成形素材を加圧して塑性流動変形されるため
の加熱温度は、200℃以上であれば良いが、好ましく
は300℃〜350℃の温度が良い。
The heating temperature for pressurizing the PTFE molding material to undergo plastic flow deformation may be 200°C or higher, but preferably 300°C to 350°C.

これは、加熱温度が低い場合には加圧によって成形素材
の剪断変形が生じる虞れがあり、PTFEの融点温度付
近まで加熱すれば分子のミクロブラウン運動が活発にな
り、塑性変形し易くなるからである。
This is because if the heating temperature is low, there is a risk of shear deformation of the molding material due to pressure, and if it is heated to near the melting point of PTFE, the micro-Brownian motion of the molecules becomes active, making it easier to deform plastically. It is.

もし、PTFE製成形素材にガラス等の充填剤が注入さ
れている場合には、金型内でこの成形素材を塑性流動変
形させる際に、PTFEが表面に滲み出て金型表面に馴
むため、シール面である表面にガラス等の充填剤が露呈
せず、この場合もシール面が滑らかになる。
If a filler such as glass is injected into the PTFE molding material, when the molding material is plastically deformed in the mold, the PTFE oozes out to the surface and adapts to the mold surface. , fillers such as glass are not exposed on the surface that is the sealing surface, and the sealing surface is smooth in this case as well.

R■凹且迷煎遺コ 以下、本発明に係るPTFEIuシール部品の製造方法
を、図面に示す実施例に基づき説明する。
Hereinafter, a method for manufacturing a PTFE Iu seal component according to the present invention will be explained based on an embodiment shown in the drawings.

第1図(A)〜(C)は本発明の一実施例を示すPTF
E製シール部品の成形過程を示す要部断面図、第2図は
同実施例に係る方法により得られるシール部品の断面図
である。
FIGS. 1(A) to (C) are PTFs showing one embodiment of the present invention.
FIG. 2 is a cross-sectional view of a main part showing the molding process of a seal part made by E, and FIG. 2 is a cross-sectional view of a seal part obtained by the method according to the same example.

第1,2図に示す本発明に係る実施例は、PTFE製シ
ール部品として第2図に示すバルブシート1を製造する
例を示す。
The embodiment according to the present invention shown in FIGS. 1 and 2 shows an example in which the valve seat 1 shown in FIG. 2 is manufactured as a seal component made of PTFE.

本実施例では、まず、前工程で加熱焼成したポリテトラ
フルオロエチレン樹脂(PTFE)を主成分とする単純
なリング形状の成形素材を、200℃以上好ましくは3
00℃〜゛350℃の温度で加熱する。その後、第1図
(A>に示すように、加熱された成形素材2を金型3に
形成されたキャビティ4内に入れる。
In this example, first, a simple ring-shaped molding material mainly composed of polytetrafluoroethylene resin (PTFE) heated and baked in the previous step was heated at 200°C or higher, preferably at 30°C.
Heat at a temperature of 00°C to 350°C. Thereafter, as shown in FIG. 1 (A>), the heated molding material 2 is placed into a cavity 4 formed in a mold 3.

次に、金型3を構成する固定型5,6.7を移動させな
いで、移動型8を固定型7方向に接近移動させ、成形素
材2を、第1図(B)、(C)に示すように加圧圧縮す
る。そうすると、成形素材2はキャビティ4内形状に沿
って塑性流動変形し、希望形状に成形される。このよう
に成形素材2をキャビテイ4内部形状に沿って塑性流動
変形させることで、PTFE¥A成形素材2の表面が配
向すると共に金型5,6,7.8の表面に馴み、その表
面が非常に滑らかになると共に硬くなる。しかも、PT
FE製成形素材2の密度が不均一になることもない。さ
らに、PTFE製成形素材2にガラス等の充填剤が注入
されている場合も同様に表面が滑らかになり、シール面
にガラス等の充填剤が露呈して相手部材を傷付けること
もない。これは、成形素材2の加圧による塑性流動変形
によって、PTFEが表面に滲み出て金型表面に馴むた
めと考えられる。
Next, without moving the fixed molds 5, 6.7 that constitute the mold 3, the movable mold 8 is moved toward the fixed mold 7, and the molding material 2 is moved as shown in FIGS. 1(B) and (C). Press and compress as shown. Then, the molding material 2 undergoes plastic flow deformation along the internal shape of the cavity 4, and is molded into the desired shape. By plastically deforming the molding material 2 along the internal shape of the cavity 4 in this way, the surface of the PTFE¥A molding material 2 is oriented and conforms to the surfaces of the molds 5, 6, 7.8. becomes very smooth and hard. Moreover, P.T.
The density of the FE molded material 2 does not become non-uniform. Furthermore, when a filler such as glass is injected into the PTFE molded material 2, the surface is similarly smooth, and the filler such as glass is not exposed on the sealing surface and will not damage the mating member. This is thought to be because the PTFE oozes out to the surface and adapts to the mold surface due to plastic flow deformation due to pressurization of the molding material 2.

最後に、成形素材2を塑性流動変形させることで成形し
たバルブシート1を金型3から取り出せば、第2図に示
すバルブシート1が得られる。このようにして成形した
バルブシート1のシール面9は非常に滑らかであると共
に、硬いものとなる。
Finally, if the valve seat 1 molded by plastic flow deformation of the molding material 2 is taken out from the mold 3, the valve seat 1 shown in FIG. 2 is obtained. The sealing surface 9 of the valve seat 1 formed in this manner is extremely smooth and hard.

しかも、PTFEにガラス等の充填剤が注入された成形
素材1を成形する場合にも、シール面にガラス等の充填
剤が露呈することもない。
Furthermore, even when molding the molding material 1 in which a filler such as glass is injected into PTFE, the filler such as glass is not exposed on the sealing surface.

一実施例によれば、本発明方法によって得られるPTF
E製シール部品の表面あらざの平均R0=2.2μmで
あった。これに対して、従来例に係る方法(最終的に切
削加工する方法)により得られるシール部品の表面あら
ざの平均Ra=4.0μmであり、本発明方法の有効性
が証明された。
According to one embodiment, PTF obtained by the method of the invention
The average surface roughness R0 of the E-manufactured seal parts was 2.2 μm. On the other hand, the average surface roughness Ra of the seal parts obtained by the conventional method (the final cutting method) was 4.0 μm, proving the effectiveness of the method of the present invention.

なお、本発明は、上述した実施例に限定されず、種々に
改変することが可能である。
Note that the present invention is not limited to the embodiments described above, and can be modified in various ways.

たとえば、上述した実施例では、PTFE製バルブシー
1〜を製造する例を示したが、これに限らず、0リング
ヤVパツキン等の一般的なシール部品、ざらにまた、バ
ルブやコック等の広い意味でのシール部品をf!A造す
る際に本発明を適用することができる。
For example, in the above-mentioned embodiment, an example was shown in which the valve seats 1 to 1 made of PTFE were manufactured, but the invention is not limited to this, and can be used in a wide range of applications such as general seal parts such as O-rings, V-packs, etc., as well as valves and cocks. The seal parts in f! The present invention can be applied when building A.

また、上述した実施例では、成形素材2を加熱した後に
金型3内に入れるようにしたが、これに限らず、金型3
内に成形素材2を入れた後に、この成形素材2を加熱し
ながら加圧するようにしても良い。
Further, in the above-described embodiment, the molding material 2 is heated and then put into the mold 3; however, the present invention is not limited to this.
After putting the molding material 2 inside, the molding material 2 may be heated and pressurized.

R班停四ス 以上説明してきたように、本発明によれば、前工程で加
熱焼成して形成した単純形状のPTFE製成形素材を加
熱状態で金型内に入れ、この成形素材を金型内で加圧し
て塑性流動変形させて希望形状に成形するようにしたの
で、均一な密度を有すると共に充填剤等が露呈せず滑ら
かなシール面を有するPTFEtlJシール部品を、切
削加工することなく低コストで簡単に製造することがで
きるという優れた効果を奏する。
As explained above, according to the present invention, a simple-shaped PTFE molding material formed by heating and firing in the previous step is put into a mold in a heated state, and this molding material is placed in the mold. Since the PTFEtlJ seal parts have a uniform density and a smooth sealing surface without exposing the filler, etc., they can be molded into the desired shape without the need for cutting. It has the excellent effect of being easy to manufacture at low cost.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(A)〜(C)は本発明の一実施例を示すPTF
E製シール部品の成形過程を示す要部断面図、第2図は
同実施例に係る方法により得られるシール部品の断面図
である。 1・・・バルブシート     2・・・成形素材3・
・・金型  8・・・移動型  9・・・シール面特許
出願人  日本バルカー工業株式会社代理人  弁理士
  鈴 木 俊一部 第  1  図 (A)          (B)         
 (C)第  2  図 手続補正書 昭和63年 3月31 El。 6□1,11,11おヵ や シー 1、事件の表示 昭和62年 特 許 願 第78,347号2、発明の
名称 ポリテトラフルオロエチレン樹脂製シール部品の製造方
法 名 称   日本バルカー工業株式会社ニーエムビル 
4階 [電話東京(444) 3151] イ 自発補正 6、補正の対象 「発明の詳細な説明」の欄tηす誓Σ 7、補正の内容 1)明細書の第2頁第10行目の 「パツキン、0リング、」とあるのを、「パツキン、ガ
スゲット、0リング、」と訂正する。 2)同書第7頁下から第2行目の 「キャビティ4内に入れる.」とあるのを、「キャビテ
ィ4内に入れる.このとき、金型温度は、特に加熱する
必要はなく、むしろ室温状態の方がよい.」と訂正する
。 3)同書第8頁最終行の 「第2図に示すバルブシート1が得られる.」とあるの
を、 「第2図に示すバルブシート1が得られる。金型から取
り出す温度はバルブシートが少なくとも60℃以下にな
ったときが好ましい.」と訂正する。 4)同書第9頁下から第4行目の 「0リングや■パツキン等の」とあるのを、「0リング
やVパツキンあるいはガスゲット等の」と訂正する。
FIGS. 1(A) to (C) are PTFs showing one embodiment of the present invention.
FIG. 2 is a cross-sectional view of a main part showing the molding process of a seal part made by E, and FIG. 2 is a cross-sectional view of a seal part obtained by the method according to the same example. 1... Valve seat 2... Molding material 3.
...Mold 8...Movable mold 9...Seal surface Patent applicant Nippon Valqua Industries Co., Ltd. Agent Patent attorney Shunichi Suzuki Figure 1 (A) (B)
(C) Figure 2 Procedural Amendment March 31, 1988 El. 6□1,11,11 Okaya Sea 1, Indication of the case 1988 Patent Application No. 78,347 2, Name of invention Method for manufacturing seal parts made of polytetrafluoroethylene resin Name Name Nippon Valqua Industries Co., Ltd. N.M. Building
4th floor [Telephone Tokyo (444) 3151] A. Voluntary amendment 6. Target of amendment ``Detailed description of the invention'' column teta. The phrase "Patsukin, 0 ring," should be corrected to "Patsukin, gas get, 0 ring." 2) In the second line from the bottom of page 7 of the same book, the phrase "Put it into the cavity 4." The condition is better,” he corrected. 3) In the last line of page 8 of the same book, the phrase ``The valve seat 1 shown in Figure 2 is obtained.'' was replaced with ``The valve seat 1 shown in Figure 2 is obtained. It is preferable when the temperature drops to at least 60 degrees Celsius or lower.'' I am corrected. 4) In the fourth line from the bottom of page 9 of the same book, the phrase ``0 ring, ■ packing, etc.'' is corrected to ``0 ring, V packing, gas get, etc.''

Claims (1)

【特許請求の範囲】 1)前工程で加熱焼成したポリテトラフルオロエチレン
樹脂を主成分とする単純形状の成形素材を約200℃以
上に加熱した状態で金型内に入れ、その後、前記金型に
おける移動型を移動して前記成形素材を加圧して塑性流
動変形させ当該成形素材を希望形状に成形することを特
徴とするポリテトラフルオロエチレン樹脂製シール部品
の製造方法。 2)前記成形素材の加熱温度は300℃〜3500Cで
あることを特徴とする特許請求の範囲第1項に記載のポ
リテトラフルオロエチレン樹脂製シール部品の製造方法
[Claims] 1) A simple-shaped molding material mainly composed of polytetrafluoroethylene resin that has been heated and fired in the previous step is heated to about 200° C. or higher and placed in a mold, and then A method for manufacturing a polytetrafluoroethylene resin sealing part, which comprises moving a movable die to apply pressure to the molding material to cause plastic flow deformation and molding the molding material into a desired shape. 2) The method for manufacturing a polytetrafluoroethylene resin seal component according to claim 1, wherein the heating temperature of the molding material is 300°C to 3500°C.
JP7834787A 1987-03-31 1987-03-31 Manufacture of polytetrafluoroethylene sealing part Granted JPS63242610A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7834787A JPS63242610A (en) 1987-03-31 1987-03-31 Manufacture of polytetrafluoroethylene sealing part

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7834787A JPS63242610A (en) 1987-03-31 1987-03-31 Manufacture of polytetrafluoroethylene sealing part

Publications (2)

Publication Number Publication Date
JPS63242610A true JPS63242610A (en) 1988-10-07
JPH0450166B2 JPH0450166B2 (en) 1992-08-13

Family

ID=13659455

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7834787A Granted JPS63242610A (en) 1987-03-31 1987-03-31 Manufacture of polytetrafluoroethylene sealing part

Country Status (1)

Country Link
JP (1) JPS63242610A (en)

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US5971399A (en) * 1993-08-17 1999-10-26 Chiyoda Corporation Dual density sanitary pipe gasket
WO2008069196A1 (en) * 2006-12-04 2008-06-12 Daikin Industries, Ltd. Polytetrafluoroethylene molded body and method for producing the same
JP2012011646A (en) * 2010-06-30 2012-01-19 Nok Corp Method of manufacturing product made from tetrafluoroethylene
JP2014059041A (en) * 2012-09-19 2014-04-03 Amadera Kuatsu Kogyo Kk Process of manufacture of lip ring
WO2014129413A1 (en) * 2013-02-20 2014-08-28 淀川ヒューテック株式会社 Gasket for secondary battery
JP2015500904A (en) * 2012-11-08 2015-01-08 江蘇微賽新材料科技有限公司Microcell TechnologyCo.,Ltd Method for producing polypropylene microporous foam plank
US20160068728A1 (en) * 2013-05-03 2016-03-10 Fmc Kongsberg Subsea As Elastomeric seal
CN110079036A (en) * 2019-04-26 2019-08-02 广东欧特派环保材料科技有限公司 A kind of wear-resisting PTFE/Cu composite material and preparation method of pressure resistance
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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5971399A (en) * 1993-08-17 1999-10-26 Chiyoda Corporation Dual density sanitary pipe gasket
WO2008069196A1 (en) * 2006-12-04 2008-06-12 Daikin Industries, Ltd. Polytetrafluoroethylene molded body and method for producing the same
JPWO2008069196A1 (en) * 2006-12-04 2010-03-18 ダイキン工業株式会社 Polytetrafluoroethylene molded body and method for producing the same
JP4858545B2 (en) * 2006-12-04 2012-01-18 ダイキン工業株式会社 Polytetrafluoroethylene molded body and method for producing the same
JP2012011646A (en) * 2010-06-30 2012-01-19 Nok Corp Method of manufacturing product made from tetrafluoroethylene
JP2014059041A (en) * 2012-09-19 2014-04-03 Amadera Kuatsu Kogyo Kk Process of manufacture of lip ring
JP2015500904A (en) * 2012-11-08 2015-01-08 江蘇微賽新材料科技有限公司Microcell TechnologyCo.,Ltd Method for producing polypropylene microporous foam plank
WO2014129413A1 (en) * 2013-02-20 2014-08-28 淀川ヒューテック株式会社 Gasket for secondary battery
CN104995759A (en) * 2013-02-20 2015-10-21 淀川惠德株式会社 Gasket for secondary battery
JP6005250B2 (en) * 2013-02-20 2016-10-12 淀川ヒューテック株式会社 Manufacturing method of gasket for secondary battery
CN104995759B (en) * 2013-02-20 2019-02-12 淀川惠德株式会社 Secondary cell liner
US20160068728A1 (en) * 2013-05-03 2016-03-10 Fmc Kongsberg Subsea As Elastomeric seal
US10047261B2 (en) * 2013-05-03 2018-08-14 Fmc Kongsberg Subsea As Elastomeric seal
CN110092436A (en) * 2018-01-31 2019-08-06 A.O.史密斯公司 UV reactor with PTFE diffusion
CN110079036A (en) * 2019-04-26 2019-08-02 广东欧特派环保材料科技有限公司 A kind of wear-resisting PTFE/Cu composite material and preparation method of pressure resistance

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