JPS63241063A - Resin composition - Google Patents
Resin compositionInfo
- Publication number
- JPS63241063A JPS63241063A JP33294887A JP33294887A JPS63241063A JP S63241063 A JPS63241063 A JP S63241063A JP 33294887 A JP33294887 A JP 33294887A JP 33294887 A JP33294887 A JP 33294887A JP S63241063 A JPS63241063 A JP S63241063A
- Authority
- JP
- Japan
- Prior art keywords
- group
- acid
- weight
- resin
- crystalline polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title claims description 18
- 229920005989 resin Polymers 0.000 claims abstract description 33
- 239000011347 resin Substances 0.000 claims abstract description 33
- 229920006039 crystalline polyamide Polymers 0.000 claims abstract description 31
- 229920001955 polyphenylene ether Polymers 0.000 claims abstract description 18
- 230000009477 glass transition Effects 0.000 claims abstract description 8
- 229920001577 copolymer Polymers 0.000 abstract description 8
- NXXYKOUNUYWIHA-UHFFFAOYSA-N 2,6-Dimethylphenol Chemical compound CC1=CC=CC(C)=C1O NXXYKOUNUYWIHA-UHFFFAOYSA-N 0.000 abstract description 6
- 229920002292 Nylon 6 Polymers 0.000 abstract description 6
- 150000001408 amides Chemical class 0.000 abstract description 3
- 125000002723 alicyclic group Chemical group 0.000 abstract description 2
- QQOMQLYQAXGHSU-UHFFFAOYSA-N 2,3,6-Trimethylphenol Chemical compound CC1=CC=C(C)C(O)=C1C QQOMQLYQAXGHSU-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 description 20
- 239000000203 mixture Substances 0.000 description 12
- 239000004952 Polyamide Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 229920002647 polyamide Polymers 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 125000001931 aliphatic group Chemical group 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- -1 alkenyl aromatic compound Chemical class 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 230000004927 fusion Effects 0.000 description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 229920006122 polyamide resin Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- 239000003549 soybean oil Substances 0.000 description 4
- 235000012424 soybean oil Nutrition 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical group CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229920006020 amorphous polyamide Polymers 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 235000014593 oils and fats Nutrition 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- YKHVVNDSWHSBPA-BLHCBFLLSA-N (2E,4E)-deca-2,4-dienoic acid Chemical compound CCCCC\C=C\C=C\C(O)=O YKHVVNDSWHSBPA-BLHCBFLLSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- ULNRTPCFRBIMKL-GHVJWSGMSA-N (e)-2-tetracosenoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCC\C=C\C(O)=O ULNRTPCFRBIMKL-GHVJWSGMSA-N 0.000 description 2
- 125000005655 1,3-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([*:2])C1([H])[H] 0.000 description 2
- 125000004955 1,4-cyclohexylene group Chemical group [H]C1([H])C([H])([H])C([H])([*:1])C([H])([H])C([H])([H])C1([H])[*:2] 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- YIYBQIKDCADOSF-UHFFFAOYSA-N alpha-Butylen-alpha-carbonsaeure Natural products CCC=CC(O)=O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- MKUWVMRNQOOSAT-UHFFFAOYSA-N but-3-en-2-ol Chemical compound CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- GWHCXVQVJPWHRF-UHFFFAOYSA-N cis-tetracosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 2
- 150000002148 esters Chemical group 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- YIYBQIKDCADOSF-ONEGZZNKSA-N trans-pent-2-enoic acid Chemical compound CC\C=C\C(O)=O YIYBQIKDCADOSF-ONEGZZNKSA-N 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- BITHHVVYSMSWAG-KTKRTIGZSA-N (11Z)-icos-11-enoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCC(O)=O BITHHVVYSMSWAG-KTKRTIGZSA-N 0.000 description 1
- XSXIVVZCUAHUJO-HZJYTTRNSA-N (11Z,14Z)-icosadienoic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCCCC(O)=O XSXIVVZCUAHUJO-HZJYTTRNSA-N 0.000 description 1
- WBBQTNCISCKUMU-PDBXOOCHSA-N (13Z,16Z,19Z)-docosatrienoic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCCCCCC(O)=O WBBQTNCISCKUMU-PDBXOOCHSA-N 0.000 description 1
- NIONDZDPPYHYKY-SNAWJCMRSA-N (2E)-hexenoic acid Chemical compound CCC\C=C\C(O)=O NIONDZDPPYHYKY-SNAWJCMRSA-N 0.000 description 1
- CWMPPVPFLSZGCY-VOTSOKGWSA-N (2E)-oct-2-enoic acid Chemical compound CCCCC\C=C\C(O)=O CWMPPVPFLSZGCY-VOTSOKGWSA-N 0.000 description 1
- SZQQHKQCCBDXCG-BAHYSTIISA-N (2e,4e,6e)-hexadeca-2,4,6-trienoic acid Chemical compound CCCCCCCCC\C=C\C=C\C=C\C(O)=O SZQQHKQCCBDXCG-BAHYSTIISA-N 0.000 description 1
- ZUUFLXSNVWQOJW-MBIXAETLSA-N (2e,4e,6e)-octadeca-2,4,6-trienoic acid Chemical compound CCCCCCCCCCC\C=C\C=C\C=C\C(O)=O ZUUFLXSNVWQOJW-MBIXAETLSA-N 0.000 description 1
- FPRKGXIOSIUDSE-SYACGTDESA-N (2z,4z,6z,8z)-docosa-2,4,6,8-tetraenoic acid Chemical compound CCCCCCCCCCCCC\C=C/C=C\C=C/C=C\C(O)=O FPRKGXIOSIUDSE-SYACGTDESA-N 0.000 description 1
- LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 description 1
- YWWVWXASSLXJHU-AATRIKPKSA-N (9E)-tetradecenoic acid Chemical compound CCCC\C=C\CCCCCCCC(O)=O YWWVWXASSLXJHU-AATRIKPKSA-N 0.000 description 1
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- 239000001373 (E)-2-methylpent-2-enoic acid Substances 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HVGRZDASOHMCSK-UHFFFAOYSA-N (Z,Z)-13,16-docosadienoic acid Natural products CCCCCC=CCC=CCCCCCCCCCCCC(O)=O HVGRZDASOHMCSK-UHFFFAOYSA-N 0.000 description 1
- KFSQJVOLYQRELE-HWKANZROSA-N (e)-2-ethylbut-2-enoic acid Chemical compound CC\C(=C/C)C(O)=O KFSQJVOLYQRELE-HWKANZROSA-N 0.000 description 1
- XKZKQTCECFWKBN-VOTSOKGWSA-N (e)-dec-4-enoic acid Chemical compound CCCCC\C=C\CCC(O)=O XKZKQTCECFWKBN-VOTSOKGWSA-N 0.000 description 1
- GCORITRBZMICMI-CMDGGOBGSA-N (e)-dodec-4-enoic acid Chemical compound CCCCCCC\C=C\CCC(O)=O GCORITRBZMICMI-CMDGGOBGSA-N 0.000 description 1
- IJBFSOLHRKELLR-BQYQJAHWSA-N (e)-dodec-5-enoic acid Chemical compound CCCCCC\C=C\CCCC(O)=O IJBFSOLHRKELLR-BQYQJAHWSA-N 0.000 description 1
- GJYMQFMQRRNLCY-ONEGZZNKSA-N (e)-pent-3-en-2-ol Chemical compound C\C=C\C(C)O GJYMQFMQRRNLCY-ONEGZZNKSA-N 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- GIEMHYCMBGELGY-UHFFFAOYSA-N 10-undecen-1-ol Chemical compound OCCCCCCCCCC=C GIEMHYCMBGELGY-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- SCFWAOWWAANBPY-UHFFFAOYSA-N 2,2-dimethyl-3-butenoic acid Chemical compound C=CC(C)(C)C(O)=O SCFWAOWWAANBPY-UHFFFAOYSA-N 0.000 description 1
- YKHVVNDSWHSBPA-UHFFFAOYSA-N 2,4-Decadienoic acid Natural products CCCCCC=CC=CC(O)=O YKHVVNDSWHSBPA-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- WCASXYBKJHWFMY-NSCUHMNNSA-N 2-Buten-1-ol Chemical compound C\C=C\CO WCASXYBKJHWFMY-NSCUHMNNSA-N 0.000 description 1
- JJYWRQLLQAKNAD-UHFFFAOYSA-N 2-Methyl-2-pentenoic acid Natural products CCC=C(C)C(O)=O JJYWRQLLQAKNAD-UHFFFAOYSA-N 0.000 description 1
- CWMPPVPFLSZGCY-UHFFFAOYSA-N 2-Octenoic Acid Natural products CCCCCC=CC(O)=O CWMPPVPFLSZGCY-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- JJYWRQLLQAKNAD-PLNGDYQASA-N 2-methyl-2-pentenoic acid Chemical compound CC\C=C(\C)C(O)=O JJYWRQLLQAKNAD-PLNGDYQASA-N 0.000 description 1
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 1
- OKJQSUPURXTNME-UHFFFAOYSA-N 2-prop-2-enylpent-4-enoic acid Chemical compound C=CCC(C(=O)O)CC=C OKJQSUPURXTNME-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- HQSBWLQFLLMPKC-BNFZFUHLSA-N 2E,4E-Dodecadienoic acid Chemical compound CCCCCCC\C=C\C=C\C(O)=O HQSBWLQFLLMPKC-BNFZFUHLSA-N 0.000 description 1
- AGULWIQIYWWFBJ-UHFFFAOYSA-N 3,4-dichlorofuran-2,5-dione Chemical compound ClC1=C(Cl)C(=O)OC1=O AGULWIQIYWWFBJ-UHFFFAOYSA-N 0.000 description 1
- ZSPTYLOMNJNZNG-UHFFFAOYSA-N 3-Buten-1-ol Chemical compound OCCC=C ZSPTYLOMNJNZNG-UHFFFAOYSA-N 0.000 description 1
- RSFQOQOSOMBPEJ-PLNGDYQASA-N 3-methyl-2Z-pentenoic acid Chemical compound CC\C(C)=C/C(O)=O RSFQOQOSOMBPEJ-PLNGDYQASA-N 0.000 description 1
- YYPNJNDODFVZLE-UHFFFAOYSA-N 3-methylbut-2-enoic acid Chemical compound CC(C)=CC(O)=O YYPNJNDODFVZLE-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- FPAQLJHSZVFKES-UHFFFAOYSA-N 5-Eicosenoic acid Natural products CCCCCCCCCCCCCCC=CCCCC(O)=O FPAQLJHSZVFKES-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- YWWVWXASSLXJHU-UHFFFAOYSA-N 9E-tetradecenoic acid Natural products CCCCC=CCCCCCCCC(O)=O YWWVWXASSLXJHU-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 description 1
- 235000021292 Docosatetraenoic acid Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- GCORITRBZMICMI-UHFFFAOYSA-N Linderic acid Natural products CCCCCCCC=CCCC(O)=O GCORITRBZMICMI-UHFFFAOYSA-N 0.000 description 1
- BGRDGMRNKXEXQD-UHFFFAOYSA-N Maleic hydrazide Chemical compound OC1=CC=C(O)N=N1 BGRDGMRNKXEXQD-UHFFFAOYSA-N 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- CUVLOCDGQCUQSI-KHPPLWFESA-N Tsuzuic acid Chemical compound CCCCCCCCC\C=C/CCC(O)=O CUVLOCDGQCUQSI-KHPPLWFESA-N 0.000 description 1
- CUVLOCDGQCUQSI-UHFFFAOYSA-N Tsuzusaeure Natural products CCCCCCCCCC=CCCC(O)=O CUVLOCDGQCUQSI-UHFFFAOYSA-N 0.000 description 1
- 229920006097 Ultramide® Polymers 0.000 description 1
- NIONDZDPPYHYKY-UHFFFAOYSA-N Z-hexenoic acid Natural products CCCC=CC(O)=O NIONDZDPPYHYKY-UHFFFAOYSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- AHANXAKGNAKFSK-PDBXOOCHSA-N all-cis-icosa-11,14,17-trienoic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCCCC(O)=O AHANXAKGNAKFSK-PDBXOOCHSA-N 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- HXBPYFMVGFDZFT-UHFFFAOYSA-N allyl isocyanate Chemical compound C=CCN=C=O HXBPYFMVGFDZFT-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- UIERETOOQGIECD-ARJAWSKDSA-N angelic acid Chemical compound C\C=C(\C)C(O)=O UIERETOOQGIECD-ARJAWSKDSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- ITMIAZBRRZANGB-UHFFFAOYSA-N but-3-ene-1,2-diol Chemical compound OCC(O)C=C ITMIAZBRRZANGB-UHFFFAOYSA-N 0.000 description 1
- PVEOYINWKBTPIZ-UHFFFAOYSA-N but-3-enoic acid Chemical compound OC(=O)CC=C PVEOYINWKBTPIZ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- QDRSJFZQMOOSAF-IHWYPQMZSA-N cis-9-undecenoic acid Chemical compound C\C=C/CCCCCCCC(O)=O QDRSJFZQMOOSAF-IHWYPQMZSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- CVCXSNONTRFSEH-UHFFFAOYSA-N docosa-2,4-dienoic acid Chemical compound CCCCCCCCCCCCCCCCCC=CC=CC(O)=O CVCXSNONTRFSEH-UHFFFAOYSA-N 0.000 description 1
- HQSBWLQFLLMPKC-UHFFFAOYSA-N dodecadienoic acid Natural products CCCCCCCC=CC=CC(O)=O HQSBWLQFLLMPKC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- WCASXYBKJHWFMY-UHFFFAOYSA-N gamma-methylallyl alcohol Natural products CC=CCO WCASXYBKJHWFMY-UHFFFAOYSA-N 0.000 description 1
- ZHYZQXUYZJNEHD-VQHVLOKHSA-N geranic acid Chemical compound CC(C)=CCC\C(C)=C\C(O)=O ZHYZQXUYZJNEHD-VQHVLOKHSA-N 0.000 description 1
- 229930008392 geranic acid Natural products 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000005826 halohydrocarbons Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010460 hemp oil Substances 0.000 description 1
- ZYXQFVIQXIIONQ-UHFFFAOYSA-N hexa-1,3-diene-3,4-diol Chemical compound CCC(O)=C(O)C=C ZYXQFVIQXIIONQ-UHFFFAOYSA-N 0.000 description 1
- IQLUYYHUNSSHIY-UHFFFAOYSA-N icosa-2,4,6,8-tetraenoic acid Chemical compound CCCCCCCCCCCC=CC=CC=CC=CC(O)=O IQLUYYHUNSSHIY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- XDQQQSFYCSYSCP-UHFFFAOYSA-N kaempferol 3-O-beta-D-glucopyranosyl(1-3)-alpha-L-rhamnopyranosyl(1-6)-beta-D-glucopyranoside Natural products CC=CCCC=CCCC(O)=O XDQQQSFYCSYSCP-UHFFFAOYSA-N 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- FSQQTNAZHBEJLS-UPHRSURJSA-N maleamic acid Chemical compound NC(=O)\C=C/C(O)=O FSQQTNAZHBEJLS-UPHRSURJSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- CPHCIYGRSFZNRD-UHFFFAOYSA-N n-methyl-1-(4,5,6,7-tetrahydro-1h-indazol-3-yl)methanamine Chemical compound C1CCCC2=C1NN=C2CNC CPHCIYGRSFZNRD-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- LQAVWYMTUMSFBE-UHFFFAOYSA-N pent-4-en-1-ol Chemical compound OCCCC=C LQAVWYMTUMSFBE-UHFFFAOYSA-N 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-N pent-4-enoic acid Chemical compound OC(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-N 0.000 description 1
- ICMWSAALRSINTC-UHFFFAOYSA-N penta-1,4-dien-3-ol Chemical compound C=CC(O)C=C ICMWSAALRSINTC-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- HMFPLNNQWZGXAH-OCOZRVBESA-N trans-2-hexacosenoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCC\C=C\C(O)=O HMFPLNNQWZGXAH-OCOZRVBESA-N 0.000 description 1
- XKZKQTCECFWKBN-UHFFFAOYSA-N trans-4-decenoic acid Natural products CCCCCC=CCCC(O)=O XKZKQTCECFWKBN-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZHYZQXUYZJNEHD-UHFFFAOYSA-N trans-geranic acid Natural products CC(C)=CCCC(C)=CC(O)=O ZHYZQXUYZJNEHD-UHFFFAOYSA-N 0.000 description 1
- LKOVPWSSZFDYPG-WUKNDPDISA-N trans-octadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCC\C=C\C(O)=O LKOVPWSSZFDYPG-WUKNDPDISA-N 0.000 description 1
- UIUWNILCHFBLEQ-NSCUHMNNSA-N trans-pent-3-enoic acid Chemical compound C\C=C\CC(O)=O UIUWNILCHFBLEQ-NSCUHMNNSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
(I)発明の背景
1、本発明の属する技術分野
本発明は機械的強度とくに板状成形品の落錘衝撃強度と
耐油性、成形加工性、に優れた樹脂組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (I) Background of the Invention 1. Technical field to which the present invention pertains The present invention relates to a resin composition that is excellent in mechanical strength, particularly in falling weight impact strength, oil resistance, and molding processability of plate-shaped molded products. relating to things.
詳しくは、ポリフェニレンエーテル樹脂、結晶性ポリア
ミド樹脂、非結晶性ないし低結晶性のポリアミド樹脂、
および所望により、不飽和基と極性基とを併せ持つ化合
物より成り板状成形品の落錘衝撃強度を中心とする機械
的強度バランス、成形加工性および耐有機溶剤性に優れ
た射出成形用、押し出し成形用および中空成形用に適し
た樹脂組成物に関する。In detail, polyphenylene ether resin, crystalline polyamide resin, amorphous or low crystalline polyamide resin,
And if desired, it is made of a compound having both an unsaturated group and a polar group, and is used for injection molding and extrusion, which has excellent mechanical strength balance, moldability, and organic solvent resistance, centering on falling weight impact strength of plate-shaped molded products. The present invention relates to a resin composition suitable for molding and blow molding.
2、先行技術と問題点
ポリフェニレンエーテル樹脂は優れた機械的性質や耐熱
性を有する有用な樹脂として注目され、例えばスチレン
系樹脂とブレンドされているが、耐溶剤性が著しく悪く
、この点を改良する為に、ポリアミド(特公昭59−4
1663号公報等)、ポリエステル(特公昭51−21
662号公報等)とのブレンドが提案されている。さら
に、これらのブレンド物の衝゛撃強度改良を目的とし、
ポリフェニレンエーテルとポリアミドの組み合わせにカ
ルボン酸、イミド、エポキシ等の基を含む化合物とゴム
質を加えてなる組成物(特開昭59−49753号公報
)等が提・案されている。一方、プラスチックの用途拡
大に伴ない、従来に無かった高いレベルの性能がプラス
チック材料に要求されるようになり、例えば、耐熱性、
耐有機溶剤性に優れた上記のブレンド物に対してとより
高いレベルの衝撃強度が要求されるようになり、これに
応えるべく、本発明者らは、ポリフェニレンエーテル樹
脂、ポリアミド樹脂、同一分子内に不飽和基と極性基を
併せ持つ化合物の組み合わせに、特定範囲のアルケニル
芳香族化合物−共役ジエンブロック共重合体を加えてな
る組成物(特願昭60−265358号)を提案した。2. Prior art and problems Polyphenylene ether resin has attracted attention as a useful resin with excellent mechanical properties and heat resistance, and is blended with styrene resin, for example, but its solvent resistance is extremely poor, and improvements in this respect have been required. In order to
1663, etc.), polyester (Special Publication No. 51-21
662, etc.) has been proposed. Furthermore, with the aim of improving the impact strength of these blends,
A composition (Japanese Unexamined Patent Application Publication No. 59-49753) has been proposed in which a compound containing a group such as carboxylic acid, imide, or epoxy and a rubber substance are added to a combination of polyphenylene ether and polyamide. On the other hand, as the uses of plastics expand, higher levels of performance than ever before are required of plastic materials, such as heat resistance,
A higher level of impact strength is now required for the above-mentioned blends, which have excellent organic solvent resistance, and in order to meet this demand, the present inventors have proposed a composition (Japanese Patent Application No. 60-265358), which is made by adding a specific range of alkenyl aromatic compound-conjugated diene block copolymers to a combination of compounds having both an unsaturated group and a polar group.
しかしながら、工業部品分野では、大型の平板状部品用
途において、重要な性能である面衝撃強度が今−少年満
足であるケースがあり、この面での改善の余地があった
。However, in the field of industrial parts, there are cases in which surface impact strength, which is an important performance for large flat plate parts, is only slightly satisfactory, and there is room for improvement in this aspect.
(n)発明の概要
本発明は、上記の問題点に解決を与え、工業部品分野で
要求される特に高いレベルの機械的物性バランスとくに
平板状部分の落錘衝撃強度を示し、耐有機溶剤性、成形
加工性の良好な樹脂組成物を与えるものである。(n) Summary of the Invention The present invention provides a solution to the above-mentioned problems, exhibits a particularly high level of mechanical property balance required in the field of industrial parts, particularly the falling weight impact strength of the flat plate part, and exhibits organic solvent resistance. , which provides a resin composition with good moldability.
このために、種々の配合成分について検討を行なった結
果、ポリフェニレンエーテル樹脂、ポリアミド樹脂、お
よび所望により同一分子内に不飽和基と極性基を有する
化合物よりなる組み合わせにおいて、主となる結晶性ポ
リアミド樹脂成分の一部を非結晶性ないし低結晶性のポ
リアミド樹脂成分と置き換えることにより、結晶性ポリ
アミド成分と非結晶性ないし低結晶のポリアミド樹脂成
分とを共用することによって、非常に高いレベルの平板
状成形品の落錘衝撃強度が得られることを見出し、本発
明を完成した。したがって本発明の要旨とするところは
、
(a) 成分:ポリフェニレンエーテル樹脂20〜7
0重量%
(b) 成分:結晶性ポリアミド樹脂29〜79重量
%
(C)成分ニガラス転移温度が70〜210℃の非結晶
性ないし低結晶性の環状
炭化水素系共重合ポリアミド
1〜55重量%
からなる樹脂組成物にある。For this purpose, as a result of examining various compounding ingredients, we found that in a combination consisting of polyphenylene ether resin, polyamide resin, and optionally a compound having an unsaturated group and a polar group in the same molecule, we found that the main crystalline polyamide resin By replacing some of the components with non-crystalline or low-crystalline polyamide resin components, by using both the crystalline polyamide component and the non-crystalline or low-crystalline polyamide resin component, a very high level of flat plate shape can be achieved. The present invention was completed by discovering that the falling weight impact strength of a molded product can be obtained. Therefore, the gist of the present invention is as follows: (a) Component: polyphenylene ether resin 20-7
0% by weight (B) Component: 29-79% by weight of crystalline polyamide resin (C) Component: 1-55% by weight of amorphous or low-crystalline cyclic hydrocarbon copolyamide with a glass transition temperature of 70-210°C The resin composition consists of:
本発明により、高いレベルの板状成形品の落錘衝撃強度
を有し、他の機械的物性レベルも良好であり、平板状部
分を有する工業部品材料として好適なポリフェニレンエ
ーテル−ポリアミド系樹脂組成物が得られる。According to the present invention, a polyphenylene ether-polyamide resin composition has a high level of falling weight impact strength for plate-shaped molded products, has good other mechanical properties, and is suitable as a material for industrial parts having a plate-shaped part. is obtained.
(III)発明の詳細な説明
1、構成成分
(1) ポリフェニレンエーテル樹脂tai本発明で使
用されるポリフェニレンエーテルは、一般式
で表わされる循環構造単位を有し、式中一つの単位のエ
ーテル酸素原子は次の隣接単位のベンゼン核に接続して
おり、nは少くとも50であり、Qはそれぞれ独立に水
素、ハロゲン、三級α−炭素原子を含有しない炭化水素
基、ハロゲン原子とフェニル核との間に少くとも2個の
炭素原子を有するハロ炭化水素基、炭化水素オシキ基お
よびハロゲン原子とフェニル核との間に少くとも2個の
炭素原子を有するへロ炭化水素オキシ基からなる群より
選択した一価置換基を示し、それぞれのQは互いに同じ
であっても異なっていてもよい。(III) Detailed Description of the Invention 1, Constituent Component (1) Polyphenylene ether resin The polyphenylene ether used in the present invention has a cyclic structural unit represented by the general formula, in which one unit of ether oxygen atom is connected to the benzene nucleus of the next adjacent unit, n is at least 50, and Q is each independently hydrogen, halogen, a hydrocarbon group not containing a tertiary α-carbon atom, a halogen atom and a phenyl nucleus. From the group consisting of halohydrocarbon groups having at least 2 carbon atoms between them, hydrocarbonoxy groups and herohydrocarbonoxy groups having at least 2 carbon atoms between the halogen atom and the phenyl nucleus Indicates selected monovalent substituents, each Q may be the same or different from each other.
また2、6−シメチルフエノールと2.3.6−ドリメ
チルフエノールの共重合体、2,6−シメチルフエノー
ルと2.3,5.6−チトラメチルフエノールの共重合
体、2,6−ジニチルフエノールと2.3.6−ドリメ
チルフエノールの共重合体などの共重合体をも挙げるこ
とができる。Also, a copolymer of 2,6-dimethylphenol and 2,3.6-dimethylphenol, a copolymer of 2,6-dimethylphenol and 2,3,5,6-titramethylphenol, 2,6 -Copolymers such as a copolymer of dinitylphenol and 2,3,6-drimethylphenol may also be mentioned.
更に、本発明で使用されるポリフェニレンエーテルは、
前記一般式で定義されたポリフェニレンエーテルにスチ
レン系モノマー(例えば、スチレン、p−メチルスチレ
ン、α−メチルスチレンなど)をグラフトしたもの等変
性されたポリフェニレンエーテルをも包含する。Furthermore, the polyphenylene ether used in the present invention is
It also includes polyphenylene ethers modified by grafting styrenic monomers (eg, styrene, p-methylstyrene, α-methylstyrene, etc.) onto the polyphenylene ether defined by the above general formula.
上記に相当するポリフェニレンエーテルの製造方法は公
知であり、例えば米国特許第3306874号、第33
06875号、第3257357号および第32573
58号各明細書および日本特許特公昭52−17880
および特開昭50−51197号明細書に記載されてい
る。Methods for producing polyphenylene ethers corresponding to the above are known, for example, U.S. Pat.
No. 06875, No. 3257357 and No. 32573
No. 58 specifications and Japanese Patent Publication No. 52-17880
and JP-A-50-51197.
本発明の目的のために好ましいポリフェニレンエーテル
の群は、エーテル酸素原子に対する2つのオルソ位にア
ルキル置換基を有するものおよび2.6−ジアルキルフ
ェノールと2.3.6− )リアルキルフェノールの共
重合体である。A group of polyphenylene ethers preferred for the purposes of the present invention are those with alkyl substituents in the two positions ortho to the ether oxygen atom and copolymers of 2,6-dialkylphenols and 2,3,6-)realkylphenols. It is.
(2)結晶性ポリアミド樹脂(b)
本発明において使用される結晶性ポリアミド樹 H
熱溶融できるものであり、且つ、測定可能な融解熱を有
する明確な融点を示すものである。融点及び融解熱は示
差走査熱量測定装置を用いて測定することができる。例
としてはPERKIN −ELMER社製DSC−11
がある。この装置を用いて、例えば1分間当たり10℃
の昇温速度で融解熱を測定することができる。試料を予
測される融点以上の温度に加熱し、次に試料を1分間あ
たり10℃の速度で降温し、30℃まで冷却し、そのま
ま約1分間放置したのち1分間あたり10℃の速度で加
熱することにより測定することができる。融解熱は最初
以後の何れかの昇温と降温のサイクルにおいて測定して
も実験誤差範囲内で一定値となるものを採用する。本発
明における結晶性ポリアミドとは、上記方法によりlC
a1/gを超える融解熱を有するものと定義する。この
方法によると、市販のナイロン−6の融解熱は約16
Cal/ gである。(2) Crystalline polyamide resin (b) The crystalline polyamide resin used in the present invention H can be thermally melted and exhibits a clear melting point with a measurable heat of fusion. Melting point and heat of fusion can be measured using a differential scanning calorimeter. For example, PERKIN-ELMER DSC-11
There is. Using this device, for example, 10°C per minute.
The heat of fusion can be measured at a heating rate of . The sample is heated to a temperature above the expected melting point, then the sample is cooled at a rate of 10°C per minute, cooled to 30°C, left for about 1 minute, and then heated at a rate of 10°C per minute. It can be measured by The heat of fusion is determined to be a constant value within the experimental error range even when measured in any cycle of temperature increase and decrease after the first. The crystalline polyamide in the present invention refers to the crystalline polyamide obtained by the above method.
It is defined as having a heat of fusion exceeding a1/g. According to this method, the heat of fusion of commercially available nylon-6 is approximately 16
Cal/g.
10、ナイロン−6,12およびナイロン−6、T(ヘ
キサメチレンジアミンとテレフタル酸よりなるポリアミ
ド)、ナイロン−MXD、6(メタキシリレンジアミン
とアジピン酸よりなるポリアミド)、ナイロン−6とナ
イロン−6,6の混合物、ヘキサメチレンジアミン、ア
ジピン酸およびカプロラクタムの共重合物等が挙げられ
、これらのうちでも、より好ましくは脂肪族ポリアミド
重合体であり、更に好ましくはナイロン−6,6および
ナイロン−6であり、これらは市販のものが使用できる
0例としては、西独BASF社等よりウルトラミツド等
の商品名で販売されているものがある。10, Nylon-6,12 and Nylon-6, T (polyamide made of hexamethylene diamine and terephthalic acid), Nylon-MXD, 6 (polyamide made of metaxylylene diamine and adipic acid), Nylon-6 and Nylon-6 . An example of a commercially available product that can be used is one sold under the trade name Ultramid by West German BASF and others.
(3)非結晶性ないし低結晶性のポリアミド樹脂(C)
本発明で使用する非結晶性ないし低結晶性のポリアミド
樹脂は、ガラス転移温度が70℃以上210℃以下、よ
り好ましくは80℃以上170℃以下、さらに好ましく
は90℃以上170℃以下、とりわけ好ましくは90℃
以上150℃以下の範囲にあるものである。非結晶性お
よび低結晶性とは一般に明確な融点や測定可能な融解熱
を有しないことを示すが、本発明においては、溶融状態
から徐々に冷却するか、固体状態で十分な熱処理により
多少の結晶を生じるものを含む。ガラス転移温度、融点
および融解熱は「結晶性ポリアミド樹脂(b)」の項に
示した方法により測定することができる。また、本発明
における非結晶性ないしは低結晶性ポリアミド樹脂とは
、上記の方法によりlCa1/g以下の融解熱を有する
ものと定義する。またメカニカルスペクトロメーター等
により測定した粘弾性の温度変化挙動から、融点やガラ
ス転移、温度を知ることも可能である。これらの非結晶
性ないし低結晶性の炭化水素系ポリアミド樹脂は、アミ
ド結合構成単位が、主に、鎖状構造または環式構造を持
つ下記のI〜■の構造式から選ばれるものより成り、上
記のガラス転移温度の範囲と非結晶性ないしは低結晶性
を満足するように構成される。(3) Amorphous or low crystalline polyamide resin (C)
The amorphous or low crystalline polyamide resin used in the present invention has a glass transition temperature of 70°C or more and 210°C or less, more preferably 80°C or more and 170°C or less, still more preferably 90°C or more and 170°C or less, particularly preferably is 90℃
The temperature is in the range of 150°C or higher. Amorphous and low crystallinity generally mean that they do not have a clear melting point or measurable heat of fusion; Including those that produce crystals. The glass transition temperature, melting point and heat of fusion can be measured by the method shown in the section of "Crystalline polyamide resin (b)". Furthermore, the amorphous or low-crystalline polyamide resin in the present invention is defined as having a heat of fusion of lCa1/g or less by the above method. It is also possible to know the melting point, glass transition, and temperature from the temperature change behavior of viscoelasticity measured with a mechanical spectrometer or the like. These non-crystalline or low-crystalline hydrocarbon polyamide resins mainly consist of amide bond constituent units selected from the following structural formulas I to ■ having a chain structure or a cyclic structure, It is constructed to satisfy the above glass transition temperature range and amorphous or low crystallinity.
なお、これらの非結晶性ないし低結晶性のポリアミド樹
脂のうち、分子鎖の繰り返し単位の中に環状構造を含む
ポリアミド樹脂が好ましい。Note that among these non-crystalline or low-crystalline polyamide resins, polyamide resins containing a cyclic structure in the repeating unit of the molecular chain are preferred.
1 −HN−W−NH−
(Wは炭素数2〜12の直鎖状または分枝状脂肪族基よ
り選ばれる少なくとも一種)
I[−1(N−X−Nli−
(Xはメタキシリレン基または炭素数5〜22の範囲に
あり、脂環式炭化水素骨格を少なくとも1個含む脂肪族
基より選ばれる少なくとも一種)
■
(Rはそれぞれ独立に水素または炭素数1〜6の範囲の
脂肪族基より選ばれる少なくとも一種であり、それぞれ
のRは同じであっても異なっていてもよい)
■
(Rはそれぞれ独立に水素または炭素数1〜6の範囲の
脂肪族基より選ばれる基でありそれぞれのRは同じであ
っても異なっていてもよい)
(Yは炭素数4〜22の範囲の脂肪族基、脂環式炭化水
素基を含む脂肪族基より選ばれる少なくとも一種)
Vl −C−Z−Nl+−
(Zは炭素数4〜14の範囲の脂肪族基、芳香族基より
選ばれる少なくとも一種)
構成単位IにおけるWの具体例としては、ブチレン基、
ヘキシレン基、オクチレン基、デカニレン基、2,2.
4−1−リメチルヘキシレン基、2.4.4−トリメチ
ルヘキシレン基、3−メチルヘキシレン基、ペンチレン
基等が挙げられ、より好ましくはブチレン基、ヘキシレ
ン基、2.4.4− )リメチルヘキシレン基、2.4
.4− )リメチルへキシレン基である。1 -HN-W-NH- (W is at least one type selected from linear or branched aliphatic groups having 2 to 12 carbon atoms) I[-1(N-X-Nli- (X is metaxylylene group or (At least one type of aliphatic group having 5 to 22 carbon atoms and containing at least one alicyclic hydrocarbon skeleton) (Each R is independently hydrogen or an aliphatic group having 1 to 6 carbon atoms) (Each R is a group independently selected from hydrogen or an aliphatic group having 1 to 6 carbon atoms, and each R is a group independently selected from hydrogen or an aliphatic group having 1 to 6 carbon atoms.) R may be the same or different) (Y is at least one type selected from aliphatic groups having 4 to 22 carbon atoms and aliphatic groups including alicyclic hydrocarbon groups) Vl -C- Z-Nl+- (Z is at least one selected from aliphatic groups and aromatic groups having 4 to 14 carbon atoms) Specific examples of W in structural unit I include butylene group,
Hexylene group, octylene group, decanylene group, 2,2.
Examples include 4-1-limethylhexylene group, 2.4.4-trimethylhexylene group, 3-methylhexylene group, pentylene group, and more preferably butylene group, hexylene group, 2.4.4- ) Limethylhexylene group, 2.4
.. 4-) Limethylhexylene group.
構成単位■におけるXの具体例としては、メタキシリレ
ン基(Xa ) 、4.4’−メチレンジシクロヘキサ
ン−1,1′−ジイル基(Xb )、2,2′−ジメチ
ル−4,4′−メチレンジシクロヘキサン−1,1’−
ジイル基(Xc ) 、1.5.5−トリメチル−1,
3−シクロヘキシレン−1−メチレン基(Xd ) 、
シクロヘキシレン−1,4−ジメチレン基(Xe)、4
−チメレンシクロヘキシレン基(Xf)、3−メチレン
シクロヘキシレン基(Xg)、シクロへキシレン−1,
3−ジメチレン基(Xh ’)、等が挙げられる。各X
の具体例について、構造式を以下に示す。Specific examples of Dicyclohexane-1,1'-
Diyl group (Xc), 1.5.5-trimethyl-1,
3-cyclohexylene-1-methylene group (Xd),
Cyclohexylene-1,4-dimethylene group (Xe), 4
-Thimelenecyclohexylene group (Xf), 3-methylenecyclohexylene group (Xg), cyclohexylene-1,
3-dimethylene group (Xh'), and the like. each X
The structural formula of a specific example is shown below.
(X a) (X b)(Xc)
(Xd)C)13 C11□
=
(Xe) (Xf)(X g)
(X h)構成単位■および■に
おけるRの具体例としては、水素原子、メチル基、ター
シャリ−ブチル基、イソプロピル基、エチル基が挙げら
れ、より好ましくは水素原子、メチル基、さらに好まし
くは水素原子である。(X a) (X b) (Xc)
(Xd)C)13 C11□
= (Xe) (Xf) (X g)
(Xh) Specific examples of R in the structural units It is an atom.
構成単位■におけるYの具体例としては、エチレン基、
プロピレン基、ブチレン基、ヘキシレン基、オクチレン
基、デカニレン基、1,4−シクロヘキシレン基、1,
3−シクロヘキシレン基、構成単位HにおけるWl (
Xa)、 (Xb)、 (Xc)、 (Xd)。Specific examples of Y in the structural unit ■ include ethylene group,
Propylene group, butylene group, hexylene group, octylene group, decanylene group, 1,4-cyclohexylene group, 1,
3-cyclohexylene group, Wl in structural unit H (
Xa), (Xb), (Xc), (Xd).
(Xe)、 (Xf)、 (Xg)、 (Xh)
等が挙げられ、より好ましくはエチレン基、プロピレン
基、ブチレン基、オクチレン基、1.4−シクロヘキシ
レン基、1.3−シクロヘキシレン基であり、より好ま
しくはエチレン基、プロピレン基、ブチレン基である。(Xe), (Xf), (Xg), (Xh)
etc., more preferably an ethylene group, a propylene group, a butylene group, an octylene group, a 1,4-cyclohexylene group, a 1,3-cyclohexylene group, and more preferably an ethylene group, a propylene group, a butylene group. be.
構成単位■におけるZの具体例としては、ブチレン基、
ペンチレン基、ヘキシレン基、デカジエン酸、ウンデカ
ニレン基、パラフェニレン基等が挙げられ、より好まし
くはペンチレン基、ヘキシレン基、ウンデカニレン基で
あり、さらに好ましくはペンチレン基である。Specific examples of Z in the structural unit ■ include butylene group,
Examples include pentylene group, hexylene group, decadienoic acid, undecanylene group, paraphenylene group, etc., with pentylene group, hexylene group, and undecanylene group being more preferred, and pentylene group being even more preferred.
なお、上記構成単位I〜■においては、I、 I[Iお
よび■を主とするものがより好ましい。In addition, in the above-mentioned structural units I to (2), those mainly containing I, I[I and (2) are more preferable.
かかるポリアミド樹脂(C)の相対粘度(98%濃硫酸
中、濃度1g/dl、測定温度25℃)は1.0〜5.
0dl/g、より好ましくは1.4〜3.5dl/g。The relative viscosity of the polyamide resin (C) (in 98% concentrated sulfuric acid, concentration 1 g/dl, measurement temperature 25°C) is 1.0 to 5.
0 dl/g, more preferably 1.4-3.5 dl/g.
さらに好ましくは1.6〜3.0a/gの範囲である。More preferably, it is in the range of 1.6 to 3.0 a/g.
これらの非結晶性ないし低結晶性のポリアミド樹脂の製
法は公知であり、例えば、特開昭58−38751号公
報、特開昭60−217237号公報、特開昭60−2
19227号公報等に示されているものが適用可能であ
る。The manufacturing method of these non-crystalline or low crystalline polyamide resins is known, for example, JP-A-58-38751, JP-A-60-217237, JP-A-60-2.
Those shown in Japanese Patent No. 19227 and the like are applicable.
なお、本発明においては、樹脂組成物の色相が問題とさ
れない場合には、所望により、同一分子内に不飽和基と
極性基とを併せ持つ化合物(d)を組成物に配合するこ
とができる。In the present invention, if the hue of the resin composition is not a problem, a compound (d) having both an unsaturated group and a polar group in the same molecule can be blended into the composition, if desired.
化合物Telとして不飽和基と極性基を併せ持つ化合物
とは、不飽和基すなわち炭素−炭素二重結合または炭素
−炭素三重結合と、極性基すなわちボ化学反応性を示す
官能基を同一分子内に併せ持つ化合物である。かかる官
能基としては、カルボン酸基、カルボン酸より誘導され
る基すなわちカルボキシル基の水素原子あるいは水酸基
が置換した各種の塩やエステル、酸アミド、酸無水物、
イミド、酸アジド、酸ハロゲン化物、あるいは、オキサ
ゾリン、ニトリル等の官能基、エポキシ基、アミノ基、
水酸基、又は、イソシアン酸エステル基等が挙げられる
。不飽和基と極性基を併せ持つ化合物としては、不飽和
カルボン酸、不飽和カルボン酸誘導体、不飽和エポキシ
化合物、不飽和アルコール、不飽和アミン、不飽和イソ
シアン酸エステルが主に用いられる。A compound that has both an unsaturated group and a polar group as a compound Tel is a compound that has an unsaturated group, that is, a carbon-carbon double bond or a carbon-carbon triple bond, and a polar group, that is, a functional group that exhibits chemical reactivity in the same molecule. It is a compound. Such functional groups include carboxylic acid groups, groups derived from carboxylic acids, that is, various salts and esters substituted with hydrogen atoms or hydroxyl groups of carboxyl groups, acid amides, acid anhydrides,
imide, acid azide, acid halide, or functional groups such as oxazoline and nitrile, epoxy group, amino group,
Examples include a hydroxyl group or an isocyanate ester group. As compounds having both an unsaturated group and a polar group, unsaturated carboxylic acids, unsaturated carboxylic acid derivatives, unsaturated epoxy compounds, unsaturated alcohols, unsaturated amines, and unsaturated isocyanate esters are mainly used.
具体的には、無水マレイン酸、マレイン酸、フマール酸
、マレイミド、マレイン酸ヒドラジド、無水マレイン酸
とジアミンとの反応物たとえばO
(但し、Rは脂肪族、芳香族基を示す。)などで示され
る構造を有するもの、無水メチルナジック酸、無水ジク
ロロマレイン酸、マレイン酸アミド、イタコン酸、無水
イタコン酸、大豆油、キリ油、ヒマシ油、アマニ油、麻
実油、綿実油、ゴマ油、菜種油、落花生油、椿油、オリ
ーブ油、ヤシ油、イワシ油などの天然油脂類、エポキシ
化大豆油などのエポキシ化天然油脂類、アクリル酸、ブ
テン酸、クロトン酸、ビニル酢酸、メタクリル酸、ペン
テン酸、アンゲリカ酸、チグリン酸、2−ペンテン酸、
3−ペンテン酸、α−エチルアクリル酸、β−メチルク
ロトン酸、4−ペンテン酸、2−ヘキセン酸、2−メチ
ル−2−ペンテン酸、3−メチル−2−ペンテン酸、α
−エチルクロトン酸、2.2−ジメチル−3−ブテン酸
、2−ヘプテン酸、2−オクテン酸、4−デセン酸、9
−ウンデセン酸、10−ウンデセン酸、4−ドデセン酸
、5−ドデセン酸、4−テトラデセン酸、9−テトラデ
セン酸、9−へキサデセン酸、2−オクタデセン酸、9
−オクタデセン酸、アイコセン酸、トコセン酸、エルカ
酸、テトラコセン酸、マイコリペンM、2.4−ペンタ
ジェン酸、2.4−へキサジエン酸、ジアリル酢酸、ゲ
ラニウム酸、2,4−デカジエン酸、2,4−ドデカジ
エン酸、9.12−へキサデカジエン酸、9.12−オ
クタデカジエン酸、ヘキサデカトリエン酸、リノール酸
、リルン酸、オクタデカトリエン酸、アイコサジエン酸
、アイコサトリエン酸、アイコサテトラエン酸、リシノ
ール酸、エレオステアリン酸、オレイン酸、アイコサペ
ンクエン酸、エルシン酸、ドコサジエン酸、ドコサトリ
エン酸、ドコサテトラエン酸、ドコサペンクエン酸、テ
トラコセン酸、ヘキシレン基、ヘキサコシエン酸、オフ
タコセン酸、トラアコンテン酸などの不飽和カルボン酸
、あるいはこれら不飽和カルボン酸のエステル、酸アミ
ド、無水物、あるいはアリルアルコール、クロチルアル
コール、メチルビニルカルビノール、アリルカルビノー
ル、メチルプロペニルカルビノール、4−ペンテン−1
−オール、10−ウンデセン−1−オール、プロパルギ
ルアルコール、1.4−ペンタジェン−3−オール、1
.4−へキサジエン−3−オール、3.5−へキサジエ
ン−2−オール、2.4−へキサジエン−1−オール、
一般式〇−11g−5OH、C−Hz−1OH。Specifically, maleic anhydride, maleic acid, fumaric acid, maleimide, maleic acid hydrazide, a reaction product of maleic anhydride and diamine, such as O (where R represents an aliphatic or aromatic group), etc. Methylnadic anhydride, dichloromaleic anhydride, maleic acid amide, itaconic acid, itaconic anhydride, soybean oil, tung oil, castor oil, linseed oil, hempseed oil, cottonseed oil, sesame oil, rapeseed oil, peanut oil , natural oils and fats such as camellia oil, olive oil, coconut oil, and sardine oil, epoxidized natural oils and fats such as epoxidized soybean oil, acrylic acid, butenoic acid, crotonic acid, vinyl acetic acid, methacrylic acid, pentenoic acid, angelic acid, tigrin acid, 2-pentenoic acid,
3-pentenoic acid, α-ethyl acrylic acid, β-methylcrotonic acid, 4-pentenoic acid, 2-hexenoic acid, 2-methyl-2-pentenoic acid, 3-methyl-2-pentenoic acid, α
-Ethylcrotonic acid, 2,2-dimethyl-3-butenoic acid, 2-heptenoic acid, 2-octenoic acid, 4-decenoic acid, 9
-undecenoic acid, 10-undecenoic acid, 4-dodecenoic acid, 5-dodecenoic acid, 4-tetradecenoic acid, 9-tetradecenoic acid, 9-hexadenoic acid, 2-octadecenoic acid, 9
-Octadenoic acid, icosenoic acid, tocosenoic acid, erucic acid, tetracosenoic acid, mycolipen M, 2.4-pentadienoic acid, 2.4-hexadienoic acid, diallylacetic acid, geranic acid, 2,4-decadienoic acid, 2,4 -Dodecadienoic acid, 9.12-hexadecadienoic acid, 9.12-octadecadienoic acid, hexadecatrienoic acid, linoleic acid, lylunic acid, octadecatrienoic acid, icosadienoic acid, icosatrienoic acid, icosatetraenoic acid , ricinoleic acid, eleostearic acid, oleic acid, icosapene citric acid, erucic acid, docosadienoic acid, docosatrienoic acid, docosatetraenoic acid, docosapene citric acid, tetracosenoic acid, hexylene group, hexacosenoic acid, oftacosenoic acid, traacontene Unsaturated carboxylic acids such as acids, esters, acid amides, anhydrides of these unsaturated carboxylic acids, allyl alcohol, crotyl alcohol, methylvinylcarbinol, allylcarbinol, methylpropenylcarbinol, 4-pentene-1
-ol, 10-undecen-1-ol, propargyl alcohol, 1,4-pentadien-3-ol, 1
.. 4-hexadien-3-ol, 3.5-hexadien-2-ol, 2.4-hexadien-1-ol,
General formula 〇-11g-5OH, C-Hz-1OH.
C,H□、−WOO(但し、nは正の整数)で示される
アルコール、3−ブテン−1,2−ジオール、2.5−
ジメチル−3−ヘキセン−2,5−ジオール、1.5−
へキサジエン−3,4−ジオール、2.6−オクタノニ
ン−4,5−ジオールなどの不飽和アルコール、あるい
はこのような不飽和アルコールの011基が、NHz基
に置き換った不飽和アミン、あるいはブタジェン、イソ
プレンなどの低重合(たとえば平均分子量が500〜1
0000 ぐらいのもの)あるいは高分子量体(たとえ
ば平均分子量が10000以上のもの)に無水マレイン
酸、フェノール類を付加したもの、あるいはアミノ基、
カルボン酸基、水酸基、エポキシ基などを導入したもの
、イソシアン酸アリルなどが挙げられる。C, H□, -WOO (where n is a positive integer) alcohol, 3-butene-1,2-diol, 2.5-
Dimethyl-3-hexene-2,5-diol, 1,5-
Unsaturated alcohols such as hexadiene-3,4-diol and 2,6-octanonine-4,5-diol, or unsaturated amines in which the 011 group of such unsaturated alcohols is replaced with an NHz group, or Low polymerization of butadiene, isoprene, etc. (for example, average molecular weight of 500 to 1
0,000) or polymers (for example, those with an average molecular weight of 10,000 or more) to which maleic anhydride or phenols are added, or amino groups,
Examples include those into which a carboxylic acid group, hydroxyl group, epoxy group, etc. have been introduced, and allyl isocyanate.
本発明における同一分子内に不飽和基と極性基を併せ持
つ化合物の定義には、不飽和基を2個以上、極性基を2
個以上(同種又は異種)含んだ化合物も含まれることは
、いうまでもなく、又、2種以上の特定化合物を使うこ
とも可能である。これらのうちでより好ましくは無水マ
レイン酸、マレイン酸、無水イタコン酸、イタコン酸等
の不飽和ジカルボン酸及びその無水物、オレイルアルコ
ール等の不飽和アルコール、エポキシ化ダイズ油等のエ
ポキシ化天然油脂類であり、さらに好ましくは無水マレ
イン酸、マレイン酸、オレイルアルコール、エポキシ化
大豆油、エポキシ化アマニ油であり、とりわけ好ましく
は無水マレイン酸である。In the present invention, the definition of a compound having both an unsaturated group and a polar group in the same molecule includes two or more unsaturated groups and two or more polar groups.
Needless to say, compounds containing more than one specific compound (same or different) are also included, and it is also possible to use two or more specific compounds. Among these, more preferred are unsaturated dicarboxylic acids and their anhydrides such as maleic anhydride, maleic acid, itaconic anhydride, and itaconic acid, unsaturated alcohols such as oleyl alcohol, and epoxidized natural oils and fats such as epoxidized soybean oil. More preferred are maleic anhydride, maleic acid, oleyl alcohol, epoxidized soybean oil, and epoxidized linseed oil, and particularly preferred is maleic anhydride.
本発明において、かかる同一分子内に不飽和基と極性基
を併せ持つ化合物(d)を配合したときは、衝撃強度が
よりいっそう改善された樹脂組成物が得られるが、一方
、成形品の色調に難点を生じ易い傾向となるため、色調
が問題とならない場合には(d)成分の使用も可能であ
る。おな、かかる(dl成分を本発明の構成成分と共に
用いたときは、一層衝撃強度を向上させることが可能で
ある。In the present invention, when the compound (d) having both an unsaturated group and a polar group is blended in the same molecule, a resin composition with further improved impact strength can be obtained, but on the other hand, the color tone of the molded product may be Since this tends to cause problems, component (d) can also be used if color tone is not a problem. In addition, when such (dl component) is used together with the constituent components of the present invention, it is possible to further improve the impact strength.
2、構成成分の組成比
以上のような(a)〜(C)成分の配合割合は、(a)
+ (b)+(C)合計重量中でそれぞれ、
(a)成分:20〜70重量%、好ましくは30〜60
重景%、重量に好ましくは40〜60重量%。2. The composition ratio of components (a) to (C) as above is (a)
+ Component (a): 20 to 70% by weight, preferably 30 to 60% in the total weight of (b) + (C)
weight%, preferably 40 to 60% by weight.
(b)成分:29〜79重量%、好ましくは34〜69
重量%、とりわけ好ましくは39〜59重量%。Component (b): 29-79% by weight, preferably 34-69%
% by weight, particularly preferably 39-59% by weight.
(C)成分:1〜55重量%、好ましくは2〜39重景
%重量に好ましくは2〜32FK量%であり、また、(
C)成分は(bl + (C)成分の合計量中で70重
量%以下が好ましく、とりわけ60重量%以下とするの
がよい。Component (C): 1 to 55% by weight, preferably 2 to 39% by weight, preferably 2 to 32% by weight of FK, and (
The amount of component C) is preferably 70% by weight or less, particularly preferably 60% by weight or less, based on the total amount of component (bl + (C)).
なお、上記(a)、 (b)及び(C)成分と共に前記
(d)成分の化合物を配合する場合には、(31,(b
)及び(C)成分の合計量を100重量部とし、これに
外数として加える(d)成分の量を、0.01〜10重
量部とするとよく、好ましくは0.05〜5重量部、と
りわけ好ましくは0.1〜2重量部、さらに好ましくは
0.2〜1.5重量部、さらに好ましくは0.2〜1重
量とするのがよい。In addition, when blending the compound of the above (d) component with the above (a), (b) and (C) components, (31, (b)
The total amount of components ) and (C) is 100 parts by weight, and the amount of component (d) added as an extra number is preferably 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight, The amount is particularly preferably 0.1 to 2 parts by weight, more preferably 0.2 to 1.5 parts by weight, and even more preferably 0.2 to 1 part by weight.
上記の組成について、(a)成分が20重量%未満では
耐熱剛性が不足し、70重量%超過では耐有機溶剤性が
不満足となり好ましくない。Regarding the above composition, if component (a) is less than 20% by weight, the heat resistance rigidity will be insufficient, and if it exceeds 70% by weight, the organic solvent resistance will be unsatisfactory, which is not preferred.
(b)成分力siga°−■−■璽鴻璽■−■−箇■曹
璽lIl■−■冒閣■79重量%超過では耐熱剛性が不
満足であり好ましくない。(b) If the component strength exceeds 79% by weight, the heat resistance stiffness is unsatisfactory, which is undesirable.
本発明の効果すなわち、高いレベルの板状成形品の落錘
衝撃強度を備えた樹脂組成物を得る目的にたいして、(
C)成分の配合量は1重量%以上55重世%以下、およ
び、(b)成分と(c)成分の合計重量の70重景気以
下で充分である。(C)成分が1重量%未満では衝撃強
度レベルが不満足であり好ましくない。また(C)成分
力< (bl + (C)成分合計量中に占める割合が
70重量%を超える範囲では板状成形品の落錘衝撃強度
のレベルが不充分となる傾向となる。Effects of the present invention, that is, for the purpose of obtaining a resin composition having a high level of falling weight impact strength for plate-shaped molded products, (
It is sufficient that the blending amount of component C) is 1% by weight or more and 55% by weight or less, and 70% by weight or less for the total weight of components (b) and (c). If component (C) is less than 1% by weight, the impact strength level will be unsatisfactory, which is not preferable. In addition, if the ratio of component (C) to the total amount of component (C) exceeds 70% by weight, the level of falling weight impact strength of the plate-shaped molded product tends to be insufficient.
では衝撃強度レベルと成形品の外観に一一腸一難点が生
じ易い傾向となる。In this case, problems tend to occur in the impact strength level and the appearance of the molded product.
本発明による組成物は、本発明の目的を損なわない範囲
で、必要に応じて上記の重合体成分以外の熱可塑性又は
熱硬化性樹脂、ラバー成分、酸化防止剤、耐候性改良剤
、造核剤影スリタブ剤、・無機又は有機の充填剤や補強
剤、難燃剤、各種着色剤、帯電防止剤、離型剤等の成分
を添加することもできる。The composition according to the present invention may optionally include a thermoplastic or thermosetting resin other than the above-mentioned polymer components, a rubber component, an antioxidant, a weather resistance improver, and a nucleating agent, as long as the object of the present invention is not impaired. Components such as a slitting agent, an inorganic or organic filler or reinforcing agent, a flame retardant, various colorants, an antistatic agent, a mold release agent, etc. can also be added.
例えば、かかる前記重合体成分((a)、 (b)、
(C)成分)以外の例として、アルケニル芳香族化合物
と共役ジエンを主な単量体成分とするランダム(殊に、
スチレン−ブタジェンラバー)、グラフト、ブロック(
殊に、スチレン−ブタジェンブロック共重合体)等の結
合様式をなす共重合体であり部゛公的に架橋構造を含む
もの、あるいは共役ジエンに由来する脂肪族不飽和結合
の一部が水素添加されているものが挙げられる。For example, such polymer components ((a), (b),
As an example other than component (C), random (in particular,
Styrene-butadiene rubber), graft, block (
In particular, copolymers with a bonding mode such as styrene-butadiene block copolymers (such as styrene-butadiene block copolymers) which include a partially crosslinked structure, or where some of the aliphatic unsaturated bonds derived from a conjugated diene are hydrogen These include things that are added.
アイゾツト衝撃強度がよりいっそう高い組成物が必要と
される場合には、かかる共重合体の添加も可能であるが
、一方、高温環境下での使用時に色相が変化する傾向が
生じ易い。If a composition with even higher Izod impact strength is required, such a copolymer can be added, but on the other hand, the color tends to change when used in a high temperature environment.
また、酸化防止剤の例として、高度立体障害フェノール
系、チオエーテル系、リン系、アミン系等の安定剤が挙
げられる。Examples of antioxidants include highly sterically hindered phenol-based, thioether-based, phosphorus-based, and amine-based stabilizers.
なお、ガラス繊維、ウオラストナイト、炭酸カルシウム
、硫酸バリウム、酸化チタン、酸化亜鉛の添加は、耐熱
性向上等に効果が顕著である。Note that the addition of glass fiber, wollastonite, calcium carbonate, barium sulfate, titanium oxide, and zinc oxide has a remarkable effect on improving heat resistance.
3、ブレンド方法
本発明組成物は、−軸押出機、二軸押出機、バンバリー
ミキサ−、ロール、ブラベンダープラストグラフ、ニー
ダ−等の通常の混線機を用いて製造することができる0
通常は押出機等で混練してペレット状のコンパウンドに
した後、加工に供するが、特殊な場合は、全成分を直接
各種成形機に供給し、成形機で混練しながら成形するこ
ともできる。又、予めフィラーや他の成分を(必要に応
じて各種添加剤とともに)高濃度に混練してマスターバ
ッチとし、それを別途他の重合体等で希釈しながらブレ
ンドコンパラディングしたり、成形したりすることもで
きる。3. Blending method The composition of the present invention can be produced using a conventional mixing machine such as a screw extruder, twin screw extruder, Banbury mixer, roll, Brabender plastograph, or kneader.
Usually, it is kneaded in an extruder or the like to form a pellet-like compound and then subjected to processing, but in special cases, all the ingredients can be directly fed to various molding machines and molded while being kneaded by the molding machine. In addition, fillers and other ingredients (along with various additives as necessary) are kneaded to a high concentration in advance to form a masterbatch, which is then separately diluted with other polymers, blended, compounded, and molded. You can also.
また、混練に際して、付加的なフィラー成分を予め結晶
性ポリアミド樹脂と混練して使用しても良い。Furthermore, during kneading, an additional filler component may be kneaded with the crystalline polyamide resin in advance.
4、本発明による樹脂組成物の応用
本発明組成物を用いる成形加工法は、特に限定されるも
のではなく、熱可塑性樹脂一般に適用される成形法すな
わち押出成形、中空成形、射出成形、シート成形、熱成
形、回転成形、積層成形等の成形法により容易に成形す
ることができるが、中でも射出成形に最も適する。機械
的物性と寸法安定性が良好であることから、自動車の内
外装部品、電気機器外装部品並びに、所謂オフィスオー
トメーション機器等の部品用途に適している。4. Application of the resin composition of the present invention The molding method using the composition of the present invention is not particularly limited, and may include molding methods generally applied to thermoplastic resins, such as extrusion molding, blow molding, injection molding, and sheet molding. It can be easily molded by molding methods such as thermoforming, rotational molding, and lamination molding, among which injection molding is most suitable. Due to its good mechanical properties and dimensional stability, it is suitable for use in parts such as interior and exterior parts of automobiles, exterior parts of electrical equipment, and so-called office automation equipment.
(IV)実験例
1、測定および評価法
以下に示す実施例および比較例中の各物性値と諸性質は
、下記の条件により測定および評価を行なった。(IV) Experimental Example 1, Measurement and Evaluation Method The physical property values and properties in the Examples and Comparative Examples shown below were measured and evaluated under the following conditions.
1)曲げ弾性率
ISOR178−1974Procedure 12
(JIS R7203)に準じインストロン試験機を用
い測定した。1) Flexural modulus ISOR178-1974 Procedure 12
It was measured using an Instron testing machine according to (JIS R7203).
2)アイゾツト衝撃強度
ISOR1801969(JIS R7110) (/
7チ付アイゾツト衝撃強度)に準じ、東洋精機製作所
製アイゾツト衝撃試験機を用いて測定した。2) Izot impact strength ISOR1801969 (JIS R7110) (/
It was measured using an Izot impact tester manufactured by Toyo Seiki Seisakusho in accordance with the Izot impact strength tester (Izot impact strength with 7 marks).
3)落錘衝撃強度
支持台(穴径4011)上に設置した試験片(120m
X3QIIm、厚み21m)に荷重センサーであるダー
トを落下させ(2mXTkgf)、試験片の衝撃荷重に
おける変形破壊挙動を測定し、得られた衝撃パターンに
おける亀裂発生点までにおいて吸収された衝撃エネルギ
ーを算出し、材料の衝撃強度とした。測定雰囲気温度は
23℃および−30’Cである。3) Test piece (120m) installed on a falling weight impact strength support stand (hole diameter 4011)
A dart, which is a load sensor, was dropped (2 m XT kgf) onto a specimen (X3 QIIm, thickness 21 m), the deformation and fracture behavior of the test piece under impact load was measured, and the impact energy absorbed up to the crack initiation point in the obtained impact pattern was calculated. , the impact strength of the material. The measurement atmosphere temperature is 23°C and -30'C.
4)耐有機溶剤性
射出成形試片(129n+X125鶴、厚み4龍)を、
市販のガソリン中に室温下7日間浸漬したのち外観の変
化を観察した。外観に変化の無い場合を○、表面荒れや
白化の生じた場合をΔ、表面荒れや白化が顕著な場合を
×とした。4) Organic solvent resistant injection molded specimen (129n+X125 Tsuru, thickness 4 Dragon),
After being immersed in commercially available gasoline at room temperature for 7 days, changes in appearance were observed. The case where there was no change in appearance was rated ◯, the case where surface roughness or whitening occurred was rated Δ, and the case where surface roughness or whitening was significant was rated ×.
2、樹脂組成物の混合および混線
表1に示した各成分の所定量をスーパーミキサーにて充
分混合撹拌したのち、池貝鉄工■製PCM2軸型押出機
を用い、設定温度280℃にて溶融混練し、組成物とし
たのちストランド状に押し出し、カッターにてペレット
とした。2. Mixing and mixing of the resin composition After thoroughly mixing and stirring the prescribed amounts of each component shown in Table 1 in a super mixer, melt-knead at a set temperature of 280°C using a PCM twin-screw extruder manufactured by Ikegai Iron Works. After forming a composition, it was extruded into strands and made into pellets using a cutter.
3、物性測定および評価用試験片の作成インラインスク
リュ一式射出成型機、東芝機械製作所製IS −908
型を用い、シリンダ一温度280℃、金型冷却温度60
℃にて射出成型を行ない試験片を作成した。尚、射出成
形に際しては、その直前まで、減圧乾燥器を用い、0.
1 mug 80℃の条件で48時間乾燥を行なった。3. Creation of test pieces for physical property measurement and evaluation In-line screw set injection molding machine, IS-908 manufactured by Toshiba Machinery Works
Using a mold, the cylinder temperature is 280℃ and the mold cooling temperature is 60℃.
Test pieces were prepared by injection molding at ℃. In addition, during injection molding, a vacuum dryer is used until immediately before injection molding.
1 mg Drying was performed at 80° C. for 48 hours.
また、射出成形試片は、成形直後にデシケータ−に入れ
、23℃で4日間〜6日間放置したのち物性を測定した
。Immediately after molding, the injection molded specimens were placed in a desiccator and left at 23° C. for 4 to 6 days, after which physical properties were measured.
4、各成分の明細
1)ポリフェニレンエーテル樹脂(a)固有粘度0.5
24/g(30℃クロロホルム中)のポリ(2,6−シ
メチルー1,4−フェニレン)エーテルを使用した。4. Details of each component 1) Polyphenylene ether resin (a) Intrinsic viscosity 0.5
24/g of poly(2,6-dimethyl-1,4-phenylene) ether (in chloroform at 30° C.) was used.
2)結晶性ポリアミド樹脂中)
バーディッシェアニリンウントゾーダアクチェンゲゼル
シャフト社(西独間)製のナイロン−6,6(商品名ウ
ルトラミツド−A4)およびナイロン−6(商品名ウル
トラミツドB4)を使用した。2) In crystalline polyamide resin) Nylon-6,6 (trade name: Ultramid-A4) and nylon-6 (trade name: Ultramid-B4) manufactured by Bardische Anirin und Soder Akchen Gesellschaft (West Germany) were used.
3)非結晶性ないし低結晶性のポリアミド樹脂(C)
環状炭化水素系の非結晶性ないし低結晶性のポリアミド
樹脂として、三菱化成工業■製のノバミフドX21(ガ
ラス転移温度125℃、JIS K6810準拠による
相対粘度2.1dl/g)を使用した。3) Amorphous or low-crystalline polyamide resin (C) As a cyclic hydrocarbon-based amorphous or low-crystalline polyamide resin, Novamifud X21 manufactured by Mitsubishi Chemical Corporation (glass transition temperature 125°C, JIS K6810 compliant) A relative viscosity of 2.1 dl/g) was used.
4)同一分子内に不飽和基と極性基を併せ持つ化合物(
e)
市販の無水マレイン酸(試薬グレード)を使用した。4) Compounds that have both an unsaturated group and a polar group in the same molecule (
e) Commercially available maleic anhydride (reagent grade) was used.
尚、各成分の混練に際し、安定剤として、イルガノック
ス1010 (チバガイギー社製)を、(a)〜(d)
の全重合体成分の総合計filoO重量部にたいして外
数として0.3重量部加えた。In addition, when kneading each component, Irganox 1010 (manufactured by Ciba Geigy) was used as a stabilizer in (a) to (d).
0.3 part by weight was added as an extra number to the total weight part of filoO of all polymer components.
以下、実施例と比較例により本発明の効果を具体的に示
すが、あくまでも例示的なものであり、これらの例によ
り本発明の範囲が限定されるものではない。Hereinafter, the effects of the present invention will be specifically illustrated by Examples and Comparative Examples, but these examples are merely illustrative, and the scope of the present invention is not limited by these examples.
5、実施例および比較例の説明
表1中実施例1と比較例1および比較例2との対比、表
2中実施例3〜実施例4と比較例1、比較例5とのそれ
ぞれの対比より、ポリフェニレンエーテルとポリアミド
の組み合わせより成る樹脂組成物において、ポリアミド
成分として結晶性ポリアミドと非結晶性ポリアミドを組
み合わせてなる樹脂組成物は、ポリアミド成分として結
晶性ポリアミドまたは非結晶性ポリアミドを単独に使用
した樹脂組成物のそれぞれに比べ、板状成形品の落錘衝
撃強度が著るしく高く本発明の効果が明らかであり、な
お、アイゾツト衝撃強度のレベルは両ポリアミドを併用
しても左程、低下することはない。5. Explanation of Examples and Comparative Examples Comparison of Example 1 with Comparative Example 1 and Comparative Example 2 in Table 1, Comparison of Examples 3 to 4 with Comparative Example 1 and Comparative Example 5 in Table 2 Therefore, in a resin composition consisting of a combination of polyphenylene ether and polyamide, a resin composition consisting of a combination of crystalline polyamide and amorphous polyamide as the polyamide component uses only crystalline polyamide or amorphous polyamide as the polyamide component. The effect of the present invention is clear as the falling weight impact strength of the plate-shaped molded product is significantly higher than that of each of the resin compositions used. Furthermore, even when both polyamides are used in combination, the level of Izot impact strength is significantly higher. There will be no decline.
さらに、表1中実施例2と比較例3、比較例4との対比
、および表2中実施例5と比較例3、比較例6との対比
より、ポリフェニレンエーテル、ポリアミド、さらに加
えて同一分子内に不飽和基と極性基を併せ持つ化合物の
例として無水マレイン酸を加えてなる樹脂組成物につい
ても、ポリアミド成分として結晶性ポリアミドと非結晶
性ポリアミドを組み合わせてなる樹脂組成物は、色調力
低下することがあるものの(表示せず)、ポリアミド成
分として結晶性ポリアミドまたは非結晶P:ポリアミド
を単独で使用した樹脂組成物に比べて板状成形品の落錘
衝撃強度が著るしく高く、本夕明の効果が明らかである
。また、アイシフト衝艷強度には顕著な差が見られない
。Furthermore, from the comparison between Example 2 and Comparative Example 3 and Comparative Example 4 in Table 1, and the comparison between Example 5 and Comparative Example 3 and Comparative Example 6 in Table 2, polyphenylene ether, polyamide, and the same molecule As an example of a compound having both an unsaturated group and a polar group in the resin composition, maleic anhydride is added, but a resin composition made by combining crystalline polyamide and non-crystalline polyamide as the polyamide component has a decrease in tonal power. (not shown), the falling weight impact strength of plate-shaped molded products is significantly higher than that of resin compositions that use crystalline polyamide or amorphous P:polyamide alone as the polyamide component, and this book The effect of evening light is obvious. Furthermore, no significant difference was observed in the eye shift impact strength.
Claims (1)
量% (b)成分:結晶性ポリアミド樹脂29〜79重量% (c)成分:ガラス転移温度が70〜210℃の非結晶
性ないし低結晶性のポリアミド樹脂1〜55重量%[Scope of Claims] (a) A resin composition comprising the following components (a) to (c). (a) Component: 20-70% by weight of polyphenylene ether resin (b) Component: 29-79% by weight of crystalline polyamide resin (c) Component: Amorphous or low-crystalline polyamide with a glass transition temperature of 70-210°C Resin 1-55% by weight
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33294887A JPS63241063A (en) | 1987-12-28 | 1987-12-28 | Resin composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33294887A JPS63241063A (en) | 1987-12-28 | 1987-12-28 | Resin composition |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61252551A Division JP2512450B2 (en) | 1986-10-23 | 1986-10-23 | Resin composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63241063A true JPS63241063A (en) | 1988-10-06 |
Family
ID=18260601
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP33294887A Pending JPS63241063A (en) | 1987-12-28 | 1987-12-28 | Resin composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63241063A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63108056A (en) * | 1986-10-24 | 1988-05-12 | Asahi Chem Ind Co Ltd | Polyamide resin composition and production thereof |
JPH0393855A (en) * | 1989-09-06 | 1991-04-18 | Unitika Ltd | Resin composition |
US5206691A (en) * | 1991-02-01 | 1993-04-27 | Minolta Camera Kabushiki Kaisha | Developing apparatus |
US20090129716A1 (en) * | 2006-06-30 | 2009-05-21 | Ntn Corporation | Heat-Resistant, Oil Resistant Rolling Bearing and Rolling Bearing for Use in a Compressor of a Refrigerating Machine |
-
1987
- 1987-12-28 JP JP33294887A patent/JPS63241063A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63108056A (en) * | 1986-10-24 | 1988-05-12 | Asahi Chem Ind Co Ltd | Polyamide resin composition and production thereof |
JPH0393855A (en) * | 1989-09-06 | 1991-04-18 | Unitika Ltd | Resin composition |
US5206691A (en) * | 1991-02-01 | 1993-04-27 | Minolta Camera Kabushiki Kaisha | Developing apparatus |
US20090129716A1 (en) * | 2006-06-30 | 2009-05-21 | Ntn Corporation | Heat-Resistant, Oil Resistant Rolling Bearing and Rolling Bearing for Use in a Compressor of a Refrigerating Machine |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2842536B2 (en) | Resin composition | |
JP2607883B2 (en) | Thermoplastic resin composition | |
EP0225170B1 (en) | Moldable composition of polyphenylene ether and polyamide resin | |
JP2715499B2 (en) | Thermoplastic resin composition | |
JP2885317B2 (en) | Method for producing impact-resistant thermoplastic resin composition | |
US4968749A (en) | Polyphenylene ether-polyamide resin composition | |
JPH03199258A (en) | Thermoplastic resin composition | |
JPH09279012A (en) | Thermoplastic resin composition | |
JP2512450B2 (en) | Resin composition | |
JPH06345918A (en) | Thermoplastic resin composition | |
JPS63241063A (en) | Resin composition | |
JPH07116354B2 (en) | Method for producing resin composition | |
JP3504342B2 (en) | Heat resistant resin composition | |
JPH0788442B2 (en) | Resin composition | |
JPS63113071A (en) | Resin composition | |
JPH05230360A (en) | Flame retardant resin composition | |
JP2670117B2 (en) | Multi-layer molded product | |
JP3110089B2 (en) | Resin composition | |
JP2798706B2 (en) | Method for producing impact-resistant thermoplastic resin composition | |
JP2636805B2 (en) | Resin composition | |
JPH0314867A (en) | Manufacture of impact-resistant thermoplastic resin composition | |
JPH107900A (en) | Polyether imide resin composition and its production | |
EP0520146B1 (en) | Process for preparing a thermoplastic resin composition | |
JP3358496B2 (en) | Thermoplastic resin composition | |
JP3330388B2 (en) | Method for producing polyphenylene ether resin composition |