JPS63234082A - Portable cooling agent - Google Patents

Portable cooling agent

Info

Publication number
JPS63234082A
JPS63234082A JP6864687A JP6864687A JPS63234082A JP S63234082 A JPS63234082 A JP S63234082A JP 6864687 A JP6864687 A JP 6864687A JP 6864687 A JP6864687 A JP 6864687A JP S63234082 A JPS63234082 A JP S63234082A
Authority
JP
Japan
Prior art keywords
powder
water
dissolved
impermeable
endothermic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6864687A
Other languages
Japanese (ja)
Inventor
Yoshio Ushiku
牛久 芳雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP6864687A priority Critical patent/JPS63234082A/en
Publication of JPS63234082A publication Critical patent/JPS63234082A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a cooling agent utilized in cooling of a food or drink or control of temperature of the body, etc., by housing a powder of water-soluble and endothermic substance and powder of metal-containing salt through a thin film in an impermeable and flexible sealed vessel. CONSTITUTION:The aimed cooling agent obtained by housing (A) a powder of water-soluble and endothermic substance consisting of ammonium nitrate, urea, etc. and (B) a powder of metal-containing salt consisting of sodium sulfate.10 hydrate, etc., in an impermeable and flexible vessel such as a sealed plastic (polypropylene, polyethylene, etc.) film not so as to be blended each other using a film such as plastic film, etc., which is permeable and capable of breaking. the blend weight ratio of the component (A) with the component (B) is preferably about 1:1.

Description

【発明の詳細な説明】 [産業上の利用分野1 本発明は、食品や飲料の冷却ないし体温の調節等に利用
するための、水に溶解するとき熱を吸収する物質を用い
た携帯用の冷却剤に関する。
Detailed Description of the Invention [Industrial Application Field 1] The present invention relates to a portable device that uses a substance that absorbs heat when dissolved in water, and is used for cooling foods and beverages, regulating body temperature, etc. Concerning coolant.

C従来の技術J 従来から、行楽等のさいに食品や瓶詰又は缶詰の飲料を
冷却して運んだり保存したりする場合、氷を詰めた容器
中に食品や飲料を入れ、氷の融解熱を利用して冷却する
ことが行なわれている。
C. Conventional technology It is being used for cooling.

又、家庭や病院で病人の発熱した頭部を冷やしたり体温
を調節し、あるいは夏期にスポーツ見物等の行楽や工事
現場などで暑さを抑えるために。
It can also be used to cool the feverish head of a sick person at home or in a hospital, or to regulate body temperature, or to reduce the heat in the summer when attending sports or at a construction site.

氷を入れた袋を頭部にあてることが一般に行なわれてい
る。
It is common practice to place a bag filled with ice on the head.

しかし、氷による食品等の冷却においては、氷が嵩ぼる
ほか、果物や魚類の場合は自重や運搬中の振動で損傷し
やすい等の不都合があった。又。
However, using ice to cool foods and the like has the disadvantage that the ice bulks up, and in the case of fruits and fish, they are easily damaged by their own weight and vibrations during transportation. or.

医療用や行楽での体温調節等のために頭部等に乗せる場
合、氷はブロック状で角ぼっているために頭部上で安定
が悪く、特に行楽や工事現場などでは使用しにくいとい
う欠点があった。
When placed on the head for medical purposes or to regulate body temperature during recreational activities, ice is block-shaped and angular, making it unstable on the head, making it difficult to use, especially in recreational activities or construction sites. was there.

そこで最近では、装入りの携帯用冷却剤も医療用ないし
行楽用などとして、米国のJobnson &J o 
b、n s o n社から市販されている。この携帯用
冷却剤は、水に溶解して熱を吸収する物質(具体的名称
は不明である)の粉末を、プラスチックフィルム等の非
透水性の小袋に封入した水と一緒に非透水性の大袋(容
器)に入れて密封したもので、小袋を破って中の水を大
袋中に流出させ、大袋中の上記溶解吸熱物質の粉末がこ
の水に溶解する時の熱の吸収により周囲を冷却するもの
である。
Recently, a portable refrigerant package has been developed by Jobnson & J.O.
b, commercially available from NSON. This portable coolant consists of powdered material (the specific name is unknown) that dissolves in water and absorbs heat. It is placed in a large bag (container) and sealed.The small bag is broken and the water inside flows out into the large bag, and the surrounding area is cooled by the absorption of heat when the powder of the above-mentioned dissolved endothermic substance in the large bag dissolves in this water. It is something to do.

しかし、この携帯用冷却剤は小型で何時でも取り出して
使用できる便利さはあるものの、冷却温度は最低でも一
7℃程度であって、しかも小袋に封入した水を一度に溶
解吸熱物質に供給するので溶解並びに吸熱反応が急速に
進行してしまい、接触面を0℃以下に冷却する効果は1
5分〜30分しか持続できなかった。
However, although this portable coolant is small and convenient to take out and use at any time, the cooling temperature is at least around -7℃, and moreover, it supplies water sealed in a sachet to the dissolved endothermic substance at once. Therefore, dissolution and endothermic reactions proceed rapidly, and the effect of cooling the contact surface below 0°C is 1
I could only last between 5 and 30 minutes.

[発明が解決しようとする問題点] 本発明は、この様な従来の事情に−み、小型で携帯や保
存に都合よく且つ何時でも簡単に使用でき、しかも優れ
た冷却効果を長時間持続することのできる。携帯用冷却
剤を提供することを目的とする。
[Problems to be Solved by the Invention] In view of these conventional circumstances, the present invention provides a device that is small and convenient for carrying and storing, can be easily used at any time, and maintains an excellent cooling effect for a long time. I can do it. Aims to provide portable coolant.

[問題点を解決するための手段] 本発明の携帯用冷却剤は、密封した非透水性の再環性容
器内に、水に溶解するとき熱を吸収する溶解吸熱性物質
の粉末と、結晶水を含有する金属含水塩の粉末とを、非
透水性の破ることができる薄膜を用いて互いに混合しな
いように収納したことを特徴とするものである。
[Means for Solving the Problems] The portable coolant of the present invention contains a powder of a dissolved endothermic material that absorbs heat when dissolved in water, and crystals in a sealed, water-impermeable, recyclable container. It is characterized by containing water-containing metal hydrate salt powder using a water-impermeable breakable thin film so that they do not mix with each other.

溶解吸熱物質としては、公知の水に溶解するとき熱を吸
収する物質であってよく、例えば硝酸アンモニウム、チ
オ硫酸ナトリウム、jn化アンモニウム、塩化カルシウ
ム6水塩、尿素等があり、これらの物質の1種又は2種
以上を用いることができる。
The endothermic dissolved substance may be a known substance that absorbs heat when dissolved in water, such as ammonium nitrate, sodium thiosulfate, ammonium chloride, calcium chloride hexahydrate, urea, etc. A species or two or more species can be used.

又、金属含水塩としては結晶水を遊離しやすいものが好
ましく1例えば硫酸ナトリウム10水塩(NazS04
・10H20)、硫酸アルミニウムカリウム12水塩(
KAI(SO4)2・12H20) 、硫酸アンモニウ
ムアルミニウム12水塩(AINH4(S04) ・1
2H20)、硫酸アルミニウム18水塩(Ah(SOi
h48ToO)、77%ニウムミHv”) /< ン(
A12 (NHs)2SOs ・H2O)等(7)1種
又は2種以上を使用することができる。
In addition, as the metal hydrate salt, one that easily releases crystal water is preferable. For example, sodium sulfate decahydrate (NazS04
・10H20), potassium aluminum sulfate dodecahydrate (
KAI(SO4)2・12H20), ammonium aluminum sulfate dodecahydrate (AINH4(S04)・1
2H20), aluminum sulfate 18 hydrate (Ah(SOi
h48ToO), 77%NiumHv”) /< N(
A12 (NHs)2SOs .H2O) etc. (7) One type or two or more types can be used.

又、これら両粉末の組合せ並びに混合割合は、所望とす
る冷却温度及び冷却持続時間などによって適宜選択する
ことができる。なかでも好ましい組合せとしては、溶解
吸熱性物質の粉末として硝酸アンモニウムと尿素の粉末
を、及び金属含水塩粉末として硫酸ナトリウム10水塩
の粉末を用いる例があげられる。又、好ましい混合割合
は、一般的に溶解吸熱物質と金属含水塩の粉末が重量比
でほぼtitである。
Further, the combination and mixing ratio of these two powders can be appropriately selected depending on the desired cooling temperature and cooling duration. Among these, a preferred combination is an example in which ammonium nitrate and urea powder is used as the dissolved endothermic substance powder, and sodium sulfate decahydrate powder is used as the metal hydrate powder. In general, a preferable mixing ratio of the dissolved endothermic substance and the powder of the metal hydrate is approximately tit in terms of weight ratio.

溶解吸熱物質の粉末と金属含水塩の粉末とは。What are powders of soluble endothermic substances and powders of metal hydrates?

使用する前は混合しないように非透水性の薄膜で両方の
粉末を分離しておく、この薄膜は結晶水が透過しないよ
うにプラスチックフィルムのような非透水性であり、使
用に際して破ることができる程度に薄いことが必要であ
る0両粉末の分離手段としては1例えば、この薄膜を下
記する容器を2分割するように容器内周面に接着し、そ
の両側に夫々溶解吸熱物質の粉末と金属含水塩の粉末を
別々に収納してもよいし、薄膜で作った小袋に片方の粉
末を収納し、この小袋を他方の粉末と一緒に容器内に収
納すむこともできる。
Before use, separate both powders with a water-impermeable thin film so that they do not mix. This thin film is water-impermeable, like a plastic film, to prevent crystallization water from penetrating, and can be broken before use. For example, this thin film is adhered to the inner peripheral surface of the container so as to divide it into two parts, and the powder of the dissolved endothermic substance and the metal are placed on both sides of the container, respectively. The hydrated salt powders may be stored separately, or one powder may be stored in a pouch made of a thin film, and this pouch may be stored together with the other powder in a container.

溶解吸熱物質と金属含水塩の両粉末を分離収納し且つ使
用の際に両粉末を混合するために用いる容器は、最終的
に硝酸アンモニウムや金属塩の水溶液が生成するので、
これを漏らさずに保持でき且つ取扱い中に破れないよう
な非透水性で厚手の容器であればよく1頭部等を冷やす
際に容器が頭部等になじみやすいように可撓性の袋状の
容器が好ましい、容器及び薄膜の材料としては、ポリプ
ロピレン、ポリエチレン、軟質ビニール等のプラスチッ
クフィルムが好適である。
The container used to separately store the dissolved endothermic substance and the metal hydrate powder and to mix the two powders during use is necessary because an aqueous solution of ammonium nitrate or metal salt is ultimately produced.
A thick, water-impermeable container that can hold the water without leaking and that does not tear during handling is sufficient.A flexible bag-like container that allows the container to easily fit into the head when cooling the head, etc. The preferred material for the container and thin film is a plastic film such as polypropylene, polyethylene, or soft vinyl.

[作用J 本発明の携帯用冷却剤では、溶解吸熱物質の粉1末と金
属含水塩の粉末とを、使用する前は混合しないように袋
等の容器中に非透水性の薄膜で両方の粉末を分離して収
納しておき、使用に際してこの薄膜を容器の外側から手
で破って両方の粉末を容器内で混合させる0両方の粉末
が混合して接触すると、金属含水塩の粉末から結晶水が
徐々に遊離して溶解吸熱物質の粉末を溶解させるので、
この溶解時の熱の吸収によって容器の周囲が冷却される
[Function J] In the portable coolant of the present invention, the dissolved endothermic substance powder and the metal hydrated salt powder are separated by a water-impermeable thin film in a container such as a bag so that they do not mix before use. The powders are stored separately, and when used, the thin film is manually broken from the outside of the container and both powders are mixed in the container. When both powders are mixed and come into contact, crystals form from the metal hydrate salt powder. As water gradually liberates and dissolves the dissolved endothermic substance powder,
The surroundings of the container are cooled by absorption of heat during this melting.

本発明では、溶解吸熱物質を溶解させるための木を金属
含水塩に含まれる結晶水から供給するので、含水塩から
の結晶水の遊離が少しづつしか進行せず、従って遊離し
た結晶水への溶解吸熱物質の溶解及びその際の吸熱反応
を長時間持続させることができる。従来の氷による冷却
や市販の簡易冷却剤に比較した場合、最終的に残る水な
いし水溶液の容積が同一であれば1本冷却剤は一17℃
程度の最低温度が得られ、温度が0℃になる迄はるかに
長い時間冷却作用を維持することができる。
In the present invention, since the wood for dissolving the dissolved endothermic substance is supplied from the water of crystallization contained in the hydrated metal salt, the release of the water of crystallization from the hydrated salt progresses only little by little, and therefore the dissolution into the free crystallized water The dissolution of the endothermic substance and the endothermic reaction at that time can be sustained for a long time. When compared to conventional ice cooling or commercially available simple coolants, one coolant cools at -17°C if the volume of water or aqueous solution remaining at the end is the same.
A very low temperature can be obtained and the cooling effect can be maintained for a much longer time until the temperature reaches 0°C.

更に、溶解吸熱物質及び金属含水塩の粉末の少なくとも
片方に、アルギン酸ナトリウムやポバール等の水を増粘
する物質の粉末、若″しくは高分子吸収体と呼ばれるア
クリル酸ソーダの粉末を混合すれば、冷却作用を一層長
い時間持続させることが可能である。又、溶解吸熱物質
と金属含水塩の粉末として結晶粒径の大きなものを使用
するほど°、冷却作用の持続時間が長くなる。
Furthermore, if at least one of the dissolved endothermic substance and the metal hydrate powder is mixed with a powder of a substance that thickens water such as sodium alginate or poval, or a powder of sodium acrylate called a polymer absorber, It is possible to maintain the cooling effect for a longer period of time.Furthermore, the larger the crystal grain size is used as the dissolved endothermic substance and metal hydrate powder, the longer the cooling effect lasts.

更に又、溶解吸熱物質及び金属含水塩とも粉末を使用す
るので、両者の接触面積が大きくなり、結晶水を利用す
るにもかかわらずその遊離が比較的容易であり1両粉末
の混合から冷却効果が発揮されるまでの時間も極めてみ
じかい。
Furthermore, since powders are used for both the dissolved endothermic substance and the metal hydrate, the contact area between the two is large, and although crystal water is used, their release is relatively easy, and the cooling effect can be obtained from mixing the two powders. The time it takes for this to manifest is also extremely short.

[実施例] 薄いポリプロピレンの小袋内に結晶粒径が約1.5mm
の硫酸ナトリウムlO水塩の粉末1.5重量部を入れて
密封した。この小袋を厚手のポリプロピレンの大きな袋
内に入れ、更に結晶粒径が約l扉鵬の硝酸アンモニウム
粉末1重量部と尿素粉末0.5重量部を混合して入れ、
大きな袋を密封した。
[Example] Crystal grain size is approximately 1.5 mm in a thin polypropylene pouch
1.5 parts by weight of powdered sodium sulfate 1O aqueous salt was added thereto and the mixture was sealed. This small bag was placed in a large thick polypropylene bag, and 1 part by weight of ammonium nitrate powder with a crystal grain size of about 1 and 0.5 part by weight of urea powder was mixed therein.
Seal the big bag.

次に、大きな袋を手でもんで中の小袋を破り。Next, use your hands to tear open the small bag inside the large bag.

硫酸ナトリウム10水塩の粉末を硝酸ナトリウム粉末及
び尿素粉末と混合させた。混合後直ちに袋の表面温度が
低下しはじめ、約1分後には一17℃の最低温度に達し
た。
Sodium sulfate decahydrate powder was mixed with sodium nitrate powder and urea powder. Immediately after mixing, the surface temperature of the bag began to drop, reaching a minimum temperature of -17°C after about 1 minute.

この袋を20℃の室温に保持すると、袋の表面温度が一
3℃に上昇するまで約3時間を要した。
When this bag was kept at room temperature of 20°C, it took about 3 hours for the surface temperature of the bag to rise to 13°C.

又、10℃の室温に保持した場合には1表面温度が一5
℃に上昇するまで約7時間かかった。参集的に大きな袋
内には、全ての粉末がほとんど溶解した水溶液が残った
Also, when kept at room temperature of 10℃, 1 surface temperature is 15℃.
It took about 7 hours to rise to ℃. Collectively, an aqueous solution remained in the large bag in which all the powder was nearly dissolved.

[発明の効果] 本発明によれば、小型で携帯や保存に都合よく且つ何時
でも簡単に使用できる冷却剤を提供することができ、し
かも溶解吸熱物質の粉末の溶解吸熱反応に金属含水塩の
結晶水を利用するので、優れた冷却効果を長時間持続す
ることができる。
[Effects of the Invention] According to the present invention, it is possible to provide a coolant that is small, convenient for carrying and storage, and can be easily used at any time. Since crystal water is used, the excellent cooling effect can be maintained for a long time.

Claims (2)

【特許請求の範囲】[Claims] (1)密封した非透水性の可撓性容器内に、水に溶解す
るとき熱を吸収する溶解吸熱性物質の粉末と、結晶水を
含有する金属含水塩の粉末とを、非透水性の破ることが
できる薄膜を用いて互いに混合しないように収納したこ
とを特徴とする携帯用冷却剤。
(1) In a sealed, water-impermeable, flexible container, a powder of a dissolved endothermic substance that absorbs heat when dissolved in water and a powder of a metal hydrate containing water of crystallization are placed in a water-impermeable container. A portable coolant characterized by being housed in a breakable thin film so that they do not mix with each other.
(2)溶解吸熱性物質が硝酸アンモニウムと尿素であり
、金属含水塩が硫酸ナトリウム10水塩であることを特
徴とする、特許請求の範囲(1)項記載の携帯用冷却剤
(2) The portable coolant according to claim (1), wherein the dissolved endothermic substances are ammonium nitrate and urea, and the metal hydrate is sodium sulfate decahydrate.
JP6864687A 1987-03-23 1987-03-23 Portable cooling agent Pending JPS63234082A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6864687A JPS63234082A (en) 1987-03-23 1987-03-23 Portable cooling agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6864687A JPS63234082A (en) 1987-03-23 1987-03-23 Portable cooling agent

Publications (1)

Publication Number Publication Date
JPS63234082A true JPS63234082A (en) 1988-09-29

Family

ID=13379683

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6864687A Pending JPS63234082A (en) 1987-03-23 1987-03-23 Portable cooling agent

Country Status (1)

Country Link
JP (1) JPS63234082A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0581250U (en) * 1992-04-08 1993-11-05 日本パイオニクス株式会社 Simple cooling bag
JPH0581251U (en) * 1992-04-08 1993-11-05 日本パイオニクス株式会社 Simple cooling bag
JPH0594253U (en) * 1991-09-30 1993-12-24 日本パイオニクス株式会社 Simple cooling bag
JPH0738155U (en) * 1991-09-30 1995-07-14 日本パイオニクス株式会社 Simple cooling bag

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55108486A (en) * 1978-10-25 1980-08-20 Kontinen Martti Chemically reactive cooling pack and its manufacture
JPS55152778A (en) * 1979-05-18 1980-11-28 Masao Ozawa Cooling bag
JPS5773069A (en) * 1980-10-25 1982-05-07 Daikin Ind Ltd Cooling agnent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55108486A (en) * 1978-10-25 1980-08-20 Kontinen Martti Chemically reactive cooling pack and its manufacture
JPS55152778A (en) * 1979-05-18 1980-11-28 Masao Ozawa Cooling bag
JPS5773069A (en) * 1980-10-25 1982-05-07 Daikin Ind Ltd Cooling agnent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0594253U (en) * 1991-09-30 1993-12-24 日本パイオニクス株式会社 Simple cooling bag
JPH0738155U (en) * 1991-09-30 1995-07-14 日本パイオニクス株式会社 Simple cooling bag
JPH0581250U (en) * 1992-04-08 1993-11-05 日本パイオニクス株式会社 Simple cooling bag
JPH0581251U (en) * 1992-04-08 1993-11-05 日本パイオニクス株式会社 Simple cooling bag

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