JPS63229056A - Deodorant - Google Patents
DeodorantInfo
- Publication number
- JPS63229056A JPS63229056A JP62062075A JP6207587A JPS63229056A JP S63229056 A JPS63229056 A JP S63229056A JP 62062075 A JP62062075 A JP 62062075A JP 6207587 A JP6207587 A JP 6207587A JP S63229056 A JPS63229056 A JP S63229056A
- Authority
- JP
- Japan
- Prior art keywords
- ferrous
- phosphate
- hexose phosphate
- present
- hexose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002781 deodorant agent Substances 0.000 title description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 25
- 229910019142 PO4 Inorganic materials 0.000 claims description 20
- 239000010452 phosphate Substances 0.000 claims description 20
- 150000002402 hexoses Chemical class 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 15
- 239000004480 active ingredient Substances 0.000 claims description 4
- 230000001877 deodorizing effect Effects 0.000 description 13
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- -1 iron ions Chemical class 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000007935 neutral effect Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- HXXFSFRBOHSIMQ-VFUOTHLCSA-N alpha-D-glucose 1-phosphate Chemical compound OC[C@H]1O[C@H](OP(O)(O)=O)[C@H](O)[C@@H](O)[C@@H]1O HXXFSFRBOHSIMQ-VFUOTHLCSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- 229950010772 glucose-1-phosphate Drugs 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- SHZGCJCMOBCMKK-UHFFFAOYSA-N D-mannomethylose Natural products CC1OC(O)C(O)C(O)C1O SHZGCJCMOBCMKK-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 2
- 239000002211 L-ascorbic acid Substances 0.000 description 2
- 235000000069 L-ascorbic acid Nutrition 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003606 tin compounds Chemical class 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical class [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004277 Ferrous carbonate Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- PNNNRSAQSRJVSB-SLPGGIOYSA-N Fucose Natural products C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C=O PNNNRSAQSRJVSB-SLPGGIOYSA-N 0.000 description 1
- SHZGCJCMOBCMKK-DHVFOXMCSA-N L-fucopyranose Chemical compound C[C@@H]1OC(O)[C@@H](O)[C@H](O)[C@@H]1O SHZGCJCMOBCMKK-DHVFOXMCSA-N 0.000 description 1
- SHZGCJCMOBCMKK-JFNONXLTSA-N L-rhamnopyranose Chemical compound C[C@@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O SHZGCJCMOBCMKK-JFNONXLTSA-N 0.000 description 1
- PNNNRSAQSRJVSB-UHFFFAOYSA-N L-rhamnose Natural products CC(O)C(O)C(O)C(O)C=O PNNNRSAQSRJVSB-UHFFFAOYSA-N 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- SHZGCJCMOBCMKK-DVKNGEFBSA-N alpha-D-quinovopyranose Chemical compound C[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O SHZGCJCMOBCMKK-DVKNGEFBSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 description 1
- 235000019268 ferrous carbonate Nutrition 0.000 description 1
- 229960004652 ferrous carbonate Drugs 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 229940116007 ferrous phosphate Drugs 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- 229910000155 iron(II) phosphate Inorganic materials 0.000 description 1
- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は脱臭剤に関し、更に詳細には第一鉄塩を含有す
る脱臭剤に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a deodorizing agent, and more particularly to a deodorizing agent containing a ferrous salt.
第一鉄塩は顔料の製造、織物工業等の原料として利用さ
れているが、更に２価の鉄はその強力な酸化力によシア
ンモニア臭気、メルカプタン類等の悪臭除去に優れた効
果を発揮することも知られている。Ferrous salts are used as raw materials for pigment production and the textile industry, and divalent iron has a strong oxidizing power that makes it highly effective in removing cyanmonia odors, mercaptans, and other odors. It is also known to do.
しかし、第一鉄化合物は水溶性の状態で放置すると、２
価の鉄イオンが非常に不安定なため、溶存酸素や空気中
の酸素と結合し、容易に３価のイオンに酸化され、活性
を失ってしまう。However, if ferrous compounds are left in a water-soluble state, 2
Since valent iron ions are extremely unstable, they combine with dissolved oxygen and oxygen in the air, are easily oxidized to trivalent ions, and lose their activity.
従来、第一鉄化合物の２価の鉄イオンの安定化のため、
ヒドロキシルアミン、スズ化合物あるいはＬ−アスコル
ビン酸等の酸化防止剤が添加されていた。Conventionally, in order to stabilize divalent iron ions in ferrous compounds,
Antioxidants such as hydroxylamine, tin compounds or L-ascorbic acid were added.
しかし、ヒドロキシルアミン、スズ化合物は人体に対す
る毒性が強く、またＬ−アスコルビン酸の多量の添加は
安全であるものの、この添加によシ液性が強酸性となる
ため、使用の範囲がおのずと制限される等の問題点があ
った。However, hydroxylamine and tin compounds are highly toxic to the human body, and although it is safe to add large amounts of L-ascorbic acid, this addition makes the liquid highly acidic, which naturally limits the scope of its use. There were problems such as:
本発明者らは、このような、従来の２価の鉄イオン化合
物水溶液の脱臭剤の欠点を克服した脱臭剤、すなわち、
毒性を有する酸化防止剤を使用せず、また組成物の臭い
や強酸性を呈する液性を改善した脱臭剤を得べく鋭意検
′＃ｔをおこなった結果、中性のヘキソースリン酸アル
カリ土類金属塩と中性または酸性の第一鉄塩を反応させ
ることにより、得られたヘキソースリン酸第一鉄塩は、
酸化防止剤を併用しなくてもそれ自身水溶液として十分
安定であり、脱臭剤として有利に利用し得ることを見出
し、本発明を完成した。The present inventors have developed a deodorizer that overcomes the drawbacks of conventional deodorizers using divalent iron ion compound aqueous solutions, namely:
As a result of intensive research in order to obtain a deodorizer that does not use toxic antioxidants and has improved composition odor and strong acidic liquid properties, we found that a neutral alkaline earth hexose phosphate The ferrous hexose phosphate obtained by reacting a metal salt with a neutral or acidic ferrous salt is
The present invention was completed based on the discovery that the compound itself is sufficiently stable as an aqueous solution without the use of an antioxidant and can be advantageously used as a deodorizing agent.
すなわち、本発明は、ヘキソースリン酸第一鉄塩を有効
成分として含有する脱臭剤を提供するものである。That is, the present invention provides a deodorizing agent containing ferrous hexose phosphate as an active ingredient.
本発明で用いるヘキソースリン酸第一鉄塩は、ヘキソー
ス、例えばグルコース、フルクトース、マンノース、ガ
ラクトース、タガトース、ツルゴース等及びその誘導体
であるフコース、キノボース、ラムノース等の一個以上
の水酸基をリン酸基で置換したリン酸エステルの第一鉄
塩で、その好ましいものとしては、例えばグルコース−
１−リン酸第一鉄塩、グルコース−５−＋７ン酸第一鉄
塩、グルコース−１，６−ゾリン酸第一鉄塩等が挙げら
れ、このうち、特にグルコース−１−リン酸第一鉄塩が
特に好ましい。このヘキソースリン酸第一鉄塩は、例え
ば中性のヘキソースリン酸アルカリ土類金属塩と、中性
または酸性の第一鉄塩を反応させることにより得られる
ものであシ、更に、副生ずる塩が水に対して難溶性であ
るように第一鉄イオンのアニオンを選択すれば、淡青緑
色〜無色透明、弱酸性（ｐＨ６，０〜６．５）かつ安定
な第一鉄塩として容易に分離収得することができるもの
である。The ferrous hexose phosphate used in the present invention is a hexose such as glucose, fructose, mannose, galactose, tagatose, turgose, etc. and its derivatives such as fucose, quinovose, rhamnose, etc., in which one or more hydroxyl groups are substituted with a phosphoric acid group. ferrous salts of phosphoric acid esters, preferred examples include glucose-
Examples include ferrous 1-phosphate, ferrous glucose-5-+7-phosphate, ferrous glucose-1,6-sophosphate, and especially ferrous glucose-1-phosphate. Particularly preferred are iron salts. This ferrous hexose phosphate is obtained, for example, by reacting a neutral alkaline earth metal salt of hexose phosphate with a neutral or acidic ferrous salt. If the ferrous ion anion is selected so that it is sparingly soluble in water, it can be easily separated as a pale bluish-green to colorless transparent, weakly acidic (pH 6.0 to 6.5) and stable ferrous salt. It is something that can be obtained.
この方法において用いるヘキソースリン酸アルカリ土類
金属塩としてはバリウム、カルシウムなどが挙げられる
が、好ましくはバリウムである。また、中性または酸性
の第一鉄塩としては硫酸第一鉄、硝酸第一鉄、炭酸第一
鉄が挙げられるが、好ましくは硫酸第一鉄である。The alkaline earth metal hexose phosphate used in this method includes barium, calcium, etc., but barium is preferred. Furthermore, neutral or acidic ferrous salts include ferrous sulfate, ferrous nitrate, and ferrous carbonate, with ferrous sulfate being preferred.
上記反応において、第一鉄塩はヘキソースリン酸アルカ
リ土類金属塩のリン酸基に対して、１モル以上用いられ
、好ましくは１〜２モル用いられる。In the above reaction, the ferrous salt is used in an amount of 1 mole or more, preferably 1 to 2 moles, based on the phosphate group of the alkaline earth metal hexose phosphate.
反応終了後、ヘキソースリン酸第一鉄塩は、無機塩を除
去した後のヘキソースリン酸第一鉄塩の水溶液を凍結乾
燥などの方法、または水溶性溶媒を添加し再沈後、沈澱
’ｅ濾過乾燥Ｊるなどの方法で処理することにより、粉
末状のヘキソースリン酸第一鉄塩として容易に単離でき
る。After the completion of the reaction, the ferrous hexose phosphate can be precipitated by a method such as freeze-drying the aqueous solution of the ferrous hexose phosphate after removing the inorganic salt, or by adding a water-soluble solvent and reprecipitating. It can be easily isolated as a powdered ferrous hexose phosphate salt by processing by methods such as filtration and drying.
本発明において脱臭剤は、その使用形態には特に制限は
ないが、粉末としであるいは水溶液として用いる他、紙
、布等に含浸、活性炭等含有の担持体に添着させて用い
ることもできる。In the present invention, there is no particular restriction on the form in which the deodorizing agent is used, but in addition to being used as a powder or an aqueous solution, it can also be used by impregnating paper, cloth, etc., or by attaching it to a carrier containing activated carbon, etc.
本発明において、水溶性脱臭剤とする場合、ヘキソース
リン酸第一鉄塩の濃度に制限はないが、通常０．１〜２
０％、好ましくは１〜２０％である。In the present invention, when used as a water-soluble deodorizing agent, there is no limit to the concentration of ferrous hexose phosphate, but it is usually 0.1 to 2.
0%, preferably 1-20%.
本発明の脱臭剤を紙、布に含浸させた形態のものとする
場合には、ヘキソースリン酸第一鉄塩水溶液を紙、布に
塗布、散布、浸漬等すれば良い。この場合のヘキソース
リン酸第一鉄塩の含有量は特に制限はないが、通常１〜
２０チ（重量係）が好ましい。When the deodorizing agent of the present invention is impregnated into paper or cloth, the paper or cloth may be coated, sprinkled, immersed, etc. in an aqueous solution of ferrous hexose phosphate. The content of ferrous hexose phosphate in this case is not particularly limited, but is usually 1 to 1.
20 inches (weight) is preferable.
本発明においてヘキソースリン酸ｇ−鉄塩を活性炭等の
担持体に添着させ、脱臭剤とする方法は、紙、布に含浸
させる方法に準じて行なうことができるが、特に浸漬す
ることによシ調製するのが好ましい。ヘキソースリン酸
第一鉄塩を含浸させる担持体の活性炭は形状をとわない
。In the present invention, the method of impregnating g-iron hexose phosphate on a carrier such as activated carbon to form a deodorizing agent can be carried out in the same manner as impregnating paper or cloth, but in particular, it can be made by soaking it. Preferably, it is prepared. The activated carbon of the carrier impregnated with the ferrous hexose phosphate has no particular shape.
本発明の脱臭剤は、対照物に直接添加して使用する他、
食品、たとえば肉、魚は脱臭剤を含浸させた紙、布で直
接つつむことによシ脱臭効果を発揮する。The deodorizer of the present invention can be used by directly adding it to a control substance, as well as
Foods such as meat and fish can be deodorized by directly wrapping them in paper or cloth impregnated with a deodorizing agent.
なお本発明の脱臭剤の有効成分であるヘキソースリン酸
第一鉄塩のマウス経口急性毒性は１．（Ｍ’／ＫＰ体重
以上であり、きわめて安全である。The acute oral toxicity in mice of ferrous hexose phosphate, which is the active ingredient of the deodorant of the present invention, is 1. (More than M'/KP weight, extremely safe.
本発明の脱臭剤は、その有効成分であるヘキソースリン
酸第一鉄塩が無臭で、弱酸性〜中性であり、しかもその
外観は淡青緑色〜無色透明、かつ安定であるため、第一
鉄が有する脱臭力を充分に発揮でき、また食品等、色、
臭い、液性の変化が望ましくない場合にも充分に応用し
得るものである。The deodorizer of the present invention has an active ingredient, ferrous hexose phosphate, which is odorless, weakly acidic to neutral, and has an appearance ranging from pale bluish green to colorless and transparent, and is stable. It can fully demonstrate its deodorizing power, and also removes food, color,
It can also be fully applied to cases where odor or changes in liquid properties are undesirable.
次に実施例及び参考例を挙げ、本発明を更に詳しく説明
する。Next, the present invention will be explained in more detail with reference to Examples and Reference Examples.
参考例ｌ
Ｂａ（ＯＨ）２−８Ｈ２００，３１５ｆ（ＩＸＩＯ−３
モル）を精製水５０ｍに溶解し、この溶液にグルコース
−１−リン酸ゾカリウム塩０．５７Ｐ（ＩＸＩＯ−”モ
ル）水溶液５０―を加え、２５℃で３０分間攪拌した。Reference example l Ba(OH)2-8H200,315f(IXIO-3
mol) was dissolved in 50 ml of purified water, and to this solution was added 50 ml of an aqueous solution of 0.57 P (IXIO-'' mol) of zopotassium glucose-1-phosphate, and the mixture was stirred at 25°C for 30 minutes.
この溶液にＦｅＳＯ４・７Ｈ２００，２７８ｆ（ＩＸＩ
Ｏ−３モル）金加え２５℃で３０分間攪拌すると白色沈
澱を生成する。遠心分離によシ白色沈澱を除去すること
によシ、淡青緑透明なグルコース−１−リン醒第−鉄塩
水溶液を得た。Add FeSO4.7H200,278f (IXI
O-3 mol) Gold was added and stirred at 25°C for 30 minutes to form a white precipitate. By removing the white precipitate by centrifugation, a pale blue-green transparent glucose-1-phosphorous ferrous salt aqueous solution was obtained.
参考例２
Ｂａ （ＯＨ）２＠ ８ Ｈ２Ｏ０，３１５ｔ （Ｉ
Ｘ １０−”モル）を精製水５０ｍ７！に溶解し、リン
酸で中和した後にグルコース−１−リン酸ゾカリウム塩
０．５７９ （ＩＸＩＯ−”モル）水溶液５０−を加え
、２５℃で３０分間攪拌した。この溶液にＦｅ ＳＯ４
・７Ｈ２ｏ Ｏ，２７８ｔ（ＩＸＩＯ−３モル）を加
え更に２５℃で３０分間攪拌後、生成した白色沈澱を遠
心分離除去することによシ、無色・透明なグルコース−
１−リン酸第−鉄溶液を得た。Reference example 2 Ba (OH)2@8 H2O0,315t (I
Dissolve X 10-" mol) in 50 m7 of purified water, neutralize with phosphoric acid, add 50-" aqueous solution of zopotassium glucose-1-phosphate 0.579 (IXIO-" mol), and stir at 25°C for 30 minutes. Stirred. Add FeSO4 to this solution
・After adding 7H2O, 278t (IXIO-3 mol) and stirring at 25°C for 30 minutes, the white precipitate formed was removed by centrifugation, resulting in colorless and transparent glucose.
A 1-ferrous phosphate solution was obtained.
比較例
ＦｅＳＯ４・７Ｈｚ０ ０．２７８ｔ（ＩＸＩＯ−３
モル）を１００ｄの精製水に溶解させ、濃青緑色第一鉄
溶液を得た。Comparative example FeSO4・7Hz0 0.278t (IXIO-3
mol) was dissolved in 100 d of purified water to obtain a dark blue-green ferrous solution.
実施例
参考例１及び２並びに比較例で得た溶液をシャーレにそ
れぞれ２０１ｎｌ取り、脱臭剤とした。この中に２８％
アンモニア水を０．５−加え、脱臭能及び脱臭後の液性
の変化を評価した。この結果を第１表に示す。201 nl of each of the solutions obtained in Examples Reference Examples 1 and 2 and Comparative Example was placed in a petri dish and used as a deodorizer. 28% of this
Aqueous ammonia was added in an amount of 0.5 mm, and the deodorizing ability and change in liquid properties after deodorizing were evaluated. The results are shown in Table 1.
第１表
以上の結果から、本発明の脱臭剤は第一鉄を安定に保持
し、かつ充分なアンモニア脱臭能を有し、脱臭後も液性
は変化しない等、広範囲に応用し得ることが明らかとな
った。From the results shown in Table 1 and above, the deodorizer of the present invention stably retains ferrous iron, has sufficient ammonia deodorizing ability, and does not change its liquid properties even after deodorization, so it can be applied in a wide range of ways. It became clear.
以上that's all
Claims (1)
る脱臭剤。1. A deodorizer containing ferrous hexose phosphate as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62062075A JPS63229056A (en) | 1987-03-17 | 1987-03-17 | Deodorant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62062075A JPS63229056A (en) | 1987-03-17 | 1987-03-17 | Deodorant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63229056A true JPS63229056A (en) | 1988-09-22 |
Family
ID=13189594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62062075A Pending JPS63229056A (en) | 1987-03-17 | 1987-03-17 | Deodorant |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63229056A (en) |
-
1987
- 1987-03-17 JP JP62062075A patent/JPS63229056A/en active Pending
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