JPS63225557A - Production of composite optical parts - Google Patents

Production of composite optical parts

Info

Publication number
JPS63225557A
JPS63225557A JP5761887A JP5761887A JPS63225557A JP S63225557 A JPS63225557 A JP S63225557A JP 5761887 A JP5761887 A JP 5761887A JP 5761887 A JP5761887 A JP 5761887A JP S63225557 A JPS63225557 A JP S63225557A
Authority
JP
Japan
Prior art keywords
resin layer
resin
base material
glass base
mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5761887A
Other languages
Japanese (ja)
Other versions
JPH0645482B2 (en
Inventor
Toru Chiba
亨 千葉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pentax Corp
Original Assignee
Asahi Kogaku Kogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kogaku Kogyo Co Ltd filed Critical Asahi Kogaku Kogyo Co Ltd
Priority to JP62057618A priority Critical patent/JPH0645482B2/en
Publication of JPS63225557A publication Critical patent/JPS63225557A/en
Publication of JPH0645482B2 publication Critical patent/JPH0645482B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To form a composite optical parts in which peeling from a joined boundary face in a time of temp. change and breakage are not caused, by forming a ground face part to the side for forming a resin layer of a glass base material and bringing the resin layer into contact with this ground face part to mold it and intruding one part of the resin layer into the ground face part and joining them. CONSTITUTION:A composite optical parts 20 constituting of a glass base material 1 and a resin layer 2 is molded by interposing thermosetting resin (monomer layer 2A) between a metallic mold 10 and the glass base material 1 and forming (polymerization and curing of the monomer) the resin layer 2 on the surface of the glass base material 1 and thereafter mold-releasing it from the metallic mold 10. In this case, a ground face part 11A is formed to the side 11 for forming the resin layer of the glass base material 1 and the resin layer 2 is brought into contact with this ground part 11A and molded. As the resin material, resin having high transmittance of light and low curing shrinkage properties e.g. epoxy resin, polyester and styrene acrylonitrile, etc., are preferably used.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、ガラスと樹脂とにより構成される複合光学部
品の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for manufacturing a composite optical component made of glass and resin.

(従来技術) 従来、非球面レンズは、その光学的効果を評価されなが
らもガラスを直接非球面に加工することが困難な為量産
出来ず、特殊な用途に限定されていた。
(Prior Art) Conventionally, aspherical lenses have been highly evaluated for their optical effects, but because it is difficult to directly process glass into an aspherical surface, they cannot be mass-produced and have been limited to special uses.

そこで、レンズ素材を光学樹脂として金型を用いて成形
してbi産化することが行なわれ、  ているが、光学
樹脂のみによって形成されたレンズはia度変化によっ
て屈折率及び面の曲率半径が変化し、焦点距離やバック
フォーカスが狂ってしまうという欠点があった。
Therefore, the lens material is made of optical resin and molded using a mold to produce bi-products.However, lenses made only of optical resin have a change in refractive index and radius of curvature of the surface due to changes in the ia degree. The disadvantage was that the focal length and back focus would be distorted.

この為、ガラス基材をベースにして光学樹脂材料(光学
プラスチック素材)を一体に成形し、ガラス基材と光学
樹脂材料が接合されて所定レンズを構成する所謂ハイブ
リッド構成としたものが考えられ、製造されている。
For this reason, a so-called hybrid structure is considered in which an optical resin material (optical plastic material) is integrally molded using a glass base material as a base, and the glass base material and the optical resin material are bonded to form a predetermined lens. Manufactured.

しかし、樹脂層形成の際の重合収縮や、温度変化による
ガラスと樹脂との熱膨張率の違いから、その接合境界面
から剥離したり、ガラス及び光学樹脂に破損を生ずると
いう問題があった。
However, due to polymerization shrinkage during the formation of the resin layer and differences in thermal expansion coefficients between the glass and the resin due to temperature changes, there have been problems such as peeling from the bonding interface and damage to the glass and optical resin.

この問題を解決する為、ガラス基材の樹脂、  層形成
面に接着性を向上させるプライマーを塗布した後、熱膨
張率の差に対して追随性の良い軟質の光学樹脂を用いて
樹脂層を形成する方法や、更にその軟質の光学極脂上に
硬質の光学樹脂による保護層を形成して多層化複合レン
ズとする方法等が考えられている。
To solve this problem, after applying a primer that improves adhesion to the resin of the glass base material and the layer forming surface, we used a soft optical resin that can easily follow the difference in thermal expansion coefficient to form the resin layer. A method of forming a multilayer composite lens, and a method of forming a protective layer of a hard optical resin on the soft optical resin to form a multilayered composite lens, etc. are being considered.

(従来技術の問題点) しかし乍ら上記従来の構成に於いて、前者の方法では、
樹脂層の安定性が悪く光学性能の維持が難しい上、傷付
き易い為に取扱いに注意を必要とし、又、後者の方法は
、製造工程が複雑化する為生産性が悪く、製造コストが
増加するという問題点があった。
(Problems with the prior art) However, in the above conventional configuration, in the former method,
The stability of the resin layer makes it difficult to maintain optical performance, and it is easily scratched, so it requires careful handling, and the latter method complicates the manufacturing process, resulting in poor productivity and increased manufacturing costs. There was a problem with that.

(発明の目的) 本発明は、上記の如き事情に鑑み、製造工程を簡素化出
来ると共に温度変化によっても接合境界面からの剥離や
破損を発生することが無い複合光学部品の製造方法を提
供すること、をそめ目的とする。
(Object of the Invention) In view of the above-mentioned circumstances, the present invention provides a method for manufacturing a composite optical component that can simplify the manufacturing process and that does not cause peeling from the bonding interface or damage due to temperature changes. The purpose is to.

(問題点を解決する手段) この為1本発明に係る複合光学部品の製造方〃:に於て
は、ガラス基材の樹脂層形成側面      −にスリ
面部を形成し、樹脂層を該スリ面部に接触させて成形し
、樹脂層の一部をスリ部面に食込ませて接合させること
により樹脂層とガラス基材との接石強度の向上と温度変
化時の樹脂層の安定化を図るものである。
(Means for Solving the Problems) For this purpose, in 1. the method of manufacturing a composite optical component according to the present invention: a slotted surface portion is formed on the resin layer forming side surface of the glass substrate, and the resin layer is attached to the slotted surface portion. By molding the resin layer in contact with the glass substrate and by biting a part of the resin layer into the slit surface and joining them, the resin layer and the glass base material are bonded to each other to improve their contact strength and to stabilize the resin layer during temperature changes. It is something.

(実 施 例) 第1乃至3図は本発明に係る複合光学部品の#JJ造方
法の説明図であり、ガラス基材に非球面の樹脂層を形成
した非球面レンズを成形するものである。
(Example) Figures 1 to 3 are explanatory diagrams of the #JJ manufacturing method of a composite optical component according to the present invention, in which an aspherical lens is formed by forming an aspherical resin layer on a glass base material. .

以下、図面に基づいて説明する。The description will be given below based on the drawings.

lは光学ガラス材料により形成されたレンズ基材、2は
光学樹脂により成形された樹脂層、lOは非球面レンズ
の金型である。
1 is a lens base material formed from an optical glass material, 2 is a resin layer molded from an optical resin, and IO is a mold for an aspherical lens.

レンズ基材lには、その樹脂層形成側面11の光学的に
影響の無い周縁部をヤスリによって所定の荒さに加工し
たスリ面11Aがリング状に形成されている(第1図)
The lens base material l has a ring-shaped slender surface 11A formed by filing the optically unaffected peripheral edge of the resin layer forming side surface 11 to a predetermined roughness (FIG. 1).
.

金!a10には、成形するレンズの非球面をを取った型
面10Aが形成されている。
Money! A mold surface 10A is formed at a10, which is an aspherical surface of the lens to be molded.

そして、レンズ金型10の型面10Aに離型剤を塗布し
た後、該型面10Aに樹脂層形成側面11を対向させる
と共に所定間隔離してガラス基材lを固定し、レンズ金
型lOとガラス基材lとの間隙に七ツマ−を注入し。
After applying a mold release agent to the mold surface 10A of the lens mold 10, the glass base material 1 is fixed with the resin layer forming side surface 11 facing the mold surface 10A and separated by a predetermined distance. Inject 7-year-old powder into the gap with the glass base material 1.

モノブ一層2Aを形成する(第2図)、該モノ望一層2
Aは、レンズ基材1の樹脂層形成側面11のスリ面部1
1Aと所定の範囲で重合接触する充填範囲となるようは
予め設定されている。
Forming a monolayer 2A (FIG. 2), the monolayer 2
A is the slotted surface portion 1 of the resin layer forming side surface 11 of the lens base material 1
The filling range is set in advance so that polymerization contact with 1A occurs within a predetermined range.

七ツマ−142Aを形成した後、全体を所定温度で所定
時間加熱することにより七ツマ−を重合・硬化させる。
After forming the 7-summer 142A, the entire 7-summer is heated at a predetermined temperature for a predetermined time to polymerize and harden the 7-summer.

七ツマ−が完全に重合・硬化した後離型すると、ガラス
基材に非球面の樹脂層2を形成した複合光学部品である
非球面レンズ 20(第3図)が成形されるものである。
When the seven lenses are completely polymerized and cured and then released from the mold, an aspherical lens 20 (FIG. 3), which is a composite optical component in which an aspherical resin layer 2 is formed on a glass substrate, is molded.

尚、樹脂素材としては、光線透過率が高く且つ低硬化収
縮性の樹脂が望ましく、エポキシ樹脂、ポリエステル、
スチレンアクリルニトリル等が良い。
The resin material is preferably a resin with high light transmittance and low curing shrinkage, such as epoxy resin, polyester,
Styrene acrylonitrile etc. are good.

このようにして形成された非球面レンズ20は、ガラス
基材lの樹脂層形成側面11のスリ面部11Aに樹脂が
密渭して食込み、樹脂層2全体がガラス基材lに強固に
接合されるものである。
In the aspherical lens 20 formed in this way, the resin is densely packed into the slotted surface portion 11A of the resin layer forming side surface 11 of the glass base material l, and the entire resin layer 2 is firmly bonded to the glass base material l. It is something that

而して、上記の如き方法によって成形された非球面レン
ズ20を熱サイクル試験を行ない、従来の方法によって
同条件で成形されたレンズとの比較を行なった結果を第
5図に示す。
The aspherical lens 20 molded by the method described above was subjected to a thermal cycle test and compared with a lens molded by a conventional method under the same conditions. The results are shown in FIG.

図中Aは、本発明による複合光学部品の製造方法により
成形されたものであり、樹脂層ツマ−は、エポキシ樹脂
(エマーソン アンド カミング 株式会社製 5TY
CAS? 12B!9A)を用い、樹脂層2Aは、ガラ
ス基材lの樹脂層形成側面11の周縁部全周に形成され
たスリ面部11A全体に亙って接触させ、80℃で10
時間加熱して重合・硬化させたものである。
In the figure, A is molded by the method for manufacturing a composite optical component according to the present invention, and the resin layer is made of epoxy resin (manufactured by Emerson & Cumming Co., Ltd. 5TY).
CAS? 12B! 9A), the resin layer 2A was brought into contact with the entire slit surface 11A formed around the entire circumference of the resin layer forming side surface 11 of the glass substrate l, and heated at 80°C for 10 hours.
It is polymerized and hardened by heating for a period of time.

Bは、従来製法による比較例であり、ガラス基材lの樹
脂層形成側面11の周縁部にスリ面部11Aが形成され
ていない他、樹脂上ツマー1加熱条件共Aと全く同一条
件としたものである。
B is a comparative example using the conventional manufacturing method, in which the grooved surface portion 11A is not formed on the peripheral edge of the resin layer forming side surface 11 of the glass substrate l, and the heating conditions for the resin top 1 are exactly the same as in A. It is.

尚、離型剤も両者同一のものを使用した。The same mold release agent was used in both cases.

試験条件は、 熱サイクル試験!では、 +5℃(低温)で30分間、+23℃±2℃(室温)で
10分間、+60℃(高温)で30分間、のサイクルを
休み無く5サイクル。
The test conditions are heat cycle test! Then, we ran 5 cycles of 30 minutes at +5°C (low temperature), 10 minutes at +23°C ± 2°C (room temperature), and 30 minutes at +60°C (high temperature) without any breaks.

熟サイクル試験■では、 一40℃(低温)で30分間、+23℃±2℃(室温)
で10分間、+60℃で30分間、のサイクルを休み無
く5サイクル。
In the ripening cycle test ■, the temperature is -40°C (low temperature) for 30 minutes, and +23°C ± 2°C (room temperature).
5 cycles of 10 minutes at +60°C and 30 minutes without a break.

である。It is.

その結果、熱サイクル試験■に於て、比較例Bには接合
面の剥離及びクラックが発生したが、未発1j1に係る
製造方法によるAには、711#及びクラック等の欠陥
の発生は認られなかった。
As a result, in the thermal cycle test (■), peeling and cracking occurred on the joint surface in Comparative Example B, but no defects such as 711# and cracks were observed in A manufactured by the manufacturing method related to Unexploded 1j1. I couldn't.

一般的な実用レベルでは、熱サイクル試験!■相当の条
件で欠陥が生じないことが必要条件であり、従来の成形
方法による比較例Bではχ用化は困難であるが1本発明
の方法により成形されたAは十分実用に耐え得るとの結
論が得られたものである。
At a general practical level, thermal cycle testing! ■It is a necessary condition that no defects occur under appropriate conditions, and it is difficult to apply Comparative Example B using the conventional molding method, but A molded by the method of the present invention is sufficiently durable for practical use. The following conclusion was reached.

尚、上記実施例に於てスリ面部11Aの加工成形はヤス
リにより行なったが、サンドブラスト等地の如何なる方
法によって加工形成しても良いことは勿論である。
In the above embodiment, the shaving surface portion 11A was formed by filing, but it goes without saying that it may be formed by any other method such as sandblasting.

(発明の効果) 本発明に係る複合光学部品の製造方法に依れば、ガラス
基材の樹脂層形成側面に形成したスリ面部に樹脂層を接
触させて成形することとした為、スリ面部に樹脂が食込
んで強固に接合されて温度変化による剥離及びクラック
等不具合が発生せず実用的な複合光学部品が得られるも
のである。
(Effects of the Invention) According to the method for manufacturing a composite optical component according to the present invention, since the resin layer is molded in contact with the scraped surface portion formed on the resin layer forming side surface of the glass base material, the resin layer is molded in contact with the scraped surface portion. The resin penetrates and the bond is firmly bonded, and a practical composite optical component can be obtained without problems such as peeling or cracking due to temperature changes.

又・樹脂層は単層である為、製造行程が簡素化出来、製
造コストの低減が可能となる。
Additionally, since the resin layer is a single layer, the manufacturing process can be simplified and manufacturing costs can be reduced.

更に、樹脂層を形成する樹脂材料は軟質材料に限定され
ず、安定性、耐候性及び耐擦傷性等に優れた材料を適宜
用いることが可能となり、加工性の上で極めて有効であ
るばかりでなくレンズ設計の幅も広がるものである・
Furthermore, the resin material forming the resin layer is not limited to soft materials, and materials with excellent stability, weather resistance, and scratch resistance can be used as appropriate, which is extremely effective in terms of processability. This also expands the range of lens design.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明に係る複合光学部品の製造方法に於るガ
ラス基材の斜視図、第2図は製造方法の説明図、第3図
は複合光学部品の断面図、第41i4は熱サイクル試験
の結果を示す表である。 l・・・ガラス基材  2・・・樹脂層10・・・金型 11・・・樹脂層形成側面 11A・・・スリ面部 20・・・非球面レンズ(複合光学部品)第1図 第2図 第3因
FIG. 1 is a perspective view of a glass substrate in the method for manufacturing a composite optical component according to the present invention, FIG. 2 is an explanatory diagram of the manufacturing method, FIG. 3 is a cross-sectional view of the composite optical component, and 41i4 is a thermal cycle. This is a table showing the results of the test. l... Glass base material 2... Resin layer 10... Mold 11... Resin layer forming side surface 11A... Slotted surface portion 20... Aspherical lens (composite optical component) Fig. 1 Fig. 2 Figure 3rd factor

Claims (1)

【特許請求の範囲】 金型とガラス基材の間に硬化性樹脂を介 在させ、前記ガラス基材表面に樹脂層を形 成した後、前記金型から離型してガラス基 材と樹脂層とにより構成される複合光学部 品を成形する複合光学部品製造方法に於 て、前記ガラス基材の樹脂層形成側面にス リ面部を形成し、前記樹脂層を該スリ面部 に接触させて成形すること、を特徴とする 複合光学部品の製造方法。[Claims] A curable resin is interposed between the mold and the glass base material. and form a resin layer on the surface of the glass substrate. After forming, the mold is released from the mold and the glass base is removed. Composite optical section composed of material and resin layer In the method of manufacturing composite optical parts that molds products. Then, apply a strip onto the side surface of the glass substrate on which the resin layer will be formed. forming a scraped surface portion, and applying the resin layer to the scraped surface portion; characterized by being molded in contact with A method for manufacturing composite optical components.
JP62057618A 1987-03-12 1987-03-12 Manufacturing method of composite optical component Expired - Fee Related JPH0645482B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62057618A JPH0645482B2 (en) 1987-03-12 1987-03-12 Manufacturing method of composite optical component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62057618A JPH0645482B2 (en) 1987-03-12 1987-03-12 Manufacturing method of composite optical component

Publications (2)

Publication Number Publication Date
JPS63225557A true JPS63225557A (en) 1988-09-20
JPH0645482B2 JPH0645482B2 (en) 1994-06-15

Family

ID=13060864

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62057618A Expired - Fee Related JPH0645482B2 (en) 1987-03-12 1987-03-12 Manufacturing method of composite optical component

Country Status (1)

Country Link
JP (1) JPH0645482B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5400182A (en) * 1991-05-21 1995-03-21 Asahi Kogaku Kogyo Kabushiki Kaisha Composite glass and resin optical element with an aspheric surface

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6090851A (en) * 1983-10-24 1985-05-22 Canon Inc Manufacture of optical member

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6090851A (en) * 1983-10-24 1985-05-22 Canon Inc Manufacture of optical member

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5400182A (en) * 1991-05-21 1995-03-21 Asahi Kogaku Kogyo Kabushiki Kaisha Composite glass and resin optical element with an aspheric surface
US5643504A (en) * 1991-05-21 1997-07-01 Asahi Kogaku Kogyo Kabushiki Kaisha Method of making a composite glass and resin optical element with an aspheric surface

Also Published As

Publication number Publication date
JPH0645482B2 (en) 1994-06-15

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