JPS6321640B2 - - Google Patents
Info
- Publication number
- JPS6321640B2 JPS6321640B2 JP55060121A JP6012180A JPS6321640B2 JP S6321640 B2 JPS6321640 B2 JP S6321640B2 JP 55060121 A JP55060121 A JP 55060121A JP 6012180 A JP6012180 A JP 6012180A JP S6321640 B2 JPS6321640 B2 JP S6321640B2
- Authority
- JP
- Japan
- Prior art keywords
- adhesive layer
- transfer material
- transfer
- pattern
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012790 adhesive layer Substances 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 21
- 239000010410 layer Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 125000003700 epoxy group Chemical group 0.000 claims description 8
- 238000010894 electron beam technology Methods 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- 229920005992 thermoplastic resin Polymers 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- -1 polyethylene terephthalate Polymers 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000007756 gravure coating Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000012461 cellulose resin Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000010023 transfer printing Methods 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】
本発明は転写材及び転写方法に関するものであ
り、優れた効率で加熱の必要なしに紫外線照射又
は電子線照射によつて転写印刷を施すことを目的
とするものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a transfer material and a transfer method, and an object of the present invention is to perform transfer printing using ultraviolet irradiation or electron beam irradiation with excellent efficiency and without the need for heating. .
転写印刷方法は種々の形態、素材からなる対象
物に図柄を形成する方法として汎用されている印
刷技術である。転写材を被転写体に圧接するのみ
で図柄を転写するいわゆる加圧転写方法では転写
図柄の密着程度が不十分なため、従来はいわゆる
加熱加圧転写方法が主に用いられている。これは
感熱接着剤よりなる接着剤層を構成した転写シー
トを接着剤層が接するように被転写体表面に載置
し、基体シート側より加熱ロール等を用いて加熱
し、熱伝導により接着剤層に接着性を与えた被転
写体に接着せしめる方法であり、容易に転写でき
るため、大量生産するのに適しており多く採用さ
れている方法である。しかしながらこの方法は次
のような欠点を有している。即ち(1)基体シート側
より加熱し、接着剤層に接着性を付与するのに時
間がかかる。(2)加熱は被転写体にも及ぶためプラ
スチツク成型品等の熱変形し易い非耐熱性基材に
対しては適用できない、という欠点があつた。 The transfer printing method is a widely used printing technique for forming designs on objects made of various shapes and materials. Conventionally, the so-called heat-pressure transfer method has been mainly used because the degree of adhesion of the transferred design is insufficient in the so-called pressure transfer method in which a pattern is transferred by simply pressing a transfer material against a transfer target. In this method, a transfer sheet with an adhesive layer made of heat-sensitive adhesive is placed on the surface of the object to be transferred so that the adhesive layer is in contact with the transfer sheet, and heated from the base sheet side using a heating roll, etc., and the adhesive is This is a method in which the layer is adhered to a transfer target with adhesive properties, and because it can be easily transferred, it is suitable for mass production and is often adopted. However, this method has the following drawbacks. That is, (1) it takes time to heat from the base sheet side and impart adhesiveness to the adhesive layer. (2) Since the heating also extends to the object to be transferred, there is a drawback that it cannot be applied to non-heat-resistant substrates that are easily deformed by heat, such as plastic molded products.
本発明者らは以上のような従来の加熱加圧転写
方法の欠点を解消せんとし、種々考察研究の結
果、本発明を完成するに至つたものである。 The present inventors sought to solve the above-mentioned drawbacks of the conventional heat-pressure transfer method, and as a result of various studies and studies, they have completed the present invention.
即ち本発明は剥離性を有する基体シート上に図
柄層・接着剤層等を有する転写材において、エポ
キシ基を有するプレポリマー或いはオリゴマー、
アリルジアゾニウム系触媒、熱可塑性樹脂並びに
有機溶剤とからなる組成物で接着剤層を形成した
ことを特徴とする転写材および前記転写材の接着
剤層側に紫外線照射又は電子線照射を施した後速
やかに被転写体表面に加圧転写して完全に接着層
を完全硬化させることを特徴とする転写方法であ
る。 That is, the present invention provides a transfer material having a pattern layer, an adhesive layer, etc. on a releasable base sheet, which uses a prepolymer or oligomer having an epoxy group,
A transfer material characterized in that an adhesive layer is formed of a composition comprising an allyldiazonium catalyst, a thermoplastic resin, and an organic solvent, and after the adhesive layer side of the transfer material is irradiated with ultraviolet rays or electron beams. This transfer method is characterized in that the adhesive layer is quickly and completely cured by pressure transfer onto the surface of the transfer target.
以下本発明にかかる転写材及び転写方法につい
て更に詳しく説明する。 The transfer material and transfer method according to the present invention will be explained in more detail below.
まず、本発明にかかる転写材は剥離性を有する
基体シート、図柄層及び接着剤層より構成され
る。剥離性を有する基体シートにはポリエチレン
テレフタレートフイルム、ポリプロピレンフイル
ム、ポリエチレンフイルム、ナイロン等にアクリ
ル、ポリオレフイン系の樹脂、塩化ビニル、酢酸
ビニル等の層を形成して離型処理を施したものを
用いる。形成手段としては例えばグラビアコート
方法、ロールコート方法による。尚、該層は転写
後、転写図柄より剥離してもよく、又は剥離後も
転写図柄上に残存してもよい。又、必要に応じて
前記基体シートの背面にも離型処理を施してもよ
い。 First, the transfer material according to the present invention is composed of a releasable base sheet, a pattern layer, and an adhesive layer. The base sheet having releasability is made of polyethylene terephthalate film, polypropylene film, polyethylene film, nylon, etc., on which a layer of acrylic, polyolefin resin, vinyl chloride, vinyl acetate, etc. is formed and then subjected to mold release treatment. As a forming means, for example, a gravure coating method or a roll coating method is used. The layer may be peeled off from the transferred pattern after the transfer, or may remain on the transferred pattern even after the layer is peeled off. Furthermore, if necessary, the back surface of the base sheet may also be subjected to mold release treatment.
前記剥離性を有する基体シート上に図柄層が通
常のインキにてオフセツト、グラビア、スクリー
ン印刷方法等により形成される。 A pattern layer is formed on the releasable base sheet using conventional ink by offset, gravure, screen printing, or the like.
図柄層上に接着剤層が形成される。接着剤層は
エポキシ基をもつプレポリマー或いはオリゴマ
ー、アリルジアゾニウム系触媒、熱可塑性樹脂並
びに有機溶剤とからなる組成物を用いてグラビア
コート方法、ロールコート方法等によつて形成さ
れる。エポキシ基を有するプレポリマー或いはオ
リゴマーとしては、光によつて分解してルイス酸
を発生する化合物を光開始剤としてエポキシ化合
物を開環重合させる組成物、等がある。又、熱可
塑性樹脂としてはアクリル、塩化ビニル等を使用
する。有機溶剤としてはトロール、酢酸エチル、
メチルエチルケトン等がある。又、本発明にかか
る転写材は前記図柄層と接着剤層とが一体的に形
成されてもよい。この場合、転写材は次のように
構成される。即ち前記と同様の剥離性を有する基
体シート上に図柄層を設け、エポキシ基をもつプ
レポリマー或いはオリゴマー、アリルジアゾニウ
ム系触媒、熱可塑性樹脂並びに有機溶剤とからな
る組成物をバインダーとして用いることにより図
柄層と接着剤層とが一体的である転写材がある。 An adhesive layer is formed on the pattern layer. The adhesive layer is formed by a gravure coating method, a roll coating method, etc. using a composition comprising a prepolymer or oligomer having an epoxy group, an allyldiazonium catalyst, a thermoplastic resin, and an organic solvent. Examples of prepolymers or oligomers having epoxy groups include compositions in which an epoxy compound is subjected to ring-opening polymerization using a photoinitiator that is a compound that generates a Lewis acid when decomposed by light. Further, as the thermoplastic resin, acrylic, vinyl chloride, etc. are used. Organic solvents include trol, ethyl acetate,
Examples include methyl ethyl ketone. Further, in the transfer material according to the present invention, the pattern layer and the adhesive layer may be integrally formed. In this case, the transfer material is configured as follows. That is, a pattern layer is provided on a base sheet having removability similar to that described above, and a pattern is formed by using a composition consisting of a prepolymer or oligomer having an epoxy group, an allyldiazonium catalyst, a thermoplastic resin, and an organic solvent as a binder. There are transfer materials in which the layer and the adhesive layer are integral.
次に本発明にかかる転写方法について説明す
る。 Next, the transfer method according to the present invention will be explained.
まず前記転写材の接着剤層側に紫外線照射又は
電子線照射を施す。この照射処理によつて接着剤
層中のアリルジアゾニウム系触媒は分解し、ルイ
ス酸を生成せしめ、エポキシ基を重合せしめる。
照射後速やかに、好ましくは10秒以内に、該転写
材を用いて被転写体上に加圧転写する。接着剤層
はその組成からある程度の接着力を有しているか
ら、図柄層と共に被転写体表面へ転写される。加
圧転写後放置することにより前記重合反応が進行
し、図柄の皮膜形成が三次元架橋構造の形成によ
り大きな凝集力を得ることができる。その結果、
図柄は強固な密着性を帯びるため堅固な転写図柄
が得られる。 First, the adhesive layer side of the transfer material is irradiated with ultraviolet rays or electron beams. By this irradiation treatment, the allyldiazonium catalyst in the adhesive layer is decomposed, producing a Lewis acid and polymerizing the epoxy group.
Immediately after irradiation, preferably within 10 seconds, the transfer material is used to perform pressure transfer onto the object to be transferred. Since the adhesive layer has a certain degree of adhesive force due to its composition, it is transferred to the surface of the object to be transferred together with the pattern layer. By allowing the image to stand after being transferred under pressure, the polymerization reaction proceeds, and the formation of a three-dimensional crosslinked structure allows the formation of a patterned film to have a large cohesive force. the result,
Since the design has strong adhesion, a solid transferred design can be obtained.
本発明は以上のような転写材及び転写方法であ
るから、本発明を適用することにより加熱の必要
なしに紫外線照射又は電子線照射によつて堅固な
図柄を転写することができる。従つて非常に速く
転写することができ、又非耐熱性基材のプラスチ
ツク成型品等へも基材表面を損なうことなく転写
することができるものである。更に加熱の必要が
ないことから、一般に加熱転写方法よりも経費を
軽減することを可能にするものである。 Since the present invention provides a transfer material and a transfer method as described above, by applying the present invention, a solid pattern can be transferred by ultraviolet irradiation or electron beam irradiation without the need for heating. Therefore, it can be transferred very quickly, and it can also be transferred to non-heat resistant substrates such as plastic molded products without damaging the surface of the substrate. Furthermore, since no heating is required, it generally allows for lower costs than thermal transfer methods.
以下本発明の実施例について説明する。 Examples of the present invention will be described below.
実施例 １
アクリル系樹脂を塗布して剥離性を付与したポ
リプロピレンシート上にグラビア印刷方法にて図
柄層を形成した。その上に下記の組成物を用いて
グラビアコート方法により接着剤層を形成した。Example 1 A pattern layer was formed by a gravure printing method on a polypropylene sheet coated with an acrylic resin to impart releasability. An adhesive layer was formed thereon by a gravure coating method using the following composition.
エポキシ樹脂アデカウルトラセツトＢ−
6136J
分子量350〜400（旭電化工業(株)製） 100部
アリルジアゾニウム系触媒溶液PP−33
（旭電化工業(株)製） ３部
熱可塑性塩化ビニル酢酸ビニル共重合体
（電気化学工業(株)製） 60部
メチルエチルケトン 10部
酢酸エチル 10部
以上のようにして得られた転写材の接着剤層側
に、高圧水銀灯2kw、２灯のランプを用いて紫外
線照射を、照射間距離10cm、照射時間0.2秒間の
条件で施した。その直後にプラスチツク容器へ該
転写材を用いて加圧転写を行い、基体シートを剥
離した後、放置すると約10分後密着性の堅固な図
柄が形成された。Epoxy resin ADEKA ULTRASET B-
6136J Molecular weight 350-400 (manufactured by Asahi Denka Kogyo Co., Ltd.) 100 parts Allyldiazonium catalyst solution PP-33 (manufactured by Asahi Denka Kogyo Co., Ltd.) 3 parts Thermoplastic vinyl chloride vinyl acetate copolymer (Denki Kagaku Kogyo Co., Ltd.) ) 60 parts Methyl ethyl ketone 10 parts Ethyl acetate 10 parts The adhesive layer side of the transfer material obtained as above was irradiated with ultraviolet rays using two 2kw high-pressure mercury lamps at a distance of 10 cm between irradiations. It was applied for a time of 0.2 seconds. Immediately thereafter, pressurized transfer was performed using the transfer material onto a plastic container, and after peeling off the base sheet, a firm and adhesive pattern was formed after about 10 minutes when left to stand.
実施例 ２
背面にシリコン樹脂を用いて離型処理を施した
ポリエチレンテレフタレートフイルム上に繊維素
系樹脂の層を形成し、その上に下記の組成分をバ
インダーとして通常インキに練り込んだインキを
用いて図柄層をグラビア印刷方法で形成した。Example 2 A layer of cellulose resin was formed on a polyethylene terephthalate film that had been subjected to mold release treatment using silicone resin on the back side, and on top of that a layer of cellulose resin was used as a binder, ink mixed with normal ink. A pattern layer was formed using a gravure printing method.
アデカウルトラセツトADX−800
分子量350〜400（旭電化工業(株)製）70部
エピコート 827 分子量360
（schell chew製） 30部
アリルジアゾニウム触媒溶液PP−33
（旭電化工業(株)製） ３部
熱可塑アクリル樹脂ダイヤナール
（三菱レーヨン(株)製） 50部
トルエン 20部
酢酸エチル 20部
以上のようにして得られた転写材の図柄層側
に、加速電圧275kv、電子線電流45mA、処理量
5Mradの条件で電子線照射を施した。その直後
にプラスチツク容器へ該転写材を用いて加圧転写
を行い、基体シートを剥離した後、放置すると実
施例１と同様に密着性の堅固な図柄が形成され
た。 ADEKA ULTRASET ADX-800 Molecular weight 350-400 (manufactured by Asahi Denka Kogyo Co., Ltd.) 70 parts Epicote 827 Molecular weight 360 (manufactured by Schell Chew) 30 parts Allyldiazonium catalyst solution PP-33 (manufactured by Asahi Denka Kogyo Co., Ltd.) 3 parts Thermoplastic acrylic resin Dianal (manufactured by Mitsubishi Rayon Co., Ltd.) 50 parts Toluene 20 parts Ethyl acetate 20 parts Accelerating voltage 275 kV, electron beam current 45 mA, processing amount
Electron beam irradiation was performed under the condition of 5 Mrad. Immediately thereafter, pressure transfer was performed using the transfer material onto a plastic container, and after peeling off the base sheet, when left to stand, a pattern with firm adhesion was formed as in Example 1.
Claims (1)
剤層等を有する転写材において、エポキシ基を有
するプレポリマー或いはオリゴマー、アリルジア
ゾニウム系触媒、熱可塑性樹脂並びに有機溶剤と
からなる組成物で接着剤層を形成したことを特徴
とする転写材。 ２ 接着剤層がエポキシ基を有するプレポリマー
或いはオリゴマー、アリルジアゾニウム系触媒、
熱可塑性樹脂並びに有機溶剤にとからなる組成物
と、着色剤とを含み、パターン化して形成される
ことによつて図柄層を不要とした特許請求の範囲
第１項に記載の転写材。 ３ 剥離性を有する基体シート上に図柄層を設
け、その上にエポキシ基を有するプレポリマー或
いはオリゴマー、アリルジアゾニウム系触媒、熱
可塑性樹脂並びに有機溶剤とからなる組成物で形
成した接着剤層を設けた転写材の接着剤層側に紫
外線照射又は電子線照射を施した後速やかに被転
写体表面に加圧転写して完全に接着層を完全硬化
させることを特徴とする転写方法。[Scope of Claims] 1. A transfer material having a pattern layer, an adhesive layer, etc. on a releasable base sheet, which is made from a prepolymer or oligomer having an epoxy group, an allyldiazonium catalyst, a thermoplastic resin, and an organic solvent. 1. A transfer material comprising an adhesive layer formed of a composition. 2 Prepolymer or oligomer whose adhesive layer has an epoxy group, allyldiazonium catalyst,
The transfer material according to claim 1, which includes a composition consisting of a thermoplastic resin and an organic solvent, and a colorant, and is formed in a pattern, thereby eliminating the need for a pattern layer. 3 A pattern layer is provided on a base sheet having peelability, and an adhesive layer formed from a composition consisting of a prepolymer or oligomer having an epoxy group, an allyldiazonium catalyst, a thermoplastic resin, and an organic solvent is provided on top of the pattern layer. A transfer method characterized by applying ultraviolet ray irradiation or electron beam irradiation to the adhesive layer side of a transfer material, and then immediately transferring the adhesive layer under pressure to the surface of an object to be transferred to completely cure the adhesive layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6012180A JPS56155789A (en) | 1980-05-06 | 1980-05-06 | Transferring material and transferring method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6012180A JPS56155789A (en) | 1980-05-06 | 1980-05-06 | Transferring material and transferring method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56155789A JPS56155789A (en) | 1981-12-02 |
| JPS6321640B2 true JPS6321640B2 (en) | 1988-05-09 |
Family
ID=13132968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6012180A Granted JPS56155789A (en) | 1980-05-06 | 1980-05-06 | Transferring material and transferring method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56155789A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111674187A (en) * | 2020-06-17 | 2020-09-18 | 深圳市祥晖光电有限公司 | Method for forming metal luster on transparent film |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0153904B1 (en) * | 1984-02-10 | 1988-09-14 | Ciba-Geigy Ag | Process for the preparation of a protection layer or a relief pattern |
| JP5322566B2 (en) * | 2008-09-30 | 2013-10-23 | 日本写真印刷株式会社 | Coating film adhesive film, in-mold coated product manufacturing method and in-mold coated product |
| CN101856922A (en) * | 2009-04-07 | 2010-10-13 | 唐玉和 | UV paint interlayer transfer wood grain and pattern process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS556515A (en) * | 1978-06-26 | 1980-01-18 | Teijin Ltd | Arranged net like fiber sheet and method |
| JPS56148580A (en) * | 1980-04-22 | 1981-11-18 | Nissha Printing Co Ltd | Transfer printing method |
-
1980
- 1980-05-06 JP JP6012180A patent/JPS56155789A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS556515A (en) * | 1978-06-26 | 1980-01-18 | Teijin Ltd | Arranged net like fiber sheet and method |
| JPS56148580A (en) * | 1980-04-22 | 1981-11-18 | Nissha Printing Co Ltd | Transfer printing method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111674187A (en) * | 2020-06-17 | 2020-09-18 | 深圳市祥晖光电有限公司 | Method for forming metal luster on transparent film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56155789A (en) | 1981-12-02 |
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