JPS63216205A - Electrically insulating oil - Google Patents
Electrically insulating oilInfo
- Publication number
- JPS63216205A JPS63216205A JP4799687A JP4799687A JPS63216205A JP S63216205 A JPS63216205 A JP S63216205A JP 4799687 A JP4799687 A JP 4799687A JP 4799687 A JP4799687 A JP 4799687A JP S63216205 A JPS63216205 A JP S63216205A
- Authority
- JP
- Japan
- Prior art keywords
- insulating oil
- electrical insulating
- electrical
- phenyl
- properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010735 electrical insulating oil Substances 0.000 claims description 43
- -1 ethylphenyl group Chemical group 0.000 claims description 13
- SZFDQMKAGLCYPA-UHFFFAOYSA-N 1-phenylbutylbenzene Chemical group C=1C=CC=CC=1C(CCC)C1=CC=CC=C1 SZFDQMKAGLCYPA-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- POLZFQOQKPVJGZ-UHFFFAOYSA-N 1-methyl-2-(1-phenylbutyl)benzene Chemical group C=1C=CC=C(C)C=1C(CCC)C1=CC=CC=C1 POLZFQOQKPVJGZ-UHFFFAOYSA-N 0.000 claims description 3
- AFOYJWZLSSXZNG-UHFFFAOYSA-N 1-phenylhexan-3-ylbenzene Chemical group C=1C=CC=CC=1C(CCC)CCC1=CC=CC=C1 AFOYJWZLSSXZNG-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 27
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 11
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 10
- 238000005259 measurement Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 6
- 230000015556 catabolic process Effects 0.000 description 6
- VUKHQPGJNTXTPY-NSCUHMNNSA-N [(e)-but-2-enyl]benzene Chemical compound C\C=C\CC1=CC=CC=C1 VUKHQPGJNTXTPY-NSCUHMNNSA-N 0.000 description 5
- 231100000209 biodegradability test Toxicity 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- LMTFUUMABUOYMU-UHFFFAOYSA-N 1-methyl-2-(3-phenylbutyl)benzene Chemical compound CC(CCc1ccccc1C)c1ccccc1 LMTFUUMABUOYMU-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- FLWSNJAEMMOZJG-UHFFFAOYSA-N 1,2-dimethyl-4-(1-phenylethyl)benzene Chemical compound C=1C=C(C)C(C)=CC=1C(C)C1=CC=CC=C1 FLWSNJAEMMOZJG-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- PWCCCKCWHBGNOZ-UHFFFAOYSA-N 1-but-2-enyl-2-methylbenzene Chemical compound CC=CCC1=CC=CC=C1C PWCCCKCWHBGNOZ-UHFFFAOYSA-N 0.000 description 1
- RQWZADNHCAQPBD-UHFFFAOYSA-N 1-ethyl-2-(3-phenylbutyl)benzene Chemical compound CCc1ccccc1CCC(C)c1ccccc1 RQWZADNHCAQPBD-UHFFFAOYSA-N 0.000 description 1
- XJGHNXQUBBXYCH-UHFFFAOYSA-N 1-phenylbutan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(CC)CC1=CC=CC=C1 XJGHNXQUBBXYCH-UHFFFAOYSA-N 0.000 description 1
- SGQUHMXHLSTYIH-UHFFFAOYSA-N 2-phenylbutan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(CC)C1=CC=CC=C1 SGQUHMXHLSTYIH-UHFFFAOYSA-N 0.000 description 1
- DPGRSARQZDBXTN-UHFFFAOYSA-N C(C)C1(CC=CC=C1)CCC(C)C1=CC=CC=C1 Chemical compound C(C)C1(CC=CC=C1)CCC(C)C1=CC=CC=C1 DPGRSARQZDBXTN-UHFFFAOYSA-N 0.000 description 1
- IWUBJKJMNCJELQ-UHFFFAOYSA-N C1(=C(C=CC=C1)CC(CC)C1=CC=CC=C1)C Chemical compound C1(=C(C=CC=C1)CC(CC)C1=CC=CC=C1)C IWUBJKJMNCJELQ-UHFFFAOYSA-N 0.000 description 1
- JHJXGDYOIUXZTK-UHFFFAOYSA-N C1(=CC=CC=C1)C1(C(C=CC=C1)CC)CCCC Chemical compound C1(=CC=CC=C1)C1(C(C=CC=C1)CC)CCCC JHJXGDYOIUXZTK-UHFFFAOYSA-N 0.000 description 1
- LSIMIYRKMNOUKL-UHFFFAOYSA-N C1(=CC=CC=C1)C1(C(C=CC=C1)CCCC)C Chemical compound C1(=CC=CC=C1)C1(C(C=CC=C1)CCCC)C LSIMIYRKMNOUKL-UHFFFAOYSA-N 0.000 description 1
- VHPKQVQHTRMUSB-UHFFFAOYSA-N C1(=CC=CC=C1)C1(CC(=CC=C1)CCCC)C Chemical compound C1(=CC=CC=C1)C1(CC(=CC=C1)CCCC)C VHPKQVQHTRMUSB-UHFFFAOYSA-N 0.000 description 1
- OPNXYFCCTGLPIS-UHFFFAOYSA-N C1(=CC=CC=C1)C1(CC=C(C=C1)CCCC)C Chemical compound C1(=CC=CC=C1)C1(CC=C(C=C1)CCCC)C OPNXYFCCTGLPIS-UHFFFAOYSA-N 0.000 description 1
- BNQLQFAIXQBPFN-UHFFFAOYSA-N CCC(CC1(CC)C=CC=CC1)C1=CC=CC=C1 Chemical compound CCC(CC1(CC)C=CC=CC1)C1=CC=CC=C1 BNQLQFAIXQBPFN-UHFFFAOYSA-N 0.000 description 1
- DLSXTNFSPMZJLN-UHFFFAOYSA-N CCCCC1(CC(=CC=C1)CC)C2=CC=CC=C2 Chemical compound CCCCC1(CC(=CC=C1)CC)C2=CC=CC=C2 DLSXTNFSPMZJLN-UHFFFAOYSA-N 0.000 description 1
- VWZUXBWFJSZFAF-UHFFFAOYSA-N CCCCC1(CC=C(C=C1)CC)C2=CC=CC=C2 Chemical compound CCCCC1(CC=C(C=C1)CC)C2=CC=CC=C2 VWZUXBWFJSZFAF-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Insulating Materials (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
主咀ム技血分舅
本発明は、新規な電気絶縁油に関し、さらに詳しくは特
定の構造を有するジアリールブタンの１種または２粍以
上からなる電気特性、無臭性および生分解性に優れた電
気絶縁油に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a novel electrical insulating oil, and more particularly to a novel electrical insulating oil that has electrical properties, odorless properties, and is composed of one or more diarylbutanes having a specific structure. Concerning electrical insulating oil with excellent biodegradability.
の ・０背−ｔらびに の０Ｑ 。・0 back-t and 0Q.
電気絶縁油は、変圧器用、遮断器用、コンデンサー用お
よびケーブル用の４つの用途に主として用いられている
。そして近年電力需要の増大に伴い、これら電気機器の
超高圧化および大容量化が要望されており、それに伴っ
て電気絶縁油の電気特性についてもより高度な性能が求
められている。Electrical insulating oils are mainly used in four applications: transformers, circuit breakers, capacitors, and cables. In recent years, as the demand for electric power has increased, there has been a demand for ultra-high voltage and large-capacity electrical equipment, and accordingly, electrical properties of electrical insulating oil are also required to have more advanced performance.
−ｍに電気絶縁油としては、（ａ）絶縁破壊電圧が高い
こと、（ｂ）誘電損失が小さいこと、（Ｃ）誘電率が高
いことなどの優れた電気特性を有することが求められて
いるほか、（ｄ）沸点が高く不揮発性で引火点が高いこ
と、（ｅ）低温流動性が良いこと、（ｆ）毒性がなく生
分解性が良いこと、（ｑ）臭気が少ないこと、（ｈ）
Ｎ４熱性に優れていること、（ｉ）安価であることなど
の特性を有することが求められている。As an electrical insulating oil, it is required to have excellent electrical properties such as (a) high dielectric breakdown voltage, (b) low dielectric loss, and (C) high dielectric constant. In addition, (d) it has a high boiling point, is nonvolatile, and has a high flash point, (e) it has good low-temperature fluidity, (f) it is non-toxic and has good biodegradability, (q) it has little odor, and (h) )
It is required to have characteristics such as excellent N4 thermal properties and (i) low cost.
このような電気絶縁油としては、従来ナフテン系および
パラフィン系の鉱油類、ポリブテン類、アルキルベンゼ
ン類、アルキルナフタレン類、アルキルジフェニル類、
ジアリールアルケン類、トリアリールアルカン類、シリ
コーン油類またはジアリールエタンおよびジアリールプ
ロパン類などが用いられているが、いずれも上記の諸条
件をすべて満足させるものは得られていなかった。Conventional electrical insulating oils include naphthenic and paraffinic mineral oils, polybutenes, alkylbenzenes, alkylnaphthalenes, alkyldiphenyls,
Diarylalkenes, triarylalkanes, silicone oils, diarylethanes, diarylpropanes, and the like have been used, but none of them have been able to satisfy all of the above conditions.
またジアリールエタンおよびジアリールプロパン類以外
のジアリールアルカンを電気絶縁油として使用すること
に関しても、従来種々の提案がなされており、たとえば
特開昭５５−４１６６７号公報、同５５−８８２０５号
公報、同５６−３６８０５号公報、同５６−１６５２０
５号公報および同５９−５１４０７号公報などに開示さ
れている。しかしながら上記の公報には、ジアリールア
ルカンのみからなる電気絶縁油は開示されておらず、ジ
アリールアルカンと他の電気絶縁油との混合物からなる
電気絶縁油が開示されているか、あるいは電気絶縁油に
ジアリールアルカンを少量漏油検出用標識ｅｌ雪として
添加してなる電気絶縁油が開示されているのみである。Furthermore, various proposals have been made regarding the use of diaryl alkanes other than diarylethanes and diarylpropanes as electrical insulating oils, such as JP-A-55-41667, JP-A-55-88205, and JP-A-56. -36805 Publication, 56-16520
It is disclosed in Publication No. 5 and Publication No. 59-51407. However, the above-mentioned publication does not disclose an electrical insulating oil made only of diaryl alkane, but discloses an electrical insulating oil made of a mixture of diaryl alkane and other electrical insulating oil, or an electrical insulating oil containing diaryl alkane. Only an electrical insulating oil in which an alkane is added as a label for detecting a small amount of oil leakage is disclosed.
また上記の公報に開示された電気絶縁油としてのジアリ
ールアルカン類は、その絶縁破壊電圧、体積抵抗率、誘
電正接および誘電率などの電気特性が劣っていなり、臭
気が強かったり、あるいは生分解性に劣るなどの問題点
があった。Furthermore, the diarylalkanes used as electrical insulating oils disclosed in the above-mentioned publications have poor electrical properties such as breakdown voltage, volume resistivity, dielectric loss tangent, and dielectric constant, have a strong odor, or are biodegradable. There were problems such as inferiority.
本発明者らはこのような問題点を解決するた°め、種々
のジアリールアルカンについてその電気絶縁油として求
められる特性を改良すべく研究を進めた結果、従来のジ
アリールアルカン類と比較して、ジアリールブタンの１
種または２種以上からなる電気絶縁油は、電気特性に優
れ、臭気が少なくがつ生分解性に優れていることを見出
して、本発明を完成するに至った。In order to solve these problems, the present inventors conducted research to improve the characteristics required for electrical insulating oils for various diaryl alkanes.As a result, compared to conventional diaryl alkanes, diarylbutane 1
The present invention was completed based on the discovery that an electrical insulating oil consisting of one or more species has excellent electrical properties, low odor, and excellent biodegradability.
灸呵例且」
本発明は、上記のような従来技術に伴う問題点を解決し
ようとするものであって、電気絶縁油として求められる
要件を満すとともに、とくに電気特性に優れ、臭気が少
なくかつ生分解性にも優れているような電気絶縁油を提
供することを目的としている。The present invention is an attempt to solve the problems associated with the conventional technology as described above, and it satisfies the requirements for an electrical insulating oil, has particularly excellent electrical properties, and has low odor. The purpose of the present invention is to provide an electrical insulating oil that also has excellent biodegradability.
及盟凶奥Ｘ
本発明に係る電気絶縁油は、下記の一爪式で表わされる
ジアリールブタンの１種または２種以上からなることを
特徴としている。The electrical insulating oil according to the present invention is characterized by comprising one or more diarylbutanes represented by the following formula.
Ｒ２ＨＨＩ−１
上記−最式中Ｒ１、Ｒ２、Ｒ３、Ｒ４およびＲ５はそれ
ぞれ水素原子、フェニル基、トリル基またはエチルフェ
ニル基であり、Ｒ１、Ｒ２、Ｒ、ＲおよびＲ５のうち水
素以外の合計置換基数は２であり、そのうちの少なくと
も１つはフェニル基である。R2HHI-1 In the above formula, R1, R2, R3, R4, and R5 are each a hydrogen atom, phenyl group, tolyl group, or ethylphenyl group, and the total substitution other than hydrogen among R1, R2, R, R, and R5 The number of bases is 2, at least one of which is a phenyl group.
＾咀ム且体調肌朋
以下本発明に係る電気絶縁油について具体的に説明する
。The electrical insulating oil according to the present invention will be explained in detail below.
本発明に係る電気絶縁油は、ジアリールブタンの１８ま
たは２種以上からなっているが、ジアリールブタンの具
体例は次のとおりである。The electrical insulating oil according to the present invention consists of 18 or more types of diarylbutanes, and specific examples of diarylbutanes are as follows.
１．１−ジフェニルブタン、１，２−ジフェニルブタン
、１．３−ジフェニルブタン、１．４−ジフェニルブタ
ン、１−フェニル−１−トリルブタン、１−フェニル−
２−トリルブタン、１−フェニル−３−トリルブタン、
１−フェニル−４−トリルブタン、１−トリル−２−フ
ェニルブタン、１−トリル−３−フェニルブタン、２−
トリル−３−フェニルブタン、１−フェニル−１−エチ
ルフェニルブタン、１−フェニル−２−エチルフェニル
ブタン、１−フェニル−３−エチルフェニルブタン、１
−フェニル−４−エチルフェニルブタン、１−エチルフ
ェニル−２−フェニルブタン、１−エチルフェニル−３
−フェニルブタン、２−エチルフェニル−３−フェニル
ブタン。1.1-diphenylbutane, 1,2-diphenylbutane, 1.3-diphenylbutane, 1.4-diphenylbutane, 1-phenyl-1-tolylbutane, 1-phenyl-
2-tolylbutane, 1-phenyl-3-tolylbutane,
1-phenyl-4-tolylbutane, 1-tolyl-2-phenylbutane, 1-tolyl-3-phenylbutane, 2-
Tolyl-3-phenylbutane, 1-phenyl-1-ethylphenylbutane, 1-phenyl-2-ethylphenylbutane, 1-phenyl-3-ethylphenylbutane, 1
-Phenyl-4-ethylphenylbutane, 1-ethylphenyl-2-phenylbutane, 1-ethylphenyl-3
-phenylbutane, 2-ethylphenyl-3-phenylbutane.
電気絶縁油を構成するジアリールブタンは、上記のよう
なジアリールブタンが単独で用いられてもよく、また混
合物として用いられてもよい。The diarylbutanes constituting the electrical insulating oil may be used alone or as a mixture.
このようなジアリールブタンは、たとえばハロゲン化ア
ルミニウム触媒存在下に、ベンゼン、トルエンまたはエ
チルベンゼンと１−フェニル−２−ブテンとを反応させ
ることにより製造することができる。またベンゼンと１
−トリル−２−ブテンまたは１−エチルフェニル−２−
ブテンとを反応させることにより製造することもできる
。Such diarylbutane can be produced, for example, by reacting benzene, toluene or ethylbenzene with 1-phenyl-2-butene in the presence of an aluminum halide catalyst. Also benzene and 1
-tolyl-2-butene or 1-ethylphenyl-2-
It can also be produced by reacting with butene.
触媒として用いられるハロゲン化アルミニウムとしては
、具体的には、ＡＩ ＣＩ ３ 、ＡＩ Ｂｒ ３、Ａ
Ｉ Ｉ３ 、Ａｔ Ｆ３などが用いられるが、このう
ちＡｌＣｌ３が好ましい。Specifically, the aluminum halide used as a catalyst includes AI CI 3 , AI Br 3 , A
I I3 , At F3, etc. are used, and among these, AlCl3 is preferred.
触媒としてのハロゲン化アルミニウムは、それ自体で使
用しても良いが、有機ニトロ化合物、エステル、エーテ
ル、ケトン、メチルベンゼンなどと錯体化して使用する
こともできる。Aluminum halide as a catalyst may be used by itself, but it can also be used in a complex with an organic nitro compound, ester, ether, ketone, methylbenzene, or the like.
また別法として既知の製造方法である硫酸の存在下にて
ベンゼン、トルエンおよび／またはエチルベンゼンとｎ
−ブチルアルデヒドとの縮合により製造することもでき
る。Alternatively, in the presence of sulfuric acid, benzene, toluene and/or ethylbenzene and n
-It can also be produced by condensation with butyraldehyde.
本発明の電気絶縁油は、電気特性に優れ、臭気が少なく
かつ生分解性に優れている。The electrical insulating oil of the present invention has excellent electrical properties, low odor, and excellent biodegradability.
また本発明に係る電気絶縁油は、単独でも通常の電気絶
縁油に要求される各扛性状とともに、電気特性、無臭性
および生分解性にとくに優れた性状を兼ね備えているが
、必要に応じて公知のフェノール系、硫黄系およびリン
系の酸化防止剤あるいはリン酸エステル系化合物、エポ
キシ化合物等からなる難燃性付与剤等を添加することも
できる。In addition, the electrical insulating oil according to the present invention has particularly excellent electrical properties, odorless properties, and biodegradability in addition to the properties required for ordinary electrical insulating oils when used alone. It is also possible to add flame retardant agents such as known phenol-based, sulfur-based, and phosphorus-based antioxidants, phosphoric acid ester compounds, and epoxy compounds.
さらに本発明に係る電気絶縁油に、鉱油系絶縁油、ポリ
ブテン、アルキルベンゼン系絶縁油や他の芳香族系絶縁
油等の電気特性改質剤を混合して使用することもできる
。Further, the electrical insulating oil according to the present invention may be mixed with an electrical property modifier such as mineral oil-based insulating oil, polybutene, alkylbenzene-based insulating oil, or other aromatic insulating oil.
一最に、鉱油系絶縁油は絶縁破壊電圧を向上させ、ポリ
ブテンは体積抵抗率および誘電正接を改善し、アルキル
ベンゼン系絶縁油および他の芳香族系絶縁油は絶縁破壊
電圧、誘電正接および流動点などを向上させるがいずれ
も誘電率を低下させることが知られている。First, mineral oil-based insulating oils improve breakdown voltage, polybutene improves volume resistivity and dissipation factor, and alkylbenzene-based insulating oils and other aromatic insulating oils improve breakdown voltage, dissipation tangent, and pour point. It is known that both of them reduce the dielectric constant.
乃皿凶効ヌ
本発明に係る電気絶縁油は、絶縁破壊電圧、体積抵抗率
、および誘電率が高く、誘電損失が小さいという優れた
電気特性を有するとともに、臭気が少なくかつ生分解性
に優れている。The electrical insulating oil according to the present invention has excellent electrical properties such as high dielectric breakdown voltage, high volume resistivity, high permittivity, and low dielectric loss, as well as low odor and excellent biodegradability. ing.
そのうえ、高沸点であり、流動性が良好でありかつ低粘
度であるという優れた諸性質を有する。Moreover, it has excellent properties such as a high boiling point, good fluidity, and low viscosity.
以下本発明を実施例により説明するが、本発明はこれら
実施例に限定されるものではない。EXAMPLES The present invention will be explained below with reference to Examples, but the present invention is not limited to these Examples.
なお実施例中の％は重量基準である。Note that the percentages in the examples are based on weight.
失旌然１
撹拌機つきの容量２Ｍのガラス反応器に、ベンゼン１０
モルと無水塩化アルミニウム０．１モルを入れて撹拌し
ながら内部温度を１０℃に保った。Failure 1 10 benzene was added to a 2M glass reactor equipped with a stirrer.
mol and 0.1 mol of anhydrous aluminum chloride were added thereto, and the internal temperature was maintained at 10°C while stirring.
ここへ１−フェニル−２−ブテン０．５モルとベンゼン
２モルの混合液を連続的に４時間にわたり滴下して反応
させた。混合液滴下終了後も撹拌しながら２０分間温度
を１０℃に保っな。その後撹拌を止め、反応生成物を分
離回収しカセイソーダ水溶液で洗浄中和し、硫酸ソーダ
上で乾燥した。さらに減圧蒸留を行い得られた無色透明
な留分を活性白土処理して精製し、ジフェニルブタン３
６８ミリモルを得た。得られたジフェニルブタンの異性
体組成は１．１一体２４％、１．２一体２５％、１，３
一体５１％であった。１−フェニル−２−ブテンの転化
率は１００％であり、１−フェニル−２−ブテン基準の
収率は７３．６％であった。A mixed solution of 0.5 mol of 1-phenyl-2-butene and 2 mol of benzene was continuously added dropwise thereto over 4 hours to cause a reaction. Even after dropping the mixture, maintain the temperature at 10°C for 20 minutes while stirring. Thereafter, stirring was stopped, and the reaction product was separated and collected, washed and neutralized with an aqueous solution of caustic soda, and dried over sodium sulfate. Further, the colorless and transparent fraction obtained by vacuum distillation was purified by activated clay treatment, and diphenylbutane 3
68 mmol was obtained. The isomer composition of the obtained diphenylbutane is 1.1 24%, 1.2 25%, 1,3
The total was 51%. The conversion rate of 1-phenyl-2-butene was 100%, and the yield based on 1-phenyl-2-butene was 73.6%.
このようにして得られた電気絶縁油の一最性状を調べる
ため、比重、沸点、流動点、粘度などの物性測定を行っ
た。結果を表１に示す。In order to investigate the properties of the electrical insulating oil thus obtained, physical properties such as specific gravity, boiling point, pour point, and viscosity were measured. The results are shown in Table 1.
また得られた電気絶縁油を用い、電気特性を調べるため
常法に従って絶縁破壊電圧、体積抵抗率、誘電正接、誘
電率を測定した。結果を表１に示す。Further, using the obtained electrical insulating oil, the dielectric breakdown voltage, volume resistivity, dielectric loss tangent, and dielectric constant were measured according to conventional methods in order to investigate the electrical properties. The results are shown in Table 1.
また得られた電気絶縁油の臭気試験を行うため、該電気
絶縁油を３０名の試験者にかがせて臭いを判定した。そ
の結果を表１に示す。Furthermore, in order to perform an odor test on the obtained electrical insulating oil, 30 testers were asked to expose the electrical insulating oil to the odor and judge the odor. The results are shown in Table 1.
得られた電気絶縁油の生分解性を調べるため、以下のよ
うな生分解性試験を行った。容量５００ｍｌの振盪フラ
スコに基礎培養基を１００ｍ１とり、この基礎培養基に
電気絶縁油を２００ ｐｐｍとなるように添加した。次
に活性汚泥を懸濁物質濃度が１００ ｐｉ）ｍとなるよ
うに添加した。フラスコは綿栓し、振盪培養器（三田村
理研製）で２５±１℃に保ちながら２週間培養しな。培
養後、振盪フラスコより電気絶縁油を抽出し、ガスクロ
マトグラフで生分解率を求めた。結果を表１に示す。In order to examine the biodegradability of the obtained electrical insulating oil, the following biodegradability test was conducted. 100 ml of basic culture medium was placed in a shaking flask with a capacity of 500 ml, and electrical insulating oil was added to this basic culture medium at a concentration of 200 ppm. Next, activated sludge was added so that the suspended solids concentration was 100 pi)m. The flask was plugged with cotton and cultured for 2 weeks while keeping it at 25±1°C in a shaking incubator (manufactured by Mitamura Riken). After culturing, electrical insulating oil was extracted from the shaking flask, and the biodegradation rate was determined using a gas chromatograph. The results are shown in Table 1.
夫施医ス
実施例１において、ベンゼンに代えてトルエンを用いた
以外は、実施例１と同様にしてフェニルトリルブタン３
８６ミリモルを得た。この異性体組成は１，１一体１３
％、１，２一体４５％、１．３一体４２％であった。１
−フェニル−２−ブテンの転化率は１００％であり、同
基準の収率は７７．２％であった。Phenyltolylbutane 3 was prepared in the same manner as in Example 1, except that toluene was used instead of benzene.
86 mmol was obtained. This isomer composition is 1,1 monolithic 13
%, 45% for 1,2 and 42% for 1.3. 1
The conversion rate of -phenyl-2-butene was 100%, and the yield based on the same standard was 77.2%.
実施例１と同様にして、得られた電気絶縁油の物性測定
、電気特性測定、臭気試験および生分解性試験を行った
。結果を表１に示す。In the same manner as in Example 1, the obtained electrical insulating oil was subjected to physical property measurements, electrical property measurements, odor tests, and biodegradability tests. The results are shown in Table 1.
丈施躬ユ
実施例１において、ベンゼンに代えてエチルベンゼンを
用いた以外は、実施例１と同様にしてフェニルエチルフ
ェニルブタン３９５ミリモルを得た。この異性体組成は
１．１一体６％、１，２一体３５％、１．３一体５９％
であった。１−フェニル−２−ブテンの転化率は１００
％であり、同基準の収率は７９．０％であった。395 mmol of phenylethyl phenylbutane was obtained in the same manner as in Example 1, except that ethylbenzene was used instead of benzene. The isomer composition is 6% of 1.1, 35% of 1,2, and 59% of 1.3.
Met. The conversion rate of 1-phenyl-2-butene is 100
%, and the yield based on the same standard was 79.0%.
実施例１と同様にして、得られた電気絶縁油の物性測定
、電気特性測定、臭気試験および生分解性試験を行った
。結果を表１に示す。In the same manner as in Example 1, the obtained electrical insulating oil was subjected to physical property measurements, electrical property measurements, odor tests, and biodegradability tests. The results are shown in Table 1.
夾施拠Ａ
撹拌機つきの容量１ｇのガラス反応器に、９４％硫酸２
．０モルを入れ、ベンゼン０．４モルおよびｎ−ブチル
アルデヒド０．０７モルの混合物を１５℃で３分間撹拌
しながら連続的に少しずつ入れた後、内容物の温度を一
１０°Ｃに冷却して保持し、撹拌しながらｎ−ブチルア
ルデヒド０．６３モルとベンゼン３．６０モルの混合物
を４時間にわたり少量ずつ連続して滴下して反応させた
。この間、反応系のｎ−ブチルアルデヒドの濃度は０．
５％以下であった。滴下終了後も一１０℃で３０分間撹
拌を続けた。その後、撹拌を止め、反応器を静置し反応
生成物を分離回収し、炭酸ソーダ水溶液で洗浄中和し、
塩化マグネシウムで乾燥した。Container A: 94% sulfuric acid 2 was added to a glass reactor with a capacity of 1 g equipped with a stirrer.
．． A mixture of 0.4 mol of benzene and 0.07 mol of n-butyraldehyde was continuously added little by little while stirring at 15°C for 3 minutes, and then the temperature of the contents was cooled to -10°C. While stirring, a mixture of 0.63 mol of n-butyraldehyde and 3.60 mol of benzene was continuously added dropwise little by little over 4 hours to react. During this time, the concentration of n-butyraldehyde in the reaction system was 0.
It was less than 5%. After the dropwise addition was completed, stirring was continued for 30 minutes at -10°C. After that, stirring was stopped, the reactor was left standing, the reaction products were separated and recovered, and washed and neutralized with an aqueous solution of sodium carbonate.
Dry with magnesium chloride.
さらに減圧蒸留を行い、得られた無色透明な留分を活性
白土処理して精製することにより１，１−ジフェニルブ
タンを収率９０％（ｎ−ブチルアルデヒド基準）で得た
。Further vacuum distillation was performed, and the resulting colorless and transparent fraction was purified by treatment with activated clay to obtain 1,1-diphenylbutane in a yield of 90% (based on n-butyraldehyde).
実施例１と同様にして得られた電気絶縁油の物性測定、
電気特性測定、臭気試験および生分解性試験を行った。Measurement of physical properties of electrical insulating oil obtained in the same manner as in Example 1,
Electrical property measurements, odor tests and biodegradability tests were conducted.
結果を表１に示す。The results are shown in Table 1.
ル救剖
電気絶縁油として１−フェニル−１−（３，４−ジメチ
ルフェニル）エタンを用いて実施例１と同様にして物性
測定、電気特性測定、臭気試験および生分解性試験を行
った。結果を表１に示す。Physical property measurements, electrical property measurements, odor tests, and biodegradability tests were conducted in the same manner as in Example 1 using 1-phenyl-1-(3,4-dimethylphenyl)ethane as the electrical insulating oil. The results are shown in Table 1.
この表１より、本発明に係る電気絶縁油は、電気特性に
優れ、臭気が少なくがっ生分解性にも優れていることが
わかる。From Table 1, it can be seen that the electrical insulating oil according to the present invention has excellent electrical properties, low odor, and excellent biodegradability.
Claims (4)
種または２種以上からなる電気絶縁油。 ▲数式、化学式、表等があります▼ ［式中Ｒ＾１、Ｒ＾２、Ｒ＾３、Ｒ＾４およびＲ＾５は
それぞれ水素原子、フェニル基、トリル基またはエチル
フェニル基であり、Ｒ＾１、Ｒ＾２、Ｒ＾３、Ｒ＾４お
よびＲ＾５のうち水素以外の合計置換基数は２であり、
かつそのうちの少なくとも１つはフェニル基である。］(1) 1 of diarylbutane represented by the general formula below
Electrical insulating oil consisting of one species or two or more species. ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [In the formula, R^1, R^2, R^3, R^4 and R^5 are each a hydrogen atom, phenyl group, tolyl group or ethylphenyl group, and R The total number of substituents other than hydrogen among ^1, R^2, R^3, R^4 and R^5 is 2,
and at least one of them is a phenyl group. ]
る特許請求の範囲第１項に記載の電気絶縁油。(2) The electrical insulating oil according to claim 1, wherein the diarylbutane is diphenylbutane.
である特許請求の範囲第１項に記載の電気絶縁油。(3) The electrical insulating oil according to claim 1, wherein the diarylbutane is phenyltolylbutane.
ルブタンである特許請求の範囲第１項に記載の電気絶縁
油。(4) The electrical insulating oil according to claim 1, wherein the diarylbutane is phenylethyl phenylbutane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4799687A JPH088016B2 (en) | 1987-03-03 | 1987-03-03 | Electrical insulating oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4799687A JPH088016B2 (en) | 1987-03-03 | 1987-03-03 | Electrical insulating oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63216205A true JPS63216205A (en) | 1988-09-08 |
| JPH088016B2 JPH088016B2 (en) | 1996-01-29 |
Family
ID=12790926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4799687A Expired - Lifetime JPH088016B2 (en) | 1987-03-03 | 1987-03-03 | Electrical insulating oil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH088016B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2016167176A1 (en) * | 2015-04-13 | 2017-12-07 | ライオン・スペシャリティ・ケミカルズ株式会社 | Electrical insulating oil base oil for oil-filled electrical equipment, electrical insulating oil containing the same, and oil-filled electrical equipment |
-
1987
- 1987-03-03 JP JP4799687A patent/JPH088016B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2016167176A1 (en) * | 2015-04-13 | 2017-12-07 | ライオン・スペシャリティ・ケミカルズ株式会社 | Electrical insulating oil base oil for oil-filled electrical equipment, electrical insulating oil containing the same, and oil-filled electrical equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH088016B2 (en) | 1996-01-29 |
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