JPS63208511A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JPS63208511A JPS63208511A JP3861887A JP3861887A JPS63208511A JP S63208511 A JPS63208511 A JP S63208511A JP 3861887 A JP3861887 A JP 3861887A JP 3861887 A JP3861887 A JP 3861887A JP S63208511 A JPS63208511 A JP S63208511A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- coating
- fine particulate
- silicon dioxide
- spherical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000003921 oil Substances 0.000 claims abstract description 9
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 239000004677 Nylon Substances 0.000 claims abstract description 3
- 239000004698 Polyethylene Substances 0.000 claims abstract description 3
- 229920001778 nylon Polymers 0.000 claims abstract description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 3
- 239000010419 fine particle Substances 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 12
- 239000011324 bead Substances 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000005204 segregation Methods 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 description 8
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 4
- 229940032094 squalane Drugs 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- CUPCBVUMRUSXIU-UHFFFAOYSA-N [Fe].OOO Chemical compound [Fe].OOO CUPCBVUMRUSXIU-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000008406 cosmetic ingredient Substances 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229960004887 ferric hydroxide Drugs 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 description 1
- 229910021519 iron(III) oxide-hydroxide Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〈発明の属する分野の説明〉
本発明は、微細球状の二酸化珪素および／または含水二
酸化珪素、 （以下これらを総称して シリカビーズと
云う、）の表面に微粒子二酸化チタンをコーティング処
理し、さらに その表面に微粒子酸化鉄またはタール系
色素をコーティング処理し、更にオイルにて処理して得
られる。DETAILED DESCRIPTION OF THE INVENTION <Description of the Field to which the Invention Pertains> The present invention provides a method for forming fine particles of titanium dioxide on the surface of fine spherical silicon dioxide and/or hydrous silicon dioxide (hereinafter collectively referred to as silica beads). It is obtained by coating the surface, coating the surface with fine particles of iron oxide or tar-based pigment, and then treating with oil.
多層コーテイング物を配合した化粧料、特にメークアッ
プ化粧料に間するもので、その目的とするところは、皮
膚に対する塗布性を円滑にし、皮膚への馴染みがよく、
くすみにくく、何等かの弊害を有することのない 優れ
た化粧料を提供することにある。Cosmetics containing multilayer coatings, especially makeup cosmetics, are intended for smooth application to the skin, good familiarity with the skin,
Our goal is to provide excellent cosmetics that are resistant to dullness and have no harmful effects.
〈従来の技術の説明〉
従来メークアップ化粧料の粉体としては、タルク、カオ
リン、酸化鉄、酸化チタン、セリサイト微結晶セルロー
ス等の種々の粉体が、汎用されていた。しかし、これら
の粉体の粒子は通常はとんどの物が不定形を有するため
、実際の化粧料に配合して皮膚へ塗布した場合、伸びの
重さ、くすみやすさ、色むらを生じ所望する使用感に限
度が有るという欠点があった。<Description of Prior Art> Conventionally, various powders such as talc, kaolin, iron oxide, titanium oxide, sericite, and microcrystalline cellulose have been widely used as powders for makeup cosmetics. However, most of these powder particles usually have an amorphous shape, so when they are blended into actual cosmetics and applied to the skin, they tend to spread hard, become dull, and have uneven color, making it difficult to achieve the desired results. The disadvantage is that there is a limit to the usability.
最近、この様な点を解消すべく特開昭５４−５５７３９
において、粒径０． ５〜３０μの球状無水珪酸を配合
した固形おしろい、特開昭５６−６８６０４ におい
て、粒径０． ５〜３０μの球状二酸化珪素に高分子物
質をコーティング処理したものが、開示されているが、
これらは単一原料または単層コーティング処理であり、
化粧料にする場合は、数種類の粉体を混合しなければな
らないので、伸びの重さ、くすみやすさ、色むらにおい
て、限度が有り、メイクアップ化粧料の皮膚への伸び、
くすみやすさ、色むらにおいては、充分でないといわれ
ている。Recently, in order to solve this problem, Japanese Patent Application Laid-Open No. 54-55739
, the particle size is 0. A solid powder containing spherical silicic anhydride of 5 to 30 microns, disclosed in Japanese Patent Application Laid-Open No. 56-68604, has a particle size of 0. It has been disclosed that spherical silicon dioxide of 5 to 30 μm is coated with a polymeric substance.
These are single raw material or single layer coating process,
When making cosmetics, it is necessary to mix several types of powder, so there are limits in terms of spreadability, dullness, and color unevenness.
It is said that it is not sufficient in terms of dullness and uneven color.
〈発明の構成及び作用の説明〉
本発明者は、上記の如き欠点を解決すべく種々実験研究
した結果、ついに望むべき本発明を見出すに至った。<Description of Structure and Effects of the Invention> As a result of various experimental studies aimed at solving the above-mentioned drawbacks, the present inventor has finally found the desired present invention.
図１を用いて、発明の構成及び作用について説明する。The configuration and operation of the invention will be explained using FIG. 1.
Ａはζ シリカビーズであり、粒径０．１〜３０μｍＢ
は、微粒子酸化チタンで 粒径０．０２〜１μｍＣは、
微粒子酸化鉄であり粒径０．０２〜２．０μｍ酸化鉄と
して、三二酸化鉄、オキシ水酸化鉄、水酸化第二鉄、四
三酸化鉄などがあり、また、フタロシアニンブルー、ヘ
リンドンピンクなどのタール系色素でもよい。A is ζ silica beads, particle size 0.1-30μmB
is fine particle titanium oxide, and the particle size is 0.02 to 1 μm.
Iron oxide particles with a particle size of 0.02 to 2.0 μm include iron sesquioxide, iron oxyhydroxide, ferric hydroxide, and triiron tetroxide, as well as phthalocyanine blue, herringdon pink, etc. A tar-based pigment may also be used.
Ａの部分のシリカビーズは、有機粉末（ポリメチルメタ
アクリレート・ナイロン・ポリエチレン・スチレン）な
どでもよく、シリカビーズにオイル（炭化水素類・エス
テル類・アルコール類脂肪酸類・シリコン類・油脂類）
をコーティング処理してもよい、また、Ｃの処理を行っ
てから、オイルにてコーティング処理を行ってもよい。The silica beads in part A may be organic powders (polymethyl methacrylate, nylon, polyethylene, styrene), etc., or the silica beads can be coated with oil (hydrocarbons, esters, alcohols, fatty acids, silicones, fats and oils).
Alternatively, after the C treatment, a coating treatment with oil may be performed.
コーティング組成物を得る方法は種々あるが、本発明に
おいては、メカノケミカル法を用いた。Although there are various methods for obtaining the coating composition, a mechanochemical method was used in the present invention.
詳しくは、上記に示すＡ及びＢから選ばれた各１種を、
室温で７２時閏混合する０次に、Ｃから選ばれた１種と
オイルを添加し、更に室温で７２時閏混合する工程にて
目的とするコーティング組成物を得る。Specifically, one type each selected from A and B shown above,
Next, one selected from C and an oil are added, and further mixed at room temperature for 72 hours to obtain the desired coating composition.
ここで用いるオイルとは、化粧品に常用されるオイル類
から選ばれた１種で有り、流動パラフィン、スクワラン
、オリーブ油、ラノリン、イソステアリン酸、シリコン
油等が挙げられる。The oil used here is one selected from oils commonly used in cosmetics, and includes liquid paraffin, squalane, olive oil, lanolin, isostearic acid, silicone oil, and the like.
この様にして得たコーティング組成物は、物理的に弱く
結び付いているのではなく、コーテイング材の薄い膜が
シリカビーズ表面を完全に被覆し、強固に、密着してい
るため、単一体となって挙動するもので、これを化粧料
成分中に配合しても全く分離すると云うことがない。The coating composition obtained in this way is not physically weakly bound, but the thin film of the coating material completely covers the surface of the silica beads, and is firmly and tightly adhered, so it becomes a single body. Therefore, even if it is blended into cosmetic ingredients, it will not separate at all.
さらに、透明感が有り、色わかれなく、くすみにくく、
肌への馴染みがよいという特性を持つ。In addition, it has a sense of transparency, does not fade, and is resistant to dullness.
It has the characteristic of being easily absorbed into the skin.
以下、実験例及び実施例を挙げて更に詳しく説明する０
本発明は、これにより限定されるものではない。The following is a more detailed explanation using experimental examples and examples.
The present invention is not limited thereby.
くくすみテスト〉
本発明を、評価するｋめにくすみテストを行った。
実験方法としては、プラスチック板にサンプルを塗布し
、その上から皮脂を噴霧し色調の変化を測定した。Dullness Test> To evaluate the present invention, a dullness test was conducted.
The experimental method involved applying a sample to a plastic plate, spraying sebum onto it, and measuring the change in color tone.
結果を、表１に示す。The results are shown in Table 1.
これにより、実施例は比較例と比べ顕著にくすみにくい
ことがわかった。比較例は実施例と同一組成で、多層コ
ーティング処理していない従来の粉体を用いた。As a result, it was found that the examples were significantly less dull than the comparative examples. In the comparative example, a conventional powder having the same composition as the example and not subjected to multilayer coating was used.
（以下余白）
く官能テスト〉
官能テストは、専門パネル５名を以て行い、表２の官能
プロファイルにその評価結果を示す。(Left below) Sensory test> The sensory test was conducted by a panel of five experts, and the evaluation results are shown in the sensory profile in Table 2.
評価は後記実施例３の処方中より本発明コーティング組
成物を除き、該コーティング組成物と同−組成で、多層
コーティング処理していない粉体に置き換えた従来のパ
ウダーファンデーション（サンプルＡ）と、本発明の後
記実施例３のパウダーファンデーション（サンプルＢ）
を比較して行った。The evaluation was conducted using a conventional powder foundation (Sample A) in which the coating composition of the present invention was removed from the formulation in Example 3 described later, and replaced with a powder having the same composition as the coating composition but not subjected to multilayer coating treatment, and a powder foundation of the present invention. Powder foundation of Example 3 (Sample B) of the invention described later
I did a comparison.
表２官能プロファイル
く製造例１〉
シリカマイクロビードＰ−１５００（触媒化成工業株式
会社製、シリカビーズ ０．５〜３０μ）１０００ｇに
酸化チタン６００Ｂ （帝国化工株式会社製、微粒子酸
化チタン）２５０ｇを加え、ボールミルにて７２時閏室
温下で混練する０次に、ＴＲ−２０（三菱金属株式会社
製、三二酸化鉄）１９０ｇとイソステアリン酸（日産化
学株式会社製）５ｇを加え、７２時間室温下で混練し本
発明のコーティング組成物１４４５ｇを得た。 （サン
プルｌ）
く製造例２〉
シリカマイクロと一ドＰ−１５００ （触媒化成工業株
式会社製、シリカビーズ ０．５〜３０μ：１０００ｇ
にスクワラン（日光ケミカルズ株式会社＆Ｉ）ｌｏｇを
加え、ライカイ機にて５時間室温下にて混練する０次に
、酸化チタンＭ７５００Ｂ（帝国加工株式会社１り２５
０ｇを加えジェットミルにて、１時間室温下で混練する
０次に、青色４０４号（東洋インキ株式会社製）４０ｇ
を加え、１時間室温下で混練し、本発明のコーティング
組成物１４００ｇを得た。 （サンプル２）〈実施例１
〉 リップスティック（重量部）Ｃ香料
０． ５（製法）
上記処方組成物Ａを加熱混合溶解し、これにＢ。Table 2 Functional Profile Production Example 1> Add 250 g of titanium oxide 600B (manufactured by Teikoku Kako Co., Ltd., fine particle titanium oxide) to 1000 g of Silica Microbeads P-1500 (manufactured by Catalysts Kasei Kogyo Co., Ltd., silica beads 0.5 to 30μ). Next, 190 g of TR-20 (manufactured by Mitsubishi Metals Corporation, iron sesquioxide) and 5 g of isostearic acid (manufactured by Nissan Chemical Co., Ltd.) were kneaded in a ball mill at 72 hours at room temperature, and the mixture was kneaded at room temperature for 72 hours. After kneading, 1445 g of the coating composition of the present invention was obtained. (Sample 1) Production Example 2> Silica Micro Todo P-1500 (manufactured by Catalysts & Chemicals Co., Ltd., silica beads 0.5-30μ: 1000g
Squalane (Nikko Chemicals Co., Ltd. & I) was added to the mixture and kneaded at room temperature for 5 hours using a Raikai machine. Next, titanium oxide M7500B (Teikoku Kako Co., Ltd.)
Add 0g and knead with a jet mill at room temperature for 1 hour. Next, add 40g of Blue No. 404 (manufactured by Toyo Ink Co., Ltd.)
was added and kneaded for 1 hour at room temperature to obtain 1400 g of the coating composition of the present invention. (Sample 2) <Example 1
〉 Lipstick (weight part) C fragrance
0. 5 (Manufacturing method) The above prescription composition A is heated and mixed and dissolved, and B is added to this.
Ｃを加えて分散混合する。減圧脱気後、所定の容器に充
填し、冷却してリップスティックを得た。Add C and disperse and mix. After degassing under reduced pressure, it was filled into a predetermined container and cooled to obtain a lipstick.
〈実施例２〉アイカラー （重量部）／Ｊ 酸
化チタン ７．０・ ベンガラ
４．０１−合成雲母
３３．ＯＢ スクワラン ４．０１
−ステアリン酸７グネシウム ２・ ＯＣ，： 本
発明コーティング組成物
Ｌ （サンプル２） １０．０（製法）
上記処方組成物Ａ、 Ｃを、ヘンシェルミキサーにて
低速混合５分間行い、次にＢを加え更にヘンシェルミキ
サーにて低速混合５分間を行う。ついで、アトマイザ−
により粉砕し、ふるい処理して圧縮成形により中皿中に
成形してアイカラーを得た。<Example 2> Eye color (parts by weight)/J Titanium oxide 7.0/Red iron
4.01-Synthetic mica
33. OB Squalane 4.01
-7gnesium stearate 2.OC,: Coating composition L of the present invention (Sample 2) 10.0 (Production method) The above formulation compositions A and C were mixed at low speed in a Henschel mixer for 5 minutes, and then B was added. Further, low speed mixing is performed for 5 minutes using a Henschel mixer. Next, the atomizer
The eye color was crushed, sieved and molded into a medium tray by compression molding.
〈実施例３〉パウダーファンデーション（重量部）Ｂ
スクワラン ８． ０Ｌ（サンプル１
） ７０．０（製法）
実施例２と同様に製造して、パウダーファンデーション
を得た。<Example 3> Powder foundation (parts by weight) B
Squalane 8. 0L (sample 1
) 70.0 (Manufacturing method) A powder foundation was obtained by manufacturing in the same manner as in Example 2.
第１図は、本発明の多層コーティング処理球状粉体の断
面図である。
Ａ： シリカビーズ
Ｂ：微粒子酸化チタン
Ｃ：微粒子酸化鉄またはタール系色素
第２図は、本発明の多層コーティング処理球状粉体（平
均粒子径３μｍ）の電子顕微鏡写真（倍率１５０００倍
）である。FIG. 1 is a cross-sectional view of the multilayer coated spherical powder of the present invention. A: Silica beads B: Particulate titanium oxide C: Particulate iron oxide or tar pigment Figure 2 is an electron micrograph (magnification: 15,000 times) of the multilayer coating treated spherical powder (average particle diameter 3 μm) of the present invention.
Claims (2)
水二酸化珪素、有機粉末の一種または二種以上に、微粒
子二酸化チタンをコーティング処理し、さらにその表面
に微粒子酸化鉄または、タール系色素をコーティング処
理して、さらにオイルにて処理した多層コーティング処
理球状粉体を配合することを特徴とする化粧料。(1) One or more types of fine spherical silicon dioxide, hydrous silicon dioxide, and organic powder with a particle size of 0.5 to 30μ are coated with fine particles of titanium dioxide, and the surface is further coated with fine particles of iron oxide or tar-based A cosmetic product characterized by containing multilayer coated spherical powder coated with pigment and further treated with oil.
ン、ポリエチレン、スチレン等の一種または二種以上で
ある特許請求の範囲第一項記載の化粧料。(2) The cosmetic according to claim 1, wherein the organic powder is one or more of polymethyl methacrylate, nylon, polyethylene, styrene, etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3861887A JPS63208511A (en) | 1987-02-20 | 1987-02-20 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3861887A JPS63208511A (en) | 1987-02-20 | 1987-02-20 | Cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63208511A true JPS63208511A (en) | 1988-08-30 |
Family
ID=12530233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3861887A Pending JPS63208511A (en) | 1987-02-20 | 1987-02-20 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63208511A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100411204B1 (en) * | 2001-02-28 | 2003-12-18 | 주식회사 태평양 | Method for preparing double silica titania complex powders having an excellent scattered reflection effect |
| KR100441272B1 (en) * | 1999-05-12 | 2004-07-21 | 한국화장품주식회사 | Ball-shaped powder cosmetics and preparation thereof |
| KR100442808B1 (en) * | 2001-06-18 | 2004-08-04 | 주식회사 엘지생활건강 | The inorganic pigment treated with complex coating on a mica substrate |
-
1987
- 1987-02-20 JP JP3861887A patent/JPS63208511A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100441272B1 (en) * | 1999-05-12 | 2004-07-21 | 한국화장품주식회사 | Ball-shaped powder cosmetics and preparation thereof |
| KR100411204B1 (en) * | 2001-02-28 | 2003-12-18 | 주식회사 태평양 | Method for preparing double silica titania complex powders having an excellent scattered reflection effect |
| KR100442808B1 (en) * | 2001-06-18 | 2004-08-04 | 주식회사 엘지생활건강 | The inorganic pigment treated with complex coating on a mica substrate |
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