JPS63207494A - Flux for zn brazing filler metal - Google Patents
Flux for zn brazing filler metalInfo
- Publication number
- JPS63207494A JPS63207494A JP4167287A JP4167287A JPS63207494A JP S63207494 A JPS63207494 A JP S63207494A JP 4167287 A JP4167287 A JP 4167287A JP 4167287 A JP4167287 A JP 4167287A JP S63207494 A JPS63207494 A JP S63207494A
- Authority
- JP
- Japan
- Prior art keywords
- flux
- brazing filler
- filler metal
- wettability
- brazing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000004907 flux Effects 0.000 title abstract description 26
- 238000005219 brazing Methods 0.000 title abstract description 23
- 239000002184 metal Substances 0.000 title abstract description 13
- 229910052751 metal Inorganic materials 0.000 title abstract description 13
- 239000000945 filler Substances 0.000 title abstract description 8
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims abstract description 16
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910052719 titanium Inorganic materials 0.000 abstract description 5
- 239000011592 zinc chloride Substances 0.000 abstract description 5
- 235000005074 zinc chloride Nutrition 0.000 abstract description 5
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 description 7
- 238000002844 melting Methods 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 239000010953 base metal Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000001603 reducing effect Effects 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
- B23K35/3603—Halide salts
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Nonmetallic Welding Materials (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は溶解性及び濡れ性にすぐれたＺｎ系ろう材用フ
ラックスに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a Zn-based brazing material flux that has excellent solubility and wettability.
［従来の技術］
たとえばアルミニウムやチタンのように熱によって酸化
あるいは物性低下をおこしやすい金属のろう付において
は比較的低温でのろう付が望まれており、低融点ろう材
の開発はもちろん低融点フラックスの開発も進められて
いる。尚ろう付に際してフラックスな使用する第１の目
的は母材金属表面に形成されている酸化物層を滓化更に
は還元して除去し、母材金属と溶融ろう材間の濡れ性を
確保する点にあり、この様な役割からしてもフラックス
はまず低融点であること（優れた溶解性）が望まれ、且
つ溶融時には母材金属酸化物を滓化して流動化させ、且
つ該酸化物を還元して金属に戻すことにより母材金属新
生面を露出してろう材を良く親和させる（濡れ性の良い
）ものでなければならない。[Prior art] For example, when brazing metals such as aluminum and titanium, which are prone to oxidation or deterioration of physical properties due to heat, it is desired to braze at relatively low temperatures. Development of flux is also progressing. The primary purpose of using flux during brazing is to remove the oxide layer formed on the surface of the base metal by turning it into slag and reducing it, thereby ensuring wettability between the base metal and the molten brazing metal. Considering this role, it is desirable that the flux has a low melting point (excellent solubility), and when melting, it turns the base metal oxide into a sludge and fluidizes it. It must have good affinity with the brazing material (good wettability) by exposing the newly formed surface of the base metal by reducing it back to metal.
［発明が解決しようとする問題点］
ところがＺｎ系ろう材のろう付に当り、従来から汎用さ
れているフラックスを使用しても、ろう材に適合した溶
解性と十分な濡れ性が得られず良好なろう付性を与える
ものではなかった。[Problems to be solved by the invention] However, when brazing Zn-based brazing filler metals, even if conventionally used fluxes are used, it is not possible to obtain solubility and sufficient wettability that are compatible with the brazing filler metals. It did not give good brazing properties.
そこで本発明においては溶解性及び濡れ性の優れたＺｎ
系ろう材用フラックスを提供することを目的として種々
研究を行なった。Therefore, in the present invention, Zn, which has excellent solubility and wettability, is used.
Various studies were conducted with the aim of providing a flux for brazing filler metals.
［問題点を解決するための手段］
上記問題点を解決することのできた本発明とはＮａＦ、
ＫＦおよびＬｉＦのうち２種以上二合算して１０〜３０
％（重量％の意味、以下同じ）ＺｎＣｌ２： １０〜２
０％
を含有し、残部がＬｉＣｌとＫＣｌおよび不可避不純物
よりなり
であることを構成要旨とするものである。[Means for solving the problems] The present invention that can solve the above problems is based on NaF,
Two or more types of KF and LiF, total of 10 to 30
% (meaning of weight %, same below) ZnCl2: 10-2
0%, and the remainder consists of LiCl, KCl, and unavoidable impurities.
［作用］
本発明者らはＺｎ系ろう材に対するフラックス成分につ
いて種々検討した結果、次に述べるようなフラックス成
分を選定すれば溶解性および濡れ性に優れたフラックス
が得られることを見出した。[Function] As a result of various studies on flux components for Zn-based brazing materials, the present inventors found that if the following flux components were selected, a flux with excellent solubility and wettability could be obtained.
ＮａＦ、ＫＦおよびＬｉＦのうち
２種以上−合算して１０〜３０％
弗化物は母材金属表面の酸化層を滓化すると共に酸化物
に対して還元作用を発揮することにより新生面を露出さ
せる効果はあるが、総量で１０％未満では、その効果が
発揮されず、３０％を超えて含有させるとフラックス全
体の融点を上昇させてしまうため溶解困難となり、フラ
ックスとしての役割を果たせなくなる。ＮａＦ、ＫＦお
よびＬｉＦのうち２種以上を含有させるのはそれぞれ単
独では融点が高く、フラックスの溶解が困難となるから
である。またＮａＦは特に融点が高いので１０％程度ま
での含有量とするのが望ましい。Two or more of NaF, KF, and LiF - 10 to 30% in total Fluoride has the effect of reducing the oxide layer on the surface of the base metal and exposing the new surface by exerting a reducing action on the oxide. However, if the total amount is less than 10%, the effect will not be exhibited, and if it is contained in more than 30%, the melting point of the entire flux will increase, making it difficult to dissolve and unable to fulfill its role as a flux. The reason why two or more of NaF, KF, and LiF are included is that each alone has a high melting point, making it difficult to dissolve the flux. Furthermore, since NaF has a particularly high melting point, it is desirable that the content be up to about 10%.
ＺｎＣ１２： １０〜２０％
ＺｎＣｌ２はフラックスが溶融した時の粘性を低下させ
て流動性を改善し、フラックスの濡れ性を向上させる役
割を果たすものてあって１０％の含有量でその効果を発
揮する。またＺｎＣｌ２はもともと前記弗化物のような
還元反応には直接関与しないものであるので２０％を超
えて含有させるとフラックスを希釈してしまうことにな
り前記弗化物による還元作用が十分に行なわれず濡れ性
が悪くなる。ZnC12: 10-20% ZnCl2 has the role of reducing the viscosity when the flux is melted, improving fluidity and improving the wettability of the flux, and exhibits its effect at a content of 10%. . In addition, since ZnCl2 does not directly participate in the reduction reaction like the fluoride mentioned above, if it is contained in an amount exceeding 20%, the flux will be diluted, and the reducing action by the fluoride will not be carried out sufficiently, resulting in wetting. Sexuality becomes worse.
上記成分に対して残部はＬｉＣｌ，ＫＣｌおよび不可避
不純物で構成する。ＬｉＣｌおよびＫＣｌは前記成分が
反応した後もなお濡れ性を維持するために必要な成分で
あり、いずれか片方のみでは融点が高くろう付性を損う
。したがって使用するＺｎ系ろう材およびフラックスを
構成する他の成分の融点とに大きな温度差を生じないた
めする必要がある。The remainder of the above components consists of LiCl, KCl and unavoidable impurities. LiCl and KCl are necessary components to maintain wettability even after the above components have reacted, and if only one of them is used, the melting point is high and brazability is impaired. Therefore, it is necessary to avoid a large temperature difference between the melting point of the Zn-based brazing material used and the other components constituting the flux.
また本発明のＺｎ系ろう材用フラックスを使用する場合
のろう付対象となる母材金属は限定されないが、チタン
やアルミニウムのように熱により酸化・劣化をおこしや
すく比較的低温でのろう付が望まれる金属に対して好適
である。Furthermore, when using the Zn-based brazing flux of the present invention, the base metal to be brazed is not limited, but metals such as titanium and aluminum are easily oxidized and deteriorated by heat and cannot be brazed at relatively low temperatures. Suitable for desired metals.
［実施例］
白金るつぼ内で第１表に示す組成のろう材用フラックス
を溶製し、Ｚｎ系ろう材を使用してチタン同士のろう付
を行ないフラックスの溶解性および濡れ性を調べた。結
果を第１表に示す。[Example] A flux for a brazing material having the composition shown in Table 1 was melted in a platinum crucible, and titanium was brazed to titanium using a Zn-based brazing material to examine the solubility and wettability of the flux. The results are shown in Table 1.
本発明で規制したフラックスは溶解性および濡れ性にす
ぐれていることがわかる。It can be seen that the flux regulated according to the present invention has excellent solubility and wettability.
［発明の効果］
本発明のＺｎ系ろう何州フラックスは以上のように構成
されており、溶解性および濡れ性に優れているのでＺｎ
系ろう材をろう付するに際して良好な接合性を与える。[Effects of the Invention] The Zn-based brazing flux of the present invention is structured as described above and has excellent solubility and wettability.
Provides good bonding properties when brazing brazing filler metals.
Claims (1)
０〜３０％（重量％の意味、以下同じ）ＺｎＣｌ＿２：
１０〜２０％ を含有し、残部がＬｉＣｌとＫＣｌおよび不可避不純物
よりなり ＬｉＣｌ（％）／ＫＣｌ（％）：１〜３ であることを特徴とするＺｎ系ろう材用フラックス。[Claims] Two or more of NaF, KF and LiF: 1 in total
0 to 30% (meaning of weight %, same below) ZnCl_2:
10 to 20%, and the balance is LiCl, KCl, and unavoidable impurities, with a ratio of LiCl (%)/KCl (%): 1 to 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4167287A JPS63207494A (en) | 1987-02-24 | 1987-02-24 | Flux for zn brazing filler metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4167287A JPS63207494A (en) | 1987-02-24 | 1987-02-24 | Flux for zn brazing filler metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63207494A true JPS63207494A (en) | 1988-08-26 |
Family
ID=12614892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4167287A Pending JPS63207494A (en) | 1987-02-24 | 1987-02-24 | Flux for zn brazing filler metal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63207494A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0753591A1 (en) * | 1995-07-10 | 1997-01-15 | Showa Aluminum Corporation | Brazeable aluminum alloy cast material and method of brazing the same |
| CN106001999A (en) * | 2016-06-14 | 2016-10-12 | 江苏阳明船舶装备制造技术有限公司 | Soldering flux used for soldering of rare earth magnesium alloy and preparation method |
| CN106041368A (en) * | 2016-06-14 | 2016-10-26 | 江苏阳明船舶装备制造技术有限公司 | Brazing flux for brazing rare earth magnesium alloy and preparation method |
| CN110508972A (en) * | 2019-08-02 | 2019-11-29 | 武汉理工大学 | A kind of zinc-aluminium parent metal scaling powder and preparation method thereof |
-
1987
- 1987-02-24 JP JP4167287A patent/JPS63207494A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0753591A1 (en) * | 1995-07-10 | 1997-01-15 | Showa Aluminum Corporation | Brazeable aluminum alloy cast material and method of brazing the same |
| US5862976A (en) * | 1995-07-10 | 1999-01-26 | Showa Aluminum Corporation | Brazeable aluminum alloy cast material and method of brazing the same |
| CN106001999A (en) * | 2016-06-14 | 2016-10-12 | 江苏阳明船舶装备制造技术有限公司 | Soldering flux used for soldering of rare earth magnesium alloy and preparation method |
| CN106041368A (en) * | 2016-06-14 | 2016-10-26 | 江苏阳明船舶装备制造技术有限公司 | Brazing flux for brazing rare earth magnesium alloy and preparation method |
| CN106041368B (en) * | 2016-06-14 | 2018-06-15 | 江苏阳明船舶装备制造技术有限公司 | A kind of brazing flux and preparation method for being brazed magnesium-rare earth |
| CN106001999B (en) * | 2016-06-14 | 2018-06-15 | 江苏阳明船舶装备制造技术有限公司 | A kind of brazing flux and preparation method for being used to be brazed magnesium-rare earth |
| CN110508972A (en) * | 2019-08-02 | 2019-11-29 | 武汉理工大学 | A kind of zinc-aluminium parent metal scaling powder and preparation method thereof |
| CN110508972B (en) * | 2019-08-02 | 2021-12-21 | 武汉理工大学 | Flux for zinc-aluminum-based solder and preparation method thereof |
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