JPS63198964A - Sheet like smoking composition - Google Patents
Sheet like smoking compositionInfo
- Publication number
- JPS63198964A JPS63198964A JP2958387A JP2958387A JPS63198964A JP S63198964 A JPS63198964 A JP S63198964A JP 2958387 A JP2958387 A JP 2958387A JP 2958387 A JP2958387 A JP 2958387A JP S63198964 A JPS63198964 A JP S63198964A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- menthol
- smoking
- tobacco
- smoking composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000391 smoking effect Effects 0.000 title claims description 39
- 239000000203 mixture Substances 0.000 title claims description 31
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 29
- 239000000796 flavoring agent Substances 0.000 claims description 19
- 241000208125 Nicotiana Species 0.000 claims description 18
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 18
- 235000019634 flavors Nutrition 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 9
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 230000014759 maintenance of location Effects 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 30
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 30
- 229940041616 menthol Drugs 0.000 description 30
- 235000019504 cigarettes Nutrition 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 9
- 230000035597 cooling sensation Effects 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 235000013355 food flavoring agent Nutrition 0.000 description 7
- 230000000717 retained effect Effects 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- -1 pulp Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 229920006184 cellulose methylcellulose Polymers 0.000 description 1
- 239000013522 chelant Chemical class 0.000 description 1
- WBLIXGSTEMXDSM-UHFFFAOYSA-N chloromethane Chemical compound Cl[CH2] WBLIXGSTEMXDSM-UHFFFAOYSA-N 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Manufacture Of Tobacco Products (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
「産業上の利用分野」
本発明は喫煙用組成物に関する。更に、詳しく述べれば
粉粒状の吸着剤に揮発性を有する香料を吸着させたのち
、該香料吸着物を再生シートたばこの原料の一部に用い
ることにより、香料の持続的保持能力を高めたシート状
喫煙用組成物に関す「従来の技術及び問題点」
一般に、たばこの製造工程において、原料のたばこ葉片
ないし、刻みや中骨刻みに各種の香料を添加して銘柄ご
とに独特の香喫味を発揮させている。しかし、ここで使
用されている香料のなかには、揮発性の強いものも含ま
れており、原料加工工程で急速に揮散し、加香効果の低
下を来す。また、製品たばことなった後にも徐々に揮散
するため香喫味品質の保証期間が限定されている。さら
に、これらの揮発性香料は温度が高くなるにつれ、一層
揮発性を増すため、喫煙時の着火直後と燃焼終了時点近
くとでは香喫味が変る。特にパイプたばこの喫煙では燃
焼温度が高くなるので、加香料は喫煙開始時で強く、濃
く感じられ、喫煙終末に近づくに従って弱く、淡くなる
傾向にある。例えば、メンソールは揮発性が強いので、
特に上述の傾向が顕著である。そこで、揮発性の強い加
香料を安定した状態で保持させることが必要となり、そ
の技術が求められている。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to smoking compositions. Furthermore, to be more specific, a sheet with increased ability to sustain flavor retention by adsorbing a volatile flavor into a powdery adsorbent and then using the flavor adsorbed material as part of the raw material for recycled sheet cigarettes. ``Prior art and problems'' related to tobacco smoking compositions Generally, in the tobacco manufacturing process, various flavoring agents are added to the raw tobacco leaves, shreds, and shredded ribs to create a unique flavor for each brand. I'm making the most of it. However, some of the fragrances used here are highly volatile and are rapidly volatilized during the raw material processing process, resulting in a reduction in the fragrance effect. In addition, even after the product is made into cigarettes, it gradually evaporates, so the warranty period for the flavor quality is limited. Furthermore, these volatile flavorings become more volatile as the temperature rises, so the flavor changes between immediately after ignition and near the end of combustion during smoking. In particular, when smoking pipe tobacco, the combustion temperature is high, so the flavoring agent tends to be strong and intense at the beginning of smoking, and become weaker and lighter toward the end of smoking. For example, menthol is highly volatile, so
In particular, the above-mentioned tendency is remarkable. Therefore, it is necessary to maintain highly volatile flavoring agents in a stable state, and a technology for this purpose is required.
従来、このような問題を解決する方法として香料の固定
化の手法が知られている。例えば合成丁字油のカプセル
化（米国特許３６２３４８９）、メンソールのカプセル
化（米国特許３５５０５９８）など、マイクロカプセル
中に香料を包含させて用いる方法が提案されている。ま
た、ゼオライトにメンソールを含浸させてたばこフィル
ターに添加する（特開昭５９−１７９７４）、金属の含
水酸化物やキレート化合物に香料を吸蔵させて喫煙物に
包含させる（特公昭５７−２２３１４）など、媒体ない
しは担体に含浸ないし吸蔵させて用いる方法が知られて
いる。しかし、このような公知の方法による揮発性香料
の保香効果は必ずしも十分ではなく、また、使用される
保持体そのものの臭いあるいは燃焼具が喫煙にとって望
ましいものでなかったりして使用上制限を受けるものが
多い。Conventionally, methods of immobilizing fragrances have been known as a method for solving such problems. For example, methods have been proposed in which fragrances are encapsulated in microcapsules, such as encapsulation of synthetic clove oil (US Pat. No. 3,623,489) and encapsulation of menthol (US Pat. No. 3,550,598). In addition, zeolite is impregnated with menthol and added to cigarette filters (Japanese Patent Publication No. 59-17974), and hydrated metal oxides and chelate compounds are occluded with fragrances to be included in smoking materials (Japanese Patent Publication No. 57-22314). A known method is to impregnate or occlude it in a medium or carrier. However, the fragrance retention effect of volatile fragrances obtained by such known methods is not necessarily sufficient, and there are also restrictions on use due to the odor of the holder itself or the fact that the combustor used is not desirable for smoking. There are many things.
本発明者は、前記製品たばことなった後の香喫味品質を
長期間安定的に保持し、しかも、喫煙時に、喫煙開始か
ら終了までできるだけ均一な香りや味を維持しうる喫煙
物を提供することを目的として本発明を行なった。The present inventor provides a smoking product that can stably maintain the aroma and taste quality for a long period of time after being made into a product cigarette, and can maintain the aroma and taste as uniform as possible from the start of smoking to the end of smoking. The present invention was made for this purpose.
「問題点を解決するための手段」
本発明者は現行の再生シートたばこの製造において、各
種原料の結合剤として用いられているカルボキシメチル
セルローズ（以下ＣＭＣと略記する）が揮発性の香料を
含浸吸着した香料の担体物質の表面を被覆して、該香料
の揮散を妨げるのに有効に作用することを見出し、本発
明を達成した。"Means for Solving the Problems" The present inventor discovered that in the current production of recycled sheet cigarettes, carboxymethyl cellulose (hereinafter abbreviated as CMC), which is used as a binder for various raw materials, is impregnated with a volatile flavoring agent. The present invention was accomplished by discovering that coating the surface of a carrier material for adsorbed perfume effectively acts to prevent volatilization of the perfume.
即ち、本発明は結合剤としてのＣＭＣを含む再生シート
たばこ原料に、メンソール溶液を含浸吸着させた粉粒状
の活性炭を配合してスラリー状となし該スラリーを成形
・乾燥してなる揮発性香料保持能力を増強したことを特
徴とするシート状喫煙用組成物である。ここで、再生シ
ートたばことは、たばこの原料・製造工程で生出する葉
くずや中骨などを粉砕した粉末たばことパルプなどの繊
維、ＣＭＣや澱粉などの結合剤、ライムストーンやパー
ライトなどの無機物添料、グリセリンやグリコールなど
のポリオールからなる保湿剤、その他公知の喫煙用組成
物などから適宜選ばれて再構成される喫煙用組成物をい
う。また、揮発性香料とは、たばこ製造において通常加
香料として用いられて料の担体として用いることができ
る粉粒状吸着剤としては活性炭が香料の保持力が太き（
、また、喫味に及ぼす悪影響もないので、最適である。That is, the present invention combines recycled sheet tobacco raw material containing CMC as a binder with activated carbon powder impregnated and adsorbed with a menthol solution to form a slurry, and the slurry is formed and dried to retain a volatile flavor. This is a sheet-shaped smoking composition characterized by enhanced potency. Here, recycled sheet tobacco refers to powdered tobacco obtained by pulverizing leaf waste and backbone produced in the tobacco raw material/manufacturing process, fibers such as pulp, binders such as CMC and starch, and inorganic materials such as limestone and perlite. It refers to a smoking composition that is reconstituted by appropriately selecting from additives, humectants made of polyols such as glycerin and glycol, and other known smoking compositions. In addition, volatile flavoring agents are commonly used as flavoring agents in tobacco manufacturing, and activated carbon is a powder adsorbent that can be used as a carrier for flavoring agents, as it has a strong ability to retain flavorants (
Moreover, it is optimal because it has no adverse effect on the taste.
次に、本発明のシート状喫煙用組成物の製造方法につい
て説明する。香料の吸着剤として活性炭を粒径１００メ
ツシユないしはそれ以下に粉砕し、該粉末をそのまま、
あるいは、温度約２００℃で約２時間乾燥して水分を除
いて用いる。次いで、たばこ用香料として用いられてい
る香料の中から最も揮敗しやすいメンソールを選び、そ
の所定量を溶解させたエタノール溶液に前記粉末とした
活性炭を浸し、攪拌したのち、しばらく放置して、活性
炭に香料を十分含浸・吸着させる。なお、含浸時間は１
０ないし２０分間でよい。このようにして得られた香料
含有活性炭を再生たばこの原料に対し、所定の香料添加
量になる割合に配合し、以下公知の再生たばこの製造方
法に従って、順次混合、成形、乾燥の各工程を径てシー
ト状喫煙用組成物の製品をうる。Next, a method for manufacturing the sheet-shaped smoking composition of the present invention will be explained. As a fragrance adsorbent, activated carbon is ground to a particle size of 100 mesh or smaller, and the powder is used as it is.
Alternatively, it is used after drying at a temperature of about 200° C. for about 2 hours to remove moisture. Next, menthol, which is the most volatile among the flavorings used as tobacco flavorings, is selected, and the powdered activated carbon is soaked in an ethanol solution in which a predetermined amount of menthol is dissolved, stirred, and left for a while. Enough impregnation and adsorption of fragrance into activated carbon. Note that the impregnation time is 1
0 to 20 minutes is sufficient. The flavor-containing activated carbon thus obtained is blended into the raw material of recycled tobacco in a proportion that will give a predetermined amount of flavor added, and the steps of mixing, molding, and drying are sequentially carried out according to a known method for producing recycled tobacco. A sheet-shaped smoking composition product is obtained.
本発明のシート状喫煙用組成物は、裁刻後バイブたばこ
あるいは巻きたばこ用として、原料葉・中骨刻みに適当
量配合して製品たばことする。After shredding, the sheet-shaped smoking composition of the present invention is used for vibrator cigarettes or rolled cigarettes, and is blended in an appropriate amount with raw material leaves and shredded backbones to obtain product cigarettes.
「実施例−１」
市販のやし殻活性炭を粉砕して、１００メツシユ以下の
微細粉粒体とし、温度２００℃の恒温電気乾燥器の中で
２時間加熱乾燥した。一方適宜な容器にエタノール３５
ｍ１を取り、これにまずメンソール３ｇを溶解させ、次
いで、前記活性炭１０ｇを攪拌しながら加えた後、１０
分間そのまま室温で、放置して、活性炭にメンソール溶
液を十分に含浸させる。別に再生シートたばこ原料とし
残粕の粉末１５ｇなどからなる混合物８５ｇを作る。こ
の混合物８５ｇと前記メンソール吸着活性炭の全量を適
宜な容器に取り、これに水３５０ｍ１、グリセリン１２
ｇを加え、よく攪拌混合してスラリー状にする。こうし
て得られたスラリーを試験用の小型スラリーシート成形
乾燥機でシート状に成形乾燥し、厚さ０．１５ｍｍ、坪
量８２ｇ／〆のシート状喫煙用組成物約１００ｇを得た
。"Example-1" Commercially available coconut shell activated carbon was pulverized into fine powder of 100 mesh or less, which was heated and dried for 2 hours in a constant temperature electric dryer at a temperature of 200°C. Meanwhile, put 35 liters of ethanol in a suitable container.
ml, first dissolve 3 g of menthol in it, then add 10 g of the activated carbon with stirring,
Leave to stand for a minute at room temperature to fully impregnate the activated carbon with the menthol solution. Separately, 85 g of a mixture consisting of 15 g of powdered residue as recycled sheet tobacco raw material is prepared. Take 85 g of this mixture and the entire amount of the menthol-adsorbing activated carbon into a suitable container, add 350 ml of water and 12 ml of glycerin.
Add g and mix well to make a slurry. The slurry thus obtained was formed into a sheet and dried using a small-sized slurry sheet forming dryer for testing, to obtain about 100 g of a sheet-like smoking composition having a thickness of 0.15 mm and a basis weight of 82 g/end.
次に、上記シート状喫煙用組成物との比較対照品をうる
ためにメンソール溶液を含浸吸着させる活性炭を含めな
いシート状喫煙用組成物（以下対照品と略記する）を作
った。すなわち、適宜な容器にエタノール３５ｍ１を取
り、これにまずメンソール３ｇを溶解させる。別に再生
シートたばこ搾汁残粕の粉末１５ｇなどからなる混合物
８５ｇを作る。この混合物８５ｇと前記メンソール溶液
の全量を適宜な容器に取り、これに水３５０ｍ１、グリ
セリン１２ｇを加えよく攪拌混合してスラリー状にする
。こうして得られたスラリーを試験用小型スラリーシー
ト成形乾燥機で厚さ０．１５ｍｍ、坪量的８０ｇ／ｍの
対照品約９０ｇを得た。Next, in order to obtain a control product for comparison with the above-mentioned sheet-like smoking composition, a sheet-like smoking composition (hereinafter abbreviated as a control product) not containing activated carbon that was impregnated with and adsorbed with a menthol solution was prepared. That is, 35 ml of ethanol is placed in a suitable container, and 3 g of menthol is first dissolved therein. Separately, 85 g of a mixture consisting of 15 g of powdered recycled sheet tobacco juice residue is prepared. 85 g of this mixture and the entire amount of the menthol solution are placed in a suitable container, and 350 ml of water and 12 g of glycerin are added thereto and thoroughly stirred and mixed to form a slurry. Approximately 90 g of the slurry thus obtained was obtained using a small-sized slurry sheet forming dryer for testing as a control product having a thickness of 0.15 mm and a basis weight of 80 g/m.
「実施例−２」
実施例−１で得られた本発明のシート状喫煙用組成物と
対照品をそれぞれ温度２２℃、相対湿度６０％の調和室
に開放状態で蔵置しておき、一定期間ごとに該喫煙用組
成物と対照品が保持しているメンソール量をガスクロマ
トグラフ分析法で測定した。メンソールの定量方法は、
前記シート状喫煙用組成物（被検物）５ｇを切り取り、
これを共栓付２００ｍ１フラスコに入瓢これに０．５れ
にＣＩ２ Ｃ１２１００ｒｎ １を加え、３０℃で約１
５時間振盪して被検物中のメンソールをＣＨ２Ｃｌよに
溶解移行させる。ＣＨ，ＣＩ２層を分離してガスクロマ
トグラフ分析に供する。操作条件は以下のとおりである
。"Example-2" The sheet-like smoking composition of the present invention obtained in Example-1 and the control product were stored in an open state in a conditioned room at a temperature of 22°C and a relative humidity of 60% for a certain period of time. The amount of menthol retained in the smoking composition and the control product was measured by gas chromatography analysis. The method for quantifying menthol is
Cut out 5 g of the sheet-shaped smoking composition (test material),
Pour this into a 200m1 flask with a stopper, add 0.5 liters of CI2 C12100rn, and mix at 30℃ for about 1 hour.
Shake for 5 hours to dissolve and transfer the menthol in the test sample to CH2Cl. The CH and CI layers are separated and subjected to gas chromatography analysis. The operating conditions are as follows.
イ、装置；日立１６３型
口、カラム；Ｂｕｔａｎ−１，４−ｄｉｏｌａｄｉｐａ
ｔｅ １０％
Ｃｈｒｏｍｏｓｏｒｂ （ＡＷ ６０〜８０メフシ
エ）ガラスカラム２爪
ハ、温度；カラム １６０℃、インジェクション２３０
℃
二、検出器；ＦＩＤ
ホ、キャリアガｘ ； Ｎ２ ６０ ｒｎ Ｉ ／分分
析結果を表−１に示す。表−１で明瞭なように、対照品
では製造直後から１ケ月でメンソールの保持量が大幅に
減少し、わずかに保持されているだけであり、その後製
造後１ケ月以上を経過するとメンソールは保持されてい
ない。一方、活性炭を添加したシート状喫煙用組成物で
は、製造直後から１ケ月ではメンソール保持量がかなり
大きく減少したが、その後はわずかに漸減傾向が認めら
れるだけで、２４ケ月においてもメンソールの清涼感を
出しうるだけのメンソール量が保持されていた。B, Equipment; Hitachi 163 model; Column; Butan-1,4-dioladipa
te 10% Chromosorb (AW 60-80 mesh) glass column 2 claws, temperature: column 160℃, injection 230℃
C. 2. Detector; FID E; Carrier gas; N2 60 rn I/min The analysis results are shown in Table 1. As is clear from Table 1, in the control product, the amount of menthol retained decreased significantly within one month immediately after manufacture, and was only slightly retained; after that, after one month or more after manufacture, menthol was retained. It has not been. On the other hand, in the case of sheet-shaped smoking compositions containing activated carbon, the amount of menthol retained decreased considerably in the first month immediately after production, but after that, only a slight tendency to decrease was observed, and even after 24 months, the amount of menthol retained was significantly reduced. The amount of menthol was maintained to be sufficient to release the amount of menthol.
「実施例−３」
実施例−１で得られたシート状喫煙用組成物と対照品と
を製造後すぐそれぞれ裁刻し、ロフクンチェア（日本た
ばこ製部品名）用バイブたばこ刻みにそれぞれ１０重量
％の割合になるように配合して、パイプで喫煙した。そ
の結果、本発明のシート状喫煙用組成物を配合したパイ
プたばこ刻みでは喫煙開始から終了までメンソールの清
涼感が均一で安定した状態で感知された。一方、対照品
を配合したパイプたばこ刻みでは喫煙開始時にはメンソ
ールの清涼感が強く感じられたが、その清涼感は喫煙が
進むにつれて弱く淡くなり、喫煙終了時にはメンソール
の清涼感はほとんど感じられなくなった。"Example-3" The sheet-like smoking composition obtained in Example-1 and the control product were each shredded immediately after production, and 10% by weight of each was shredded into vibrator tobacco for Lofkun chair (part name manufactured by Nippon Tobacco Co., Ltd.). It was mixed in such a proportion as to be smoked in a pipe. As a result, in the cut pipe tobacco containing the sheet-like smoking composition of the present invention, the cooling sensation of menthol was perceived uniformly and stably from the start to the end of smoking. On the other hand, with chopped pipe tobacco containing the control product, the cooling sensation of menthol was felt strongly at the beginning of smoking, but the cooling sensation weakened and faded as smoking progressed, and by the end of smoking, the cooling sensation of menthol was hardly felt. .
「実施例−４」
メンソールの使用量を実施例−１において用いた量の１
／２とした他は、実施例−１と全（同様にして、本発明
のシート状喫煙用組成物及び対照品を製造した。こうし
て得られた本発明のシート状喫煙用組成物と対照品とを
それぞれ裁刻し、それぞれの刻みをシガレット状に巻き
上げ、温度２２℃、相対湿度６０％の調和室に開放状態
で蔵置しておき、２４ケ月にわたって、１ケ月間隔で喫
煙してそのメンソールによる清涼感がどれくらいの期間
保持されているかを調査した。その結果、本発明のシー
ト状喫煙用組成物のシガレットでは２４ケ月経過しても
メンソールの清涼感が感知できた。しかし、対照品のシ
ガレットでは１ケ月でメンソールの清涼感はほとんど感
知されなくなった。"Example-4" The amount of menthol used was 1 of the amount used in Example-1.
A sheet-shaped smoking composition of the present invention and a control product were produced in the same manner as in Example-1, except that the composition was changed to /2. Each cut was cut into cigarettes, rolled up into cigarettes, stored in an open state in a harmonized room at a temperature of 22°C and a relative humidity of 60%, and smoked at monthly intervals for 24 months to release the menthol. We investigated how long the cooling sensation was maintained.As a result, the cooling sensation of menthol could be perceived even after 24 months in the cigarettes made of the sheet-shaped smoking composition of the present invention.However, the cigarettes of the control product After one month, the cooling sensation of menthol was almost unnoticeable.
「発明の効果」
本発明のシート状喫煙用組成物では、揮発性の強いメン
ソールが粉粒状の活性炭に吸着保持され、しかも該活性
炭の表面がＣＭＣで被覆された状態となっているので、
該喫煙用組成物は長期間にわたってメンソールを安定的
に保持する効果を発揮するとともに、該喫煙用組成物を
配合したたばこの喫煙時において喫煙の開始から終了ま
で、メンソールの清涼感を、均一で安定した状態に保持
する効果を示す。"Effects of the Invention" In the sheet-shaped smoking composition of the present invention, highly volatile menthol is adsorbed and retained on powdery activated carbon, and the surface of the activated carbon is coated with CMC.
The smoking composition exhibits the effect of stably retaining menthol over a long period of time, and when smoking a cigarette containing the smoking composition, the cooling sensation of menthol is uniformly maintained from the start to the end of smoking. Demonstrates the effect of maintaining a stable state.
Claims (1)
シートたばこ原料に、揮発性香料を含浸吸着させた粉粒
状の活性炭を配合してスラリー状となし、該スラリーを
成形・乾燥してなる揮発性香料保持能力を増強したこと
を特徴とするシート状喫煙用組成物。Volatile flavor retention capacity obtained by mixing recycled sheet tobacco raw material containing carboxymethyl cellulose as a binder with granular activated carbon impregnated and adsorbed with a volatile flavor to form a slurry, and molding and drying the slurry. 1. A sheet-shaped smoking composition characterized by having enhanced
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2958387A JPS63198964A (en) | 1987-02-13 | 1987-02-13 | Sheet like smoking composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2958387A JPS63198964A (en) | 1987-02-13 | 1987-02-13 | Sheet like smoking composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63198964A true JPS63198964A (en) | 1988-08-17 |
| JPH0318869B2 JPH0318869B2 (en) | 1991-03-13 |
Family
ID=12280107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2958387A Granted JPS63198964A (en) | 1987-02-13 | 1987-02-13 | Sheet like smoking composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63198964A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7234648B2 (en) | 2003-10-31 | 2007-06-26 | The Procter And Gamble Company | Volatile substance-controlling composition |
| WO2006076065A3 (en) * | 2005-01-10 | 2007-08-09 | Dow Global Technologies Inc | Personal care compositions |
| CN105747264A (en) * | 2016-04-20 | 2016-07-13 | 贵州中烟工业有限责任公司 | Method for preparing heat-not-burn tobacco bases containing active carbon |
| CN107242603A (en) * | 2017-06-29 | 2017-10-13 | 滁州卷烟材料厂 | A kind of production method of reconstituted tobacoo |
| WO2022264356A1 (en) | 2021-06-17 | 2022-12-22 | 日本たばこ産業株式会社 | Flavor molded body for non-combustion heating type flavor inhalers, method for producing same and non-combustion heating type flavor inhaler |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54154527A (en) * | 1978-05-23 | 1979-12-05 | Kyowa Leather Cloth | Aroma producing particular composition and method |
| JPS552275A (en) * | 1978-06-22 | 1980-01-09 | Copyer Co Ltd | Toner deficiency detector |
| JPS5578965A (en) * | 1978-12-11 | 1980-06-14 | Kokando Kk | Heating smell sendinggforth matter |
| JPS5955255A (en) * | 1982-08-20 | 1984-03-30 | ナ−ルデン・インタ−ナシヨナル・エヌ・ベ− | Production of air refreshing gel and obtainedgel |
-
1987
- 1987-02-13 JP JP2958387A patent/JPS63198964A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54154527A (en) * | 1978-05-23 | 1979-12-05 | Kyowa Leather Cloth | Aroma producing particular composition and method |
| JPS552275A (en) * | 1978-06-22 | 1980-01-09 | Copyer Co Ltd | Toner deficiency detector |
| JPS5578965A (en) * | 1978-12-11 | 1980-06-14 | Kokando Kk | Heating smell sendinggforth matter |
| JPS5955255A (en) * | 1982-08-20 | 1984-03-30 | ナ−ルデン・インタ−ナシヨナル・エヌ・ベ− | Production of air refreshing gel and obtainedgel |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7234648B2 (en) | 2003-10-31 | 2007-06-26 | The Procter And Gamble Company | Volatile substance-controlling composition |
| WO2006076065A3 (en) * | 2005-01-10 | 2007-08-09 | Dow Global Technologies Inc | Personal care compositions |
| CN105747264A (en) * | 2016-04-20 | 2016-07-13 | 贵州中烟工业有限责任公司 | Method for preparing heat-not-burn tobacco bases containing active carbon |
| CN105747264B (en) * | 2016-04-20 | 2020-11-20 | 贵州中烟工业有限责任公司 | Activated carbon-containing heating non-combustible tobacco substrate and preparation method and application thereof |
| CN107242603A (en) * | 2017-06-29 | 2017-10-13 | 滁州卷烟材料厂 | A kind of production method of reconstituted tobacoo |
| WO2022264356A1 (en) | 2021-06-17 | 2022-12-22 | 日本たばこ産業株式会社 | Flavor molded body for non-combustion heating type flavor inhalers, method for producing same and non-combustion heating type flavor inhaler |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0318869B2 (en) | 1991-03-13 |
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