JPS63176173A - Sheet for ink jet recording - Google Patents
Sheet for ink jet recordingInfo
- Publication number
- JPS63176173A JPS63176173A JP62008819A JP881987A JPS63176173A JP S63176173 A JPS63176173 A JP S63176173A JP 62008819 A JP62008819 A JP 62008819A JP 881987 A JP881987 A JP 881987A JP S63176173 A JPS63176173 A JP S63176173A
- Authority
- JP
- Japan
- Prior art keywords
- water
- aldehydes
- epoxies
- amines
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 125000002339 acetoacetyl group Chemical group O=C([*])C([H])([H])C(=O)C([H])([H])[H] 0.000 claims abstract description 13
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 13
- 239000004593 Epoxy Substances 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 14
- 150000001299 aldehydes Chemical class 0.000 claims description 12
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940015043 glyoxal Drugs 0.000 claims description 3
- 125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 abstract description 13
- -1 acetoacetyl ester Chemical class 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 abstract 1
- 150000002148 esters Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 19
- 229920005989 resin Polymers 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000123 paper Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 150000002484 inorganic compounds Chemical class 0.000 description 4
- 229910010272 inorganic material Inorganic materials 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 238000007127 saponification reaction Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910003475 inorganic filler Inorganic materials 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical compound NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000008429 bread Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 description 1
- MECNWXGGNCJFQJ-UHFFFAOYSA-N 3-piperidin-1-ylpropane-1,2-diol Chemical compound OCC(O)CN1CCCCC1 MECNWXGGNCJFQJ-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- NSEMPCRVNANTIM-UHFFFAOYSA-N C.NC(=O)C=C Chemical compound C.NC(=O)C=C NSEMPCRVNANTIM-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920002160 Celluloid Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920002085 Dialdehyde starch Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- UZZFFIUHUDOYPS-UHFFFAOYSA-L disodium 4-amino-3,6-bis[[4-[(2,4-diaminophenyl)diazenyl]phenyl]diazenyl]-5-oxido-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccc(cc4)N=Nc4ccc(N)cc4N)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 UZZFFIUHUDOYPS-UHFFFAOYSA-L 0.000 description 1
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- JGEMYUOFGVHXKV-OWOJBTEDSA-N fumaraldehyde Chemical compound O=C\C=C\C=O JGEMYUOFGVHXKV-OWOJBTEDSA-N 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- ZWLUXSQADUDCSB-UHFFFAOYSA-N phthalaldehyde Chemical compound O=CC1=CC=CC=C1C=O ZWLUXSQADUDCSB-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
Landscapes
- Paper (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はインクジェット記録用のシートに関し、特にイ
ンク吸収性に優れ、かつ著(2く耐水性に優rしたイン
クジェット記録用のシートに関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an inkjet recording sheet, and particularly to an inkjet recording sheet that has excellent ink absorbency and excellent water resistance.
B、従来の技術
インクジェット記録方式は騒音が少いこと、カラー化が
容易であること、高速記録が可能であること等の理由か
ら、ファクシミリ、各種プリンター等への応用か進めら
れている。従来、インクジェット記録方式に使用ざnる
被記録材としては通常の紙が使用ざrしてさた。しかし
、−記録の高速化あるいは多色化などインクジェット記
録機の性能向上に伴いインクジェット記録用のシートに
対してもより高度な特性が要求ざrしてきている。すな
わち第1にインクの吸収速度が大きいこと、第2にイン
クドツトの径が必要以上に大きくならないこと、第3に
インクジェット記録用のシート自体の耐水性が高いこと
等である。B. Conventional technology The inkjet recording method is being applied to facsimiles, various printers, etc. because of its low noise, ease of colorization, and high-speed recording. Conventionally, ordinary paper has been used as a recording material for inkjet recording methods. However, as the performance of inkjet recording machines improves, such as higher recording speeds and multicolor recording, more advanced properties are being required for inkjet recording sheets. Firstly, the ink absorption speed is high; secondly, the diameter of the ink dots does not become larger than necessary; and thirdly, the inkjet recording sheet itself has high water resistance.
従来これらの要求を満たすため水浴性のインクジェット
用インクの吸収材として紙あるいは水溶性樹脂を用いる
など種々の検討がなざ才して(゛るが、インク吸収速度
を大きくするとインクドツト径が必要以上に大きくなっ
たり、耐水性が著しく低くなる等、実用レベルの要求に
は遠くおよばないというのが現状である。In order to meet these requirements, various studies have been made in the past, such as using paper or water-soluble resin as an absorbent material for water-bathable inkjet ink. The current situation is that it is far from meeting the requirements for practical use, such as increased size and significantly lower water resistance.
C1本発明が解決しようとする問題点
本発明の目的は、前記のような諸要求を満足させ、特に
インク吸収性と耐水性に優れたインクジェット記録用の
シートを提供することにある。C1 Problems to be Solved by the Present Invention An object of the present invention is to provide an inkjet recording sheet that satisfies the above requirements and is particularly excellent in ink absorption and water resistance.
本発明の更にもう一つの目的は、スライドや・0LLP
等の光学機器により記録画像をスクリーン等へ投影する
ことにより観察に用いるもの、あるいはカラーディスプ
レイ等の透過光観測用に用いることのでさる透明性にす
ぐ几たインクジェット記録用のシートを提供することに
ある。Yet another object of the present invention is to
To provide an inkjet recording sheet that has a high transparency that can be used for observation by projecting a recorded image onto a screen etc. using an optical device such as the above, or for observation of transmitted light such as a color display. be.
D1問題点を解決′するための手段
本発明苔らは上記の問題点を解決し、と述の目的を達成
すべく鋭意検討した結果、支持基体にアセトアセチル基
を有する変性ポリビニルアルコール(以下ポリビニルア
ルコールをPVAと略記する)とアルデヒド類、アミン
類、エポキシ類から選ばれる少(とも1種の有機化合物
とを含有せしめたインクジェット記録用のシートは、イ
ンク吸収性に優rL、かつ著しく耐水性に優れたインク
ジニット記録用のシートであることを見出し本発明を完
成するに到ったものである。D1 Means for Solving the Problems of the Present Invention As a result of intensive studies to solve the above-mentioned problems and achieve the above-mentioned purpose, we found that modified polyvinyl alcohol (hereinafter referred to as polyvinyl alcohol) having an acetoacetyl group on the supporting substrate Inkjet recording sheets containing alcohol (abbreviated as PVA) and at least one organic compound selected from aldehydes, amines, and epoxies have excellent ink absorbency and are extremely water resistant. The inventors discovered that this is an ink dinit recording sheet with excellent properties and completed the present invention.
以下に本発明について更に詳細に説明する。The present invention will be explained in more detail below.
本発明において用いら几るアセトアセチル基をせるか、
アセト酢酸エステルでエステル交換反応する方法等によ
って得ることかでさる。アセトアセチル基の含有量とし
てはU、1〜20モル念、好ましくは0.5〜10モル
%の範囲から選ばれる。アセトアセチル基の含有量が0
.1モル%未満の場合には耐水性向上効果が低く、20
0モル%超える場合にはインク吸収速度が低下する。ま
た上記変性PVAの重合匣は通常100〜30fJU
、好ましくは500〜20υOの範囲から選ばれ、けん
化度としては水溶性の範囲であれは特に制限はないが通
常70〜ILI(1モル%、好ましくは80〜95モル
%の範囲から選ばれる。Adding an acetoacetyl group, which is not used in the present invention,
It can be obtained by a method such as transesterification with acetoacetate. The content of acetoacetyl group is selected from the range of 1 to 20 mol %, preferably 0.5 to 10 mol %. Content of acetoacetyl group is 0
.. If it is less than 1 mol%, the effect of improving water resistance is low;
If it exceeds 0 mol%, the ink absorption speed will decrease. Moreover, the polymer box of the above-mentioned modified PVA is usually 100 to 30 fJU.
, preferably from the range of 500 to 20 υO, and the degree of saponification is not particularly limited as long as it is water-soluble, but is usually selected from the range of 70 to ILI (1 mol%, preferably 80 to 95 mol%).
本発明において用いられるアルデヒド類、アミン類、エ
ポキシ類のうち、アルデヒド類としては、例え(iホル
ムアルデヒド、アセトアルデヒド、プロピオンアルデヒ
ド、ブチルアルデヒド等のモノアルデヒド、ダリオキザ
ール、マロンジアルデヒド、スクシンジアルデヒド、グ
ルタルジアルデヒド、マレインジアルデヒド、フタルジ
アルデヒド、ジアルデヒドでん粉等のジアルデヒドが挙
げられ、ダリオキザールが好適に用いらnる。Among the aldehydes, amines, and epoxies used in the present invention, examples of the aldehydes include monoaldehydes (i. Examples include dialdehydes such as aldehyde, maleic dialdehyde, phthaldialdehyde, and dialdehyde starch, and daryoxal is preferably used.
また、アミン類としては、尿素、メチルール尿素、メラ
ミン、メチロールメラミン、ヘキサメチレンジアミン、
トリエタノールアミン等が挙げらrL、特にメチロール
メラミン、メチロール尿素か好適に用いら几る。In addition, amines include urea, methylol urea, melamine, methylol melamine, hexamethylene diamine,
Preferred examples include triethanolamine, particularly methylolmelamine and methylolurea.
ざらにエポキシ類としては、エチレングリコールシダリ
ンジルエーテル、ポリエチレングリコールジグリシジル
エーテル、グリセリンジまたはトリダリシジルエーテル
、トリメチロールプロパントリグリシジルエーテル、1
.6−ヘキサンシオールジグリシジルエーテル等が挙げ
られる。Examples of the epoxies include ethylene glycol cydalidyl ether, polyethylene glycol diglycidyl ether, glycerin di- or tridalicidyl ether, trimethylolpropane triglycidyl ether, 1
.. Examples include 6-hexanesiol diglycidyl ether.
本発明において用いらf’Lる上述の変性1’VAとア
ルデヒド類、アミン類、エポキシ類から選ば几る少くと
も1種の有機化合物との配合率は重量で1013/1−
100/20、好ましくはlυ0/2〜1()0/10
の範囲から選ばれる。上述の有機化合物の配合比率が1
以下の場合は耐水性が十分でなく、20を超える場合に
はインク吸収性が低下する傾向がある。The blending ratio of the above-mentioned modified 1'VA used in the present invention and at least one organic compound selected from aldehydes, amines, and epoxies is 1013/1- by weight.
100/20, preferably lυ0/2~1()0/10
selected from the range. The blending ratio of the above organic compounds is 1
In the following cases, the water resistance is not sufficient, and in the case of more than 20, the ink absorbency tends to decrease.
本発明において用いられる変性1’VAと上述の有機化
合物はそrしらのみで使用することもでざるが、他の水
溶性樹脂、水分散性樹脂、水溶性無機化合物あるいは無
機充填材等を併用して使用することもできる。The modified 1'VA used in the present invention and the above-mentioned organic compounds may be used alone, but they may also be used in combination with other water-soluble resins, water-dispersible resins, water-soluble inorganic compounds, or inorganic fillers. It can also be used as
併用使用できる他の水溶性あるいは水分散性樹脂として
は、アルブビン、ゼラチン、カゼイン、でんぷん、アラ
ビアゴム、メチルセルロース、ヒドロキシエチルセルロ
ース等のセルロースm 導体、ポリアミド樹脂、メラミ
ン樹脂、通常の未変性PVA、ポリ(メタコアクリルア
ミド、ポリビニルピロリドン等のノニオン性水溶性樹脂
、e Sl e、ポリ(メタ)アクリル酸ナトリウム、
アニオン変性1’VA、アルギン酸すl−IJウム、水
溶性ポリエステル等のアニオン性水溶性樹脂、ポリエチ
レンイミン、ポリビニルアミン、ボリア命すルアミン、
ボリアdh l)ルアミンスルホン共重合体あるいはこ
才しらのアンモニウム塩、カチオン化でん粉、カチオン
化ポリ(メタンアクリルアミド、カチオン変性PVA、
カチオン化ポリアミド樹脂等のカチオン性水溶性樹脂、
5DI(ラテックス、NBlIラテックス、[2ビニル
系エマルジヨン、エチレン/A1E 酸ビニル共重合体
エマルジョン、(メタ)アクリルエステル系エマルジョ
ン、塩化ビニル系エマルジョン等の水分散性樹脂がおば
らnる。Other water-soluble or water-dispersible resins that can be used in combination include arbuvin, gelatin, casein, starch, gum arabic, cellulose conductors such as methyl cellulose and hydroxyethyl cellulose, polyamide resins, melamine resins, ordinary unmodified PVA, poly( Nonionic water-soluble resins such as methacoacrylamide and polyvinylpyrrolidone, eSle, sodium poly(meth)acrylate,
Anion-modified 1'VA, sulfur alginate, anionic water-soluble resin such as water-soluble polyester, polyethyleneimine, polyvinylamine, boria sulfuramine,
Boria dh l) Ruamine sulfone copolymer or small ammonium salt, cationized starch, cationized poly(methane acrylamide, cation-modified PVA,
Cationic water-soluble resins such as cationic polyamide resins,
Water-dispersible resins such as 5DI latex, NBlI latex, vinyl emulsion, ethylene/A1E acid vinyl copolymer emulsion, (meth)acrylic ester emulsion, and vinyl chloride emulsion are available.
これらの水溶性あるいは水分散性樹脂を本発明において
用いらnる変性PVAとアルデヒド類等上述の有機化合
物とに併用して使用する場合の併用割合としては、本発
明の変性i’V、AltlU重量部に対してxuuf(
:i部以下、好ましくは50重量部以下で使用ざrしる
。When these water-soluble or water-dispersible resins are used in combination with the modified PVA used in the present invention and the above-mentioned organic compounds such as aldehydes, the ratio of the combined use is as follows: xuuf(
: Not more than i part, preferably not more than 50 parts by weight.
また、本発明において併用使用できる水溶性の無機化合
物としては、硫酸アルミニウム、カリ明パン、アンモニ
ウム明パン、塩化マグネシウム、塩化並塩、塩化第二鉄
、塩化アルミニウム等が挙げられる。これらの水溶性無
機化合物を併用使用する場合には上述のアセトアセチル
糸を有す変性PVA100重量部に対して0.5〜10
重量部の範囲で用いることが好ましい。In addition, examples of water-soluble inorganic compounds that can be used in combination in the present invention include aluminum sulfate, potassium bright bread, ammonium bright bread, magnesium chloride, common salt chloride, ferric chloride, aluminum chloride, and the like. When these water-soluble inorganic compounds are used in combination, the amount is 0.5 to 10 parts by weight per 100 parts by weight of the above-mentioned modified PVA having acetoacetyl threads.
It is preferable to use within the range of parts by weight.
また、本発明において併用使用しうる無機充填材として
はシリカ、クレー、タルク、ケインウ土、ゼオライト、
炭酸カルシウム、アルミナ、酸化化塩、サチンホワイト
等が挙げら才1.る。この場合の併用割合としては透明
性にすぐtした記録用シートとそれ以外の場合とで異な
るが、通常本発明で用いら才りる〔変性1’VA/充填
材〕が]、/100〜100/1、好ましくは5/10
0〜too/sの範囲から選ばれる。In addition, inorganic fillers that can be used in combination in the present invention include silica, clay, talc, cane earth, zeolite,
Examples include calcium carbonate, alumina, oxidized salts, and sachin white.1. Ru. In this case, the combination ratio differs depending on whether the recording sheet has high transparency or other cases, but the ratio of [modified 1'VA/filler] used in the present invention is usually from /100 to 100/1, preferably 5/10
It is selected from the range of 0 to too/s.
本発明において用いられるアセトアセチル基を有する変
性PVAとアルデヒド類、アミン類、エポキシ類から選
ば71.る少くとも1種のη機化合物とよりなる組成物
は、それ自体インク吸収性に優れているためインク吸収
層として使用することもできるが、他のインク吸収性材
料よりなるインク吸収層の上に該組成物よりなる層を形
成せしめ耐水性I−として使用することもできる。71. Selected from modified PVA having an acetoacetyl group used in the present invention, aldehydes, amines, and epoxies. A composition comprising at least one type of η-organic compound can be used as an ink-absorbing layer because it has excellent ink-absorbing properties itself, but it can also be used as an ink-absorbing layer on an ink-absorbing layer made of other ink-absorbing materials. It is also possible to form a layer made of the composition and use it as water-resistant I-.
本発明で用いらγしる支持基体としては、透明性、不透
明性の従来公知の支持基体がいずれも使用できる。透明
性支持基体としては、例えばポリエステル、ポリスチレ
ン、ポリ塩化ビニル、ポリメチルメタクリレート、酢酸
セルロース、ポリカーボネート、ポリイミド、セロハン
、セルロイド等のフィルム、シー1−、Rるいは透明性
の高い紙等が挙げられる。不透明性支持基体としては、
例えば一般の紙、顔料コート紙、布、木材、金属板、合
成紙、不透明化処理した合成樹脂系フィルムあるいはシ
ート等が挙げらrしる。As the transparent supporting substrate used in the present invention, any conventionally known transparent or opaque supporting substrate can be used. Examples of the transparent support substrate include films of polyester, polystyrene, polyvinyl chloride, polymethyl methacrylate, cellulose acetate, polycarbonate, polyimide, cellophane, celluloid, etc., C1-, R-1, or highly transparent paper. . As an opaque support substrate,
Examples include general paper, pigment-coated paper, cloth, wood, metal plates, synthetic paper, and opaquely treated synthetic resin films or sheets.
本発明の目的の一つである透明性にすぐれたインクジェ
ット記録用のシートの場合には透明性支持基体が用いら
れる。In the case of an inkjet recording sheet with excellent transparency, which is one of the objects of the present invention, a transparent support substrate is used.
本発明において支持基体に上述のアセトアセチル基を有
する変性PVAとアルデヒド類、アミン類、エポキシ類
から選ばrしる少くとも1種の有機化合物よりなる組成
物を含有せしめる方法とじては、上述の組成物の水溶液
またはこnと他の水溶性または水分散性樹脂、水溶性無
機化合物あるいは充填材との混合物水溶液あるいは水分
散液をサイズプレス、エアーナイフコーター、ロールコ
ータ−、バーコーター、ブレードコーター等通常のコー
ティング方法によって支持基体中に含浸するか、支持基
体の上表面あるいは上表面と下表面との両表面上にコー
ト層を形成せしめる等の方法が使用できる。In the present invention, the method of making the supporting substrate contain a composition consisting of the above-mentioned modified PVA having an acetoacetyl group and at least one organic compound selected from aldehydes, amines, and epoxies includes the above-mentioned method. An aqueous solution or aqueous dispersion of the composition or a mixture thereof with other water-soluble or water-dispersible resins, water-soluble inorganic compounds, or fillers is prepared using a size press, air knife coater, roll coater, bar coater, or blade coater. It can be impregnated into the supporting substrate by a conventional coating method, or a coating layer can be formed on the upper surface or both the upper and lower surfaces of the supporting substrate.
また支持基体が紙である場合には抄紙時に上記水溶液あ
るいは水分散液を内添する方法も使用しうる。Furthermore, when the supporting substrate is paper, a method of internally adding the above-mentioned aqueous solution or aqueous dispersion during paper making can also be used.
本発明のインクジェット記録用のシート中の変性P V
aとアルデヒド類、アミン類、エポキシ類から選ばれ
る少くとも1種の有機化合物からなる組成物の含有量と
しては特に制限はないが、通常0.1〜200 y/l
ri好ましくは1〜1 (I 09/警が用いられる。Modified PV in the inkjet recording sheet of the present invention
There is no particular restriction on the content of the composition consisting of a and at least one organic compound selected from aldehydes, amines, and epoxies, but it is usually 0.1 to 200 y/l.
ri is preferably 1 to 1 (I09/K) is used.
81作用および発明の効果
本発明のインクジェット記録用のシートがインり吸収性
に優れ、かつ著しく耐水性に優れる理由については十分
解明されているわけではないが次のように推定される。81 Effects and Effects of the Invention The reason why the inkjet recording sheet of the present invention has excellent ink absorption properties and extremely excellent water resistance is not fully elucidated, but is presumed to be as follows.
本発明において用いられるアセトアセチル基変性PVΔ
とアルデヒド類、アミン類、エポキシ類から選ばれる少
くとも1pJiの有機化合物とよりなる組成物は皮脂形
成前は水溶性であり、皮膜形成後も親水性であるが、得
られる皮膜は著しく耐水性が高いためインク吸収性とと
もに耐水性も著しく優れたインクジェット記録用のシー
トを形成しうるものと推定される。Acetoacetyl group-modified PVΔ used in the present invention
and at least 1 pJi of an organic compound selected from aldehydes, amines, and epoxies is water-soluble before sebum formation and remains hydrophilic after film formation, but the resulting film is extremely water resistant. It is presumed that it is possible to form an inkjet recording sheet that has extremely excellent ink absorbency and water resistance because of its high properties.
以下に実施例を挙げて本発明を更に詳しく説明するが、
本発明はこrしによって限定されるものではない。尚実
施例中、特にことわりのないかぎり、「%」及び「部」
は重量基準を表わす。The present invention will be explained in more detail with reference to Examples below.
The invention is not limited by this. In the examples, unless otherwise specified, "%" and "part"
represents weight basis.
なお実施例中の諸物性の測定方法を以下に示す。The methods for measuring various physical properties in Examples are shown below.
(1) インクジェット記録方法
60μmの吐出オリフィス径のオンディヤント型インク
ジェット記録ヘッドを有する記録装置を用い、下記4色
のインクを用いてカラーインクジェット記録を行い、記
録特性の評価を行った。(1) Inkjet Recording Method Color inkjet recording was performed using the following four colors of ink using a recording apparatus having an ondiant type inkjet recording head with an ejection orifice diameter of 60 μm, and the recording characteristics were evaluated.
イエローインク(組成)
C,1,アシッドイエロー2,3 2部ジエチレ
ングリコール 30部水
70部マゼンタインク(組成)
0、1.7シツドレツド32 2部ジエチレン
グリコール 30部水
70部シアンインク(組成)
0.1.ダイレクトブルー86 2部ジエチレン
グリコール 30部水
7部部ブラックインク(組成)
0.1.ダイレクトブラック19 2部ジエチレング
リコール 30部水
70部インクジェット記録後、一定時
間ごとに記録シートとの印字を指でこすり、印字部分が
変化しなくなるまでの時間を測定した。時間が短かいほ
どインク吸収速度が大である。Yellow ink (composition) C, 1, acid yellow 2, 3 2 parts diethylene glycol 30 parts water
70 parts Magenta ink (composition) 0, 1.7 Shredded 32 2 parts diethylene glycol 30 parts water
70 parts Cyan ink (composition) 0.1. Direct Blue 86 2 parts diethylene glycol 30 parts water
7 parts part black ink (composition) 0.1. Direct Black 19 2 parts diethylene glycol 30 parts water
After inkjet recording of 70 copies, the print on the recording sheet was rubbed with a finger at regular intervals, and the time until the print part stopped changing was measured. The shorter the time, the faster the ink absorption speed.
(3) にじみ度
印字ドツトの直径を実体顕微鏡で測定し、インク滴の何
倍になったかを示した。倍率が低いほどにじみが少ない
ことを示す。(3) Bleeding degree The diameter of the printed dot was measured using a stereomicroscope, and it was shown how many times larger it was than the ink droplet. The lower the magnification, the less blurring.
(4)透明度
インクジェット記録用のシートの非印字部分の可視光線
透過率圀を5Utlnmの波長の可視光線を用いて分光
光度計で測定した。この透過率をもって透明度とする。(4) Transparency The visible light transmittance of the non-printed portion of the inkjet recording sheet was measured using a spectrophotometer using visible light having a wavelength of 5 Utlnm. This transmittance is defined as transparency.
透過率が大である程、透明性が高いことを示す。The higher the transmittance, the higher the transparency.
(5)耐水性
インクジェット記録後のシートの印字部に水をつけ、指
でこすった時、印字部が溶解したりにじんだりするかど
うかで判定した。5:変化なし〜l:にじみ、溶解があ
る。(5) Water resistance When the printed area of the sheet after inkjet recording was soaked in water and rubbed with a finger, judgment was made based on whether the printed area dissolved or smeared. 5: No change to l: Bleeding and dissolution.
実施例1
厚さ50μm、透明+19596のポリエステルシート
上に、アセトアセチル基を6モル%含有し、けん化度8
8モル%、重合度1000の変性PVA100部とグリ
オキザール5部とを含む10雨水溶液を乾燥後の塗布量
が15 y/dとなるよう塗布し乾燥してインクジェッ
ト記録用のシートを得た。Example 1 A 50 μm thick, transparent +19596 polyester sheet containing 6 mol% of acetoacetyl groups and a saponification degree of 8
A 10 rainwater solution containing 100 parts of modified PVA with 8 mol % and a degree of polymerization of 1000 and 5 parts of glyoxal was applied so that the coating amount after drying was 15 y/d and dried to obtain an inkjet recording sheet.
このシートのインク吸収速度、にじみ度、透明度、耐水
性を第1表に示す。Table 1 shows the ink absorption speed, degree of bleeding, transparency, and water resistance of this sheet.
比較例1〜4
実施例1で用いられた組成物にかえて以下の樹脂を用い
る以外は実施例1と同様に行った。結果を併せて第1表
に示す。Comparative Examples 1 to 4 Comparative examples were carried out in the same manner as in Example 1 except that the following resins were used in place of the composition used in Example 1. The results are also shown in Table 1.
比較例1で用いた樹脂:実施例1で用いられた変性PV
Aのみ。Resin used in Comparative Example 1: Modified PV used in Example 1
A only.
比較例2で用いた樹脂;重合度1000、けん化度88
モル%のi’vΔ100部とグリオキザール5部。Resin used in Comparative Example 2; degree of polymerization 1000, degree of saponification 88
100 parts of mole% i'vΔ and 5 parts of glyoxal.
比較例3で用いた樹脂:ポリビニルピロリドン。Resin used in Comparative Example 3: polyvinylpyrrolidone.
比較例4で用いた樹脂:カチオン基2モル%含有し、重
合度1750、けん化度88モル%のカチオン変性PV
A。Resin used in Comparative Example 4: Cation-modified PV containing 2 mol% of cationic groups, a degree of polymerization of 1750, and a degree of saponification of 88 mol%
A.
実施例2
比較例3で得られたインクジェット記録用のシートのポ
リビニルピロリドン層上に実施例1で用いらfした組成
物を乾燥固形分が5 fib侃となるように塗布し乾燥
してインクジェット記録用のシートを得た。結果を併せ
て第】表に示す。Example 2 The composition used in Example 1 was applied onto the polyvinylpyrrolidone layer of the inkjet recording sheet obtained in Comparative Example 3 so that the dry solid content was 5 fib, and dried to perform inkjet recording. I got a sheet for it. The results are also shown in Table 1.
実施例3
比較例4で得られたインクジェット記録用のシートのカ
チオン変性PVA層上に実施例1で用いらルた配合物を
乾燥面Jl−9分が3 y//r11となるよう塗布し
乾燥してインクジェット記録用のシートを得た。結果を
併せて第1表に示す。Example 3 The formulation used in Example 1 was applied onto the cation-modified PVA layer of the inkjet recording sheet obtained in Comparative Example 4 so that the dry surface Jl-9 min was 3 y//r11. It was dried to obtain an inkjet recording sheet. The results are also shown in Table 1.
以下余白
第 1 表
実施例4〜l】
支持基体としてアート紙を用い、第2表に示す如き変性
PVaと有機化合物とを用いる以外は実施例1と同様に
行った。結果を併せて第2表に示す。The following is a margin: Table 1 Examples 4 to 1 The same procedure as in Example 1 was carried out except that art paper was used as the support substrate and modified PVa and organic compounds as shown in Table 2 were used. The results are also shown in Table 2.
実施例12
支持基体として上質紙を用い実施例】で用いられた組成
物を用いた下記組成の塗工液を乾燥固形分が20 y/
rrtとなるようにバーコーターにより塗布し乾燥して
記録用のシートを得た。このシートのインク吸収速度、
にじみ度、耐水性を第3表に示す。Example 12 Using high-quality paper as a support substrate, a coating solution with the following composition using the composition used in Example was coated with a dry solid content of 20 y/
It was coated with a bar coater so as to give rrt and dried to obtain a recording sheet. The ink absorption speed of this sheet,
Table 3 shows the degree of bleeding and water resistance.
比較例5
実施例12で用いられた組成物にかえて比較例2で用い
ら几た組成物を用いる以外は実施例12と同様に行った
。結果を併せて第3表に示す。Comparative Example 5 The same procedure as Example 12 was carried out except that the composition used in Comparative Example 2 was replaced with the composition used in Example 12. The results are also shown in Table 3.
実施例13
支持基体として上質紙を用い実施例1で用いられた組成
物を乾燥固形分が5 y/rdとなるよう塗布し乾燥し
て記録用のシートを得た。このシートの性能を第4表に
示す。Example 13 Using high-quality paper as a supporting substrate, the composition used in Example 1 was coated so that the dry solid content was 5 y/rd and dried to obtain a recording sheet. The performance of this sheet is shown in Table 4.
比較例6
実施例13において用いられた組成物にかえてポリビニ
ルピロリドンを用いる以外は実施例13と同様に行った
。結果を併せて第4表に示す。Comparative Example 6 The same procedure as in Example 13 was carried out except that polyvinylpyrrolidone was used instead of the composition used in Example 13. The results are also shown in Table 4.
第 4 表Table 4
Claims (2)
ニルアルコールとアルデヒド類、アミン類、エポキシ類
から選ばれる少くとも1種の有機化合物とを含有してな
ることを特徴とする耐水性に優れたインクジェット記録
用のシート。(1) An inkjet with excellent water resistance characterized in that the supporting substrate contains modified polyvinyl alcohol having an acetoacetyl group and at least one organic compound selected from aldehydes, amines, and epoxies. Sheet for recording.
る少くとも1種の有機化合物がグリオキサールであり、
かつ該変性ポリビニルアルコール100重量部に対する
重量配合比率が1〜20重量部である特許請求の範囲第
1項に記載のインクジェット記録用のシート。(2) at least one organic compound selected from aldehydes, amines, and epoxies is glyoxal,
The sheet for inkjet recording according to claim 1, wherein the weight blending ratio is 1 to 20 parts by weight based on 100 parts by weight of the modified polyvinyl alcohol.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62008819A JPS63176173A (en) | 1987-01-16 | 1987-01-16 | Sheet for ink jet recording |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62008819A JPS63176173A (en) | 1987-01-16 | 1987-01-16 | Sheet for ink jet recording |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63176173A true JPS63176173A (en) | 1988-07-20 |
Family
ID=11703415
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62008819A Pending JPS63176173A (en) | 1987-01-16 | 1987-01-16 | Sheet for ink jet recording |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63176173A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01190483A (en) * | 1988-01-27 | 1989-07-31 | Canon Inc | Material to be recorded |
EP1010738A1 (en) * | 1998-12-18 | 2000-06-21 | Eastman Kodak Company | Ink jet printing method |
EP1437229A2 (en) | 2003-01-08 | 2004-07-14 | Fuji Photo Film Co., Ltd. | Ink jet printing sheet |
EP1609613A1 (en) | 2004-06-22 | 2005-12-28 | Fuji Photo Film Co., Ltd. | Image recording medium manufacturing method |
JP2006169297A (en) * | 2004-12-13 | 2006-06-29 | Nippon Synthetic Chem Ind Co Ltd:The | Coating agent composition |
DE112004002698T5 (en) | 2004-02-03 | 2008-09-04 | Mitsubishi Paper Mills Limited | Ink jet recording material |
EP2055498A1 (en) | 2007-10-31 | 2009-05-06 | Fujifilm Corporation | Inkjet-recording medium and inkjet-recording method using same |
EP2055497A2 (en) | 2007-10-31 | 2009-05-06 | FUJIFILM Corporation | Inkjet-recording medium and inkjet-recording method using same |
EP2130876A1 (en) | 2004-02-24 | 2009-12-09 | FUJIFILM Corporation | Inorganic fine particle dispersion and manufacturing method thereof as well as image-recording material |
EP2275274A2 (en) | 2009-03-31 | 2011-01-19 | Fujifilm Corporation | Method of producing recording medium |
EP2436740A1 (en) | 2003-09-29 | 2012-04-04 | Fujifilm Corporation | Ink for inkjet printing, ink set for inkjet printing, inkjet recording material and producing method for inkjet recording material, and inkjet recording method |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60189481A (en) * | 1984-03-09 | 1985-09-26 | Daio Seishi Kk | Ink jet recording paper improved in water resistance |
JPS61125878A (en) * | 1984-11-22 | 1986-06-13 | Honshu Paper Co Ltd | Ink jet recording sheet |
JPS61189986A (en) * | 1985-02-20 | 1986-08-23 | Canon Inc | Recording material |
-
1987
- 1987-01-16 JP JP62008819A patent/JPS63176173A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60189481A (en) * | 1984-03-09 | 1985-09-26 | Daio Seishi Kk | Ink jet recording paper improved in water resistance |
JPS61125878A (en) * | 1984-11-22 | 1986-06-13 | Honshu Paper Co Ltd | Ink jet recording sheet |
JPS61189986A (en) * | 1985-02-20 | 1986-08-23 | Canon Inc | Recording material |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01190483A (en) * | 1988-01-27 | 1989-07-31 | Canon Inc | Material to be recorded |
EP1010738A1 (en) * | 1998-12-18 | 2000-06-21 | Eastman Kodak Company | Ink jet printing method |
EP1437229A2 (en) | 2003-01-08 | 2004-07-14 | Fuji Photo Film Co., Ltd. | Ink jet printing sheet |
EP2436740A1 (en) | 2003-09-29 | 2012-04-04 | Fujifilm Corporation | Ink for inkjet printing, ink set for inkjet printing, inkjet recording material and producing method for inkjet recording material, and inkjet recording method |
DE112004002698T5 (en) | 2004-02-03 | 2008-09-04 | Mitsubishi Paper Mills Limited | Ink jet recording material |
EP2130876A1 (en) | 2004-02-24 | 2009-12-09 | FUJIFILM Corporation | Inorganic fine particle dispersion and manufacturing method thereof as well as image-recording material |
EP1609613A1 (en) | 2004-06-22 | 2005-12-28 | Fuji Photo Film Co., Ltd. | Image recording medium manufacturing method |
JP2006169297A (en) * | 2004-12-13 | 2006-06-29 | Nippon Synthetic Chem Ind Co Ltd:The | Coating agent composition |
EP2055498A1 (en) | 2007-10-31 | 2009-05-06 | Fujifilm Corporation | Inkjet-recording medium and inkjet-recording method using same |
EP2055497A2 (en) | 2007-10-31 | 2009-05-06 | FUJIFILM Corporation | Inkjet-recording medium and inkjet-recording method using same |
EP2275274A2 (en) | 2009-03-31 | 2011-01-19 | Fujifilm Corporation | Method of producing recording medium |
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