JPS63175158A - Production of uniform long fiber nonwoven fabric - Google Patents

Production of uniform long fiber nonwoven fabric

Info

Publication number
JPS63175158A
JPS63175158A JP62000822A JP82287A JPS63175158A JP S63175158 A JPS63175158 A JP S63175158A JP 62000822 A JP62000822 A JP 62000822A JP 82287 A JP82287 A JP 82287A JP S63175158 A JPS63175158 A JP S63175158A
Authority
JP
Japan
Prior art keywords
fiber nonwoven
long
nonwoven fabric
laminate
long fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP62000822A
Other languages
Japanese (ja)
Inventor
肇 渡部
岡本 三宜
正夫 梅澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP62000822A priority Critical patent/JPS63175158A/en
Publication of JPS63175158A publication Critical patent/JPS63175158A/en
Pending legal-status Critical Current

Links

Landscapes

  • Nonwoven Fabrics (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 C産業上の利用分野〕 本発明は長繊維不織布の製造法に関する。更に詳しくは
、異方性がとくに少なく、かつ目付変動率が小さいとい
った均斉な長繊維不織布の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION C. Industrial Application Field The present invention relates to a method for producing a long fiber nonwoven fabric. More specifically, the present invention relates to a method for producing a uniform long-fiber nonwoven fabric with particularly low anisotropy and a small rate of variation in area weight.

〔従来の技術〕[Conventional technology]

主として連続フィラメント群より成る長繊維不織布の製
造方法に関しては種々提案され、工業的生産に適用され
ている。これらの多くは、熱可塑性繊維の連続フィラメ
ントを溶融紡糸し、これを捕集して長繊維不織ウエップ
とした後、フィラメント間を結合して、主として長繊維
より成る長繊維不織布を製造するものである。しかし、
これらの方法においては、溶融紡糸されたフィラメント
群を広げて工業的に必要とされる幅のシートを得るため
幅方向に長い矩形の紡糸装置を設けるか、複数の紡糸装
置を幅方向に配列する方法が一般的に行われており、フ
ィラメント間や錘間の相互干渉や紡糸するのに使用され
た流体の部分的乱流あるいは静電気による斥力や引力に
よりウエップの堆積が不均一となり、どうしても目付斑
が大きくなるという致命的な問題があった。更に、連続
フィラメント群を溶融紡糸しこれを捕集することによっ
て得られた不織ウエップは、それを構成するフィラメン
トの方向がどうしてもウエップの進行方向に偏り、この
ようなウエップから得られる長繊維不織布は長さ方向に
裂は易い致命的な欠陥(いわゆる異方性)を存していた
Various methods for producing long fiber nonwoven fabrics mainly composed of continuous filaments have been proposed and applied to industrial production. In most of these, continuous filaments of thermoplastic fibers are melt-spun, collected to form a long-fiber nonwoven web, and then the filaments are bonded to produce a long-fiber nonwoven fabric mainly made of long fibers. It is. but,
In these methods, in order to spread the melt-spun filaments and obtain a sheet with an industrially required width, a rectangular spinning device that is long in the width direction is provided, or a plurality of spinning devices are arranged in the width direction. This method is commonly used, and due to mutual interference between filaments and spindles, partial turbulence of the fluid used for spinning, or repulsion or attraction due to static electricity, the deposition of the wap becomes uneven, resulting in uneven basis weight. There was a fatal problem in that the size of the Furthermore, in a nonwoven woven fabric obtained by melt-spinning a group of continuous filaments and collecting them, the direction of the filaments constituting the filament is biased toward the traveling direction of the woven fabric, and the long-fiber nonwoven fabric obtained from such a woven woven fabric is difficult to obtain. had a fatal defect (so-called anisotropy) that made it easy to crack in the length direction.

本発明は、上記の諸問題を解決するのが目的である。即
ち、目付斑が小さく、且つ異方性が極めて小さいといっ
た均斉な長繊維不織布を能率良く製造する方法を狙いと
するものである。
The present invention aims to solve the above problems. That is, the aim is a method for efficiently producing a uniform long-fiber nonwoven fabric with small unevenness in area weight and extremely low anisotropy.

〔問題点を解決するための手段〕[Means for solving problems]

本発明者はこれらの問題点に関し、長期にわたり鋭意検
討を重ねた結果、ついに本発明に到達し即ち、本発明は
、長繊維不織布を製造する方法において、主として連続
フィラメント群より成る長繊維不織ウエップをクロスラ
ッパーに導いて積層する第一の工程と、第一の工程で形
成された長繊維不織ウエップの積層体を延伸する第二の
工程と、第二の工程を経た長繊維不織ウエップの積層体
を結合処理する第三の工程を、少なくとも含むことを特
長とする均斉な長繊維不織布の製造法である。
As a result of long-term intensive studies regarding these problems, the present inventor has finally arrived at the present invention. Namely, the present invention provides a long-fiber nonwoven fabric mainly consisting of continuous filaments in a method for producing a long-fiber nonwoven fabric. A first step of guiding the webs to a cross wrapper and laminating them, a second step of stretching the laminate of long fiber nonwoven webs formed in the first step, and a long fiber nonwoven web after the second step. This is a method for producing a uniform long-fiber nonwoven fabric, characterized in that it includes at least a third step of bonding a laminate of webs.

以下本発明の詳細な説明する。The present invention will be explained in detail below.

本発明に於いては、主として連続フィラメント群より成
る長繊維不織ウエップ(以下ウエップと称する)をクロ
スランバーに導いて積層する第一の工程が含まれること
を必須要件としている。
In the present invention, it is an essential requirement that a first step is included in which a long fiber nonwoven web (hereinafter referred to as a web) mainly consisting of a group of continuous filaments is guided to a cross lumbar and laminated.

該第−の工程では、主として均斉な目付分布が形成され
る。即ち、該工程に於いてウエップは、クロスランパー
に於いて、供給方向に対してほぼ直角方向に移動するフ
ロア−コンベア上にほぼ一定の行程で往復して垂下せし
められ、両端で折り返され概ね等間隅にずれて積層され
、長繊維不織ウエップの積層体(以下積層体と称する)
が形成される。この場合の積層条件は、最終製品が目標
規格に合致するように、次に示す(1)式、(2)式、
(3)式の関係に於いて選択するのが好ましい。
In the second step, a mainly uniform basis weight distribution is formed. That is, in this process, the wap is suspended in a cross ramper on a floor-conveyor that moves in a direction approximately perpendicular to the supply direction, reciprocating in an approximately constant stroke, and is folded back at both ends to form approximately the same shape. A laminate of long-fiber nonwoven webs stacked with deviations between the corners (hereinafter referred to as a laminate)
is formed. In this case, the lamination conditions are as shown in the following equations (1) and (2) so that the final product meets the target specifications.
It is preferable to select based on the relationship expressed by equation (3).

N=Y/X・・・・・・・・・・・・・・ (1)v=
 (SxW)/ (NxD)  ・−−−・−(2)Y
=FX (1/R,) x (1/nz)  ・・・・
 (3)但し、 N:積層数 Y s fiN体の平均目付(g/m)X:ウエップの
平均目付(g/ m )■=積層体の排出速度(m/m
1n) S:ウエップの供給速度(m/win)W:ウエップの
幅(m) D=積層体の幅(m) F:長繊維不織布の目標平均目付(g#+?)R1:本
発明の第二の工程に於ける延伸前後の面積比(延伸部面
積/延伸後面積) R2:本発明の第三の工程に於ける結合前後の面積比(
結合部面積/結合後面積) 長繊維不織布の均斉性を表す係数の一つである目付変動
率は本発明の第一の工程の積層数を増す程低減する傾向
があり積層数60程度でほぼ飽和するので、特に限定す
るものではないが、積層数3〜60の範囲が好ましく、
生産性を勘案すると積層数10〜30の範囲が特に好ま
しい。
N=Y/X・・・・・・・・・・・・・・・ (1) v=
(SxW) / (NxD) ・---・−(2)Y
=FX (1/R,) x (1/nz)...
(3) However, N: Number of laminated layers Ys fiN Average basis weight of the body (g/m) X: Average basis weight of the wap (g/m)
1n) S: Supply speed of wap (m/win) W: Width of wap (m) D = Width of laminate (m) F: Target average basis weight of long fiber nonwoven fabric (g#+?) R1: According to the present invention Area ratio before and after stretching in the second step (stretched part area/area after stretching) R2: Area ratio before and after bonding in the third step of the present invention (
Bonded area/area after bonding) The variation rate of basis weight, which is one of the coefficients expressing the uniformity of long fiber nonwoven fabric, tends to decrease as the number of laminated layers in the first step of the present invention increases, and it almost decreases when the number of laminated layers is about 60. Since saturation occurs, the number of laminated layers is preferably in the range of 3 to 60, although it is not particularly limited.
In consideration of productivity, the number of laminated layers is particularly preferably in the range of 10 to 30.

本発明に於いては、続いて該ウエップ積層体を延伸する
第二の工程が必須要件として含まれる。
In the present invention, a second step of subsequently stretching the web laminate is included as an essential requirement.

該第二の工程に於いては、主として引き裂き強力の異方
性が修正される。即ち、第一の工程に於いてはフィラメ
ントの方向が長さ方向に偏ったウエップが交叉して積層
されるので排出される積層体は逆にフィラメントの方向
が幅方向に偏ったものとなり、そのまま結合処理すると
幅方向に裂は易い長繊維不織布となるので、該第二の工
程に於いて積層体は主として長さ方向に延伸される。延
伸装置に関しては、シート状物を把持して移送するよう
に成した複数の移送装置を進行方向にその移送速度が順
に高くなるようにして配設した装置が好ましく、ピンテ
ンクー等で積層体の幅を規制するように成した装置が更
に好ましく、又、二軸延伸機を用いて長さ方向の延伸倍
率を幅方向の延伸倍率より高くして延伸する方法が品質
がより安定し好ましい。長さ方向の延伸距離、即ち速度
の異なる一対の移送装置間の距離又は二軸延伸機の軸接
線間距離、は次の(4)式の範囲が好ましく、更に好ま
しくは次の(5)式の範囲である。
In the second step, the anisotropy of tear strength is mainly corrected. That is, in the first step, the waps with the filament direction biased in the length direction are stacked in an intersecting manner, so the laminate that is discharged has the filament direction biased in the width direction. Since the bonding process results in a long fiber nonwoven fabric that is easily torn in the width direction, the laminate is mainly stretched in the length direction in the second step. Regarding the stretching device, it is preferable to use a device in which a plurality of transfer devices configured to grip and transfer the sheet-like material are arranged so that the transfer speed thereof increases in order in the direction of movement. It is more preferable to use a device configured to regulate the amount of film, and a method in which the stretching ratio in the length direction is made higher than the stretching ratio in the width direction using a biaxial stretching machine is more preferable because the quality is more stable. The stretching distance in the length direction, that is, the distance between a pair of transfer devices with different speeds or the distance between the axis tangents of a biaxial stretching machine, is preferably within the range of the following equation (4), and more preferably within the range of the following equation (5). is within the range of

L<W/2・・・・・・・・・・・・・・ (4)L<
W/4・・・・・・・・・・・・・ ・ (5)但し、
L:長さ方向の延伸距離(m) 延伸イg率は長繊維不織布の異方性が客先の要求を満足
する範囲になるように選択すれば良く特に限定しない。
L<W/2・・・・・・・・・・・・・・・ (4) L<
W/4・・・・・・・・・・・・・ (5) However,
L: Stretching distance in the length direction (m) The stretching Ig ratio is not particularly limited as long as it is selected so that the anisotropy of the long fiber nonwoven fabric satisfies the customer's requirements.

本発明に於いては、第二の工程を経た積層体を結合処理
する第三の工程が含まれる。該第三の工程に於いては、
主として第一の工程及び第二の工程で形成された均斉性
が固定される。即ち、本発明に於いて、結合処理とは、
積層体に実用上十分な形態安定性を付与することを目的
として、該積層体を構成するフィラメント間を部分的に
拘束する手段のことであり、高速流体処理、接着処理、
融着処理、圧着処理などが用途に応じて好ましく適用さ
れ、樹脂を含む溶液又は乳化液を含浸せしめた後凝固、
乾燥する方法を適宜併用するのがより好ましい。該第三
の工程を経た積層体は、それを構成するフィラメント間
が拘束されているが故に、以後の工程に於いて受ける張
力及び搬送や保管などの際に被る部分的な外力に対して
極めて安定で、均斉性が保持される。
The present invention includes a third step of bonding the laminate that has undergone the second step. In the third step,
Mainly the symmetry formed in the first step and the second step is fixed. That is, in the present invention, the joining process is
A means for partially restraining the filaments that make up the laminate, with the aim of imparting practically sufficient morphological stability to the laminate, and includes high-speed fluid processing, adhesive treatment,
Fusion treatment, pressure bonding treatment, etc. are preferably applied depending on the application, and after impregnation with a solution or emulsion containing resin, solidification,
It is more preferable to use a drying method in combination as appropriate. The laminate that has gone through the third process is extremely resistant to tension during subsequent steps and partial external forces during transportation and storage, since the filaments that make up the laminate are constrained. Stable and maintains symmetry.

また、本発明に用いられるウエップの素材としては、主
として連続フィラメントから成る長繊維不織ウエップを
形成出来るものであれば良く、例えばポリアミド、ポリ
エステル、ポリオレフィン、ポリフェニレン等の単独重
合体や共重合体及びこれらの混合体から選択される。フ
ィラメントの形態も特に限定されない。即ち、単−成分
系でも複数成分系でも良く、芯鞘型複合体でも海島型複
合体でも分割型複合体でも良い。フィラメント群も同種
フィラメントから成るものに限らず、異種フィラメント
が混在して成るものでも良い。フィラメントの断面の形
状は、円、楕円、偏平、多角形、中空でも良く、不規則
な断面のフィラメントが混在するものでも良い。フィラ
メント繊度も特に限定されない。又、適宜、各工程で、
天然又は人造の短繊維を混入しても良いことは云うまで
もない。
Furthermore, the material for the web used in the present invention may be any material that can form a long fiber non-woven web mainly consisting of continuous filaments, such as homopolymers and copolymers such as polyamide, polyester, polyolefin, polyphenylene, etc. selected from a mixture of these. The form of the filament is also not particularly limited. That is, it may be a single-component system or a multi-component system, and may be a core-sheath type composite, a sea-island type composite, or a split type composite. The filament group is not limited to being composed of the same kind of filaments, but may also be composed of a mixture of different kinds of filaments. The cross-sectional shape of the filament may be circular, elliptical, oblate, polygonal, or hollow, or may include a mixture of filaments with irregular cross-sections. The filament fineness is also not particularly limited. Also, as appropriate, in each process,
It goes without saying that natural or artificial short fibers may be mixed.

次に実施例によって本発明を更に詳細に説明するが、こ
れによって本発明が限定解釈されたり、本発明の有効性
が損なわれたりするものではない。
EXAMPLES Next, the present invention will be explained in more detail with reference to Examples, but this does not limit the present invention or impair the effectiveness of the present invention.

なお、実施例中の評価値は以下の方法で測定し算出した
値である。
In addition, the evaluation values in the examples are values measured and calculated by the following method.

(1)目付と目付変動率 一辺が5CI11の正方形サンプルを、幅方向に20行
、長さ方向に20列マトリックス状に400個採取し、
個々の重量を測定し、目付(g/mJに換算した値に付
いて、平均値と不偏分散の平方根の平均目付(g/mz
)に対する百分率値(%)を求め、それぞれ平均目付(
g/m2) 、目付変動率(%)とした。
(1) Fabric weight and fabric weight variation rate Collect 400 square samples of 5CI11 on each side in a matrix of 20 rows in the width direction and 20 columns in the length direction,
Measure the weight of each individual, convert it to g/mJ, and calculate the average weight (g/mz
) and calculate the percentage value (%) for each average basis weight (
g/m2) and area weight variation rate (%).

(2)引き裂き強力 幅方向及び長さ方向に付いてそれぞれ、ヨコが7.5c
mでタテが20cmでヨコ方向の中央部に7゜5cmの
切り込みを入れた矩形のサンプルを、それぞれ10個採
取し、引張速度10cm/minで引き裂き強力を測定
し、それぞれの方向毎に平均値を求め、幅方向引き裂き
強力(kg)及び長さ方向引き裂き強力(kg)とした
(2) Tear strength: 7.5c in both width and length directions.
Ten rectangular samples with a length of 20 cm and a cut of 7°5 cm in the center in the horizontal direction were taken, and the tearing strength was measured at a tensile speed of 10 cm/min, and the average value was obtained for each direction. were calculated and defined as the tear strength in the width direction (kg) and the tear strength in the length direction (kg).

(3)異方性 幅方向引き裂き強力(kg)と長さ方向引き裂き強力(
kg)の差の絶対値の平均値に対する百分率(%)を求
め、これを異方性(%)とした。
(3) Anisotropic width direction tear strength (kg) and length direction tear strength (kg)
The percentage (%) of the absolute value of the difference in kg) with respect to the average value was determined, and this was defined as the anisotropy (%).

実施例1 溶融紡糸機、空気エジェクター、反射板から主として成
る紡糸ユニットを進行方向に30CI11間隔で5個配
設した直接ウエップ製造装置を用いて、平均単糸繊度が
0.9デニールのナイロン6連続フィラメント群から成
り平均目付力月4 g/m2、幅50cmのウエップを
連続して捕集し、続いて該ウエップに油剤(プチルスチ
アレート=6%、ラウリルアルコールのエチレンオキサ
イド付加物:4%、ホスフェイト系制電剤:1%、水:
89%)をウエップ重量に対して4.5%付与し、供給
速度60m/minでクロスラッパーに供給し積層数1
5で幅5mの積層体を排出速度0.4m/minで得た
Example 1 Using a direct web manufacturing device in which five spinning units mainly consisting of a melt spinning machine, an air ejector, and a reflector were arranged at intervals of 30 CI 11 in the traveling direction, nylon 6 continuous yarn with an average single yarn fineness of 0.9 denier was produced. A wap consisting of a group of filaments with an average basis weight of 4 g/m2 and a width of 50 cm was collected continuously, and then an oil agent (butyl sthialate = 6%, ethylene oxide adduct of lauryl alcohol: 4%) was collected on the wap. , phosphate antistatic agent: 1%, water:
89%) was applied at 4.5% to the weight of the wafer, and the material was fed to the cross wrapper at a feeding speed of 60 m/min, and the number of layers was 1.
5, a laminate with a width of 5 m was obtained at a discharge speed of 0.4 m/min.

積層体の平均目付は210.6 g/m”であった。続
いて該積層体を・軸延伸装置に4き、長さ方向に1゜3
7倍に延伸した。積層体の幅は延伸することによって延
伸前の0.95倍の4.75mとなった。続いて該延伸
された積層体をニードルパンチ装置に導き、表裏からそ
れぞれ針密度300木/cI11の結合処理を施し、乾
燥した後両端の耳部を2cmずつ切除して、平均目付が
180g/m”、幅4.46mの長繊維不織布を速度0
.5 m/minで得た。
The average basis weight of the laminate was 210.6 g/m''.Subsequently, the laminate was placed in an axial stretching device and stretched 1°3 in the length direction.
It was stretched 7 times. By stretching, the width of the laminate became 4.75 m, which was 0.95 times the width before stretching. Subsequently, the stretched laminate was introduced into a needle punching device, where it was bonded with a needle density of 300 wood/cI11 from the front and back sides, and after drying, the ears at both ends were cut off by 2 cm to give an average basis weight of 180 g/m. ”, a long fiber nonwoven fabric with a width of 4.46 m at a speed of 0
.. It was obtained at a speed of 5 m/min.

比較例1 溶融紡糸機、空気エジェクター、反射板から主として成
る紡糸ユニットを、進行方向に対して直角方向(幅方向
)に30cm間隔で、5個配設した直接ウニ、ブ製造装
置を用いて、平均単糸繊度が0.9デニールのナイロン
6連続フィラメント群から成り平均目付が162g/m
2、幅146cmのつ工・7ブを連続して捕集し、続い
て該ウエップに実施例1と同じ油剤をウエップ重量に対
して4.5%付与した後、ニードルパンチ装置に導き、
表裏からそれぞれ針密度300本/ ciの結合処理を
施し、乾燥した後、両端の耳部を10cmずつ切除して
、平均目付が180g/m”、幅1.26mの長繊維不
織布を速度1.6 m/minで得た。
Comparative Example 1 Using a direct sea urchin manufacturing device, five spinning units mainly consisting of a melt spinning machine, an air ejector, and a reflector were arranged at 30 cm intervals in the direction perpendicular to the direction of travel (width direction). Consisting of 6 continuous nylon filaments with an average single filament fineness of 0.9 denier and an average basis weight of 162 g/m
2. Continuously collect 7 pipes with a width of 146 cm, and then apply the same oil as in Example 1 to the web at 4.5% of the weight of the web, and then introduce it to a needle punch device.
Bonding treatment was applied to the front and back sides at a needle density of 300 needles/ci, and after drying, the ears at both ends were cut out by 10 cm, and the long fiber nonwoven fabric with an average basis weight of 180 g/m" and a width of 1.26 m was dried at a speed of 1. 6 m/min.

上記各側に於ける長繊維不織布の特性を第1表に示す。Table 1 shows the properties of the long fiber nonwoven fabric on each side.

第1表 〔発明の効果〕 上述したように、本発明によれば、異方性が特に少なく
、且つ目付変動率が小さいといった均斉な長繊維不織布
を効率良く提供できるので、その工業的価値は極めて大
なるものである。
Table 1 [Effects of the Invention] As described above, according to the present invention, it is possible to efficiently provide a uniform long-fiber nonwoven fabric with particularly low anisotropy and a small rate of variation in basis weight. It is extremely large.

Claims (1)

【特許請求の範囲】[Claims] 長繊維不織布を製造する方法において、主として連続フ
ィラメント群より成る長繊維不織ウエップをクロスラッ
パーに導いて積層する第一の工程と、第一の工程で形成
された長繊維不織ウエップの積層体を延伸する第二の工
程と、第二の工程を経た長繊維不織ウエツプの積層体を
結合処理する第三の工程を、少なくとも含むことを特長
とする均斉な長繊維不織布の製造法。
A method for producing a long-fiber nonwoven fabric includes a first step of guiding a long-fiber nonwoven web mainly consisting of a group of continuous filaments to a cross wrapper and laminating the same, and a laminate of the long-fiber nonwoven web formed in the first step. 1. A method for producing a uniform long fiber nonwoven fabric, comprising at least a second step of stretching a long fiber nonwoven web, and a third step of bonding a laminate of long fiber nonwoven webs that have undergone the second step.
JP62000822A 1987-01-06 1987-01-06 Production of uniform long fiber nonwoven fabric Pending JPS63175158A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62000822A JPS63175158A (en) 1987-01-06 1987-01-06 Production of uniform long fiber nonwoven fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62000822A JPS63175158A (en) 1987-01-06 1987-01-06 Production of uniform long fiber nonwoven fabric

Publications (1)

Publication Number Publication Date
JPS63175158A true JPS63175158A (en) 1988-07-19

Family

ID=11484347

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62000822A Pending JPS63175158A (en) 1987-01-06 1987-01-06 Production of uniform long fiber nonwoven fabric

Country Status (1)

Country Link
JP (1) JPS63175158A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013020A1 (en) * 1995-10-06 1997-04-10 Nippon Petrochemicals Company, Limited Water jet intertwined nonwoven cloth and method of manufacturing the same
JP2006301641A (en) * 2005-04-19 2006-11-02 E I Du Pont De Nemours & Co Method for thermal development of photosensitive element using oriented development medium

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997013020A1 (en) * 1995-10-06 1997-04-10 Nippon Petrochemicals Company, Limited Water jet intertwined nonwoven cloth and method of manufacturing the same
JP2006301641A (en) * 2005-04-19 2006-11-02 E I Du Pont De Nemours & Co Method for thermal development of photosensitive element using oriented development medium

Similar Documents

Publication Publication Date Title
US4310594A (en) Composite sheet structure
DE10080786B3 (en) Cleavable multicomponent fiber and fibrous article comprising it
US3864198A (en) Interconnected network structures
DE1435116B2 (en) FLEECE-LIKE AREA, CONTAINING PLEXUS THREAD MATERIAL
JPH02127553A (en) Stretchable non-woven fabric and production thereof
DE3248572A1 (en) HOT SEALING TAPE
EP0106604A2 (en) Patterned belt bonded material and method for making the same
JPS63175158A (en) Production of uniform long fiber nonwoven fabric
JPS6026859B2 (en) Nonwoven fabric stretching device
US2794237A (en) Method of producing fiber glass mats
DE1560660A1 (en) Non-woven fabric
US6214463B1 (en) Hydrophilic fibers and cloth-like articles and filters made by using the same
JP4015831B2 (en) Ultrafine fiber nonwoven fabric and method for producing the same
US3847729A (en) Deep-drawable plastic composite comprising plastic film on fibrous support
JP2751451B2 (en) Laminated nonwoven sheet
JP4026279B2 (en) Split type composite fiber and fiber molded body using the same
JP3790013B2 (en) Stretched orthogonal nonwoven fabric and its production method
JPH04126815A (en) Ultra-fine fiber-forming conjugate fiber
EP0043390B1 (en) Composite sheet structure, process for its preparation and laminates comprising said structure
JP4453179B2 (en) Split fiber and fiber molded body using the same
JPH01201566A (en) Bulky spun-bond nonwoven fabric
JP4026280B2 (en) Polyolefin-based split composite fiber, production method thereof, and fiber molded body using the fiber
JPS6059121A (en) Heat-bondable conjugate fiber and production thereof
JPS616306A (en) Ultrafine plastic tube structure and its production
JP4785659B2 (en) Thermally divided composite fiber and fiber assembly