JPS63154610A - Prehair rinse type hair treating agent composition - Google Patents
Prehair rinse type hair treating agent compositionInfo
- Publication number
- JPS63154610A JPS63154610A JP30103386A JP30103386A JPS63154610A JP S63154610 A JPS63154610 A JP S63154610A JP 30103386 A JP30103386 A JP 30103386A JP 30103386 A JP30103386 A JP 30103386A JP S63154610 A JPS63154610 A JP S63154610A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- treatment composition
- rinse type
- hair treatment
- type hair
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 229960001230 asparagine Drugs 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- YSMODUONRAFBET-UHFFFAOYSA-N delta-DL-hydroxylysine Natural products NCC(O)CCC(N)C(O)=O YSMODUONRAFBET-UHFFFAOYSA-N 0.000 description 1
- PMMYEEVYMWASQN-UHFFFAOYSA-N dl-hydroxyproline Natural products OC1C[NH2+]C(C([O-])=O)C1 PMMYEEVYMWASQN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- YSMODUONRAFBET-UHNVWZDZSA-N erythro-5-hydroxy-L-lysine Chemical compound NC[C@H](O)CC[C@H](N)C(O)=O YSMODUONRAFBET-UHNVWZDZSA-N 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000002523 gelfiltration Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- QJHBJHUKURJDLG-UHFFFAOYSA-N hydroxy-L-lysine Natural products NCCCCC(NO)C(O)=O QJHBJHUKURJDLG-UHFFFAOYSA-N 0.000 description 1
- 229960002591 hydroxyproline Drugs 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229960000310 isoleucine Drugs 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ヘアリンス前に毛髪に塗布して用いるプレヘ
アリンス型毛髪処理剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a pre-hair rinse type hair treatment composition that is used by applying it to the hair before rinsing the hair.
更に詳しくは、少なくとも一種以上の陰イオン性高分子
を含み、毛髪になめらかさ、しなやかさを与えながら、
張り、こしをも付与することを特徴とするプレヘアリン
ス型毛髪処理剤組成物に関する。More specifically, it contains at least one kind of anionic polymer, gives smoothness and suppleness to the hair,
The present invention relates to a pre-hair rinse type hair treatment composition that also imparts firmness and stiffness.
［従来の技術］
従来シャンプーは、地肌や毛髪についた汚れを洗浄し清
潔にする機能を有するが、その反面幾つかの欠点が指摘
されてきている。それは、頭皮から分泌される皮脂成分
を過剰に除去するため毛髪の手触り感触、ブラシもしく
は櫛の通り、光沢、まとまりやすさ等が劣ることである
。[Prior Art] Conventional shampoos have the function of cleaning and cleaning dirt from the skin and hair, but on the other hand, several drawbacks have been pointed out. This is because the sebum components secreted from the scalp are removed excessively, so that the texture of the hair, the ability to brush or comb it, the shine, and the ease with which it is combed are deteriorated.
そのためシャンプー後の毛髪に、なめらかさ、しなやか
さ、光沢を回復させ櫛通りを良くする事を目的とした毛
髪化粧料としては、ヘアリンス、ヘアー）・リートメン
ト、ヘアーコンデショナー等の名称（以下、ヘアリンス
剤として総称する）のものが市販されている。これら毛
髪化粧料には、主に、第４級アンモニウム塩が配合され
、更になめらかさ、しっとりさ、光沢を向上させる目的
で、油分やタンパク質等が添加されてきた。Therefore, hair cosmetics that aim to restore smoothness, suppleness, and luster to hair after shampooing and improve combability include hair rinse, hair treatment, hair conditioner, etc. (hereinafter referred to as hair conditioner). (generally referred to as agents) are commercially available. These hair cosmetics mainly contain quaternary ammonium salts, and oils, proteins, etc. have also been added for the purpose of improving smoothness, moisture, and gloss.
［発明が解決しようとする問題点］
しかしながら、シャンプー後に従来のヘアリンス剤を使
用することにより、髪のしなやかさ、なめらかさ、光沢
を回復させ櫛通りをよくすることはできるが、その反面
、油っぽさ、へたつき等が現れ、更には仕上り感の重さ
から髪に張り、こしがなくなり自然な感じでのまとまり
やすさに難点があることが指摘されてきた。[Problems to be Solved by the Invention] However, by using a conventional hair rinse after shampooing, it is possible to restore the suppleness, smoothness, and luster of the hair and make it easier to comb, but on the other hand, it removes oil. It has been pointed out that hair tends to feel stiff and dry, and it also has a heavy finish that causes it to stick to the hair.
本発明者らは、こうした事情にかんがみ、上記の欠点を
解決すべく鋭意研究を重ねた結果、シャンプー後ヘアリ
ンス剤を使用する前に、特定の陰イオン性高分子を有効
成分として配合したプレヘアリンス型毛髪処理剤組成物
を毛髪に塗布し、その後ヘアリンス剤で処理すれば、シ
ャンプー後の髪に、しなやかさ、なめらかさ、光沢を与
え、更には櫛通りを回復させ、尚且つＪ油つぼさ、べた
つき感がなく髪にはり、こしを与え、自然な感じでのま
とまりやすさが得られることを見いだしこの知見にもと
すいて本発明を完成するに至った。In view of these circumstances, the present inventors have conducted extensive research to solve the above-mentioned drawbacks, and as a result, we have developed a pre-hair rinse containing a specific anionic polymer as an active ingredient, before using a post-shampoo hair rinse. By applying the hair treatment composition to the hair and then treating it with a hair rinse, it gives suppleness, smoothness, and luster to the hair after shampooing, and also restores combability. The present inventors have discovered that the hair does not have a sticky feeling, gives hair elasticity, stiffness, and provides natural-looking manageability, and based on this knowledge, the present invention has been completed.
［問題点を解決するための手段および作用］すなわち、
本発明は、少なくとも一種以上の陰イオン性高分子を含
有することを特徴とするプレヘアリンス型毛髪処理剤組
成物を提供するものである。[Means and actions for solving the problem] That is,
The present invention provides a pre-hair rinse type hair treatment composition characterized by containing at least one kind of anionic polymer.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明に用いられる陰イオン性高分子は、キサンタンガ
ム、グルコマンナン、クインスシードガム、ローカスト
ビーンガム、アラビアガム、グアーガム、アルギン酸ソ
ーダ、カラギーナン（カッパー。The anionic polymers used in the present invention include xanthan gum, glucomannan, quince seed gum, locust bean gum, gum arabic, guar gum, sodium alginate, and carrageenan (kappa).
ラムダ、アイオタ）、ペクチン、ヒアルロン酸、コンド
ロイチン４硫酸、コンドロイチン８硫酸、デルマタン硫
酸、コンドロイチン４，８ジ硫酸、デルマタン４，８ジ
硫酸、ケラタン硫酸、又はヘパラン硫酸といった天然多
糖類又はポリアクリル酸ソーダ、カルボキシメチルセル
ロース、メチルビニールエーテル／無水マレイン酸共重
合物、アクリル酸エステル／メタアクリル酸エステル／
ダイアセトンアクリルアマイド／アクリル酸／メタアク
リル酸共重合物又は架橋化カルボキシビニールポリマー
などの合成高分子であり、これらのうち一種又は二種以
上が任意に選択されて用いられる。natural polysaccharides or sodium polyacrylates such as lambda, iota), pectin, hyaluronic acid, chondroitin 4 sulfate, chondroitin 8 sulfate, dermatan sulfate, chondroitin 4,8 disulfate, dermatan 4,8 disulfate, keratan sulfate, or heparan sulfate. , carboxymethylcellulose, methyl vinyl ether/maleic anhydride copolymer, acrylic ester/methacrylic ester/
It is a synthetic polymer such as diacetone acrylamide/acrylic acid/methacrylic acid copolymer or crosslinked carboxyvinyl polymer, and one or more of these may be arbitrarily selected and used.
陰イオン性高分子の配合量はプレヘアリンス型毛髪処理
剤組成物全量中の０．０１〜５重量％（以下、単に％と
略す）、好ましくは０．１〜３％である。０．０１未満
では、本プレへアリンス型毛髪処理剤組成物を塗布後、
ヘアリンス剤で処理してもしなやかさ、なめらかさ、光
沢が発現しにくく、毛髪の、はり、こしも満足されるも
のではない。また５％を越えると毛髪がべたついたり乾
いた後でごねついたりして好ましくない。The amount of anionic polymer blended is 0.01 to 5% by weight (hereinafter simply referred to as %), preferably 0.1 to 3%, based on the total amount of the pre-hair rinse type hair treatment composition. If it is less than 0.01, after applying this pre-hair rinse type hair treatment composition,
Even when hair is treated with a hair rinse agent, suppleness, smoothness, and luster are difficult to develop, and the strength and stiffness of the hair are also unsatisfactory. Moreover, if it exceeds 5%, the hair becomes sticky or sticky after drying, which is not preferable.
本発明に係る陰イオン性高分子を含有してなるプレヘア
リンス型毛髪処理剤組成物は、更に下記一般式［１コで
示される第４級トリメチルアンモニウム誘導ポリペプタ
イドの一種又は二種以上を併用することによって、毛髪
への効果が更に改善される。The pre-hair rinse type hair treatment composition containing the anionic polymer according to the present invention further comprises a combination of one or more quaternary trimethylammonium-derived polypeptides represented by the following general formula [1]. By doing so, the effect on hair is further improved.
Ｃ■■３Ｒ１
ＣＨ３０）ｒ
（式中、Ｒ１はコラーゲンより誘導されるポリペプタイ
ドを構成するアミノ酸であり、ｎは８〜２０である。）
以下に、第４級トリメチルアンモニウム誘導ポリペプタ
イドについて説明する。C■■3R1 CH30)r (In the formula, R1 is an amino acid constituting a polypeptide derived from collagen, and n is 8 to 20.) The quaternary trimethylammonium-derived polypeptide is explained below. .
上記一般式（Ｉ）におけるポリペプタイド部分はコラー
ゲンを構成する蛋白質（絹蛋白質）より誘導されるもの
であり、Ｒ１で示される側鎖はコラーゲンを構成する蛋
白質の側鎖アミノ酸を示す。The polypeptide moiety in the general formula (I) is derived from a protein (silk protein) constituting collagen, and the side chain represented by R1 represents the side chain amino acid of the protein constituting collagen.
一般的には、アラニン、グリシン、バリン、ロイシン、
イソロイシン、プロリン、フェニルアラニン、チロシン
、セリン、トレオニン、アルギニン、リジン、アスパラ
ギン酸、アスパラギン、グルタミン酸、ヒスチジン、メ
チオニン、ヒドロキシプロリン、ヒドロキシリジンなど
の混合物であり、その−例を挙げれば表１のような組成
である。Generally, alanine, glycine, valine, leucine,
It is a mixture of isoleucine, proline, phenylalanine, tyrosine, serine, threonine, arginine, lysine, aspartic acid, asparagine, glutamic acid, histidine, methionine, hydroxyproline, hydroxylysine, etc., and its composition is as shown in Table 1, for example. It is.
（以下余 白）
（以下余白）
このような一般式（１）で示される第４級トリメチルア
ンモニウム誘導ポリペプタイドは、一般的には３−クロ
ロ−２−ヒドロキシプロピルトリメチルアンモニウムク
ロライドとコラーゲン誘導ポリペプタイドとの反応によ
って得られる。(Hereinafter in the margin) (Hereinafter in the margin) The quaternary trimethylammonium-derived polypeptide represented by the general formula (1) is generally composed of 3-chloro-2-hydroxypropyltrimethylammonium chloride and collagen-derived polypeptide. Obtained by reaction with
上記反応に使用される８−クロロ−２−ヒドロキシプロ
ピルトリメチルアンモニウムクロライド（以下、ＣＴＡ
という）は、既存化学物質（２）−１８１として公知の
ものであり、濃度５０％（重量％、以下同様）程度の水
溶液が市販されていて容易に入手可能である。一方、コ
ラーゲン誘導ポリペプタイドは一般的には、コラーゲン
の変性物であるゼラチンを酸、アルカリあるいは蛋白質
分解酵素などを用いて加水分解することによって得られ
る。8-chloro-2-hydroxypropyltrimethylammonium chloride (hereinafter referred to as CTA) used in the above reaction
) is known as existing chemical substance (2)-181, and an aqueous solution with a concentration of about 50% (weight %, hereinafter the same) is commercially available and can be easily obtained. On the other hand, collagen-derived polypeptides are generally obtained by hydrolyzing gelatin, which is a denatured product of collagen, using an acid, alkali, or a protease.
加水分解に際して、添加する酸、アルカリあるいは酵素
の量、反応温度、反応時間を適宜選択することによって
、得られる動物性蛋白質誘導ポリペプタイドの重合度（
一般式（１）のｎの値）を８〜２０すなわち分子量で約
３００〜約２０００の範囲に適宜調製できる。During hydrolysis, the degree of polymerization (
The value of n in general formula (1) can be suitably adjusted to a range of 8 to 20, that is, a molecular weight of about 300 to about 2,000.
なお、このような分子量範囲のコラーゲン誘導ポリペプ
タイドは、従来より天然物誘導の安全な化粧品原料とし
て多方面に使用されている。そして一般式（’ Ｉ ）
で示される第４級トリメチルアンモニウム誘導ポリペプ
タイドにおいてｎが３未満では毛髪への吸着が充分でな
く、またｎが２０１ｅ超えると毛髪への吸着が弱くなり
、かつゲル化することなどにより取り扱いが困難になる
からである。Note that collagen-derived polypeptides having such a molecular weight range have been used in a wide range of fields as safe cosmetic raw materials derived from natural products. and the general formula ('I)
If n is less than 3 in the quaternary trimethylammonium-derived polypeptide shown, adsorption to hair is insufficient, and if n exceeds 201e, adsorption to hair becomes weak and gelation occurs, making it difficult to handle. This is because it becomes
そして、反応はコラーゲン誘導ポリペプタイドの水溶液
を滴下し、コラーゲン誘導ポリペプタイドとＣＴＡを水
中で接触させることによって行なわれる。反応に際して
反応系内のｐＨを８〜１２、とくに９〜１１に保つこと
が望ましく、そのため水酸化ナトリウム、水酸化カリウ
ムなどのアルカリ水溶液を必要に応じて反応液中に滴下
することが行なわれる。Then, the reaction is carried out by dropping an aqueous solution of collagen-induced polypeptide and bringing the collagen-induced polypeptide and CTA into contact with each other in water. During the reaction, it is desirable to maintain the pH within the reaction system at 8 to 12, particularly 9 to 11, and for this reason, an aqueous alkaline solution such as sodium hydroxide or potassium hydroxide is added dropwise into the reaction solution as necessary.
反応時、反応系内のｐ Ｈを前記のごとき範囲に維持す
るのは、コラーゲン誘導ポリペプタイドのアミノ基がＣ
ＴＡと反応するにはｐＨ８以」二のアルカリであること
が望ましく、またｐ Ｈが１２を超えるとＣＴＡやコラ
ーゲン誘導ポリペプタイドが加水分解を起こすからであ
る。During the reaction, the pH within the reaction system is maintained within the above range because the amino groups of the collagen-derived polypeptide are carbon
In order to react with TA, it is desirable that the alkali has a pH of 8 or higher, and if the pH exceeds 12, hydrolysis of CTA and collagen-derived polypeptides will occur.
反応は常温でも進行するが温度が高いほど反応がはやく
なる。しかし、ｐｌ（が高い状態では温度が高くなると
コラーゲン誘導ポリペプタイドやＣＴＡの加水分解が促
進され、低分子のものしが得られなくなるので、高くて
も６０℃以下にするのが好ましい。反応に際してコラー
ゲン誘導ポリペプタイドは、濃度が高いと粘度が高くな
り均一な反応が難しくなるので、濃度３０〜５０％程度
の水溶液にするのが好ましく、ＣＴＡは市販の濃度的５
０％の水溶液をそのまま使用すればよい。The reaction proceeds even at room temperature, but the higher the temperature, the faster the reaction. However, if the temperature is high in a state where PL is high, the hydrolysis of collagen-induced polypeptides and CTA will be promoted, making it impossible to obtain a low-molecular compound, so it is preferable to keep the temperature at most 60°C or lower. Collagen-induced polypeptide is preferably an aqueous solution with a concentration of about 30 to 50%, since a high concentration increases the viscosity and makes it difficult to react uniformly.
A 0% aqueous solution may be used as is.
コラーゲン誘導ポリペプタイドへのＣＴＡの滴下は３０
分〜６時間で終わるのが好ましい。Dripping CTA onto collagen-induced polypeptides is 30
It is preferable to complete the process in minutes to 6 hours.
ＣＴＡを滴下すると、下記の式に示すような反応が進行
し、
（以下余白）
Ｈ３Ｒ
Ｈ３０Ｈ
Ｈ３Ｒ
塩化水素が生成して反応液のｐｌ（が低下するので、ア
ルカリをＣＴＡの滴下と同時に滴下し、撹拌して液中の
ｐＨを反応に適するｐＨに維持するのが・ 好ましく
、そのため滴下に少なくとも８０分間程度の時間をかけ
るのが好ましい。ＣＴＡの滴下後、約２〜６時間撹拌を
続け、かつｐＨを９〜１１に保ち、さらに１昼夜放置す
るか、あるいは約６０℃まで加温して反応を完了させる
のが好ましい。そして、反応の進行と終了は、Ｖａｎ
５ｌａｋｅ法によりポリへブタイド中のアミノ態チッ素
を測定することによって確認される。When CTA is added dropwise, a reaction as shown in the following formula proceeds, (blank below) H3R H30H H3R Hydrogen chloride is generated and the PL of the reaction solution decreases, so alkali is added dropwise at the same time as CTA is added. It is preferable to maintain the pH of the liquid at a pH suitable for the reaction by stirring, and therefore it is preferable to allow at least 80 minutes for the dropwise addition.After dropping the CTA, continue stirring for about 2 to 6 hours, and It is preferable to maintain the pH at 9 to 11 and to complete the reaction by leaving it for one day or night or by heating it to about 60°C.The progress and completion of the reaction is determined by Van
This is confirmed by measuring amino nitrogen in polyhebutide using the 5lake method.
第４級トリメチルアンモニウム誘導ポリペプタイドの配
合量は、プレヘアリンス型毛髪処理剤組成物全量中の０
．００１〜５重量％、好ましくは０．０１〜３重量％で
ある。これ未満では頭髪に対する親和性が不足して吸着
性に劣り、この範囲を越えると使用感触がべたつき気味
となり、好ましくない。The blending amount of the quaternary trimethylammonium-derived polypeptide is 0% in the total amount of the pre-hair rinse type hair treatment composition.
．． 0.001 to 5% by weight, preferably 0.01 to 3% by weight. If it is less than this range, the affinity for the hair will be insufficient and the adsorption properties will be poor, and if it exceeds this range, the feel of the product will feel sticky when used, which is not preferable.
本発明において使用される陰イオン性高分子を仮にカチ
オン性界面活性剤を主成分とするヘアリンス剤組成物中
に併用配合しても本発明の様な優れた効果は得られない
ばかりか、組成物中で凝集物が生じたり、又経日で分離
、沈澱が起こり安定性はきわめて悪いものであった。Even if the anionic polymer used in the present invention were to be combined in a hair rinse composition containing a cationic surfactant as a main component, not only would the excellent effects of the present invention not be obtained, but the composition The stability was extremely poor, with aggregates forming in the product and separation and precipitation occurring over time.
本発明のプレヘアリンス型毛髪処理剤組成物には、上記
の必須成分に加えて配合組成物を完成させるための水を
要する他、毛髪化粧料に常用される成分や添加剤を配合
することも可能である。即ち、高級アルコール、シリコ
ーン油、流動パラフィン等の油分、プロピレングリコー
ル、グリセリン等の保湿剤、ＰＯＥ（ポリオキシエチレ
ン：以下同じ）硬化ヒマシ油、ＰＯＥアルキルエーテル
等の非イオン性界面活性剤、クエン酸、乳酸等の有機酸
、塩化ナトリウム、塩化カリウム等の無機塩、香料、色
剤、防腐剤、キレート剤、紫外線吸収剤等を本発明の効
果を損なわない範囲で適宜配合できる。In addition to the above-mentioned essential ingredients, the pre-hair rinse type hair treatment composition of the present invention requires water to complete the composition, and may also contain ingredients and additives commonly used in hair cosmetics. It is possible. In other words, oils such as higher alcohols, silicone oils, and liquid paraffin, humectants such as propylene glycol and glycerin, nonionic surfactants such as POE (polyoxyethylene; the same applies hereinafter), hydrogenated castor oil, and POE alkyl ether, and citric acid. , organic acids such as lactic acid, inorganic salts such as sodium chloride and potassium chloride, fragrances, coloring agents, preservatives, chelating agents, ultraviolet absorbers, etc. may be appropriately incorporated within the range that does not impair the effects of the present invention.
［実施例］
次に実施例によって本発明を更に詳細に説明する。本発
明はこれにより限定されるものではない。[Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby.
配合量は重量％である。 尚、プレヘアリンス型毛髪処
理剤組成物の性能評価は以下の方法によった。The blending amount is in weight%. The performance of the pre-hair rinse type hair treatment composition was evaluated by the following method.
洗髪後のらの感触
女性パネル２０名によるＨａｌｆ−Ｈｅａｄ法（生類比
較法）にて比較判定した。すなわち、市販シャンプーＬ
ｏｇで１回洗髪し軽くすすいだ後、同じシャンプー５ｇ
で２回目の洗髪をした。軽くすすいだ後、頭髪の半分に
本発明のプレヘアリンス型毛髪処理剤組成物１．０ ｇ
を塗布し、もう半分は何もつけない。２分後に、市販ヘ
アリンス剤を頭髪全部に塗布し２分後、お湯で全てを洗
い流す。The feel of dry hair after washing the hair was evaluated by a panel of 20 women using the Half-Head method (organism comparison method). That is, commercially available shampoo L
After washing your hair once with OG and rinsing it lightly, use 5g of the same shampoo.
I washed my hair for the second time. After rinsing lightly, apply 1.0 g of the pre-hair rinse type hair treatment composition of the present invention to half of the hair.
, and the other half is left unapplied. After 2 minutes, apply a commercially available hair rinse to all of your hair, and after 2 minutes, rinse everything off with hot water.
その後、風乾し官能によって評価した。Thereafter, it was air-dried and evaluated by sensory evaluation.
評価は、「なめらかさ」「シなやかさ」丁光沢」「毛髪
のはり、こし」「髪のまとまり易さ」の５項目について
実施した。Evaluations were made on five items: "smoothness,""flexibility,""shininess,""hairstiffness," and "easiness of hair to manage."
官能評価は、本発明のプレヘアリンス型毛髪処理剤組成
物を塗布しない方を基準として一対比較によって以下の
４段階評価でおこなった。The sensory evaluation was performed on the following 4-grade scale based on the comparison without applying the pre-hair rinse type hair treatment composition of the present invention.
著しく良好であれば◎、良好であれば○、普通であれば
△、劣っていれば×と評価した。The evaluation was rated as ◎ if it was extremely good, ◯ if it was good, △ if it was fair, and × if it was poor.
実施例１〜８
表２に示す毛髪処理剤組成物を以下の方法にて調整した
。Examples 1 to 8 Hair treatment compositions shown in Table 2 were prepared in the following manner.
（製法）
比較例１．２は、イオン交換水にジプロピレングリコー
ル又はグルセリンを添加溶解し、更に、加熱溶解したＰ
ＯＥ（２０）オレイルエーテルを添加し順次防腐剤、色
剤、香料を添加し試料を得た。(Manufacturing method) Comparative example 1.2 was prepared by adding and dissolving dipropylene glycol or glycerin in ion-exchanged water, and then heating and dissolving P.
OE (20) oleyl ether was added, followed by a preservative, a coloring agent, and a fragrance to obtain a sample.
比較例３は、イオン交換水に、ジプロピレングリコール
、カセイカリを添加し、加熱溶解し７０℃に保つ。（Ａ
部）他の成分を混合し加熱溶解して７０℃に保つ。（Ｂ
部）Ａ部にＢ部を添加し、攪拌混合した後、ホモミキサ
ーにて乳化した。乳化後かきまぜながら３０℃まで冷却
して、乳液状のヘアクリームを得た。In Comparative Example 3, dipropylene glycol and caustic potash were added to ion-exchanged water, dissolved by heating, and kept at 70°C. (A
Part) Mix other ingredients, heat and dissolve and keep at 70°C. (B
Part) Part B was added to Part A, stirred and mixed, and then emulsified using a homomixer. After emulsification, the mixture was cooled to 30°C while stirring to obtain a milky hair cream.
実施例１〜３はイオン交換水に各種陰イオン性高分子を
攪拌溶解し、その後加熱溶解したＰＯＥ（２０）オレイ
ルエーテル防腐剤、香料、色剤を順次添加しゲル状の試
料を得た。In Examples 1 to 3, various anionic polymers were stirred and dissolved in ion-exchanged water, and then heated and dissolved POE (20) oleyl ether preservative, fragrance, and colorant were sequentially added to obtain gel-like samples.
（効果）
表２かられかるように本発明例では、なめらかさ、しな
やかさ、光沢、毛髪のはり、こし髪のまとまりやすさの
全ての項目において、比較例の保湿剤水溶液やヘアクリ
ームに比べ非常に優れていることがわかる。(Effects) As can be seen from Table 2, the examples of the present invention were superior to the moisturizer aqueous solution and hair cream of the comparative examples in all items of smoothness, suppleness, luster, hair elasticity, and ease of curling hair. It turns out that it is very good.
（以下余白）
実施例４〜９
表３に示す毛髪処理剤組成物を以下の方法にて調整した
。(Hereinafter, blank spaces) Examples 4 to 9 Hair treatment compositions shown in Table 3 were prepared by the following method.
（製 法）
表３に示す各種高分子をジプロピレングリコールに湿潤
分散させ、イオン交換水に添加し攪拌溶解し、その後、
加熱溶解したＰＯＥ（２０）オレイルエーテル、防腐剤
、香料、色剤を順次溶解し試料を得た。(Manufacturing method) The various polymers shown in Table 3 were wet-dispersed in dipropylene glycol, added to ion-exchanged water, stirred and dissolved, and then
A sample was obtained by sequentially dissolving POE (20) oleyl ether, a preservative, a fragrance, and a coloring agent which had been heated and dissolved.
（効果）
表３かられかるように、陰イオン性高分子を含有してい
ない毛髪処理剤を用いた場合、なめらかさが著しく劣り
、しなやかさ、光沢も好ましくなく、又、毛髪のはり、
こしも適切でなくかえってごわつく傾向にあった。陰イ
オン性高分子を含有した系が非常に優れたなめらかさ、
しなやかさと、セットのしやすい毛髪へのはり、こしを
付与する理由は定かでないがシャンプー後、陰イオン性
高分子が毛髪に静電的に吸着しコートした状態となす、
その後ヘアリンス剤で処理すると、ヘアリンス剤中の陽
イオン性界面活性剤との親和性が増して複合体を形成し
更に、ヘアリンス剤中の油分が、陽イオン界面活性剤の
親油基に物理的に吸着することにより、洗い流した後も
、複合体ならびに油分が毛髪に残存することにより、優
れた使用性が現れるためと考えられる。(Effects) As can be seen from Table 3, when a hair treatment agent that does not contain anionic polymers is used, the smoothness is significantly inferior, and the flexibility and gloss are also unfavorable.
The strain was not appropriate and it tended to become stiff. The system containing anionic polymer has excellent smoothness,
The reason for giving the hair elasticity and stiffness that makes it easy to set is unclear, but after shampooing, the anionic polymer electrostatically adsorbs to the hair and coats it.
When subsequently treated with a hair rinse, the affinity with the cationic surfactant in the hair rinse increases and a complex is formed. This is thought to be due to the fact that the complex and oil remain in the hair even after washing, resulting in excellent usability.
（以下余白）
実施例１０〜１１
表４に示す毛髪処理剤組成物を実施例１〜９と同様にし
て調整し効果を調べた。(The following is a blank space) Examples 10 to 11 The hair treatment compositions shown in Table 4 were prepared in the same manner as in Examples 1 to 9, and their effects were investigated.
尚、比較例９、実施例１１に配合された第４級トリメチ
ルアンモニウム誘導コラーゲンポリペプタイドは次の参
考例１で示された方法により得られた。The quaternary trimethylammonium-derived collagen polypeptides blended in Comparative Example 9 and Example 11 were obtained by the method shown in Reference Example 1 below.
参考例
濃度４０．５％のコラーゲン誘導ポリペプタイド８３８
ｇ（コラーゲン誘導ポリペプタイドの平均分子量１５０
０、アミノ態チッ素の総量２１６ミリモル）を反応容器
に入れ、撹拌しながら濃度４９％のＣＴＡ水溶液７１ｇ
（コラーゲン誘導ポリペプタイドのアミノ態チッ素の０
．８５当量）を８０分間かけて滴下し、かつその間２０
％水酸化ナトリウム水溶液を適宜滴下して反応後のＰＨ
を１１．０に維持しながら２時間撹拌を続け、ついで２
４時間放置した後、アミノ態チッ素を測定したところ、
アミノ態チッ素の総量は３９ミリモルであり、アミノ態
チッ素の８２％が反応していた。Reference example Collagen-induced polypeptide 838 at a concentration of 40.5%
g (average molecular weight of collagen-derived polypeptide 150
0, total amount of amino nitrogen (216 mmol) was placed in a reaction container, and while stirring, 71 g of CTA aqueous solution with a concentration of 49% was added.
(0 of amino nitrogen in collagen-derived polypeptide
．． 85 equivalents) was added dropwise over 80 minutes, and during that time 20
% sodium hydroxide aqueous solution dropwise as needed to adjust the pH after the reaction.
Continue stirring for 2 hours while maintaining the temperature at 11.0, then
After leaving it for 4 hours, amino nitrogen was measured.
The total amount of amino nitrogen was 39 mmol, and 82% of the amino nitrogen had reacted.
つぎに弱酸型陽イオン交換樹脂アンバーライトＩＲＣ−
５０（商品名、オルガノ（株））１２０ｍｌを加え、ｐ
Ｈ６，７に中和し、反応液中のナトリウムイオンとわず
かに残存している未反応のＣＴＡをイオン交換樹脂に吸
着させ、ついでイオン交換樹脂を除去して乾燥残分３０
％の水溶液を得た。Next, weak acid type cation exchange resin Amberlite IRC-
Add 120 ml of 50 (trade name, Organo Co., Ltd.) and
The sodium ions in the reaction solution and the slightly remaining unreacted CTA are adsorbed on an ion exchange resin, and then the ion exchange resin is removed to leave a dry residue of 30
% aqueous solution was obtained.
得られた水溶液について第４級アンモニウム塩の呈性反
応を行なったところ、テトラフェニルホウ素ナトリウム
により白色の沈澱を生じ、またドラーゲンドルフ試薬に
より赤色の沈澱を生じ、陽性を示した。When the obtained aqueous solution was subjected to a characteristic reaction of quaternary ammonium salt, a white precipitate was produced by sodium tetraphenylboron, and a red precipitate was produced by Dragendorff's reagent, indicating a positive result.
さらに、コラーゲン誘導ポリペプタイドとＣＴＡとが結
合していることを確認するために、得られた水溶液を用
い、ゲル濾過（Ｇ−２５、ファルマシア社製）を行ない
、各分子量フラクションについて、上記の呈性反応を行
なったところ、各フラクションはいずれも第４級アンモ
ニウム塩の呈性反応が陽性であり、コラーゲン誘導ポリ
ペプタイドとＣＴＡとが結合していることが確認された
。Furthermore, in order to confirm that the collagen-derived polypeptide and CTA are bound, the resulting aqueous solution was subjected to gel filtration (G-25, manufactured by Pharmacia), and each molecular weight fraction was analyzed as described above. When a sexual reaction was performed, each fraction was positive for the quaternary ammonium salt reaction, confirming that the collagen-induced polypeptide and CTA were bound together.
（効果）
表４かられかるように、第４級トリメチルアンモニウム
誘導コラーゲンポリペプタイド配合だけでは、髪への効
果は決して満足されるものではなかった。しかし、本発
明の陰イオン性高分子と組合せ配合した試料は、全ての
項目において優れており、特に、毛髪のはり、こし又、
髪のまとまりやすさにおいて、一段と優れた効果を示し
た。(Effects) As can be seen from Table 4, the effects on hair were by no means satisfactory just by incorporating quaternary trimethylammonium-derived collagen polypeptides. However, the sample formulated in combination with the anionic polymer of the present invention was excellent in all items, especially in terms of hair elasticity, stiffness, and stiffness.
It showed an even better effect in making hair more manageable.
［発明の効果］
本発明のプレヘアリンス型の毛髪処理剤組成物は従来の
シャンプーとヘアリンスの間に使用する。[Effects of the Invention] The pre-hair rinse type hair treatment composition of the present invention is used between a conventional shampoo and a hair rinse.
而して、髪にしなやかさ、なめらかさ、光沢を与え、櫛
通りをよくし、且つへたつき、油っぽさがなく、髪に張
り、こしを与えて自然な感じで髪をまとめることができ
る。Therefore, it gives suppleness, smoothness, and luster to the hair, makes it easy to comb, and is free from frizz and oiliness, giving tension and stiffness to the hair and tying it up in a natural manner. I can do it.
Claims (6)
ることを特徴とするプレヘアリンス型毛髪処理剤組成物
。(1) A pre-hair rinse type hair treatment composition containing at least one kind of anionic polymer.
範囲第（１）項記載のプレヘアリンス型毛髪処理剤組成
物。(2) The pre-hair rinse type hair treatment composition according to claim (1), wherein the anionic polymer is a natural polysaccharide.
クインスシードガム、ローカストビーンガム、アラビア
ガム、グアーガム、アルギン酸ソーダ、カラギーナン（
カッパー、ラムダ、アイオタ）、ペクチン、ヒアルロン
酸、コンドロイチン４硫酸、コンドロイチン８硫酸、デ
ルマタン硫酸、コンドロイチン４，８ジ硫酸、デルマタ
ン４，８ジ硫酸、ケラタン硫酸又はヘパラン硫酸である
特許請求の範囲第（２）項記載のプレヘアリンス型毛髪
処理剤組成物。(3) Natural polysaccharides include xanthan gum, glucomannan,
Quince seed gum, locust bean gum, gum arabic, guar gum, sodium alginate, carrageenan (
Copper, lambda, iota), pectin, hyaluronic acid, chondroitin 4 sulfate, chondroitin 8 sulfate, dermatan sulfate, chondroitin 4,8 disulfate, dermatan 4,8 disulfate, keratan sulfate or heparan sulfate ( 2) Pre-hair rinse type hair treatment composition.
範囲第（１）項記載のプレヘアリンス型毛髪処理剤組成
物。(4) The pre-hair rinse type hair treatment composition according to claim (1), wherein the anionic polymer is a synthetic polymer.
メチルセルロース、メチルビニールエーテル／無水マレ
イン酸共重合物、アクリル酸エステル／メタアクリル酸
エステル／ダイアセトンアクリルアマイド／アクリル酸
／メタアクリル酸共重合物又は架橋化カルボキシビニー
ルポリマーである特許請求の範囲第（４）項記載のプレ
ヘアリンス型毛髪処理剤組成物。(5) The synthetic polymer is polysodium acrylate, carboxymethyl cellulose, methyl vinyl ether/maleic anhydride copolymer, acrylic ester/methacrylic ester/diacetone acrylamide/acrylic acid/methacrylic acid copolymer, or The pre-hair rinse type hair treatment composition according to claim (4), which is a crosslinked carboxyvinyl polymer.
メチルアンモニウム誘導ポリペプタイドの一種又は二種
以上を含有することを特徴とする特許請求の範囲第（１
）項乃至第（５）のいずれかに記載のプレヘアリンス型
毛髪処理剤組成物。 ▲数式、化学式、表等があります▼・・・・・（１） （式中、Ｒ＿１はコラーゲンより誘導されるポリペプタ
イドを構成するアミノ酸であり、ｎは３〜２０である。 ）(6) Claim No. 1 characterized in that it further contains one or more quaternary trimethylammonium-derived polypeptides represented by the following general formula [1].
The pre-hair rinse type hair treatment composition according to any one of items ) to (5). ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・(1) (In the formula, R_1 is an amino acid that constitutes a polypeptide derived from collagen, and n is 3 to 20.)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30103386A JPH0713007B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30103386A JPH0713007B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63154610A true JPS63154610A (en) | 1988-06-27 |
| JPH0713007B2 JPH0713007B2 (en) | 1995-02-15 |
Family
ID=17892042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30103386A Expired - Lifetime JPH0713007B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0713007B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175924A (en) * | 1987-12-28 | 1989-07-12 | Hoou Kk | Hair treatment agent |
-
1986
- 1986-12-17 JP JP30103386A patent/JPH0713007B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01175924A (en) * | 1987-12-28 | 1989-07-12 | Hoou Kk | Hair treatment agent |
| JPH0460564B2 (en) * | 1987-12-28 | 1992-09-28 | Hoyu Kk |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0713007B2 (en) | 1995-02-15 |
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