JPS63152679A - Fluid ink for printer - Google Patents
Fluid ink for printerInfo
- Publication number
- JPS63152679A JPS63152679A JP62280514A JP28051487A JPS63152679A JP S63152679 A JPS63152679 A JP S63152679A JP 62280514 A JP62280514 A JP 62280514A JP 28051487 A JP28051487 A JP 28051487A JP S63152679 A JPS63152679 A JP S63152679A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- dye
- alcohol
- printer
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012530 fluid Substances 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000003960 organic solvent Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 5
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 4
- 239000012046 mixed solvent Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 abstract description 9
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 abstract description 4
- 235000019445 benzyl alcohol Nutrition 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 53
- 239000000975 dye Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical compound CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- GDXHBFHOEYVPED-UHFFFAOYSA-N 1-(2-butoxyethoxy)butane Chemical compound CCCCOCCOCCCC GDXHBFHOEYVPED-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- CNJRPYFBORAQAU-UHFFFAOYSA-N 1-ethoxy-2-(2-methoxyethoxy)ethane Chemical compound CCOCCOCCOC CNJRPYFBORAQAU-UHFFFAOYSA-N 0.000 description 1
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- -1 n-heptatool Chemical compound 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、流体インクを媒体とするプリンタ、特にイン
クジェットプリンタ、インク式ワイヤドツトプリンタの
インクに関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to inks for printers using fluid ink as a medium, particularly inkjet printers and ink-type wire dot printers.
インクジェットプリンタは、現在ノンインパクト式プリ
ンタとして注目を集めているが、その印刷システムは、
流体インクを加圧することにより５０〜１５０μｍのノ
ズルオリフィスからインク小満として分離せしめ、該小
滴を必要に応じて記録紙に噴出することにより印刷する
ことができる。Inkjet printers are currently attracting attention as non-impact printers, but their printing system is
Printing can be performed by pressurizing the fluid ink to separate it from a nozzle orifice of 50 to 150 .mu.m as a droplet of ink, and ejecting the droplet onto recording paper as required.
一方、インク式ワイヤドツトプリンタは、ドツトプリン
タのワイヤにインクを付着させ、ワイヤ表面のインクを
記録紙に転写することにより印刷するシステムである０
両者いずれも、流体インクを用いるため、記録ヘッドへ
のインク供給方法など共通する点が多い、従って問題点
の共通する点が多く、インクで必要とされる要件は、次
の事柄が挙げられる。On the other hand, an ink-type wire dot printer is a system that prints by attaching ink to the wire of the dot printer and transferring the ink on the wire surface to recording paper.
Since both use fluid ink, they have many things in common, such as the method of supplying ink to the recording head.Therefore, they have many problems in common, and the requirements for the ink include the following.
（１） インクが記録ヘッドノズルにおいて目詰りを
しないこと。(1) Ink should not clog the recording head nozzles.
（２）インクが記録紙に転写された時、迅速に乾燥する
こと。(2) When the ink is transferred to the recording paper, it dries quickly.
（３） インクが温度変化により凝固して、インク中
に気泡を発生しないこと。(3) The ink should not solidify due to temperature changes and bubbles should not be generated in the ink.
（４）インクが長期にわたり変質を起こさず、貯蔵性が
よいこと。(4) The ink does not deteriorate over a long period of time and has good storage properties.
（５）インクがガラスや金属を腐食しないこと。(5) The ink should not corrode glass or metal.
（６）インクの濃度が大きく紙に転写されたとき、ドツ
トの円形度、コントラストが明確であること。(6) When the ink has a high density and is transferred to paper, the circularity and contrast of the dots should be clear.
以上がインクジェットプリンタおよびインク式ワイヤド
ツトプリンタに要求されるインクの要件であるが、これ
らは前記（１）、（２）のようにお互いに相反する性質
があり、これらすべてを満足するインクをつくることは
非常に難しいことであった。The above are the requirements for ink for inkjet printers and ink-type wire dot printers, but these have mutually contradictory properties as described in (1) and (2) above, and it is difficult to create ink that satisfies all of them. was extremely difficult.
本発明の目的は、前記インク要件をすべて満足するイン
クジェットプリンタ、インク式ワイヤドツトプリンタに
適するインクを提供することにある。An object of the present invention is to provide an ink suitable for inkjet printers and ink-type wire dot printers that satisfies all of the above ink requirements.
従来のインクジェットプリンタ用インクは、はとんどが
水溶性インクであり、該インクの構成は染料、湿潤剤、
水、より成るが、この系においては湿潤剤が染料のバイ
ンダーの役割を果し、乾燥によるノズルの目詰りを防止
している。その反面記録紙に転写後のインクの速乾性は
なく、速乾性を出す場合には前記系に界面活性剤を添加
し、インクの表面張力を低下させ記録紙に浸透させるこ
とにより速乾性をだす方法が用いられている。しかし、
この方法によると、前記インク要件（６）のドツトの円
形度が、紙の繊維のにじみのため出せない欠点がある。Conventional ink for inkjet printers is mostly water-soluble ink, and the composition of the ink is dye, wetting agent,
In this system, the wetting agent acts as a binder for the dye and prevents the nozzle from clogging due to drying. On the other hand, the ink does not dry quickly after being transferred to the recording paper, and in order to achieve quick drying, a surfactant is added to the system to reduce the surface tension of the ink and allow it to permeate into the recording paper. method is used. but,
This method has the drawback that the circularity of the dots, which is the ink requirement (6), cannot be achieved due to bleeding of paper fibers.
また、水溶性インクのほとんどは凝固点が一１０℃以上
のため、凍結による気泡の発生がインク中に起こり、イ
ンクジェットプリンタの場合、気泡の存在によりインク
の圧力が伝播されず、印刷不能となる。Furthermore, since most water-soluble inks have a freezing point of 110° C. or higher, air bubbles are generated in the ink due to freezing, and in the case of an inkjet printer, the pressure of the ink is not propagated due to the presence of air bubbles, making printing impossible.
本発明は、かかる欠点を除去したプリンタ用流体インク
を提供することを目的とする。An object of the present invention is to provide a fluid ink for printers that eliminates such drawbacks.
本発明のプリンタ用流体インクは、油溶染料に代表され
る有機溶剤に可溶な染料を用いたプリンタ用流体インク
において、染料の溶媒が２０℃１１気圧の特性をもつ単
体のアルコール類又はアルキルエーテル誘導体類、又は
単独で蒸気圧が７ｍｍＨｇ以下、粘度２０ｃｐ以下の特
性をもつと共にそれらの混合物も蒸気圧が７ｍｍＨｇ以
下、粘度ことを特徴とする。The fluid ink for printers of the present invention is a fluid ink for printers using a dye soluble in an organic solvent such as an oil-soluble dye, in which the solvent of the dye is a simple alcohol or alkyl having a property of 20°C and 11 atm. Ether derivatives, or alone, have the characteristics of a vapor pressure of 7 mmHg or less and a viscosity of 20 cp or less, and a mixture thereof is also characterized by a vapor pressure of 7 mmHg or less and a viscosity.
なお、これらの単体、又は混合溶媒は、好ましくは融点
が一１０’Ｃ以下、さらに好ましくは一３０℃以下が望
ましい。The melting point of these single solvents or mixed solvents is preferably 110'C or less, more preferably 130'C or less.
本発明のインクに使用できる前記有機溶剤には、ｎ−ア
ミルアルコール、イソアミルアルコール、ｎ−ヘキサノ
ール、メチルアミルアルコール、２−エチルブタノール
、ｎ−ヘプタツール、ｎ−ドデカノール、ベンジルアル
コール、フルフリルアルコール、等のアルコール類、エ
チレングリコールモノメチルエーテルアセテート、エチ
レングリコールモノエチルエーテル、エチレングリコー
ルモノエチルエーテルアセテート、エチレングリコール
ジブチルエーテル、エチレングリコールモノブチルエー
テルアセテート、ジエチレングリコールメチルエチルエ
ーテル、ジエチレングリコールジエチルエーテル、ジエ
チレングリコールジブチルエーテル、等の多価アルコー
ルのアルキルエーテル誘導体類がある。The organic solvents that can be used in the ink of the present invention include n-amyl alcohol, isoamyl alcohol, n-hexanol, methyl amyl alcohol, 2-ethylbutanol, n-heptatool, n-dodecanol, benzyl alcohol, furfuryl alcohol, Alcohols such as ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol dibutyl ether, ethylene glycol monobutyl ether acetate, diethylene glycol methyl ethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, etc. There are alkyl ether derivatives of polyhydric alcohols.
また、本発明に用いる染料は、前記有機溶剤に可溶なも
のがノズルの目詰りをおこし難しいことがら油溶染料が
適している。Further, as the dye used in the present invention, an oil-soluble dye is suitable because dyes soluble in the organic solvent are difficult to clog the nozzle.
例えば、
Ｃ，Ｉ、５ｏｌｖｅｎｔ Ｙｅｌｌ ｏｗ ２．１４．
１６．２１．５６．６１．８０Ｃ，１，５ｏｌｖｅｎｔ
Ｏｒａｎｇｅ １．２．５．６．１４．３７．４０
Ｃ，Ｉ、５ｏｌｖｅｎｔ Ｒｅｄ １．８．２３．
３０．４９．８１．８２．８３８４．１００．１０９．
１２１
Ｃ，１，５ｏｌｖｅｎｔ Ｖｉｏｌｅｔ ８．２１．
２７Ｃ，１，５ｏｌｖｅｎｔ Ｂｌｕｅ ２．５５
．７３Ｃ，１，５ｏｌｖｅｎｔ Ｂｌａｃｋ ５．２
２．２３．１２３等がある。For example, C, I, 5olvent Yellow 2.14.
16.21.56.61.80C,1,5olvent
Orange 1.2.5.6.14.37.40
C, I, 5olvent Red 1.8.23.
30.49.81.82.8384.100.109.
121 C,1,5olvent Violet 8.21.
27C,1,5olvent Blue 2.55
．． 73C,1,5olvent Black 5.2
2.23.123 etc.
油溶染料の中でもモノアゾ系の染料は本発明に用いるイ
ンクに適しており、有ｍ溶剤に対する溶融性が優れてい
る。Among oil-soluble dyes, monoazo dyes are suitable for the ink used in the present invention, and have excellent solubility in aqueous solvents.
本発明のインクの組成としては、油溶染料２〜３０部（
重量部）を有機溶剤に溶解したものが好ましい。前記有
機溶剤の数種類の混合物を溶媒としていることも可能で
ある。The composition of the ink of the present invention includes 2 to 30 parts of oil-soluble dye (
Parts by weight) are preferably dissolved in an organic solvent. It is also possible to use a mixture of several types of the above-mentioned organic solvents as the solvent.
本発明のインクは、常温でそれ自体揮発が遅い溶剤から
成るため、ノズル部の目詰りはほとんど起らない。また
、凝固点も有機溶剤自体の融点が一３０℃以下であるた
め、それ以下になると考えてよいから、凝固による気泡
の発生は起らない。Since the ink of the present invention is composed of a solvent that itself evaporates slowly at room temperature, nozzle clogging hardly occurs. Further, since the melting point of the organic solvent itself is 130° C. or lower, it can be considered that the solidification point is lower than that, so that no bubbles are generated due to solidification.
実際、インクジェットプリンターに本発明のインクを用
いた場合、３日間程度インクを詰めたヘッドを放置して
も、印刷可能であった。また、油性インクは記録紙への
浸透が早いため、ドツトの円形度などきれいに出す、印
刷品質が劣ると一般的には考えられて来たが、本発明の
インクでは記録紙への浸透が瞬時にしておこり、紙の繊
維のにじみも少なく、良好な円形ドツトが得られた。し
かも、浸透が瞬時におこることにより、見かけ上のイン
クの速乾性がでてきて、印刷−秒後に印刷物に触れても
、紙がよごれることはなかった。In fact, when the ink of the present invention was used in an inkjet printer, printing was possible even if the ink-filled head was left for about three days. In addition, oil-based inks have been generally thought to be inferior in print quality, such as the circularity of dots, because they penetrate quickly into recording paper, but with the ink of the present invention, penetration into recording paper is instantaneous. Good circular dots were obtained with little bleeding of the paper fibers. Moreover, because the ink penetrates instantaneously, the ink dries apparently quickly, and even if the printed matter was touched seconds after printing, the paper did not become stained.
インク式ワイヤドツトプリンタに本発明のインクを用い
た場合も、前記インクジェットプリンタと同様の効果が
得られ、しかもワイヤーなどの金属部分を腐食すること
なく、潤滑油としての効果もあるため、本発明のインク
は非常に有効である。When the ink of the present invention is used in an ink-type wire dot printer, the same effects as those of the inkjet printer described above can be obtained, and in addition, it does not corrode metal parts such as wires and has the effect of lubricating oil. Ink is very effective.
本発明のインクの貯蔵性に関しては、該インクを構成す
る系が安定性の高い有機溶剤であるため直射日光をさ番
するなど薬品の最低限の保守を行えば、数年に渡る貯蔵
においても変質は起こらない。Regarding the storability of the ink of the present invention, since the system constituting the ink is a highly stable organic solvent, it can be stored for several years if minimal maintenance is done, such as keeping it out of direct sunlight. No alteration occurs.
次に本発明の実施例を挙げる。Next, examples of the present invention will be described.
実施例１
上記の組成に基いて、ベンジルアルコールを攪拌機に入
れ６０℃の温度の基で、５ｐｉｌｏｎ ＶｉｏｌｅｔＲ
Ｈを徐々に加えながら、およそ２〜３時間攪拌を続ける
。攪拌後、未溶解分や不純物、ごみ等を除去するため、
ミリポアフィルタ−１μｍで濾過を行い所望のインクを
得た。Example 1 Based on the above composition, put benzyl alcohol into a stirrer and at a temperature of 60°C, 5pilon Violet®
Continue stirring while gradually adding H for approximately 2-3 hours. After stirring, to remove undissolved matter, impurities, dirt, etc.
The desired ink was obtained by filtration using a 1 μm Millipore filter.
実施例２
上記の組成に基いて、ベンジルアルコール、ｎ−ヘキサ
ノールを攪拌機に入れ、実施例１と同様にして、所望の
インクを得た。Example 2 Based on the above composition, benzyl alcohol and n-hexanol were placed in a stirrer, and the same procedure as in Example 1 was carried out to obtain a desired ink.
実施例３
上記の組成の基いて、実施例２と同様にして、所望のイ
ンクを得た。Example 3 Based on the above composition, a desired ink was obtained in the same manner as in Example 2.
なお、上記溶媒は単体又は混合系でいづれも２０℃１気
圧のもとでの蒸気圧が７ｍｍＨｇ以下、粘度２０ｃ２以
下であった。The above-mentioned solvents, either alone or as a mixture, had a vapor pressure of 7 mmHg or less and a viscosity of 20 c2 or less at 20°C and 1 atm.
これらのインクをい用いて、インクジェットプリンタ、
インク式ドツトプリンタで印刷した結果、目詰りは３日
間の放置に対しても起らず、速乾性１秒以下でドツトコ
ントラストが濃く、良好な印刷物が得られた。Using these inks, inkjet printers,
As a result of printing with an ink-type dot printer, clogging did not occur even after being left for 3 days, and good printed matter was obtained with quick drying time of 1 second or less and high dot contrast.
以上の如く、本発明のインクは、流体インクを媒体をす
るプリンタ用インクに、目詰り、速乾性、気泡発生の防
止、貯蔵性、ドツト形とコントラストの点で優れており
、その効果は非常に大きい。As described above, the ink of the present invention is superior to ink for printers using fluid ink as a medium in terms of clogging, quick drying, prevention of bubble generation, storability, dot shape and contrast, and its effects are extremely high. big.
以 上that's all
Claims (1)
おいて、前記染料の溶媒が２０℃１気圧のもとで蒸気圧
が７ｍｍＨｇ以下、粘度２０＿Ｃ＿Ｐ以下の特性をもつ
単体のアルコール類又はアルキルエーテル誘導体類、又
は単体で蒸気圧が７ｍｍＨｇ以下粘度２０＿Ｃ＿Ｐ以下
の特性をもつと共にそれらの混合物も蒸気圧が７ｍｍＨ
ｇ以下、粘度２０＿Ｃ＿Ｐ以下の特性をもつアルコール
類及び／又は多価アルコールのアルキルエーテル誘導体
類からなる混合溶媒であることを特徴とするプリンタ用
流体インク。In a fluid ink for a printer using a dye soluble in an organic solvent, the solvent for the dye is a simple alcohol or alkyl ether derivative having a vapor pressure of 7 mmHg or less and a viscosity of 20_C_P or less at 20°C and 1 atm. or a single substance has the characteristics of a vapor pressure of 7 mmHg or less and a viscosity of 20_C_P or less, and a mixture thereof also has a vapor pressure of 7 mmH
A fluid ink for a printer, characterized in that it is a mixed solvent comprising an alkyl ether derivative of an alcohol and/or a polyhydric alcohol having a property of a viscosity of 20_C_P or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62280514A JPS63152679A (en) | 1987-11-06 | 1987-11-06 | Fluid ink for printer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62280514A JPS63152679A (en) | 1987-11-06 | 1987-11-06 | Fluid ink for printer |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6723579A Division JPS55160070A (en) | 1979-05-30 | 1979-05-30 | Fluid ink for printer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63152679A true JPS63152679A (en) | 1988-06-25 |
Family
ID=17626159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62280514A Pending JPS63152679A (en) | 1987-11-06 | 1987-11-06 | Fluid ink for printer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63152679A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100796784B1 (en) | 2006-07-18 | 2008-01-22 | 박영보 | Fluorescence ink composition and method for manufacturing thereof |
-
1987
- 1987-11-06 JP JP62280514A patent/JPS63152679A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100796784B1 (en) | 2006-07-18 | 2008-01-22 | 박영보 | Fluorescence ink composition and method for manufacturing thereof |
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