JPS63147505A - Method and device for regenerating microfilter - Google Patents

Method and device for regenerating microfilter

Info

Publication number
JPS63147505A
JPS63147505A JP29613286A JP29613286A JPS63147505A JP S63147505 A JPS63147505 A JP S63147505A JP 29613286 A JP29613286 A JP 29613286A JP 29613286 A JP29613286 A JP 29613286A JP S63147505 A JPS63147505 A JP S63147505A
Authority
JP
Japan
Prior art keywords
microfilter
regenerant
cartridge
tank
foaming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29613286A
Other languages
Japanese (ja)
Inventor
Yoshimi Sano
義美 佐野
Megumi Watanabe
渡邊 惠
Sumie Omomo
大桃 すみえ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TOYO KAGAKU KENKYUSHO KK
Original Assignee
TOYO KAGAKU KENKYUSHO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TOYO KAGAKU KENKYUSHO KK filed Critical TOYO KAGAKU KENKYUSHO KK
Priority to JP29613286A priority Critical patent/JPS63147505A/en
Publication of JPS63147505A publication Critical patent/JPS63147505A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16Use of chemical agents
    • B01D2321/164Use of bases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16Use of chemical agents
    • B01D2321/168Use of other chemical agents

Abstract

PURPOSE:To remove the clogging of a microfilter by supplying a regenerant consisting of a mixture of a peroxide, a pH regulator having a chelating function, and a foaming agent along with hot water, and injecting the regenerant under pressure into the microfilter in the reverse direction by the pressure of the gas produced by the foaming agent. CONSTITUTION:A freely attachable and detachable regenerant tank 5 is connected to the delivery port 4 of a microfilter cartridge 1. The regenerant consisting of the mixture of the peroxide such as sodium percarbonate, a pH regulator such as citric acid, and the foaming agent such as sodium bicarbonate is charged in the tank 5 along with hot water, a cap 7 is immediately put on, hence the regenerant is injected under pressure into the pore of the microfilter by the action of the foaming agent, the turbidity particles collected in the deep part of the pore of the microfilter are removed by the fine foam, the bacterial colony is simultaneously decomposed and removed, the scales of CaCO3, etc., are eluted by the pH regulator having a chelating function, and the waste liq. is discharged from a cartridge water feed port 3.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、除菌用ミクロフィルターの目詰りを解消する
ための再生方法及びその装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a regeneration method and apparatus for unclogging a sterilizing microfilter.

[従来の技術] 従来、水中の雑菌を除去する目的でメンブランフィルタ
−等を用いる方法が実施されている。しかし、上記メン
ブランフィルタ−は、0.01μ〜0.5μの微少細孔
によって除菌しているため、種々の原因で目詰りを起こ
しやすい。
[Prior Art] Conventionally, a method using a membrane filter or the like has been implemented for the purpose of removing bacteria in water. However, since the membrane filter sterilizes bacteria through micropores of 0.01 μm to 0.5 μm, it is likely to become clogged for various reasons.

例えば、目詰りの原因は、次の2点に大別できる。その
1つは、水中の濁度成分による細孔の目詰りであり、そ
してもう1つは、除菌した水中の雑菌によってメンブラ
ンフィルタ−表面に形成されるコロニーによる細孔の目
詰りである。
For example, the causes of clogging can be broadly classified into the following two points. One of these is clogging of pores due to turbidity components in water, and the other is clogging of pores due to colonies formed on the membrane filter surface by bacteria in sterilized water.

従って、目詰りが生じた場合には、メンプランフィルタ
ーを頻繁に交換する必要がある。そのため、メンブラン
フィルタ−自体が高価であることと相まって、ランニン
グコストが非常に高くなっている。
Therefore, if clogging occurs, it is necessary to frequently replace the Menplan filter. Therefore, coupled with the fact that the membrane filter itself is expensive, running costs are extremely high.

[発明が解決しようとする問題点] 上記メンブランフィルタ−などの除菌用ミクロフィルタ
ーの目詰りを除去する手段として、洗滌処理がある。例
えば、清水をミクロフィルターの吐出側から加圧注入す
る洗滌処理によれば、ミクロフィルターの再生はある程
度可能であるが、これには高圧水の注入を非常に長い時
間をかけて行わなければならない欠点がある。加えて、
この洗滌処理ではミクロフィルターの細孔の深部に捕捉
されている濁度粒子を完全に取り除くことが不可能であ
り、またミクロフィルター表面上の細菌コロニーを分解
することも可能である。
[Problems to be Solved by the Invention] As a means for removing clogging of a microfilter for sterilization such as the above membrane filter, there is a cleaning process. For example, a cleaning process in which clean water is injected under pressure from the discharge side of the microfilter allows regeneration of the microfilter to some extent, but this requires injecting high-pressure water over a very long period of time. There are drawbacks. In addition,
This washing process cannot completely remove turbidity particles trapped deep within the pores of the microfilter, and it is also possible to decompose bacterial colonies on the surface of the microfilter.

本発明は、メンブランフィルタ−などの除菌用ミクロフ
ィルターの目詰りを除去する再生方法及びその装置を提
供することを主たる目的としている。
The main object of the present invention is to provide a regeneration method and apparatus for removing clogging of a microfilter for sterilization such as a membrane filter.

[問題点を解決するための手段] 本発明に係るミクロフィルターの再生方法は、再生剤と
して過酸化物と、キレート機能をもつPH調整剤と1発
泡剤との混合物を用い、この再生剤を温水と共にミクロ
フィルターのカートリッジ内に供給し、再生剤中の発泡
剤で発生する気体圧力によって再生剤をミクロフィルタ
ーに逆方向から加圧注入することを特徴としているもの
である。
[Means for Solving the Problems] The method for regenerating a microfilter according to the present invention uses a mixture of peroxide, a PH adjuster having a chelating function, and a blowing agent as a regenerating agent. This method is characterized by supplying the regenerant together with warm water into the microfilter cartridge, and injecting the regenerant into the microfilter under pressure from the opposite direction using the gas pressure generated by the foaming agent in the regenerant.

さらに本発明に係るミクロフィルターの再生装置は、ミ
クロフィルターのカートリッジの吐出口に、再生剤を温
水と共に収容するタンクを着脱自在に連結し、再生剤中
の発泡剤で発生する気体圧力によって再生剤をミクロフ
ィルターに逆方向から加圧注入させ、ミクロフィルター
を透過した排液をカートリッジの給水口側から取り出せ
る構成としたことを特徴としているものである。
Furthermore, in the microfilter regeneration device according to the present invention, a tank containing a regenerant together with hot water is removably connected to the discharge port of the microfilter cartridge, and the regenerant is regenerated by gas pressure generated by a foaming agent in the regenerant. It is characterized by a structure in which the liquid is injected into the microfilter under pressure from the opposite direction, and the waste liquid that has passed through the microfilter can be taken out from the water supply port side of the cartridge.

[作用コ 本発明のミクロフィルターの再生方法においては、前記
配合成分の再生剤を温水につけると、微少な気泡と発生
期酸素を発生する。そこで、通常ミクロフィルターを使
用する方向とは逆の方向。
[Function] In the method for regenerating a microfilter of the present invention, when the regenerating agent of the above-mentioned blended components is immersed in hot water, minute bubbles and nascent oxygen are generated. Therefore, the direction opposite to the direction in which microfilters are normally used.

すなわち吐出口側から加圧注入することにより、ミクロ
フィルターの細孔の深部に捕捉されている濁度粒子は微
少な泡の作用で取り除かれ、同時に過酸化物の分解で発
生する発生期の酸素の作用により、ミクロフィルター表
面上の細菌コロニーは分解される。
In other words, by pressurizing injection from the discharge port side, turbidity particles trapped deep in the pores of the microfilter are removed by the action of minute bubbles, and at the same time, nascent oxygen generated by decomposition of peroxide is removed. The bacterial colonies on the surface of the microfilter are decomposed by the action of .

また、本発明のミクロフィルターの再生装置においては
、再生剤を温水と共に収容する密閉状のタンクがミクロ
フィルターカートリッジに着脱自在に連結できる構成と
されているので、再生剤のタンクは加圧注入タンクとし
て機能する。また、1つの再生剤タンクを多数のミクロ
フィルターカートリッジに共用できる。
Furthermore, in the microfilter regeneration device of the present invention, the sealed tank that accommodates the regenerant together with hot water is configured to be detachably connected to the microfilter cartridge, so the regenerant tank is a pressurized injection tank. functions as Additionally, one regenerant tank can be shared by multiple microfilter cartridges.

[発明の実施例] 第1図は本発明方法を実施する装置の基本構成を示した
ものである。
[Embodiments of the Invention] FIG. 1 shows the basic configuration of an apparatus for carrying out the method of the present invention.

1はミクロフィルターカートリッジ、2はミクロフィル
ター、3はカートリッジ給水口、4はカートリッジ吐出
口、5は再生剤を温水と共に収容する再生剤タンク、6
は再生剤送出口、7はタンクキャップであり、再生剤タ
ンク5の送出口6をカートリッジ1の吐出口4に着脱自
在に連結できるようになっている。
1 is a microfilter cartridge, 2 is a microfilter, 3 is a cartridge water supply port, 4 is a cartridge discharge port, 5 is a regenerant tank that stores a regenerant together with hot water, 6
1 is a regenerant outlet; 7 is a tank cap, and the outlet 6 of the regenerant tank 5 can be detachably connected to the outlet 4 of the cartridge 1.

本発明方法で使用する再生剤の成分中、過酸化物として
使用できるものは、過炭酸塩、過酸化水素、ベルオキソ
ニ硫酸塩、ペルオクソ硼酸塩等であり、キレート機能を
もつPH調整剤として使用できるものは、クエン酸、リ
ン酸、コハク酸、EOTA等であり、そして発泡剤とし
て使用できるものは、炭酸塩、酸化カルシウム等である
Among the components of the regenerant used in the method of the present invention, those that can be used as peroxides include percarbonate, hydrogen peroxide, peroxonisulfate, peroxoborate, etc., and can be used as a pH adjuster with a chelating function. Examples include citric acid, phosphoric acid, succinic acid, EOTA, etc., and those that can be used as blowing agents include carbonate, calcium oxide, etc.

代表例または好ましい例は、過酸化物が過炭酸ナトリウ
ム、PH調整剤がリン酸またはクエン酸。
Representative or preferred examples include sodium percarbonate as the peroxide, and phosphoric acid or citric acid as the pH adjuster.

そして発泡剤が炭酸水素ナトリウムである。また再生剤
を構成する混合物の成分割合は、過酸化物が30〜50
重景%、PH調整剤が20〜40重景%、そして発泡剤
が10〜30重量%であればよい。再生剤を構成する混
合物の極めて好適な成分割合例を挙げれば1次の通りで
ある。
And the blowing agent is sodium hydrogen carbonate. In addition, the component ratio of the mixture constituting the regenerant is 30 to 50% peroxide.
It is sufficient that the amount of the PH adjuster is 20 to 40% by weight, and the blowing agent is 10 to 30% by weight. Examples of very suitable component ratios of the mixture constituting the regenerant are as follows.

過炭酸ナトリウム   40g クエン酸       35g 炭酸水素ナトリウム  25g 混合は適当な手段で行えばよい。Sodium percarbonate 40g Citric acid 35g Sodium hydrogen carbonate 25g Mixing may be performed by any suitable means.

再生処理においては、上記再生剤を温水と共にタンク5
に入れ、直ちにキャップ7を取付けると、発泡剤の作用
によって再生剤がミクロフィルターの細孔内に加圧注入
され、微少な気泡により、ミクロフィルターの細孔の深
部に捕捉されている濁度粒子が除去され、同時にフィル
ター表面上の細菌コロニーも分解除去され、またCaC
0□などのスケール分がキレート機能をもつPH調整成
分により溶出され、排液がカートリッジ給水口3から外
に流れることが認められた。また、この再生処理によっ
て再生したミクロフィルターは新しいフィルターとほと
んど同じ濾過機能を具備していることが認められた。
In the regeneration process, the regenerant is added to tank 5 along with hot water.
When the cap 7 is immediately attached, the regenerating agent is injected under pressure into the pores of the microfilter by the action of the foaming agent, and the turbidity particles trapped deep within the pores of the microfilter are removed by the minute air bubbles. At the same time, bacterial colonies on the filter surface are also decomposed and removed, and CaC
It was observed that scale components such as 0□ were eluted by the pH adjusting component having a chelating function, and the drained liquid flowed outside from the cartridge water supply port 3. Furthermore, it was confirmed that the microfilter regenerated by this regeneration process had almost the same filtration function as a new filter.

第2図に示したものは、実用型の再生装置である。第1
図と同一または類似する部材には同じ符号を付しである
6 すなわち、1はミクロフィルターカートリッジ。
What is shown in FIG. 2 is a practical reproducing device. 1st
Components that are the same or similar to those in the figures are given the same reference numerals. 6 That is, 1 is a microfilter cartridge.

2はミクロフィルター、3は給水口、4は吐出口、5は
再生剤タンク、6はタンクの送出口、7はタンクキャッ
プであり、再生剤タンク5内には、その上部に温水を収
容するタンク8が設けられ、タンク8の底板と送出口6
とのあいだが再生剤を収容しておく薬室9とされていた
2 is a micro filter, 3 is a water supply port, 4 is a discharge port, 5 is a regenerant tank, 6 is a tank outlet, 7 is a tank cap, and inside the regenerant tank 5, hot water is stored in the upper part. A tank 8 is provided, and the bottom plate of the tank 8 and the outlet 6
The space between the two was considered to be chamber 9, which contained the regenerant.

前記温水タンク8の底抜の中心開口部には、ゴム製弁体
10が設けられ、この弁体10を開放する弁軸11がタ
ンク8からキャップ7を貫通し、キャップ7上に回動自
在に立設された筒軸12を通して外に突出され、その突
出端に採用ツマミ12が取付けられ、弁軸11の一部が
筒軸12と螺合されており、ツマミ12aの回動操作で
弁軸11を下降させることにより、その下端部で前記弁
体10が開放され、タンク8の温水が薬室9に移流し、
そこで再生剤が温水に混和され、そこからミクロフィル
タカートリッジ1内に供給されるようになっている。
A rubber valve body 10 is provided at the bottom central opening of the hot water tank 8, and a valve shaft 11 for opening the valve body 10 passes through the cap 7 from the tank 8 and is rotatable on the cap 7. It protrudes outward through an upright cylindrical shaft 12, and a adoption knob 12 is attached to the protruding end. A part of the valve shaft 11 is screwed to the cylindrical shaft 12, and the valve can be opened by rotating the knob 12a. By lowering the shaft 11, the valve body 10 is opened at its lower end, and the hot water in the tank 8 is advected to the chamber 9.
There, the regenerant is mixed with the hot water and supplied from there into the microfilter cartridge 1.

前記筒軸12にはハンドル13が取付けられ、またその
一部に環体14が螺合されている6環体14には放射方
向に突出する金属製の支腕15が固定され、その先端に
は再生剤タンク5の側面の受部16に通した金属製の吊
子17の上端が連結され、吊子17の下端には、カート
リッジ1の側面の受部18に通した金属製吊子19の上
端が連結され、吊子19はさらにカートリッジ1の持受
体20の側面に設けた受部21を通り、そこから屈曲し
て持受体2oの底に設けた脚部22に連結されており、
カートリッジ1に再生剤タンク5を結合させたあと、ハ
ンドル13を回動操作して環体14を上方に移動させる
と、前記吊子17゜19を介してカートリッジ1が再生
剤タンク5側に寄せ付けられ、両者の結合が固く保持さ
れるようになっている。図中、23は再生剤タンク5の
底部に配設したフィルターである。
A handle 13 is attached to the cylindrical shaft 12, and a metal support arm 15 protruding in the radial direction is fixed to the six-ring body 14, to which a ring body 14 is screwed. The upper end of a metal hanger 17 passed through a receiving part 16 on the side surface of the regenerant tank 5 is connected to the upper end of the metal hanger 17, and a metal hanger 19 passed through a receiving part 18 on the side surface of the cartridge 1 is connected to the lower end of the hanger 17. The upper end of the hanger 19 is connected, and the hanger 19 further passes through a receiving part 21 provided on the side surface of the supporting body 20 of the cartridge 1, bends from there, and is connected to a leg part 22 provided at the bottom of the supporting body 2o. Ori,
After the regenerant tank 5 is connected to the cartridge 1, when the handle 13 is rotated to move the ring 14 upward, the cartridge 1 is brought closer to the regenerant tank 5 via the hanger 17°19. The connection between the two is maintained firmly. In the figure, 23 is a filter disposed at the bottom of the regenerant tank 5.

上記構成のミクロフィルターの再生装置は、カー 1−
リッジと再生剤タンクとの結合を強固に保持できると共
に分解も容易であり、また再生処理を開始する際に再生
剤に温水を供給混合できるので、発泡ガスによる加圧注
入の効果を高めることができる。
The microfilter regeneration device having the above configuration is as follows:
It is possible to firmly maintain the connection between the ridge and the regenerant tank, and it is also easy to disassemble.Also, since hot water can be supplied and mixed with the regenerant when starting the regeneration process, the effect of pressurized injection using foaming gas can be enhanced. can.

[発明の効果コ 以上述べたように、ミクロフィルターの再生方法によれ
ば、ミクロフィルターの目詰りを迅速確実に除去できる
ので、フィルターのランニングコストの大幅な低減が図
れる。
[Effects of the Invention] As described above, according to the method for regenerating a microfilter, clogging of the microfilter can be quickly and reliably removed, so that the running cost of the filter can be significantly reduced.

また、本発明のミクロフィルターの再生装置によれば、
とくに再生剤タンクを加圧注入タンクとして機能させる
ことができるので、ポンプその他の補助加圧手段の使用
を省くことができると共にミクロフィルターの再生処理
作業の能率向上に大きく寄与することができる。
Furthermore, according to the microfilter regeneration device of the present invention,
In particular, since the regenerant tank can function as a pressurized injection tank, the use of a pump or other auxiliary pressurizing means can be omitted, and it can greatly contribute to improving the efficiency of the microfilter regeneration process.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明によるミクロフィルターの再生装置の基
本構造を示す縦断面図、第2図は実用型に構成した装置
の一部切断側面図である。 1・・・ミクロフィルターカートリッジ、2・・・ミク
ロフィルター、 3・・・給水口、 4・・・吐出口、 5・・・再生剤タンク、 6・・・送出口、 7・・・キャップ。 8・・・温水タンク、 9・・・薬室、 10・・・弁体、 11・・・弁軸、 12・・・筒軸、 12a・・・ツマミ、 13・・・ハンドル、 14・・・環体。 15・・・支腕、 16.18.21・・・受部、 17.19・・・吊子、 20・・・待受体、 22・・・脚部、 23・・・フィルター。
FIG. 1 is a vertical cross-sectional view showing the basic structure of a microfilter regeneration device according to the present invention, and FIG. 2 is a partially cutaway side view of the device configured for practical use. DESCRIPTION OF SYMBOLS 1... Micro filter cartridge, 2... Micro filter, 3... Water supply port, 4... Discharge port, 5... Regenerant tank, 6... Outlet port, 7... Cap. 8... Hot water tank, 9... Gun chamber, 10... Valve body, 11... Valve shaft, 12... Cylinder shaft, 12a... Knob, 13... Handle, 14... - Ring body. 15...Support arm, 16.18.21...Receiving part, 17.19...Hipper, 20...Standard body, 22...Leg part, 23...Filter.

Claims (3)

【特許請求の範囲】[Claims] (1)再生剤として過酸化物と、キレート機能をもつP
H調整剤と、発泡剤との混合物を用い、この再生剤を温
水と共にミクロフィルターのカートリッジ内に供給し、
再生剤中の発泡剤で発生する気体圧力によって再生剤を
ミクロフィルターに逆方向から加圧注入することを特徴
とするミクロフィルターの再生方法。
(1) Peroxide as a regenerant and P with chelating function
Using a mixture of an H regulator and a blowing agent, feeding the regenerant along with hot water into a microfilter cartridge;
A method for regenerating a microfilter, which comprises injecting a regenerant into the microfilter under pressure from the opposite direction using gas pressure generated by a foaming agent in the regenerant.
(2)過酸化物が過酸化ナトリウム、PH調整剤がリン
酸またはクエン酸、そして発泡剤が炭酸水素ナトリウム
である特許請求の範囲第1項記載のミクロフィルターの
再生方法。
(2) The method for regenerating a microfilter according to claim 1, wherein the peroxide is sodium peroxide, the pH adjuster is phosphoric acid or citric acid, and the blowing agent is sodium hydrogen carbonate.
(3)ミクロフィルターのカートリッジの吐出口に、再
生剤を温水と共に収容するタンクを着脱自在に連結し、
再生剤中の発泡剤で発生する気体圧力によって再生剤を
ミクロフィルターに逆方向から加圧注入させ、ミクロフ
ィルターを透過した排液をカートリッジの給水口側から
取り出せることを構成したことを特徴とするミクロフィ
ルターの再生装置。
(3) A tank containing a regenerant along with hot water is removably connected to the discharge port of the microfilter cartridge,
The regenerating agent is pressurized and injected into the microfilter from the opposite direction by gas pressure generated by the foaming agent in the regenerating agent, and the waste liquid that has passed through the microfilter can be taken out from the water supply port side of the cartridge. Microfilter regeneration device.
JP29613286A 1986-12-11 1986-12-11 Method and device for regenerating microfilter Pending JPS63147505A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29613286A JPS63147505A (en) 1986-12-11 1986-12-11 Method and device for regenerating microfilter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29613286A JPS63147505A (en) 1986-12-11 1986-12-11 Method and device for regenerating microfilter

Publications (1)

Publication Number Publication Date
JPS63147505A true JPS63147505A (en) 1988-06-20

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ID=17829557

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29613286A Pending JPS63147505A (en) 1986-12-11 1986-12-11 Method and device for regenerating microfilter

Country Status (1)

Country Link
JP (1) JPS63147505A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100398953B1 (en) * 2000-11-04 2003-09-19 일동화학 주식회사 Method for recycling microfilter used for filtering chromium etchant comprised mainly of ceric ammonium nitrate

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54162684A (en) * 1978-06-14 1979-12-24 Ebara Infilco Co Ltd Preliminary treating method for contaminated membrane

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54162684A (en) * 1978-06-14 1979-12-24 Ebara Infilco Co Ltd Preliminary treating method for contaminated membrane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100398953B1 (en) * 2000-11-04 2003-09-19 일동화학 주식회사 Method for recycling microfilter used for filtering chromium etchant comprised mainly of ceric ammonium nitrate

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