JPS63130518A - Hair treatment composition and method - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a hair styling composition. More particularly, it relates to a mixture of polydiorganosiloxane and a cationic organic polymer component as a hair styling composition that provides combability and long-life hair styles without rinsing after application to the hair.

[Prior Art and Problems to be Solved by the Invention] Many popular hairstyles require a means to hold the hair in the desired style. Several methods are commonly used to style hair at home or in a beauty salon. For example, curlers or rondos? There are methods to curl your hair and then dry it, to wrap your damp hair around a hot curling iron, and to dry your hair with a blow dryer while wrapping your damp hair around a bristle brush.

It is generally accepted that the physical and chemical effects of water play an important role in the method of setting hair. When hair is damp, the hydrogen bonds in the hair's keratin are broken. The hair is then shaped with curlers, irons or brushes, and when it dries, the hydrogen bonds are re-formed in different positions and the style is set.

If you set your hair using only water, it will absorb moisture from the atmosphere and rearrange hydrogen bonds, causing your hairstyle to gradually lose its shape. A considerable number of hair styling compositions have been proposed that increase the durability of hairstyles, and in particular extend the length of time the hair remains set. Such compositions include permanent wave types that act by chemically breaking and reforming disulfide bonds in hair proteins, and those that act by forming a thin film of film-forming resin on the hair to strengthen the hair fibers. Some even adhere to each other to maintain a pre-formed shape.

Generally, the film-forming resin composition includes polyvinylpyrrolidone, polyvinylpyrrolidone vinyl acetate copolymer,
It consists of an aqueous or alcoholic solution of anionic polymers such as polymethacrylate resins, polymethyl vinyl ether and ethyl and butyl monoesters of maleic acid, or carboxylated polyvinyl acetate copolymers.

Such film-forming resins are used in several different ways. For example, the finishing spray is applied as a fine mist (with an aerosol or pump system) after the hair has been styled and dried. Finishing sprays extend the life of the set by bonding between the hair fibers and retaining the shape of the hair even after the shape held by hydrogen bonds is removed by moisture.

In contrast to finishing sprays, preset compositions are applied to the hair before shaping and drying. After drying, the hair is treated with the dried resin film already formed on the hair to form the final style. Shape retention due to open fiber-to-fiber bonding is not effective for preset compositions because post-drying treatments generally destroy the bond. As a result, the preset composition coats or impregnates each hair with a resin film, thereby not bonding the hair to other hairs, but still extending the memory life of the set. .

When using preset compositions containing conventional resins to extend set memory, the hair often becomes undesirably stiff or sticky. Furthermore, when combing or brushing, the coating tends to break and the resin forms flakes or lint-like particles on the walls. Additionally, the rigid and sticky nature of the resin coating makes it difficult to comb or brush the coated hair, and such manipulation can damage or destroy the hair.

Organic cationic compounds and polymers such as stearyldimethylbenzylammonium chloride, quaternary nitrogen derivatives of cellulose ethers, and homopolymers and copolymers of dimethyldiallylammonium chloride are known for hair conditioning composition applications. Hair conditioners make the hair easier to comb and also add flexibility to the hair. Cationic polymers are known in the industry for their ability to fixate and remain in the hair.

Taking this property into account, hair conditioners are generally applied to damp hair, rinsed and then dried so as to leave a more even and thinner film on the hair.

Compared to anionic polymers, conventional cationic polymers generally do little to promote the setting of bare styles or to maintain a set hairstyle for long periods of time.

The purpose of the present invention is to facilitate hairstyle cents;
Prolongs hair set memory without making hair unnaturally stiff or sticky; and provides flexible shape retention to hair without substantially losing set memory after setting To provide a preset composition that allows a comb to be inserted.

”5ilicones Provide Real B
enefits for AerosolCosmet
ics” (American Perfumer a
nd Cosmetics.

(October 1971), Todd et al. used dimethyl silicone (CTPA Co5a+etic In
The GradientDictionary nomenclature describes the action of several types of silicones, including "dimethicone"). U.S. Patent No. 3,257.28
No. 1 (Maeder.

(June 21, 1966) describes a new hair styling resin for use in aerosol hair treatments. This resin contains an N,N-dialkylamino substituent that becomes water soluble upon neutralization with acid. Maeder further teaches incorporating a silicone oil antifoam agent into the resin of the aerosol hair composition.

5ilicones in 1lair Care P
``Dimethicone'' (by Starch, ``Defiant'', June 1984) describes the use of dimethicone in some commercially available conditioners; Its use in hair care products is limited because of its tendency to form . 5ta
rch has further shown that silicones modified or adapted by replacing some of the silicon-bonded methyl groups with other more hydrophobic groups, such as polyoxyalkylene or aminoalkyl groups, can be used in a wide variety of hair care applications. Teach the product that it is useful.

U.S. Patent No. 4,369,037 (Matsunaga
(January 18, 1983) describe various hair treatment cosmetics containing cationic keratin derivatives. Specifically, a hair conditioner composition comprising 1% cationic keratin and 3% dimethylpolysiloxane in water is described. After applying conditioner, Matsu-naga et al. rinsed their hair with tap water,
Then dry. In contrast, a composition using cationic keratin in a preset hair conditioner composition includes 1% cationic keratin, 10% ethanol, 0.5% polyoxyalkylene-substituted silicone, 0.1% fragrance,
and teaches compositions consisting of residual water.

US Pat. No. 4,586,518 (Cornwall et al., May 6, 1986) teaches a hair styling method in which aminoalkyl-substituted polydiorganosiloxanes are applied to hair and set without rinsing. Additionally, a method of styling hair using a quaternary nitrogen-containing organic conditioner, such as a quaternary nitrogen derivative of cellulose ether, mixed with an equal amount of an aminoalkyl-substituted polydiorganosiloxane is taught.

U.S. Patent No. 791,047 (Tloman et al., 198
(October 24, 2005) teaches a hair styling product that is applied to and left on the hair before setting. The composition includes a blend of a cationic organic polymer and a carboxyalkyl-substituted polydimethylsiloxane. Lloman et al. teach that the composition forms a flexible film on the hair to maintain the desired hairstyle without the formation of flakes or lint particles during combing. Furthermore, it is reported that this shape retention property is maintained for a long time even under humid conditions.

However, there does not seem to be anything in the above literature that suggests mixing a cationic organic resin and an unsubstituted polydimethylsiloxane for a hair styling composition that is applied to the hair before setting and does not require rinsing afterwards.

Means and Effects for Solving Problem C] The present invention provides a hair fixative composition suitable for application to hair without the need for rinsing afterwards.
(composition). This composition comprises formula (A) QMe2SiO (MeRSi) in a suitable aqueous carrier.
O) ySiMe2Q (wherein Me represents a methyl group, R independently represents a methyl group, an ethyl group, a vinyl group, or a phenyl group, provided that at least 90% of R is a methyl group, and Q is a hydroxyl group) , a methyl group, an ethyl group, a vinyl group or a phenyl group, and y has an average value of 20 to 2000]; and (B) an amine bonded in or to the polymer chain. or ammonium groups, and the weight ratio of component (A) to component (B) is in the range of 1:20 to 2:1.

The present invention further provides a method of hair styling (meth) comprising the steps of wetting the hair with water, applying an effective amount of the above composition to the hair, winding the hair in a shaping device, and drying the hair while wound.
(for setting hair).

The hair styling composition of the present invention contains a mixture of a silicone component and a cationic organic polymer component. When applied to the hair before setting, the composition forms a film on the hair, extending the setting memory and giving the hair a natural feel and appearance of flexibility.

Further, when the composition of the present invention is used for setting, combing is easier than when the cationic organic polymer is used alone. The composition is particularly useful in forming a flexible film on the hair that allows it to be combed without loss of throat memory and without the formation of flakes or lint-like particles. be. Furthermore, this coating extends the retention period of the hairstyle under humid conditions.

The cationic organic polymers used in the present invention are known materials that are typically non-flowing, solid or rubbery solid materials at room temperature. The first feature of this polymer is that it has an amine group or an ammonium group in the polymer chain or as a substituent bonded to the polymer chain. It is believed that the amine or ammonium groups impart cationic properties to the polymer, which contribute to its properties for hair. The polymer is generally soluble or easily dispersible in water. Cationic organic polymer is British Patent Application No. 2.114,5
No. 80 and US Pat. No. 4,445,521, which also describe examples of cationic organic polymers.

Cationic organic polymers include, inter alia, quaternary ammonium mN1 = cellulose ethers; copolymers of hydroxyethylcellulose and dimethyldiallylammonium halide; copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate; vinylcaprolactam, vinylpyrrolidone and dimethylaminoethyl-methacrylate. quaternary ammonium derivatives of copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers of acrylamide and dimethyldiallylammonium halide; and quaternary ammonium derivatives of copolymers of acrylamide and dimethylaminoethyl methacrylate. Although any cationic polymer can be used in the compositions of the present invention, polymers containing quaternary ammonium groups are preferred. Compositions containing these polymers provide a more effective and more durable film when applied to hair.

Particularly preferred polymers include quaternary ammonium derivatives of cellulose ethers, copolymers of hydroxyethyl cellulose and dimethyldiallylammonium halide, quaternary ammonium derivatives of copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate, copolymers of acrylamide and dimethyldiallylammonium halide, and copolymers of acrylamide and dimethyldiallylammonium halide. There is a quaternary ammonium ff1i form of a copolymer of dimethylaminoethyl methacrylate. Among the preferred polymers, copolymers of acrylamide and dimethyldiallylammonium halide and copolymers of hydroxyethylcellulose and dimethyldiallylammonium halide are most preferred.

Polydiorganosiloxanes for use in the present invention range from dilute fluids with viscosities of about 20 cS at 25°C to thick gums with viscosities of over 100 cS. This diorganosiloxane polymer generally has the formula QMe2SiO
(MeRSiO)ysiMe2Q (wherein, Me is a methyl group, each R independently represents a methyl group, an ethyl group, a vinyl group, or a phenyl group, and Q is a hydroxyl group, a methyl group, an ethyl group, a vinyl group, or a phenyl group) The diorganosiloxane polymers most useful in this invention are predominantly methyl-substituted polymers in which at least 90% of the R groups in the formula are methyl groups.

Most preferably, a polydimethylsiloxane in which substantially all R groups are methyl groups is used. However, 1
Substitution of small amounts up to 0% with other hydrophobic substituents, such as ethyl, vinyl, and phenyl groups, generally does not significantly alter the properties of the polydimethylsiloxane;
Such polymers would function similarly in the present invention. The polymer chains can be end-terminated with triorganosiloxanes, such as trimethylsiloxane or dimethylvinylsiloxane, or with hydroxyl groups.

In the general formula of polydiorganosiloxane, the value of y is called the degree of polymerization of the polymer. This value substantially determines the viscosity of the polymer, and for the materials most useful in this invention is about 20 to 200.
It is in the range of 0. Generally, about 200-150 at 25℃
A polydiorganosiloxane having a viscosity of 00 cS,
It is preferred because it can be more easily emulsified in water and can be advantageously carried out with a wide variety of cationic organic resins. A polydiorganosiloxane having a viscosity in this preferred range is about 1
It has an average degree of polymerization of 00 to 600.

Polydimethylsiloxane is known (CTF^Cos
metic Ingredient Dictionary
ry (referred to as "dimethicone") is commercially available in various viscosities. Polydimethylsiloxane is a hydrophobic oil that is insoluble in water. Therefore, to make a hair conditioner suitable for application to the hair, one or more surfactants are used and dispersed in water to form a stable emulsion. Polydimethylsiloxane emulsions typically have a cloudy or milky white appearance and are composed of discrete grains or domains of silicone (approximately 120 nm particle size) uniformly dispersed throughout the carrier water. Become.

Emulsions of polydimethylsiloxane are also known and commercially available. This can be prepared by mixing silico in water with one or more surfactants. Any of cationic, anionic and nonionic surfactants can be used in known manner to stabilize the emulsion. A mixture of two or more types of surfactants may be used, such as a mixture of two types of nonionic surfactants, a mixture of anionic and nonionic surfactants, or a mixture of cationic and nonionic surfactants. Often useful in improving stability.

Generally, emulsions employ about 1 to 30 parts by weight of surfactant per 100 parts by weight of silicone. The method for emulsifying polydimethylsiloxane is described in U.S. Patent No. 4.246.029.
Further explanation is provided in the issue.

Hair styling compositions are prepared by forming an aqueous dispersion or emulsion of silicone in an aqueous solution of an organic polymer. The silicone may already be emulsified in the aqueous medium containing the organic polymer, or the silicone may be first emulsified in water and then the silicone emulsion mixed with a second solution containing the organic polymer. Alternatively, the organic polymer may be dissolved in the preferred emulsion of silicone.

The mixture of cationic organic polymer and polydiorganosiloxane is diluted in an aqueous carrier liquid to facilitate moderate and effective treatment of the hair.

The carrier liquid may be water alone or a mixture of water and a compatible organic solvent as is known in the hair care industry. Such compatible organic vehicles include alcohols (sopropanol), glycols (eg propyl glycol), or other solvents.

The amount of carrier used in the composition is not critical (and can vary within a wide range; compositions containing about 0.1 to 20% by weight of a mixture of silicone and organic polymer are generally preferred for ease of application). Even more preferred are compositions containing 0.5 to 8% by weight of a mixture of silicone and organic polymer.

The weight ratio of silicone to organic polymer in the compositions of the present invention is within the range of about 1:20 to 2:1. For example, the composition may include 10 parts silicone, 90 parts organic polymer, 5 parts
0 parts silicone and 50 parts organic polymer, or 6
It can include 5 parts silicone and 35 parts organic polymer. The ratio of silicone to organic polymer is 1:10~
More preferably, the ratio is within the range of 1:1. Compositions with the above ingredient ratios are preferred because they generally provide a highly desirable combination of hair soft setting and conditioning action.

The compositions of the present invention provide many improvements in tenacity that cannot be obtained with the use of silicones or organic polymers alone.

For example, on damp hair, the composition improves combability in wet conditions and also provides a silky touch. After the cosmetic has dried, a film is formed on each individual hair to mechanically maintain the hairstyle, but the hair maintains its silky touch and easy-to-comb properties. Organic polymers may also provide some silkiness and combability, but gamma blending with polydiorganosiloxanes improves these properties. Typically, organic polymers alone have a tacky feel, but the addition of silicone removes this tackiness. Similarly, while organic polymers alone may provide some set memory benefit, the blending of silicone and organic polymer in the hair makes the set more durable, long-lasting, flexible, and easy to comb. lubricated to provide better memory of set. Compositions of the invention containing unmodified silicones also have the additional advantage that silicones are not harsh on the hair so that no particulates form on the hair even with frequent use.

The compositions of the invention may also contain other ingredients, such as thickeners, flavors, colorants, propellant gases, and small amounts of acids or salts to adjust the pH as desired. For applications in which the composition is applied to the hair by first dispensing it on a part of the hand and then transferring it to the hair, it is preferred that the composition comprises a thickening agent. When a thickener is used, it is generally 0.5 to 30% by weight, preferably 0.5 to 30% by weight. 5
~15% by weight.

Thickening agents that can be used include sodium alginate, gum arabic, polyoxyethylene, guar gum, hydroxypropyl guar gum, cellulose derivatives such as methylcellulose, methylhydroxypropylcellulose, hydroxypropylcellulose, polypropylhydroxyethylcellulose, starch, and starch derivatives. Examples include hydroxyethyl amylose and starch amylose, and flying insect bean gum.

Perfume that may be used in the composition is a cosmetically acceptable perfume, which may be present in an amount of 0.1 to 0.5% by weight.

When the composition is used as an aerosol type cosmetic such as a mousse, propellants such as carbon dioxide, nitrogen, nitrous oxide, volatile hydrocarbons such as butane, isobutane or propane, and chlorinated or fluorinated hydrocarbons are used. , such as dichlorodifluoromethane and dichlorotetrafluoromethane.

The present invention further provides a method of centrifuging hair comprising the steps of wetting the hair with water, applying an effective amount of a hair styling product of the invention to the hair, wrapping the hair around a shaping device, and drying the hair while the hair is wrapped. Pertains to. The steps of the method of the invention can be carried out in any order or simultaneously, the only exception being that the hair is left curled and of course after the hair has been moistened with water and treated with the hair styling product of the invention. It is to dry.

In the method of the invention, the desired hairstyle is imparted to the hair by wrapping it around a shaping device. Any conventional equipment commonly used for styling hair can be used in the method of the present invention. For example, hair can be curled with curlers, curling irons or hand-held brushes. Hair may be curled when damp, such as after shampooing, or curled when dry and then moistened with water. Moistening the curly, dry hair may be done simultaneously with the application of the hair styling composition as it provides an aqueous emulsion.

In the method of the present invention, the hair styling product may be applied to the hair surface in any suitable manner, for example, the hair styling product may be combed manually over the hair, or the hair may be immersed in the hair styling product. You can also apply hair conditioner to your hair with a brush or comb.
Alternatively, the hair may be lightly dabbed (banded) with a sponge or cloth that absorbs and contains the hair styling product. The hair conditioner may be applied either before or after curling the hair. however,
Generally, it is preferable to apply the hair styling product before the hair is curled because the entire hair can be treated evenly.

The hair styling composition is formulated to be suitable for application to the hair without the need for subsequent rinsing with water. Such leave-on compositions of the present invention are preferred because they provide longer-lasting hairstyle retention.

-i, the hair conditioner is applied in an amount effective to improve curl retention. The amount needed will vary depending on each individual's hair type and type. The amount applied also depends on the degree of curl retention desired. The appropriate amount for each individual's hair is easily determined by one or two trials.

The hair dries while being rolled into the desired shape. Drying the hair may be accomplished in any convenient manner, such as by heating the hair with a blow dryer or with a heated curling iron.

You may also dry your hair naturally at room temperature.

〔Example〕

The following examples illustrate the invention to those skilled in the art:
It should not be construed as limiting the invention. The scope of the invention is defined in the claims. All parts or percentages are by weight unless otherwise specified.

Flaming This example compares the durability of hair curls set after treatment with a cationic organic polymer or polydiorganosiloxane alone or a mixture of a cationic organic polymer and polydiorganosiloxane.

European dark brown hair was arranged in several strands 5 inches long and weighing 2 grams. The walls were treated with 0.5 cc of the hair styling composition by combing the hair for 30 seconds and then combing it three times. Next, separate each of the tassels with a 3/4 inch 0. D.
Wrap it in a curler and keep it at low humidity (30%R) less than 12~
It was dried for 14 hours. Remove the tresses from the curler and heat to 70%RH.
It was suspended in front of a scale plate in the O room and then combed three times.

The length of the tresses was measured before and immediately after combing and after 2, 4.8 and 24 hours. Curl fall was determined by subtracting the length of the comb from the measurement table after combing.

In addition, the feel of the tresses in a dry state and the degree of combing were evaluated (ratings range from 1 to 5, with lower numbers indicating better).

The walls were treated with an aqueous mixture of a cationic organic copolymer and a trinotylsiloxane terminated polydimethylsiloxane (PDMS) or, for comparison, a modified polydimethylsiloxane containing polyoxyalkylene substituents. The cationic organic polymer used in the hair styling composition was a copolymer of hydroxyethyl cellulose and dimethyl diallylammonium chloride (National 5tarch & C).
Chemical Corporation, New Jersey (((, CELQI from Filmwater)
(elaborated as IAT L200).

An aqueous silicone emulsion was used, which was 25
Approximately 60% PDMS with a viscosity of approximately 350 cS at °C, 3.5% polyoxyethylene (6) isolauryl ether (a nonionic surfactant for stabilizing silicone emulsions) and tallow trimethylammonium chloride (
Cationic surfactant for stabilizing silicone emulsions) 0.23% and polyprene glycol 0.25%
and 0.15% preservative. This silicone emulsion had a milky white appearance and an average particle size of 300 nm.

As a comparison mixture, it has a viscosity of 1000 cS at 25 °C, is compatible with water, and has an average of 157 dimethylsiloxane units and 21 methylpolyoxyalkylene siloxane units per molecule (polyoxyalkylene substituents). About 60% of the polyoxyalkylene substituents are about 36 units long, consisting of an equal mixture of oxyethylene and oxypropylene units, and the remaining polyoxyalkylene substituents are about 12 units long, consisting entirely of oxyethylene units.)
Polyoxyalkylene-substituted silicone, which is a polymer of

Hair styling compositions were prepared by mixing the above components in various ratios shown in Table 1. The results observed in the two clusters for each treatment are also shown in Table 1.

Table 1 shows that those with less curl loss have improved cent memory than those with more curl loss. This data indicates that polydimethylsiloxane alone does not improve cent memory. However, a mixture of cationic organic polymer and polydimethylsiloxane significantly improves cent memory. Also,
This data shows that blends of organic polymers and polydimethylsiloxanes surprisingly improve cent memory compared to blends of organic polymers and polyoxyalkylene substituted silicones.

It was also observed that dry hair was more easily removed from the curler after treatment with a mixture of silicone and organic polymer than after treatment with organic resin alone.

Table 1 Hair styling composition (wt%) Curl removal (
ω) CELQUAT PDMS PDMS-PO8 0 hours 2 hours 4 hours 8 hours 24 hours After evaluation of curl removal, several interlayers were moistened and wound again on curlers without additional treatment. After drying, the interlayer was removed from the curler and evaluated on a panel for ease of combing and feel. The scale is from 1 to 5, with 1 being the most desirable characteristic and 5 being the worst.

Table 2 shows the average of each of the five evaluations.

Table 2 The data in Table 2 shows that the hair styling composition of the present invention improves hair combability and feel while providing the greatest improvement in set memory.

1. Dissolve the organic resin in water and add the appropriate amount of silicone emulsion described in Example 1 to make 2.5% CELQUAT.
A hair styling composition containing L200 and 2.5% polydiorganosiloxane was prepared. Five interlayers were treated with the hair styling composition according to the procedure of Example 1 and tested for curl retention. For comparison, control tests were conducted using only water or only 5% CELQUAT solution as the treatment agent. The average curl fall for each treatment is shown in Table 3.

Table 3 General Description This example illustrates the use of several different polydimethylsiloxanes and emulsion types in an aqueous mixture of a copolymer of acrylamide and dimethyldiallylammonium chloride.

Composition I is the silicone emulsion described in Example 1.
42g to 3.13g MERQ[IAT S(Mar
k & Company.

8% solids aqueous solution of copolymer resin of acrylamide and dimethyldiallylammonium chloride marketed by Rahway, New Chassis) and 6.45
It was prepared by mixing with g of water.

Composition (1) was prepared by combining 0.71 g of silicone gum emulsion with 3.13 g of MHRQUAT S and 6.16 g of water. Silicone gum emulsion is 2
It contained 35% polydimethylsiloxane with a viscosity of 100.000 cS at 5°C. The gum emulsion is produced by emulsion polymerization of cyclic dimethylsiloxane and neutralized with 2.3% polyoxyethylene (10) nonylphenyl ether (nonionic surfactant) and 1.9% triethanolamine (dodecylbenzenesulfonic acid). It was prepared by stabilizing it with anionic surfactant). The emulsion was milky white and had an average particle size of 180 nm.

Composition ■ contains 0.42 g of anionic silicone emitter/
3.13 g of L/John (DMEIQUAT S
and 6.45 g) water? Prepared by combining. The anionic silicone emulsion contained 60% polydimethylsiloxane with a viscosity of 350 cS at 25°C. The emulsion consists of 3.8% polyoxyethylene (6) isolauryl ether (nonionic surfactant) and 0.23%
Sodium alkyl lauryl polyether sulfate (Ro
TRITON W-30, an anionic surfactant available from hm and Haas Company, Philadelphia, Pennsylvania. The anionic silicone emulsion is milky white and 27
It had an average particle size of 0no+.

Compositions r, n, and m each contained 2.5% polydimethylsiloxane and 2.5% organic resin.

Five strands of hair were treated with each composition according to the procedure of Example 1 and tested for curl retention. Table 4 shows the average curl fall for each treatment.

Table 4 The data in Table 4 shows that this particular cationic emulsion of organic resin and silicone is effective in extending the life of set memories.

Margin below

Claims (1)

[Claims] 1. Formula (A) QMe_2SiO(MeRSiO)ySiMe in a suitable aqueous carrier
_2Q [wherein, Me represents a methyl group, R independently represents a methyl group, an ethyl group, a vinyl group, or a phenyl group, provided that at least 90% of R is a methyl group, and Q
represents a hydroxyl group, a methyl group, an ethyl group, a vinyl group or a phenyl group, and y has an average value of 20 to 2,000. ]
and (B) a cationic organic polymer containing amine or ammonium groups in or attached to the polymer chain; A hair styling composition that does not require post-rinsing, characterized in that the weight ratio of ) is within the range of 1:20-2:1. 2. The cationic organic polymer is a quaternary ammonium derivative of cellulose ether; a copolymer of hydroxyethylcellulose and dimethyldiallylammonium halide; a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate; a terpolymer of vinylcaprolactam, vinylpyrrolidone and dimethylaminoethylmethacrylate; Claim 1 selected from the group consisting of quaternary ammonium derivatives of copolymers of vinylpyrrolidone and dimethylaminoethyl methacrylate; copolymers of acrylamide and dimethyldiallylammonium halide; and quaternary ammonium derivatives of copolymers of acrylamide and dimethylaminoethyl methacrylate. The hair styling composition described in Section 1. 3. Wet the hair with water;
) Formula QMe_2SiO(MeRSiO)ySiMe_2
Q [In the formula, Me represents a methyl group, R independently represents a methyl group, an ethyl group, a vinyl group, or a phenyl group, provided that at least 90% of R is a methyl group, and Q represents a hydroxyl group, a methyl group, group, ethyl group, vinyl group or phenyl group, and y has an average value of 20 to 2000. ]; and (B) a cationic organic polymer containing amine or ammonium groups in or bonded to the polymer chain; A method for styling hair comprising the steps of: applying an effective amount of the composition of B) in a weight ratio of 1:20 to 2:1; winding the hair around a shaping device; and drying the hair while wound. 4. The cationic organic polymer is a quaternary ammonium derivative of cellulose ether; a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate; a terpolymer of vinylcaprolactam, vinylpyrrolidone and dimethylaminoethyl methacrylate; a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate. 4. The method of claim 3, wherein the method is selected from the group consisting of quaternary ammonium derivatives; copolymers of acrylamide and dimethyldiallylammonium halide; and quaternary ammonium derivatives of copolymers of acrylamide and dimethylaminoethyl methacrylate.