JPS63128567A - Manufacture of spiral electrode for use in battery - Google Patents
Manufacture of spiral electrode for use in batteryInfo
- Publication number
- JPS63128567A JPS63128567A JP61274842A JP27484286A JPS63128567A JP S63128567 A JPS63128567 A JP S63128567A JP 61274842 A JP61274842 A JP 61274842A JP 27484286 A JP27484286 A JP 27484286A JP S63128567 A JPS63128567 A JP S63128567A
- Authority
- JP
- Japan
- Prior art keywords
- separator
- electrode plate
- heat
- spiral
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000004804 winding Methods 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000004745 nonwoven fabric Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- -1 polypropylene Polymers 0.000 abstract description 13
- 239000004743 Polypropylene Substances 0.000 abstract description 12
- 229920001155 polypropylene Polymers 0.000 abstract description 12
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 3
- 239000010935 stainless steel Substances 0.000 abstract description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007599 discharging Methods 0.000 abstract description 2
- 229910052744 lithium Inorganic materials 0.000 abstract description 2
- 230000004927 fusion Effects 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 2
- 230000037303 wrinkles Effects 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 1
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/04—Cells with aqueous electrolyte
- H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
- H01M6/10—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with wound or folded electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】 (イ)産業上の利用分野 この発明は、電池用渦巻電極の製造方法に関する。[Detailed description of the invention] (b) Industrial application fields The present invention relates to a method of manufacturing a spiral electrode for a battery.
(ロ)従来の技術と問題点
渦巻電極を使用する電池では、正負両極を分離するとと
もに、極板からの活物質の剥離やデンドライト生長によ
る内部短絡を防止するために、セパレータを袋状にし、
その中に正極板と負極板のいずれか一方または両方を入
れて被包し、被包した状態で正極板と負極板を重ね合わ
せて渦巻状に巻いて渦巻電極を製造することが行われて
いる。(b) Conventional technology and problems In batteries using spiral electrodes, the separator is made into a bag shape in order to separate the positive and negative electrodes as well as to prevent peeling of the active material from the electrode plate and internal short circuits due to dendrite growth.
A spiral electrode is produced by putting one or both of a positive electrode plate and a negative electrode plate in it and encapsulating it, and then stacking the positive electrode plate and negative electrode plate in the encapsulated state and winding them in a spiral shape. There is.
ところが、そのように渦巻状に巻くとセパレータは中に
入れられた極板の厚さも加わるため外周側部分と円周側
部では必要な局長がかなり異なることになる。しかしな
がらセパレータは、外周側となる部分も内周側となる部
分も等しい長さに作られているため外周側では伸び円周
側では縮むことが望まれるが実際には縮み得ないので内
周側の部分にシワが生成する。そのシワ部分に電極間の
圧力が集中しシワ部が破損し内部短絡の原因となつてい
る。この破損防止法として、特開昭60−2:9964
では、巻き方向に対して垂直な熱融着部を設け、大きな
シワの発生を防止することが提案さnている。しかしこ
の方法では多くの熱融着部を設ける必要があるので面倒
であるだけでなく作業性にも問題がある。However, when the separator is spirally wound in this manner, the thickness of the electrode plate inserted therein is also added to the separator, so that the required length is considerably different between the outer circumferential side and the circumferential side. However, since the separator is made to have the same length on the outer and inner sides, it is hoped that the outer side will expand and the separator will contract on the circumferential side, but in reality it cannot shrink, so the inner side Wrinkles appear in the area. Pressure between the electrodes concentrates at the wrinkled portion, causing damage to the wrinkled portion and causing an internal short circuit. As a method for preventing this damage, Japanese Patent Application Laid-Open No. 60-2:9964
proposed that a heat-sealed portion be provided perpendicular to the winding direction to prevent the occurrence of large wrinkles. However, this method requires the provision of many heat-sealed parts, which is not only troublesome but also poses problems in workability.
この発明は、渦巻電極において、上記のごとき内周部の
シワ、特にl!極間の圧力が最大になる電極中央部の大
きなシワを減少させてセパレータの破損による内部短絡
を防止することを目的とするものである。This invention solves the problem of wrinkles on the inner periphery as described above in a spiral electrode, especially l! The purpose is to prevent internal short circuits due to separator breakage by reducing large wrinkles at the center of the electrodes, where the pressure between the electrodes is maximum.
(ハ)問題点を解決するための手段と作用この発明は、
正極板および負極板の少なくとも一方を袋状セパレータ
に入れて被包した状態で、正極板と負極板とを重ね合わ
せて渦巻状に巻いて渦巻電極を製造するにあたり、前記
セパレータの一方の面に巻方向に並行した少な(とも一
つの線状または細幅帯状の熱融着部を設け、前記熱融着
部を設けた側を内側にして渦巻状に巻くことを特徴とす
る電池用渦巻電極の製造方法を提供するものである。(c) Means and action for solving the problems This invention has the following features:
At least one of the positive electrode plate and the negative electrode plate is placed in a bag-like separator and encapsulated, and when the positive electrode plate and the negative electrode plate are overlapped and wound into a spiral shape to produce a spiral electrode, one surface of the separator is A spiral electrode for a battery, characterized in that a few linear or narrow band-shaped heat-sealed parts are provided parallel to the winding direction, and the electrode is wound in a spiral shape with the side on which the heat-sealed parts are provided inside. The present invention provides a method for manufacturing.
この発明に用いられるセパレータの材料としては、従来
渦巻電極に用いられているものや、その他の、渦巻成極
の成池円で使用可能な特性を有するシート状材料であっ
て、局部的に加熱することによって線状もしくは細幅帯
状の熱融着部を設けることができるものであればよい。The material of the separator used in this invention is one that is conventionally used for spiral electrodes, or other sheet-like materials that have characteristics that can be used in spiral polarization circles, and are heated locally. Any material may be used as long as it can provide a linear or narrow band-shaped heat-sealed portion by doing so.
例えば微孔性ポリプロピレンフィルム、ポリプロピレン
不織布などがあげられ、これらの一枚もしくは複数枚重
ねたものが用いられる。Examples include microporous polypropylene film and polypropylene nonwoven fabric, and a single sheet or a stack of multiple sheets of these may be used.
そしてこれらのセパレータ材料を袋状にして、その一方
面に、袋の長さ方向に並行して1つ以上の線状もしくは
細幅帯状の熱融着部を設ける。なおセパレータ材料が複
数層の場合は、この熱融着部によって構成シート全体が
結合しているのが好ましい。この袋状セパレータに、正
負両極板の少なくとも一方を挿入し、前記熱融着部を設
けた面を内側にして巻いてこの発明による渦巻電極が作
製される。Then, these separator materials are made into a bag shape, and one or more linear or narrow band-shaped heat-sealed parts are provided on one side of the bag in parallel with the length direction of the bag. In addition, when the separator material has multiple layers, it is preferable that the entire constituent sheet is bonded by this heat-sealed portion. A spiral electrode according to the present invention is produced by inserting at least one of the positive and negative polar plates into this bag-shaped separator and winding it with the surface provided with the heat-sealed portion inside.
渦巻電極においてセパレータのシワはその中央部に最大
のものが発生し、これが二、三重に重なり、最も電極か
らの圧力を受けやすく破損しやすい。しかしこの発明に
おける熱融着部は、熱融着されていない部分よりも機械
的強度が大きいので渦巻電極の中央部でもシワになりに
くくそのため破損しに<<、シたがって破損による内部
短絡が防止される。In a spiral electrode, the largest wrinkles on the separator occur in the center, which overlap in two or three layers, and are most susceptible to pressure from the electrode and are easily damaged. However, since the heat-sealed part in this invention has greater mechanical strength than the non-heat-sealed part, it is difficult to wrinkle even in the center of the spiral electrode, so it is less likely to break. Prevented.
なお前記熱融着部は1つであっても、これがないものと
比べれば短絡防止の効果は大きいが、複数にすると更に
効果が大きくなる。Even if there is only one heat-sealed part, the effect of preventing short circuits is greater than when there is no heat-sealed part, but if there are a plurality of heat-sealed parts, the effect becomes even greater.
また、複数の熱融着部で構成される帯状部の幅は、この
帯状部と、前記袋状セパレータの長さ方向と平行な端縁
との間の幅より狭い方が、短絡防止の効果が大きく好ま
しいものである。In addition, the width of the band-shaped part composed of a plurality of heat-sealed parts is narrower than the width between this band-shaped part and the edge parallel to the length direction of the bag-shaped separator to prevent short circuits. is highly desirable.
次にこの発明を実施例によって説明するがこの発明を限
定するものではない。Next, this invention will be explained by examples, but this invention is not limited to this invention.
に)実施例
(実施例1)
第1a図に微孔性ポリプロピレンフィルムとポリプロピ
レン不織布を重ね合せて長方形状のシート(ロ))を示
した。これとは別に微孔性ポリプロピレンフィルムとポ
リプロピレン不織布を重ね合わせて長方形状のシートに
し、その長さ方向に幅約2鰭の熱融着部(lb) (2
b)を2本設けたシート伽)を第1b図に示した。B) Example (Example 1) Figure 1a shows a rectangular sheet (b) made by laminating a microporous polypropylene film and a polypropylene nonwoven fabric. Separately, a microporous polypropylene film and a polypropylene non-woven fabric are layered to form a rectangular sheet, and the heat-sealed part (lb) (2 lb) with a width of approximately 2 fins extends along the length of the sheet.
A sheet seat provided with two b) is shown in Fig. 1b.
上記シート(転)(ロ)をその微孔性ポリプロピレンフ
ィルム側が外側になるように重ね合せてその三方を熱融
着して第2図に示すように長方形の袋を作製しこれをセ
パレータとした。上記セパレータに二酸化マンガンを正
極活物質とする正極合剤を集電用のステンレス鋼製網に
保持させた厚み0.4flで70mX45jo+正極板
を入れ、正極板をセパレータで被包し、これにリチウム
を集電用のステンレス鋼製網に圧着した厚み0.8 f
lで大きさが前記正極板と同じの負極板を重ね合わせ渦
巻状に巻いて渦巻電極を製造した。The above sheets (rolled) (b) were stacked so that the microporous polypropylene film side was on the outside, and the three sides were heat-sealed to make a rectangular bag as shown in Figure 2, which was used as a separator. . A 70 m x 45 jo + positive electrode plate with a thickness of 0.4 fl in which a positive electrode mixture containing manganese dioxide as a positive electrode active material is held in a stainless steel net for current collection is placed in the above separator, the positive electrode plate is covered with the separator, and lithium is added to this. 0.8 f thick crimped onto a stainless steel mesh for current collection
A spiral electrode was manufactured by stacking negative electrode plates having the same size as the positive electrode plate and winding them in a spiral shape.
上記渦巻電極の製造に際しては、電極中央部での大きな
シワが発生することなく内部短絡もなく極めて良好であ
った。The production of the spiral electrode was extremely successful with no large wrinkles occurring at the center of the electrode and no internal short circuits.
(実施例2〜6および比較例1)
活物質として酸化亜鉛85ffiffi%及び亜鉛粉末
10重量%と添加剤として酸化カドミウム2.5 WL
m%と結着剤としてポリフルオロエチレン粉末2.5重
1に%を加え混合した。この混合物に水を加え混練り後
ローうにより圧延して亜鉛極活物質シートとし、このシ
ートを集電体の両面に圧着して厚みQ、8m’l、大き
さが70WII×45MIRの亜鉛極を作製した。セパ
レータとしては、前記第2図に示すものと同じ構成のも
ので、約2n幅の線状の熱融着部を2本有しその位置を
変えたもの人、BおよびCと、中央に前記熱融着部を1
本だけ設けたものDと、熱融着部なしのものEを使用し
たが内訳を第1表に示した。(Examples 2 to 6 and Comparative Example 1) 85% zinc oxide and 10% by weight zinc powder as active materials and 2.5 WL of cadmium oxide as additives
m% and 2.5 parts by weight of polyfluoroethylene powder as a binder were added and mixed. Water is added to this mixture, kneaded, and then rolled by a rower to form a zinc electrode active material sheet.This sheet is pressed onto both sides of a current collector to form a zinc electrode with a thickness of Q, 8 ml, and a size of 70 WII x 45 MIR. was created. The separator has the same structure as that shown in FIG. Heat fused part 1
A type D with only a book and a type E without a heat-sealed part were used, and the details are shown in Table 1.
正極としては公知の焼結式ニッケル極を使用し、第1表
に示すそれぞれのセパレータに前記亜鉛極を入れて被包
し、これに前記ニッケル極を重ね合せて渦巻状に巻いて
渦巻電極とした。この渦巻電極を円筒容器内に挿入し、
電極群が含浸される程度の電解液を注入し、IJAHの
ニッケル亜鉛蓄電池(1)〜■)を作製した。A well-known sintered nickel electrode is used as the positive electrode, the zinc electrode is placed in each separator shown in Table 1 and encapsulated, and the nickel electrode is superimposed on this and wound into a spiral to form a spiral electrode. did. Insert this spiral electrode into a cylindrical container,
An amount of electrolyte solution was injected to the extent that the electrode group was impregnated, and IJAH nickel-zinc storage batteries (1) to (2) were produced.
第1表
第8図はこれら蓄電池のサイクル特性比較図である。充
放電条件は、4時間率の電流値で5時間充電を行ない、
4時間率の1流値で放fi?ff圧が1、Ovになるま
で放電を行なった。族1容漬が初期の60%以下になっ
た時を1池寿命とした。FIG. 8 of Table 1 is a comparison chart of cycle characteristics of these storage batteries. The charging and discharging conditions were to charge for 5 hours at a current value of 4 hours,
4 hour rate 1st flow value? Discharge was performed until the ff pressure reached 1.0V. The life of one pond was defined as the time when the Group 1 capacity was reduced to 60% or less of the initial value.
@8図から次のようなことが分かる。@ Figure 8 shows the following.
l)セパレータに熱融着部のない比較例1の電池(6)
は充放電サイクル特性が最低で著しく劣る。l) Battery of Comparative Example 1 (6) in which the separator does not have a heat-sealed part
has the lowest charge-discharge cycle characteristics and is extremely inferior.
11)実施例2〜5の電池(4)〜(2)の中では電池
(4)が最高の充放電サイクツし特性を示しく4)から
(ロ)へと順に低下する。11) Among the batteries (4) to (2) of Examples 2 to 5, battery (4) exhibits the highest charge/discharge cycle characteristics, which decreases in order from 4) to (b).
上記サイクル寿命を経過した後電池(4)〜の)を分解
して内部を観察した結果は次のとおりである。After the cycle life had elapsed, the batteries (4) to (4) were disassembled and the inside was observed, and the results are as follows.
1)比較例1の電池(ト))では、セパレータに全般的
にシワが発生し、特に渦巻電極の中央部では大シワが多
発して何重にも重なり著しく破損していた。 ・11)
実施例電池(4)〜(6)のなかで、電池■のセパレー
タには大きなシワがな(、その重なりも認められなかっ
た。セパレータのシワの発生は電池囚。1) In the battery (g) of Comparative Example 1, wrinkles were generally generated on the separator, and in particular, large wrinkles occurred frequently in the center of the spiral electrode, which overlapped in multiple layers and was severely damaged.・11)
Among the Example Batteries (4) to (6), there were no large wrinkles in the separator of Battery (1) (and no overlapping was observed. The occurrence of wrinkles on the separator was due to battery defects).
ω)、 (0)、(6)の順に増加する傾向が認められ
る。p)では熱融着部が中央の1行だけなので、熱融着
部の存在する中央にはシワはないが、その外の部分にシ
ワが発生してわずかに破損している部分が認められた。A tendency to increase in the order of ω), (0), and (6) is observed. In p), the heat-sealed part is only in one row in the center, so there are no wrinkles in the center where the heat-sealed part exists, but there are wrinkles and slight damage in areas outside of that. Ta.
しかし比較例1の電池(ト))と比べて著しく改善され
ている。However, it is significantly improved compared to the battery of Comparative Example 1 (g)).
以上の結果から、本願発明のように熱融着部をセパレー
タに設ければ、渦巻電極を作製したときにセパレータの
破損が防止され、電池の充放電サイクル特性が改善され
ることは明らかである。また、熱F11着部もセパレー
タの幅方向のシワの発生しやすい中央部に複数で設ける
のが好ましい。From the above results, it is clear that if the separator is provided with a thermally fused portion as in the present invention, damage to the separator will be prevented when a spiral electrode is fabricated, and the charge/discharge cycle characteristics of the battery will be improved. . Further, it is preferable that a plurality of thermal F11 attachment parts be provided in the central part of the separator where wrinkles are likely to occur in the width direction.
(ホ)発明の効果
この発明によれば、セパレータの破損が原因の内部短絡
が防止され、その結果すぐれた充放電サイクル特性を有
する渦巻形電極の電池が得られる。(e) Effects of the Invention According to the present invention, internal short circuits caused by breakage of the separator are prevented, and as a result, a spiral electrode battery having excellent charge/discharge cycle characteristics can be obtained.
第1a図とglb図は、この発明に用いられる一実施例
のセパレータの材料の構成説明図、第2図はこの発明に
用いられる袋状セパレータの一実施例の構成説明図、第
8図は、この発明による実施列および比較例のセパレー
タを用いて作製した渦巻形電極を用いた電池の充放電サ
イクル特性の比較グラフ図である。
(a e b )・・・セパレータ用シート、(lb、
2b)・・・熱融着部。Figures 1a and glb are diagrams for explaining the construction of materials for a separator according to an embodiment of the present invention, Figure 2 is a diagram for explaining the composition of an embodiment of a bag-like separator used for this invention, and Figure 8 is FIG. 2 is a graph showing a comparison of charge/discharge cycle characteristics of batteries using spiral electrodes manufactured using separators of embodiments according to the present invention and comparative examples. (a e b)...Separator sheet, (lb,
2b)...Heat-sealed part.
Claims (1)
ータに入れて被包した状態で、正極板と負極板とを重ね
合わせて渦巻状に巻いて渦巻電極を製造するにあたり、
前記セパレータの一方の面に巻方向に並行した少なくと
も一つの線状または細幅帯状の熱融着部を設け、前記熱
融着部を設けた側を内側にして渦巻状に巻くことを特徴
とする電池用渦巻電極の製造方法。 2、セパレータ材料が、熱融着可能な、微孔性樹脂フィ
ルムと不織布とを重ね合わせたものである特許請求の範
囲第1項記載の方法。 3、前記熱融着部を複数行とし、複数の熱融着部で形成
される帯状部の幅を、この帯状部とセパレータの長さ方
向と平行な端縁との間の間隔より狭くしてなる特許請求
の範囲第1項記載の方法。[Claims] 1. In manufacturing a spiral electrode by stacking the positive electrode plate and the negative electrode plate and winding them in a spiral shape, with at least one of the positive electrode plate and the negative electrode plate being encapsulated in a bag-like separator. ,
At least one linear or narrow band-shaped heat-sealed part is provided on one surface of the separator parallel to the winding direction, and the separator is spirally wound with the side on which the heat-sealed part is provided inside. A method for manufacturing a spiral electrode for batteries. 2. The method according to claim 1, wherein the separator material is a superposition of a heat-sealable microporous resin film and a nonwoven fabric. 3. The heat-sealed portions are arranged in multiple rows, and the width of the strip formed by the plurality of heat-sealed portions is narrower than the distance between this strip and an edge parallel to the longitudinal direction of the separator. The method according to claim 1, comprising:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61274842A JPS63128567A (en) | 1986-11-18 | 1986-11-18 | Manufacture of spiral electrode for use in battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61274842A JPS63128567A (en) | 1986-11-18 | 1986-11-18 | Manufacture of spiral electrode for use in battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63128567A true JPS63128567A (en) | 1988-06-01 |
Family
ID=17547343
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61274842A Pending JPS63128567A (en) | 1986-11-18 | 1986-11-18 | Manufacture of spiral electrode for use in battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63128567A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5478362A (en) * | 1993-01-29 | 1995-12-26 | Sanyo Electric Co., Ltd. | Method for producing a spiral electrodes |
US7951480B1 (en) | 2003-10-29 | 2011-05-31 | Quallion Llc | Separator bag for use in electrochemcial cell |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58198867A (en) * | 1982-05-14 | 1983-11-18 | Matsushita Electric Ind Co Ltd | Manufacturing method of plate for spiral cell |
JPS6023964A (en) * | 1983-07-15 | 1985-02-06 | Hitachi Maxell Ltd | Manufacture of spiral electrode |
-
1986
- 1986-11-18 JP JP61274842A patent/JPS63128567A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58198867A (en) * | 1982-05-14 | 1983-11-18 | Matsushita Electric Ind Co Ltd | Manufacturing method of plate for spiral cell |
JPS6023964A (en) * | 1983-07-15 | 1985-02-06 | Hitachi Maxell Ltd | Manufacture of spiral electrode |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5478362A (en) * | 1993-01-29 | 1995-12-26 | Sanyo Electric Co., Ltd. | Method for producing a spiral electrodes |
US7951480B1 (en) | 2003-10-29 | 2011-05-31 | Quallion Llc | Separator bag for use in electrochemcial cell |
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