JPS6311576A - Electromolten body and manufacture - Google Patents
Electromolten body and manufactureInfo
- Publication number
- JPS6311576A JPS6311576A JP61079277A JP7927786A JPS6311576A JP S6311576 A JPS6311576 A JP S6311576A JP 61079277 A JP61079277 A JP 61079277A JP 7927786 A JP7927786 A JP 7927786A JP S6311576 A JPS6311576 A JP S6311576A
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- electric melt
- melt
- producing
- electric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000012768 molten material Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 13
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910008484 TiSi Inorganic materials 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000007664 blowing Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 229910052863 mullite Inorganic materials 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910007948 ZrB2 Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021359 Chromium(II) silicide Inorganic materials 0.000 description 1
- 229910019742 NbB2 Inorganic materials 0.000 description 1
- 229910020040 NbS Inorganic materials 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- 229910004217 TaSi2 Inorganic materials 0.000 description 1
- 229910033181 TiB2 Inorganic materials 0.000 description 1
- 229910008814 WSi2 Inorganic materials 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Physical Or Chemical Processes And Apparatus (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
産業上の利用分野
この発明はＡＱ２０３、Ｓｉ ０２および７ｒ０２の３
成分からなる電融体およびその製造方法の改良に関する
ものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application This invention is applicable to AQ203, Si02 and 7r02.
The present invention relates to improvements in an electric melt consisting of components and a method for producing the same.
【Ｌへ１１
従来、Ｚｒ ０２ 、ＡＱ２０３ 、Ｓｉ ０２の３成
分からなるジルコニア・ムライト電融体はＺＲＭとして
知られており、鉱物組成としてはバデライトとムライト
より成り、一部／）１１ランダムを含有しているものも
ある。[To L11 Conventionally, the zirconia-mullite fused body consisting of the three components Zr 02 , AQ203 , and Si 02 is known as ZRM, and its mineral composition is composed of baddellite and mullite, and contains a portion of /) 11 random. Some do.
また、ＺＲＭは組成としてバデライトとムライトから出
来ているが、その熱膜Ｉ【率はバデライトのみの電融体
のような大きな変化がなく、ムライト又は安定化ジルコ
ニアより低い値となっている。Furthermore, although ZRM is composed of baddeleyte and mullite, its hot film I ratio does not change as much as in the case of a baddeleyte-only electromelt, and has a lower value than mullite or stabilized zirconia.
従来は、前述のような電融体は主としてアーク溶融法に
よって作られていた。Conventionally, the above-mentioned molten bodies were mainly produced by an arc melting method.
日が ンしよ−とする１１
従来の技術では、電融体の用途によって所望の特性が得
られないという欠点があった。The conventional technology has the disadvantage that desired characteristics cannot be obtained depending on the application of the molten material.
Ｕ列ｌ糺
この発明は前述のような実情に鑑みて成されたものであ
り、各種用途に応じて所望の特性を改善出来る電融体お
よびその製造方法を提供することを目的としている。This invention was made in view of the above-mentioned circumstances, and an object of the present invention is to provide a molten material capable of improving desired characteristics in accordance with various uses, and a method for manufacturing the same.
旦ｉとｌ１−
前述の目的を達成づるために、第１琵明はＡ１２２０３
、Ｓｉ ０２およびＺｒＯ２の３成分からなる電融体に
第４成分として非酸化物が５〜４０重品％混入されてい
る電融体を要旨としている。dan i and l1- In order to achieve the aforementioned purpose, the first bimei A12203
, Si02 and ZrO2, and a non-oxide as a fourth component is mixed in an amount of 5 to 40% by weight.
また、第２発明はＡ２２０３ 、Ｓｉ ０２およびＺｒ
Ｏ２の３成分からなる液状の電融体にそのタップ１前又
はタップと同時に非酸化物を混入させることを特徴とす
る電融体の製造方法を要旨としている。Moreover, the second invention is A2203, Si 02 and Zr
The gist of this invention is a method for producing an electric melt, which is characterized in that a non-oxide is mixed into a liquid electric melt consisting of three components, O2, before or at the same time as the first tap.
目 ；を トするための
この発明においては、Ａｂ０３、Ｓｉ ０２およびＺｒ
０ｚの３成分からなる電融体に第４成分として非酸化物
を混入する。非酸化物の混入量は５〜４０重量％である
。In this invention, Ab03, Si02 and Zr
A non-oxide is mixed as a fourth component into an electric melt consisting of three components of 0z. The amount of non-oxide mixed in is 5 to 40% by weight.
そのような非酸化物の一例をあげれば、Ｓｉ Ｃ，Ｔｉ
Ｃ，Ｔａ Ｃ，Ｎｂ Ｃ，ＶＣ，ＷＣｌＭＯＣ，Ｚｒ
Ｃ，Ｃｒ ３ Ｃ２の金属炭化物である。このように
非酸化物として金属炭化物を使用した場合、特にＳｉＣ
を使用した場合、熱伝導性と熱膨張特性が格段に改善さ
れる。Examples of such non-oxides include Si C, Ti
C, Ta C, Nb C, VC, WClMOC, Zr
It is a metal carbide of C, Cr 3 C2. When metal carbide is used as a non-oxide in this way, especially SiC
When used, thermal conductivity and thermal expansion properties are significantly improved.
まノζ、前述の非酸化物として、ＴｉＮ、７ｒ Ｎ、
Ｔａ Ｎ、Ｎｂ Ｎ、 Ｃｒ ２ ＮＸ Ｖ
Ｎ、△Ｑ Ｎ、３ｉ ３ Ｎ４の金属窒化物があげられ
る。Mano ζ, as the aforementioned non-oxides, TiN, 7r N,
TaN, NbN, Cr2NXV
Examples include metal nitrides of N, ΔQ N, and 3i 3 N4.
このように非酸化物として金属窒化物を使用した場合、
特に、３ｉ ３ Ｎ４を使用した場合、溶鋼やガラスに
ぬれ難くなる。When metal nitride is used as a non-oxide in this way,
In particular, when 3i 3 N4 is used, it becomes difficult to wet with molten steel or glass.
また、非酸化物として、Ｔｉ Ｂ２ 、Ｚｒ Ｂ２ 、
Ｍｏ Ｂ、ＷＢ、Ｃｒ Ｂ、Ｔａ ８２ 、ＮｂＢ２の
金、属ホウ化物を使用することができる。In addition, as non-oxides, TiB2, ZrB2,
Gold metal borides of Mo B, WB, Cr B, Ta 82 , NbB2 can be used.
このように非酸化物どして金属ホウ化物を使用した場合
、特にＺｒＢ２を使用した場合、耐蝕性が飛躍的に向上
する。In this way, when a metal boride is used as a non-oxide, especially when ZrB2 is used, the corrosion resistance is dramatically improved.
さらに、非酸化物として、１ｉ３ｉ２、Ｚｒ５ｉ２、Ｍ
ＯＳｉ２、ＷＳｉ２、ＣｒＳｉ２、ＴａＳｉ２、ＮｂＳ
ｉ２の金属ケイ化物を使用することも出来る。Furthermore, as non-oxides, 1i3i2, Zr5i2, M
OSi2, WSi2, CrSi2, TaSi2, NbS
i2 metal silicides can also be used.
この発明においては、非酸化物として、前述の金属炭化
物、金属窒化物、金属ホウ化物、金属ケイ化物の１種又
は２種以上を電融体に混入づる。In this invention, one or more of the aforementioned metal carbides, metal nitrides, metal borides, and metal silicides are mixed into the molten material as non-oxides.
電融体に前述の非酸化物を第４成分として混入させる方
法は色々のものがあるが、不活性ガスと一緒に非酸化物
を液状の電融体の中に吹き込むのが最善のやり方である
。まｌζ、非酸化物を液状の電融体に投入することも出
来る。非酸化物を混入しＩζ液状の電融体を層状に流す
こともできる。There are various ways to mix the above-mentioned non-oxide into the molten material as the fourth component, but the best method is to blow the non-oxide into the liquid molten material together with an inert gas. be. Alternatively, non-oxides can also be added to the liquid melt. It is also possible to mix a non-oxide and flow the Iζ liquid electric melt in a layered manner.
非酸化物の形状は種々のものが可能であり、たとえば、
粉状、粒状、ファイバー状、ウィスカー状等である。粉
状又は粒状の非酸化物を使用する場合、直径が２〜３ｍ
ｍ以下であるのが望ましい。粉状のものを結合剤によっ
て造粒して粒状にしてもよい。また、ファイバー状やウ
ィスカー状の場合には、５＋ｎｍ以下の長さで、直径が
２００μｍ以下であるのが望ましい。Various shapes of the non-oxide are possible, for example:
It is in the form of powder, granules, fibers, whiskers, etc. When using powdered or granular non-oxide, the diameter is 2 to 3 m.
It is desirable that it be less than m. A powder may be granulated with a binder to form granules. Further, in the case of a fiber shape or a whisker shape, it is desirable that the length is 5+nm or less and the diameter is 200 μm or less.
また、電融体に含める非酸化物の予の限定について説明
すれば、非酸化物が５重量％よりも少ないと、添加する
効果が明瞭でなく、逆に４０重最％よりし多いと均一に
分散させることが困難である。Also, to explain the limitations of non-oxides to be included in the melt, if the amount of non-oxides is less than 5% by weight, the effect of adding it will not be clear, whereas if it is more than 40% by weight, it will be uniform. difficult to disperse.
第４成分としての非酸化物は一般にアルミナ、ジルコニ
ア、シリカ等の酸化物と比較して溶融させにくいので、
混入後ただちに冷却固化させればその原料特性を保持さ
せたまま、従来の３成分から成る電融体の特性を向上さ
せたものが得られる。非酸化物の種類によっては、従来
の電融体に比較して熱伝導が大きくて熱膨張の小さいも
のを得ることができる。Non-oxides as the fourth component are generally difficult to melt compared to oxides such as alumina, zirconia, and silica.
If the mixture is cooled and solidified immediately after mixing, it is possible to obtain a melt that improves the properties of conventional three-component melts while retaining its raw material properties. Depending on the type of non-oxide, it is possible to obtain a material with greater thermal conductivity and smaller thermal expansion than conventional molten materials.
その他、各種の熱伝導と熱膨張の組合Ｕにできる。さら
に、耐摩耗性、耐蝕性などについて調整可能である。用
途に応じて第４成分として適当な非酸化物をえらぶこと
により物性を変えられるのである。In addition, various combinations U of heat conduction and thermal expansion can be made. Furthermore, wear resistance, corrosion resistance, etc. can be adjusted. The physical properties can be changed by selecting an appropriate non-oxide as the fourth component depending on the application.
なお、いうまでもないことであるが、本発明は、非酸化
物を電融体中に均一に分散さぜるための造粒その他の手
段として第４成分に加えて第５成分としてたとえば無機
結合剤として知られているコロイダル・シリカ、コロイ
ダル・アルミナ、コロイダル・ジルコニア、リン酸アル
ミニウム、水ガラスなどの酸化物を使用するものも含み
得る。It goes without saying that in the present invention, as a fifth component in addition to the fourth component, for example, inorganic It may also include the use of oxides such as colloidal silica, colloidal alumina, colloidal zirconia, aluminum phosphate, and water glass, which are known as binders.
見【ｉ
第１図を参照して、この発明にょる電融体のｌ１１造方
法の一例を説明づる。[i] Referring to FIG. 1, an example of a method for manufacturing an electric melt according to the present invention will be explained.
従来公知の電炉の中に液状の電融体１ｏが収容されてい
る。符号１１はその電炉の底を示している。符号１２は
電融体１ｏの液面を示している。このような液状の電融
体１ｏの中にほぼ垂直に吹き込み管１３が浸漬されてい
る。吹き込み管１３の内部には長手方向に通路１４が形
成されており、下端部に吹き込み出口１５が形成されて
いる。吹き込み管１３は例えばカーボン管で作る。A liquid molten material 1o is housed in a conventionally known electric furnace. Reference numeral 11 indicates the bottom of the electric furnace. Reference numeral 12 indicates the liquid level of the melt 1o. A blowing pipe 13 is immersed almost vertically into such a liquid melt 1o. A passage 14 is formed in the inside of the blow pipe 13 in the longitudinal direction, and a blow outlet 15 is formed at the lower end. The blowing pipe 13 is made of, for example, a carbon pipe.
電融体のｒＦＡ造にあたっては、まず、電融体１０を１
７５０〜２２００℃に保持する。この電融体１０はＺ
ＲＭとして知られているジルコニア−ムライト電融体で
ある。When fabricating the rFA of the melted material, first, the melted material 10 is
Maintain at 750-2200°C. This molten body 10 is Z
It is a zirconia-mullite electromelt known as RM.
Ｔ１融体１０を電炉から流出させる直前に、吹き込み管
１３を電炉の底１１近くまで垂直に浸漬させる。そして
電融体１０のタップ寸萌に吹き込み管１３の吹き込み出
口１５からアルゴンガスや窒素ガス等の不活性ガスと一
緒に粒状の非酸化物を吹ぎ込む。例えば、２〜３分間に
わたって不活性ガスと非酸化物とを電融体１０の下方部
に吹き込む。Immediately before the T1 melt 10 is discharged from the electric furnace, the blowing pipe 13 is immersed vertically to near the bottom 11 of the electric furnace. Then, particulate non-oxide is blown into the tap of the molten material 10 from the blowing outlet 15 of the blowing pipe 13 together with an inert gas such as argon gas or nitrogen gas. For example, an inert gas and a non-oxide are blown into the lower part of the melt 10 for 2 to 3 minutes.
非酸化物は粒状ものが望ましいが、ウィスカー状やファ
イバー状のものでもよい。粉状のものは館述の結合剤を
使って造粒してから投入してもよい。その場合結合剤は
分散剤としても機能する。It is desirable that the non-oxide be in the form of particles, but it may also be in the form of whiskers or fibers. Powdered products may be granulated using the binder specified in the publication before being added. The binder then also functions as a dispersant.
非酸化物の具体例についてはすでに説明したので、ここ
では説明を省略する。Specific examples of non-oxides have already been explained, so their explanation will be omitted here.
以上のように電炉内において電融体の中に非酸化物を所
定量混入させ、しかるのち、ずみやかに電融体を電炉か
ら流出させ、あとは従来と同様に処理する。As described above, a predetermined amount of non-oxide is mixed into the molten material in the electric furnace, and then the molten material is immediately flowed out of the electric furnace, and the rest is treated in the same manner as in the conventional method.
次は別の実施例を説明する。電炉内の液状の電融体は１
７５０〜２２００℃に１０〜３０分間保持し、均一な組
成にしておく。これに粉状の非酸化物を投入し、５〜１
０分間保持後、すみやかに鋳型に流し込む。このように
して得た電融体は３〜ｂ
一に非酸化物が混入されている複合体が１９られる。Next, another embodiment will be described. The liquid electrolyte in the electric furnace is 1
The temperature is maintained at 750-2200°C for 10-30 minutes to obtain a uniform composition. Add powdered non-oxide to this and add 5 to 1
After holding for 0 minutes, immediately pour into the mold. The thus obtained molten material is a composite in which a non-oxide is mixed into 3 to 19.
このような複合体はスキッドボタンとして適している。Such a complex is suitable as a skid button.
さらに別の実施例を説明する。液状の電融体を電炉から
流出させながら、炉外で電融体の流出部分に少量ずつ非
酸化物を添加する。Yet another example will be described. While the liquid molten material is flowing out of the electric furnace, a non-oxide is added little by little to the outflowing portion of the molten material outside the furnace.
この場合、電融体に非酸化物を混入させたものが層状に
形成される。In this case, the molten material mixed with a non-oxide is formed in a layered manner.
さらに別の実施例を説明すれば、まず非酸化物を混入さ
せた電融体を層状に流し、それを急冷したあと、その上
に再び同じ非酸化物を混入させた電融体を流し、非酸化
物を混入した電融体のｆ！ｉＩＩ体を形成する。To explain yet another example, first, an electrolytic melt mixed with a non-oxide is poured in a layered manner, and then it is rapidly cooled, and then an electrolytic melt mixed with the same non-oxide is poured on top of it again. f! of the molten material mixed with non-oxides! Forms III form.
いずれの実施例においても、冷ｕｊ後に電融体を粉砕し
て耐大材料にし、それを使って耐火レンガ等をつくるこ
ともできるし、また直接、鋳型で任意の形状につくるこ
ともできる。In any of the embodiments, after cooling, the molten material can be crushed into a large-sized material, which can be used to make refractory bricks, etc., or it can also be directly made into any shape with a mold.
ｌ匪二亙■
この発明によれば、用途に応じｃ１非酸化物の特性を利
用して熱膜ｌ＆性、熱伝導性、耐蝕性や、溶鋼又はガラ
スに対づる濡れ特性等を格段に向上させたものが得られ
る。また、所望の耐スポーリング性が１（１られる。According to this invention, the properties of C1 non-oxide are utilized depending on the application, and the properties of hot film, thermal conductivity, corrosion resistance, wetting properties for molten steel or glass, etc. are significantly improved. You get what you put in. Further, the desired spalling resistance is reduced by 1 (1).
それ故、例えば、この発明にょる電融体を鋳造用ノズル
（例えば浸漬ノズルやスライディングノズル）に適用し
た場合、ピーリングや割れに対して優れた効果を発揮す
る。Therefore, for example, when the molten material according to the present invention is applied to a casting nozzle (for example, an immersion nozzle or a sliding nozzle), it exhibits excellent effects against peeling and cracking.
第１図はこの発明による電融体の製造方法を実施するた
めの装置の概略を示す説明図である。
１０、、、、、電融体
１１、、、、、炉の底
１２、、、、、電融体の液面
１３、、、、、吹込み管
１５、、、、、吹込み出［ＩFIG. 1 is an explanatory diagram schematically showing an apparatus for carrying out the method for producing a molten material according to the present invention. [I
Claims (12)
３成分からなる電融体に第４成分として非酸化物が５〜
４０重量％混入されていることを特徴とする電融体。(1) Five to five non-oxides are added as a fourth component to an electric melt consisting of three components: Al_2O_3, SiO_2 and ZrO_2.
An electric melt characterized by containing 40% by weight.
Ｃ、ＶＣ、ＷＣ、ＭｏＣ、Ｚｒｃ、Ｃｒ＿３Ｃ＿２、Ｓ
ｉ＿３Ｎ＿４、ＴｉＮ、ＺｒＮ、ＴａＮ、ＮｂＮ、Ｃｒ
＿２Ｎ、ＡｌＮ、ＶＮ、ＴｉＢ＿２、ＺｒＢ＿２、Ｍｏ
Ｂ、ＷＢ、ＣｒＢ、ＴａＢ＿２、ＮｂＢ＿２、ＴｉＳｉ
＿２、ＺｒＳｉ＿２、ＭｏＳｉ＿２、ＷＳｉ＿２、Ｃｒ
Ｓｉ＿２、ＴａＳｉ＿２、ＮｂＳｉ＿２の１種又は２種
以上からなる特許請求の範囲第１項に記載された電融体
。(2) The non-oxide is SiC, TiC, TaC, Nb
C, VC, WC, MoC, Zrc, Cr_3C_2, S
i_3N_4, TiN, ZrN, TaN, NbN, Cr
_2N, AlN, VN, TiB_2, ZrB_2, Mo
B, WB, CrB, TaB_2, NbB_2, TiSi
_2, ZrSi_2, MoSi_2, WSi_2, Cr
The molten body according to claim 1, comprising one or more of Si_2, TaSi_2, and NbSi_2.
はウィスカー状からなる特許請求の範囲第１項又は第２
項に記載された電融体。(3) Claim 1 or 2 in which the fourth component has a powder, granule, fiber, or whisker shape.
The molten material described in Section.
ものである特許請求の範囲第３項に記載された電融体。(4) The electric melt according to claim 3, wherein the fourth component is a powder granulated with a binder.
３成分からなる液状の電融体にそのタップ寸前又はタッ
プと同時に非酸化物を混入させることを特徴とする電融
体の製造方法。(5) A method for producing an electric melt, characterized in that a non-oxide is mixed into a liquid electric melt consisting of the three components Al_2O_3, SiO_2 and ZrO_2 just before or at the same time as the tap.
の中に吹きこむことを特徴とする特許請求の範囲第５項
に記載された電融体の製造方法。(6) The method for producing an electric melt according to claim 5, characterized in that the non-oxide is blown into the liquid electric melt together with an inert gas.
徴とする特許請求の範囲第５項に記載された電融体の製
造方法。(7) A method for producing an electric melt according to claim 5, characterized in that the non-oxide is added to a liquid electric melt.
すことを特徴とする特許請求の範囲第５項に記載された
電融体の製造方法。(8) The method for producing an electric melt according to claim 5, characterized in that the liquid electric melt mixed with the non-oxide is flowed in a layered manner.
の電融体の流出部分に少量ずつ添加することを特徴とす
る特許請求の範囲第５項に記載された電融体の製造方法
。(9) Manufacturing the electric melt according to claim 5, wherein the non-oxide is added little by little to the outflow portion of the liquid electric melt while flowing out the electric melt. Method.
Ｃ、ＶＣ、ＷＣ、ＭｏＣ、ＺｒＣ、Ｃｒ＿３Ｃ＿２、Ｓ
ｉ＿３Ｎ＿４、ＴｉＮ、ＺｒＮ、ＴａＮ、ＮｂＮ、Ｃｒ
＿２Ｎ、ＡｌＮ、ＶＮ、ＴｉＢ＿２、ＺｒＢ＿２、Ｍｏ
Ｂ、ＷＢ、ＣｒＢ、ＴａＢ＿２、ＮｂＢ＿２、ＴｉＳｉ
＿２、ＺｒＳｉ＿２、ＭｏＳｉ＿２、ＷＳｉ＿２、Ｃｒ
Ｓｉ＿２、ＴａＳｉ＿２、ＮｂＳｉ＿２の１種又は２種
以上である特許請求の範囲第５〜９項のいずれか１項に
記載された電融体の製造方法。(10) The non-oxide is SiC, TiC, TaC, Nb
C, VC, WC, MoC, ZrC, Cr_3C_2, S
i_3N_4, TiN, ZrN, TaN, NbN, Cr
_2N, AlN, VN, TiB_2, ZrB_2, Mo
B, WB, CrB, TaB_2, NbB_2, TiSi
_2, ZrSi_2, MoSi_2, WSi_2, Cr
The method for producing an electric melt according to any one of claims 5 to 9, wherein the molten material is one or more of Si_2, TaSi_2, and NbSi_2.
たはウィスカー状からなる特許請求の範囲第５〜１０項
のいずれか１項に記載の電融体の製造方法。(11) The method for producing an electric melt according to any one of claims 5 to 10, wherein the fourth component has a powder, granule, fiber, or whisker shape.
たものである特許請求の範囲第１１項に記載した電融体
の製造方法。(12) The method for producing an electric melt as set forth in claim 11, wherein the fourth component is a powder that is granulated with a binder.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5377686 | 1986-03-13 | ||
| JP61-53776 | 1986-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6311576A true JPS6311576A (en) | 1988-01-19 |
Family
ID=12952215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61079277A Pending JPS6311576A (en) | 1986-03-13 | 1986-04-08 | Electromolten body and manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6311576A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011030658A1 (en) * | 2009-09-09 | 2011-03-17 | ジャパンスーパークォーツ株式会社 | Composite crucible, method for producing same, and method for producing silicon crystal |
| US7980086B2 (en) * | 2006-01-25 | 2011-07-19 | Daikin Industries, Ltd. | Air conditioner |
-
1986
- 1986-04-08 JP JP61079277A patent/JPS6311576A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7980086B2 (en) * | 2006-01-25 | 2011-07-19 | Daikin Industries, Ltd. | Air conditioner |
| WO2011030658A1 (en) * | 2009-09-09 | 2011-03-17 | ジャパンスーパークォーツ株式会社 | Composite crucible, method for producing same, and method for producing silicon crystal |
| CN102471926A (en) * | 2009-09-09 | 2012-05-23 | 日本超精石英株式会社 | Composite crucible, method for producing same, and method for producing silicon crystal |
| US9133063B2 (en) | 2009-09-09 | 2015-09-15 | Sumco Corporation | Composite crucible, method of manufacturing the same, and method of manufacturing silicon crystal |
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