JPS63114690A - Three primary color sublimation transfer material - Google Patents
Three primary color sublimation transfer materialInfo
- Publication number
- JPS63114690A JPS63114690A JP61260981A JP26098186A JPS63114690A JP S63114690 A JPS63114690 A JP S63114690A JP 61260981 A JP61260981 A JP 61260981A JP 26098186 A JP26098186 A JP 26098186A JP S63114690 A JPS63114690 A JP S63114690A
- Authority
- JP
- Japan
- Prior art keywords
- sublimation transfer
- sublimation
- yellow
- disperse
- transfer material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000859 sublimation Methods 0.000 title claims abstract description 41
- 230000008022 sublimation Effects 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 29
- 239000000975 dye Substances 0.000 claims description 18
- 239000000976 ink Substances 0.000 abstract description 11
- 238000004040 coloring Methods 0.000 abstract description 9
- 239000003086 colorant Substances 0.000 abstract description 5
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 abstract description 4
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 abstract description 3
- JSFUMBWFPQSADC-UHFFFAOYSA-N Disperse Blue 1 Chemical compound O=C1C2=C(N)C=CC(N)=C2C(=O)C2=C1C(N)=CC=C2N JSFUMBWFPQSADC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000049 pigment Substances 0.000 description 8
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920001225 polyester resin Polymers 0.000 description 6
- 239000004645 polyester resin Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 239000001856 Ethyl cellulose Substances 0.000 description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 4
- 229920001249 ethyl cellulose Polymers 0.000 description 4
- 235000019325 ethyl cellulose Nutrition 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- -1 propatool Chemical compound 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- FOQABOMYTOFLPZ-ISLYRVAYSA-N Disperse Red 1 Chemical compound C1=CC(N(CCO)CC)=CC=C1\N=N\C1=CC=C([N+]([O-])=O)C=C1 FOQABOMYTOFLPZ-ISLYRVAYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- TUBQDCKAWGHZPF-UHFFFAOYSA-N 1,3-benzothiazol-2-ylsulfanylmethyl thiocyanate Chemical compound C1=CC=C2SC(SCSC#N)=NC2=C1 TUBQDCKAWGHZPF-UHFFFAOYSA-N 0.000 description 1
- QOSTVEDABRQTSU-UHFFFAOYSA-N 1,4-bis(methylamino)anthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(NC)=CC=C2NC QOSTVEDABRQTSU-UHFFFAOYSA-N 0.000 description 1
- DVCMHLZPRDGHKK-UHFFFAOYSA-N 1-amino-4-hydroxy-2-(2-methoxyethoxy)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(N)C(OCCOC)=CC(O)=C3C(=O)C2=C1 DVCMHLZPRDGHKK-UHFFFAOYSA-N 0.000 description 1
- AQXYVFBSOOBBQV-UHFFFAOYSA-N 1-amino-4-hydroxyanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(O)=CC=C2N AQXYVFBSOOBBQV-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 240000000972 Agathis dammara Species 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229920002871 Dammar gum Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000012745 brilliant blue FCF Nutrition 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- BEYOBVMPDRKTNR-UHFFFAOYSA-N chembl79759 Chemical compound C1=CC(O)=CC=C1N=NC1=CC=CC=C1 BEYOBVMPDRKTNR-UHFFFAOYSA-N 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 150000004662 dithiols Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、昇華熱転写記録方式によるカラーハードコピ
ーに使用される昇華転写体に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a sublimation transfer body used for color hard copying by a sublimation thermal transfer recording method.
〈従来の技術〉
昇華熱転写による画像記録方式は、熱により色素を昇華
させて像を形成させる方式であり、現在、テレビ、ＣＲ
Ｔカラーディスプレー、カラーファクシミリ、磁気カメ
ラなどからフルカラーのハードコピーを得る方法として
注目されている。熱源としては、サーマルヘッドなどの
発熱素子またはレーザー、特に半導体レーザーが用いら
れ、与えられる熱エネルギーにより、昇華移行する色素
の量を制御できるので、良好な階調記録を得られるのが
特徴である。この方式は、昇華移行性色素を転写基体に
塗布した昇華転写体を用いて、画像信号で制御されたサ
ーマルヘッドにより受像体に転写記録するものであり、
イエロー、マゼンタ、シアンの三原色の昇華転写体を用
いることによりフルカラーが達成される。<Prior art> The image recording method using sublimation thermal transfer is a method in which an image is formed by sublimating dye using heat, and is currently used in televisions, CR
It is attracting attention as a method of obtaining full-color hard copies from T-color displays, color facsimiles, magnetic cameras, etc. As the heat source, a heating element such as a thermal head or a laser, especially a semiconductor laser, is used, and the amount of dye sublimated and transferred can be controlled by the applied thermal energy, making it possible to obtain good gradation recording. . This method uses a sublimation transfer body with a transfer substrate coated with a sublimation-transferable dye, and transfers and records it onto an image receptor using a thermal head controlled by an image signal.
Full color is achieved by using sublimation transfer materials of the three primary colors of yellow, magenta, and cyan.
こうした昇華転写体に関しては、分散染料、塩基性染料
などから比較的昇華性の良好な色素を選んで作成されて
いる。Such sublimation transfer materials are made by selecting dyes with relatively good sublimation properties from disperse dyes, basic dyes, and the like.
〈発明が解決しようとする問題点〉
しかしながら、従来の方法によれば、イエロー、マゼン
タ、シアンの各色相の昇華転写体に使用される色素の熱
移行性が嚢なる為に、色調の再現性が悪いとか、各色相
の昇華転写体の移行性を合せる為にサーマルヘッドから
の熱エネルギーを各昇華転写体毎に調整する必要がある
などの問題があった。<Problems to be Solved by the Invention> However, according to the conventional method, the heat transfer properties of the dyes used in the sublimation transfer materials of each hue of yellow, magenta, and cyan are compromised, resulting in poor color tone reproducibility. There have been problems such as the thermal energy from the thermal head needs to be adjusted for each sublimation transfer body in order to match the transfer properties of each sublimation transfer body for each hue.
〈問題点を解決するための手段〉
本発明者等は、夫々熱移行性が非常に近似した、イエロ
ー、マゼンタ、シアンの三原色の各昇華転写１体を得る
ことを目的に鋭意検討の結果、一般に色素化合物は、構
造が異なれば、昇゛華性、拡散性、分配係数などの物性
が異なり、その結果、熱移行性が異なってくると考えら
れるにもかかわらず、各三原色の昇華転写体において、
同一色相の色素成分を少くとも三種以上含むことにより
目的が達成されることを見出し本発明を完成するに至っ
た。<Means for Solving the Problems> As a result of intensive studies, the inventors of the present invention aimed to obtain one sublimation transfer unit for each of the three primary colors of yellow, magenta, and cyan, which have very similar thermal transfer properties. In general, it is thought that if dye compounds have different structures, their physical properties such as sublimation, diffusivity, and distribution coefficients will differ, and as a result, their thermal transfer properties will differ. In,
The present inventors have discovered that the object can be achieved by including at least three types of pigment components of the same hue, and have completed the present invention.
すなわち、本発明は、イエロー色、マゼンタ色あるいは
シアン色の昇華性色素成分を含有してなる各三原色昇華
転写体にして、該昇華性色素成分が三１以上の色素を含
有してなる三原色昇華転写体を提供する。That is, the present invention provides three primary color sublimation transfer materials containing sublimable dye components of yellow, magenta, or cyan, and three primary color sublimation transfer materials in which the sublimable dye components contain 31 or more dyes. Provide a transcript.
本発明におりるイエロー、マゼンタおよびシアン色の各
色素は、比較的昇華性の良好な分散染料、油溶性染料か
ら適宜選択される。The yellow, magenta and cyan color pigments used in the present invention are appropriately selected from disperse dyes and oil-soluble dyes that have relatively good sublimability.
本発明においてイエロー色の昇華性色素成分として用い
られる色素としてはＣ，１，ディスパース−イエロー８
．５，７，８，１８．１６ 。In the present invention, the pigments used as yellow sublimable pigment components include C,1, Disperse Yellow 8
．． 5, 7, 8, 18.16.
１８．８Ｂ、４２，５４，５９，６０，６１゜６４．６
６．７７．７９．１１９．１８３ 。18.8B, 42, 54, 59, 60, 61°64.6
6.77.79.119.183.
２０４．２１８など、Ｃ，１，ソルベント・イエロー７
７．１１６など、マゼンタ色の色素としてはＣ，１，デ
ィスパース・レッド１ 、−１ 、１１ 。204.218 etc., C, 1, Solvent Yellow 7
Examples of magenta pigments such as 7.116 include C,1, Disperse Red 1, -1, and 11.
１５．１７，２５，５８，５５，５９，６０゜７５ 、
８８Ｃ，１，ディスパー嘉イオレ７トｊ゛１７．２６，
２８．５６など、Ｃ，１，ソルベント−レッド２８．２
５など、シアン色の色素としてはＣ，１，ディスパース
・ブルー１．３゜１４．１９．２８，２４．２Ｇ、５Ｊ
７３゜９９．１０８，１８５，８８４など、Ｃ，！、ソ
ルベント・ブルー８６．８８，１０５などが例示される
。これらの色素は各昇華性色素成分中１０重２％以上、
好ましくは２ＯＮ量％以とを占める話が用いられる。15.17, 25, 58, 55, 59, 60°75,
88C, 1, Disper Kaiore 7toj゛17.26,
28.56 etc., C, 1, Solvent-Red 28.2
C, 1, Disperse Blue 1.3゜14.19.28, 24.2G, 5J, etc.
73°99.108,185,884 etc., C,! , Solvent Blue 86, 88, 105, etc. These pigments account for 10% or more by weight of each sublimable pigment component,
Preferably, a material containing 2ON amount % or more is used.
本発明の各三原色昇華転写体は、転写基体１夫々の色素
インクを塗布して製造することができる。転写基体とし
ては、一般に、コンデンサー紙、セロハン、ポリイミド
樹脂、ポリエステル樹脂、ポリエーテルスルホン樹脂ま
たはこれらの樹脂に耐熱性向上および／または平滑性向
上などの処理を施したリボン状またはフィルム状のもの
が例示される。Each of the three primary color sublimation transfer bodies of the present invention can be manufactured by applying the respective pigment inks of the transfer substrate 1. Transfer substrates are generally capacitor paper, cellophane, polyimide resins, polyester resins, polyethersulfone resins, or ribbon- or film-shaped materials treated with these resins to improve heat resistance and/or smoothness. Illustrated.
色素インクは、三種以上の昇華性色素、バインダー、お
よび熱源としてレーザーを使用する場合は、レーザーの
発振波長に吸収を有する化合物から構成され、溶媒中で
ボールミル又はペイントコンディジ璽ナーなどを用いて
溶解または数粒化して製造することができる。Dye ink is composed of three or more sublimable dyes, a binder, and, if a laser is used as a heat source, a compound that absorbs at the laser oscillation wavelength. It can be manufactured by melting or dividing into several particles.
バインダーとしては、ダンマー、アラビアゴム、トラガ
ントガム、デキストリンまたはカゼインなどの天然樹脂
またはその変性樹脂、メチルセルロース、エチルセルロ
ース、ヒドロキシエチルセルロース、エチルヒドロキシ
セルロースまたはニトロセルロースなどのセルロース系
樹脂、アクリル酸系樹脂、ポリビニルアルコールまたは
ポリビニルアセテートなどのビニル系樹脂などが例示さ
れ、これらの−ｌまたは三種以上の混合物が使用される
。As a binder, natural resins such as dammar, gum arabic, gum tragacanth, dextrin or casein or modified resins thereof, cellulosic resins such as methylcellulose, ethylcellulose, hydroxyethylcellulose, ethylhydroxycellulose or nitrocellulose, acrylic acid resins, polyvinyl alcohol or Vinyl resins such as polyvinyl acetate are exemplified, and -1 or a mixture of three or more of these resins are used.
各色素およびバインダーなどを溶解または分散させる溶
媒としては、水、エタノール、プロパツール、ブタノー
ルなどのアルコール類、アセトン、メチルエチルケトン
、メチルイソブチルケトンなどのケトン類、トルエン、
キシレン、モノクロルベンゼンなどの芳香族炭化水素類
、ジクロルエタン、トリクロルエチレン、パークロルエ
チレンなどの塩素系溶媒類、酢酸エチル、酢酸ブチル、
酢酸エトキシエチルなどの酢酸エステル類などが例示さ
れ、これらの一種または二穏以との混合物が個用される
。Solvents for dissolving or dispersing each coloring matter and binder include water, alcohols such as ethanol, propatool, and butanol, ketones such as acetone, methyl ethyl ketone, and methyl isobutyl ketone, toluene,
Aromatic hydrocarbons such as xylene and monochlorobenzene, chlorinated solvents such as dichloroethane, trichloroethylene, and perchlorethylene, ethyl acetate, butyl acetate,
Examples include acetate esters such as ethoxyethyl acetate, and one or a mixture of two or more of these may be used individually.
レーザーの発振波長に吸収を持つ化合物としては、カー
ボンブラック、フタロシアニン色素類、ジチオール錯体
類、ナフトキノン類などが例示される。Examples of compounds that absorb at the laser oscillation wavelength include carbon black, phthalocyanine dyes, dithiol complexes, and naphthoquinones.
このようにして得られた色素インクを、バーコーター、
ロールコータ−、ナイフコーター、スクリーン印刷、グ
ラビヤ印刷などを用いて転４基体上に塗布して、昇華転
写体が製造される。The dye ink thus obtained is coated with a bar coater,
A sublimation transfer body is manufactured by coating onto a transfer base using a roll coater, knife coater, screen printing, gravure printing, or the like.
このようにして製造された本発明の各三原色昇！１１転
写体は、夫々の熱移行性が近似しているため、従来の色
調の再現性の問題、サーマルヘッドの調整の繁雑さなど
の問題を一挙に解決し得るものである。Each of the three primary colors of the present invention produced in this way! Since the transfer bodies No. 11 have similar thermal transfer properties, they can solve the conventional problems such as color tone reproducibility and the complexity of thermal head adjustment all at once.
本発明の昇華転写体を用いてプリントする方法としては
公知のいずれの方法でもよく、プリント紙上に解明な画
像を得ることができる。Any known method may be used for printing using the sublimation transfer material of the present invention, and a clear image can be obtained on printing paper.
プリント紙としては、ポリエステル系樹脂またはポリア
ミド系樹脂などをコートした紙、ポリプロピレン、ポリ
塩化ビニルまたはポリエステルなどの合成紙、またはこ
れら合成紙に耐熱性向上などの処理を施した上、必要に
応じて色素と親和性の強いポリエステル系樹脂、ポリア
ミド系樹脂などをコートしたものなどが使用される。Printing paper can be paper coated with polyester resin or polyamide resin, synthetic paper such as polypropylene, polyvinyl chloride, or polyester, or synthetic paper that has been treated to improve heat resistance, etc., as necessary. Materials coated with polyester resin, polyamide resin, etc., which have a strong affinity for dyes, are used.
以下、実施例をあげて、本発明の詳細な説明する。実施
例中、部とあるのは！危部を表わす。Hereinafter, the present invention will be described in detail with reference to Examples. In the example, what is written as “part”? Represents a crisis point.
実施例１
■ イエロー昇華転写体
エチルセルロース ９部
Ｃ，Ｘ、ディスパースーイエｏ−４２１部Ｃ・工、ディ
スパース・イエロー６４ １部Ｃ，１，ディスパ
ース・イエロー８ １部キシレン
７０部
ｎ−ブタノール １８部
上記組成のインク組成物をペイントコンディジ望ナーに
より、充分混線した後、バーコーターを用いて、厚さ１
０μｍのコンデンサー紙に塗布し、乾燥してイエローの
昇華転写体を得た。Example 1 ■ Yellow sublimation transfer material Ethyl cellulose 9 parts C,
70 parts n-butanol 18 parts The ink composition having the above composition was thoroughly mixed with a paint conditioner, and then coated with a bar coater to a thickness of 1
It was coated on 0 μm condenser paper and dried to obtain a yellow sublimation transfer material.
■ マゼンタ昇華転写体
エチルセルロース ９部Ｃ，１，ディス
パースφレッド６０ １部Ｃ，１，ディスパース
・レッド１５ １部Ｃ，１，ンルベント・レッド
２５ １部キシレン ７
０部
ｎ−ブタノール １８部上記組成のイン
ク組成物をペイントコンディジ９ナーで充分混練した後
、バーコーターを用いて、厚さ１０μｍのコンデンサー
紙に塗布し、乾燥してマゼンタの昇華転写体を得た。■ Magenta sublimation transfer material Ethyl cellulose 9 parts C, 1, Disperse φ Red 60 1 part C, 1, Disperse Red 15 1 part C, 1, Rubent Red 25 1 part Xylene 7
0 parts n-butanol 18 parts The ink composition having the above composition was sufficiently kneaded with a paint conditioner, and then applied to a 10 μm thick condenser paper using a bar coater and dried to form a magenta sublimation transfer material. Obtained.
■ シアン昇華転写体
エチルセルロース ９部Ｃ，１弗ディス
パースーブルー８ １部Ｃ，１，ディスパー
スーブルー１４ １部Ｃ，１，ディスパースφ
ブルー２４ １部上記組成のインク組成物をペ
イントコンディショナーで充分品練した後、バーコータ
ーを用いて、厚さ１０μｍのコンデンサー紙に塗布し、
乾燥してシアンの昇華転写体を得た。■ Cyan sublimation transfer material ethyl cellulose 9 parts C, 1, Disperse Blue 8 1 part C, 1, Disperse Blue 14 1 part C, 1, Disperse φ
Blue 24 1 part The ink composition having the above composition was thoroughly refined with a paint conditioner, and then applied to a 10 μm thick condenser paper using a bar coater.
After drying, a cyan sublimation transfer material was obtained.
上記三原色の昇苗転写体を用いて、ポリエステル樹脂を
コートした合成紙を受像体にして、サーマルヘッドによ
り印加エネルギーを変えて転写記録を実施した。記録濃
度は、米国マクベス社デンシトメーターＲＤ−５１４型
により測定した。Transfer recording was carried out using the above-mentioned three primary color seedling transfer bodies, using synthetic paper coated with polyester resin as an image receptor, and changing the applied energy with a thermal head. The recorded density was measured using a Macbeth Densitometer Model RD-514.
各昇華転写体とも印加エネルギーに応じて記録濃度が変
化し、それらの濃度曲線（記Ｊ濃度の熱エネルギー依存
性）は非常に類似した結果が得られた。The recording density of each sublimation transfer body changed depending on the applied energy, and their density curves (thermal energy dependence of density) were very similar.
実施例２
■ イエロー昇華転写体
とドロキシエチルセルロース ９部Ｃ，１，ディス
パース−イエロー７ ０．５部Ｃ，！、ディスパ
ース・イエロー８ ０．５部Ｃ１１ｉａ７’イス
バ一ス番イエロー７７ １部ｃ、１．ディスパ
ース拳イエロー６４ １部トルエン
７０部インプロパツール １８
部上記組成のインク組成物をペイントコンディジ曹ナー
で充分混線した後、バーコーターを用いて、厚さ６μｍ
のポリエステルフィルムに塗布し、乾燥してイエローの
昇華転写体を得た。Example 2 ■ Yellow sublimation transfer material and droxyethyl cellulose 9 parts C, 1, Disperse Yellow 7 0.5 parts C,! , Disperse Yellow 8 0.5 parts C11ia7' Isba Ichiban Yellow 77 1 part c, 1. Disperse Fist Yellow 64 1 part toluene
70 parts Improper Tools 18
After thoroughly mixing the ink composition having the above composition with a paint conditioner, use a bar coater to coat the ink composition with a thickness of 6 μm.
It was applied onto a polyester film and dried to obtain a yellow sublimation transfer material.
■ マゼンタ昇華転写体
ヒドロキシエチルセルロース ９部Ｃ，ｒ
、ディスパースーレッドＩ Ｏ，５部Ｃ，１，
ディスパース・レッド５９ ０．５部Ｃ，！、ディ
スパース拳レッド６０ １部Ｃ，１，ディスパー
ス・ンッド１５ ・ １部トルエン
７０部
イソプロパツール １８部
上記組成のインク組成物をべ、インドコンディジ望ナー
で充分混線した後、バーコーターを用いて、厚さ６μｍ
のポリエステルフィルムを塗布し、乾燥してマゼンタの
昇華転写体を得た。■ Magenta sublimation transfer material hydroxyethyl cellulose 9 parts C, r
, Disperse Red IO, 5 parts C, 1,
Disperse Red 59 0.5 part C,! , Disperse Fist Red 60 1 part C, 1, Disperse Nd 15 ・ 1 part Toluene
70 parts isopropanol 18 parts The ink composition having the above composition was mixed thoroughly with an indocondigi scanner, and then coated with a bar coater to a thickness of 6 μm.
A polyester film was applied and dried to obtain a magenta sublimation transfer material.
■ シアン昇華転写体
とドロキシエチルセルロース ９部Ｃ，Ｌディス
パース・ブルー５６ ０．５部Ｃ，１，ディスパー
ス・ブルー９９ ０．５部Ｃ，！、ディスパース・
ブルー１０８ １部Ｃ・工・ンルベント・ブルー１
０５ １ 部トルエン ７
０部
インプロパツール １８部
上記組成のインク組成物をペイントコンディジ曹ナーで
充分混練した後、バーコーターを用いて、厚さ６μｍの
ポリエステルフィルムに塗布し、乾燥してシアンの昇華
転写体を得た。■ Cyan sublimation transfer material and droxyethyl cellulose 9 parts C, L Disperse Blue 56 0.5 parts C, 1, Disperse Blue 99 0.5 parts C,! , Disperse
Blue 108 Part 1 C・Engineering・Nrubento・Blue 1
05 1 part toluene 7
0 parts Improper tool 18 parts After thoroughly kneading the ink composition of the above composition with a paint conditioner, it was applied to a 6 μm thick polyester film using a bar coater, and dried to form a cyan sublimation transfer material. Obtained.
上記三原色の昇華転写体を用いて、ポリエステル樹脂を
コートした合成紙を受像体にして、サーマルヘッドによ
り印加エネルギーを変えて転写記録を実施した。各昇華
転写体とも印加エネルギーに応じて記録濃度が変化し、
それらの濃度曲線（記録濃度の熱エネルギー依存性）は
非常に類似した結果が得られた。Using the three primary color sublimation transfer bodies described above, transfer recording was carried out using a synthetic paper coated with a polyester resin as an image receptor and changing the energy applied by a thermal head. The recording density of each sublimation transfer material changes depending on the applied energy,
Very similar results were obtained for their density curves (thermal energy dependence of recorded density).
実施例８〜８
実施例１と同様にして、色素成分が下記組成の昇華転写
体を作製し、ポリエステル樹脂をコートした合成紙を受
像体にして、サーマルヘッドにより熱エネルギーを変え
て転写記録を実施した。いずれの実施例においても、非
常に類似した濃度曲線が得られた。Examples 8 to 8 In the same manner as in Example 1, a sublimation transfer material having the following composition of dye components was prepared, synthetic paper coated with polyester resin was used as an image receptor, and transfer recording was performed by changing thermal energy with a thermal head. carried out. Very similar concentration curves were obtained in both examples.
Claims (1)
成分を含有してなる各三原色昇華転写体にして、該昇華
性色素成分が三種以上の色素を含有してなる三原色昇華
転写体。A three primary color sublimation transfer material containing a sublimable dye component of yellow, magenta or cyan color, wherein the sublimable dye component contains three or more types of dyes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61260981A JPS63114690A (en) | 1986-10-31 | 1986-10-31 | Three primary color sublimation transfer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61260981A JPS63114690A (en) | 1986-10-31 | 1986-10-31 | Three primary color sublimation transfer material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63114690A true JPS63114690A (en) | 1988-05-19 |
Family
ID=17355419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61260981A Pending JPS63114690A (en) | 1986-10-31 | 1986-10-31 | Three primary color sublimation transfer material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63114690A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077264A (en) * | 1988-12-19 | 1991-12-31 | Sumitomo Chemical Company, Ltd. | Cyan dye-donor element used in thermal transfer and thermal transfer sheet using it |
-
1986
- 1986-10-31 JP JP61260981A patent/JPS63114690A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077264A (en) * | 1988-12-19 | 1991-12-31 | Sumitomo Chemical Company, Ltd. | Cyan dye-donor element used in thermal transfer and thermal transfer sheet using it |
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