JPS63111906A - Production of hollow yarn module - Google Patents

Production of hollow yarn module

Info

Publication number
JPS63111906A
JPS63111906A JP61259469A JP25946986A JPS63111906A JP S63111906 A JPS63111906 A JP S63111906A JP 61259469 A JP61259469 A JP 61259469A JP 25946986 A JP25946986 A JP 25946986A JP S63111906 A JPS63111906 A JP S63111906A
Authority
JP
Japan
Prior art keywords
case
yarn
binder
hollow
hollow fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61259469A
Other languages
Japanese (ja)
Inventor
Minoru Koda
穣 幸田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nok Corp
Original Assignee
Nok Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nok Corp filed Critical Nok Corp
Priority to JP61259469A priority Critical patent/JPS63111906A/en
Publication of JPS63111906A publication Critical patent/JPS63111906A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/022Encapsulating hollow fibres

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

PURPOSE:To facilitate the operations and to produce the title hollow yarn module without wasting the binder by dipping hollow yarn in a soln. for dissolving or swelling the yarn to close the end opening, inserting the yarn into a case, and dipping the yarn in the binder to fill the binder into the yarn. CONSTITUTION:The end of the hollow yarn 1 of polyvinylidene fluoride for an ultrafilter membrane, etc., is dipped in the soln. 4 of acrylonitrile, etc., for dissolving or swelling the yarn, and the yarn is pulled up before being completely dissolved and dried to close the end opening. The hollow yarn 1 is set in the case 2 so that the yarn protrudes slightly from the end edge of the case 2. The case is then dipped in the binder 3, then pulled up after the binder 3 is filled in the gaps between the inner wall of the case 2 and the hollow yarn 1 and between the respective hollow yarns 1, and dried. The other end is treated in the same way. After the binder 3 is cured, the end edge of the hollow yarn 1 protruding from the end edge of the case 2 is cut with a knife, and the hollow yarn module, wherein both ends of the hollow yarn 1 are opened, is obtained.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、選択透過性を備えた多数本の中空糸を使用し
て流体をろ過する中空糸モジュールの製造方法に関する
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for manufacturing a hollow fiber module that filters a fluid using a large number of hollow fibers having permselectivity.

本発明の対象となる中空糸モジュールの一例を第2図に
ホす。
An example of a hollow fiber module to which the present invention is applied is shown in FIG.

同図の中空糸モジュールは、選択透過性を備えた中空糸
(1)の多数本を筒状を呈するケース(2)内に挿入さ
れ、両端部において、ケース(2)の内壁と中空糸(1
)の間及び各中空糸(1)の間に、結合剤(3)を充填
されて成るものである。
In the hollow fiber module shown in the figure, a large number of hollow fibers (1) with permselectivity are inserted into a cylindrical case (2), and the inner wall of the case (2) and the hollow fibers ( 1
) and between each hollow fiber (1), a binder (3) is filled.

(従来の技術) 従来の技術による中空糸モジュールの製造方法の一例を
、第3図に基づいて説明する。
(Prior Art) An example of a method for manufacturing a hollow fiber module using a conventional technology will be explained based on FIG. 3.

先ず、同図(1)に示すよう【こ、多数本の中空糸(1
)を、端部がケース(2)の端縁が6突出するようにな
してケース(2)内に挿入し1、各中空糸(1)の端部
の開口を接着剤(5)により閉塞させた後に、注入孔(
7)を備えたカバー(6)をケース(2)の端部tこ被
せ、5夜1犬に調合された結合剤(3)を注入孔(7)
を通してケース(2)の内壁と中空糸(1)の間及び各
中空糸(1)間の隙間に注入し、結合剤(3)の固化後
に、同図(2)に示すように、カバー(6)を外し、ケ
ース(6)から突出した結合剤(3)及び中空糸(1)
の端部を切除して接着剤(5)による中空糸(1)の端
部の閉塞を開放させるものである。
First, as shown in the same figure (1), a large number of hollow fibers (1
) into the case (2) so that the edge of the case (2) protrudes 1, and the opening at the end of each hollow fiber (1) is closed with adhesive (5). After the injection hole (
7) over the end of the case (2), and pour the binder (3) mixed into the injection hole (7) into the case (7).
The binder (3) is injected into the space between the inner wall of the case (2) and the hollow fibers (1) and between each hollow fiber (1) through the binder (3), and after the binder (3) has solidified, the cover ( 6) and the binder (3) and hollow fiber (1) protruding from the case (6).
The ends of the hollow fibers (1) are cut off to release the end portions of the hollow fibers (1) from being blocked by the adhesive (5).

(発明が解決しようとする間憇点) 上記した従来の技術によ′る中空糸モジュールの製造方
法においては、結合剤(3)の注入に使用されるカバー
(6)がケース(2)に対し略音封状態を保持すること
を必要とし、しかも、カバー(6)の取り外しとケース
(2)の’AG&から突出した中空糸(1)の端部及び
結合剤(3)の余材の除去が、結合剤(3)の固化後に
なされるので、作業工程が煩雑であるばかりでなく、カ
バー(6)内で固化した結合剤(3)の無駄を生じ、更
に、接着剤(5)による中空糸(1)の閉塞作業にも困
ズ「性を伴、つと言う問題点を有している。
(The impasse to be solved by the invention) In the method for manufacturing a hollow fiber module according to the conventional technique described above, the cover (6) used for injecting the binder (3) is attached to the case (2). However, it is necessary to maintain a substantially sound-tight state, and in addition, it is necessary to remove the cover (6) and remove the ends of the hollow fibers (1) protruding from the 'AG & of the case (2) and the remaining material of the binder (3). Since the removal is done after the binder (3) has solidified, not only is the work process complicated, but also the binder (3) that has solidified within the cover (6) is wasted, and the adhesive (5) is removed. It is also difficult to close the hollow fibers (1) using the method.

本発明は、上記した問題点を解消して、作業が・容易で
あり、かつ、無駄を生じない中空糸モジュールの製造方
法を提示することを目的とするものである。
SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems and provide a method for manufacturing a hollow fiber module that is easy to work with and does not produce waste.

(問題点を解決するための手段) 本発明は、上記した従来の技術による中空糸モジュール
の製造方法における問題点を考慮して、中空糸を膨潤又
は溶解させる溶液内に、ケースの長さくこ比べ貝〈セッ
トされた中空、糸の端部を浸漬させて端部の開口を閉塞
させ、低粘度に調合された結合剤内に、中空糸を挿入さ
れたケースの端部を浸漬させて結合剤をケースと中空糸
の間及び各中空糸間の隙間に充填し、結合剤の固化後(
乙中空糸の閉塞端部を切除して中空糸モジュールを完成
させるものである。
(Means for Solving the Problems) In consideration of the problems in the method for manufacturing hollow fiber modules according to the above-described conventional technology, the present invention provides a solution for swelling or dissolving the hollow fibers by inserting the length of the case into the solution. Comparison shell〈The end of the set hollow fiber is immersed to close the opening at the end, and the end of the case into which the hollow fiber is inserted is immersed in a binder mixed with a low viscosity to bond it. Fill the binder between the case and the hollow fibers and the gaps between each hollow fiber, and after the binder solidifies (
A hollow fiber module is completed by cutting off the closed end of the hollow fiber.

中空糸の端部を溶解又は膨潤させて開口を閉塞する溶液
としては、中空糸の製作に使用されたポリマーがポリフ
ッ化ビニリデンである場合には、アセトン、メチルエチ
ルケトン、酢酸メチル、酢酸エチル1.酢酸ブチル、リ
ン酸トリエチル、N。
When the polymer used to manufacture the hollow fibers is polyvinylidene fluoride, the solutions for dissolving or swelling the ends of the hollow fibers and closing the openings include acetone, methyl ethyl ketone, methyl acetate, and ethyl acetate. Butyl acetate, triethyl phosphate, N.

N−ジメチルホルムアミド、N、N−ジメチルアセトア
ミド、N−メチル−2−ピロリドン、ジメチルスルホキ
シド、アクリロニトリル、シクロヘキサノン、ベンセン
、ピリジントルエン、テトラヒドロフラン、ジオキサン
等が有効であり、中空糸の製作に使用されたポリマーが
ポリサルホンである場合には、ジクロメタン、トリクロ
ロエチレン、クロロホルム、酢酸メチル、酢酸エチル、
アセトン、メチルエチルケトン、シクロヘキサン、N、
N−ジメチルホルムアミド、N、N−ジメチルアセトア
ミド、N−メチル−2−ピロリドン、ジメチルスルホキ
シド等が有効であり、ケース及び中空糸の端部に充填す
る結合剤には、エポキシ系接着剤、ポリウレタン系接着
剤、ニトリル系接着剤、フェノール樹脂、ポリエステル
接着剤、シリコン樹脂、ワックス、ポリ酢酸ビニル、ア
クリル樹脂、メタクリル樹脂、ポリアミド樹脂等が有効
である。
N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidone, dimethyl sulfoxide, acrylonitrile, cyclohexanone, benzene, pyridine toluene, tetrahydrofuran, dioxane, etc. are effective polymers used for making hollow fibers. is polysulfone, dichloromethane, trichloroethylene, chloroform, methyl acetate, ethyl acetate,
Acetone, methyl ethyl ketone, cyclohexane, N,
N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidone, dimethyl sulfoxide, etc. are effective, and epoxy adhesives, polyurethane adhesives, etc. Adhesives, nitrile adhesives, phenolic resins, polyester adhesives, silicone resins, waxes, polyvinyl acetate, acrylic resins, methacrylic resins, polyamide resins, etc. are effective.

(作用) 上記した。構成を備えた中空糸モジュールの製造方法に
おいては、溶解又は膨潤による端部開口の閉塞が、ケー
ス内壁と中空糸の間及び各中空糸間の隙間への結合剤の
充填作業時における中空糸内への充填剤の侵入を阻止す
る。
(Function) As mentioned above. In the manufacturing method of the hollow fiber module having the above structure, the end openings are blocked due to dissolution or swelling, and the inside of the hollow fibers is removed during filling of the binder between the inner wall of the case and the hollow fibers and into the gaps between each hollow fiber. Prevents filler from entering.

(実施例) 以下、本発明の実施例について説明する。(Example) Examples of the present invention will be described below.

第1図の(1)に示すように、外径が1mmのポリフッ
化ビニリデンの限外ろ過膜の中空糸(1)の端部をアク
リルニトリルの溶液(4)内)こ浸漬し、完全に溶解す
る前に引き上げ、杓5分間ドライヤーで乾燥して端部の
開口を閉塞させ、次いで、同図の(2)に示すように、
中空糸(1)がケース(2)の端縁から僅かに突出する
ようにセットしてケース(2)の端縁か60.5〜1c
mを結合剤(エボトートYH315[東部化成])に浸
漬し、結合剤(3)がケース(2)の内壁と中空糸(1
)の間及び各中空糸(1)間の隙間に充填されたところ
で引き上げて乾燥させた。
As shown in Figure 1 (1), the end of the hollow fiber (1) of a polyvinylidene fluoride ultrafiltration membrane with an outer diameter of 1 mm is immersed in an acrylonitrile solution (4), and completely soaked. Before dissolving, pull it out and dry it with a dryer for 5 minutes to close the opening at the end, and then, as shown in (2) in the same figure,
Set the hollow fiber (1) so that it slightly protrudes from the edge of the case (2), and attach it to the edge of the case (2).
immersed in a binder (Evototo YH315 [Tobu Kasei]), and the binder (3) was applied to the inner wall of the case (2) and the hollow fiber (1).
) and between the hollow fibers (1), the fibers were pulled up and dried.

同様な手順で他端部を処理し、結合剤(3)が流出しな
い゛程度に硬化した時点(約2Bi間)で、同図の(3
)に示すように、ケース(2)のDi !かう突出した
中空糸(1)の端部をナイフで切断し、更に杓20時間
掛けて結合剤(3)を完全に硬化させ、中空糸(1)の
両端部が開口した中空糸モジュールを得た。
Treat the other end in the same manner, and when the binder (3) has hardened to the extent that it will not flow out (approximately 2 Bi),
), Di ! of case (2)! The ends of the protruding hollow fibers (1) were cut with a knife, and the binder (3) was completely cured using a ladle for 20 hours to obtain a hollow fiber module with both ends of the hollow fibers (1) open. Ta.

(発明の効果) 本発明の中空糸モジュールの製造方法が、上記したよう
に、中空糸を溶解又は膨潤させる溶液中に中空糸の端部
を浸漬して端部の開口を閉塞させる工程、ケース内に挿
入した中空糸の端部をケースの端縁から突出させ、ケー
ス及び中空糸の端部を結合剤中に浸漬してケースの内壁
と中空糸の間及び各中空糸間の隙間に結合剤を充填させ
る工程及びケースの端縁か6突出した中空糸の端部を切
除する工程を含んでいることにより、作業が容易であっ
て、中空糸の端部開口を閉塞させず、ケiス内の中空糸
間に必要以上に艮〈充填された結合剤によって中空糸の
有効面積を減少させることもなく、更に、結合剤の充填
不足による不安定な中空糸の保持・状態を示さない中空
糸モジュールが得られた。
(Effects of the Invention) As described above, the method for manufacturing a hollow fiber module of the present invention includes the step of immersing the end of the hollow fiber in a solution that dissolves or swells the hollow fiber to close the opening at the end, and the case. The ends of the hollow fibers inserted into the case are made to protrude from the edge of the case, and the ends of the case and the hollow fibers are dipped in a binder and bonded to the spaces between the inner wall of the case and the hollow fibers and between each hollow fiber. By including the step of filling the case with the agent and the step of cutting off the end of the hollow fiber that protrudes from the edge of the case, the work is easy, the end opening of the hollow fiber is not blocked, and the case is removed. There is no unnecessarily crowded space between the hollow fibers in the chamber (the filled binder does not reduce the effective area of the hollow fibers, and furthermore, the hollow fibers are not held or in an unstable state due to insufficient filling of the binder). A hollow fiber module was obtained.

られた。It was done.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の一実施例の各工程を示す部分断面図
、第2図は、本発明の対象となる中空糸モジュールの一
例の断面図、第3図は、従来の技術による中空糸モジュ
ールの製造方法の一例の各工程を示す部分断面図である
。 1・・・中空糸、2・・・ケース、3・・・結合剤、4
・・・溶液、5・・・接着剤、6・・・カバー、7・・
・注入口。
FIG. 1 is a partial cross-sectional view showing each step of an embodiment of the present invention, FIG. 2 is a cross-sectional view of an example of a hollow fiber module to which the present invention applies, and FIG. It is a partial sectional view showing each process of an example of the manufacturing method of a thread module. 1... Hollow fiber, 2... Case, 3... Binder, 4
...Solution, 5...Adhesive, 6...Cover, 7...
・Inlet.

Claims (1)

【特許請求の範囲】[Claims] 1、多数本の中空糸(1)を筒状のケース(2)内に挿
入し、前記ケース(2)両端部において、前記ケース(
2)の内壁と前記中空糸(1)の間及び各中空糸(1)
間の隙間に結合剤(3)を充填して成る中空糸モジュー
ルの製造方法において、前記ケース(2)のを端縁から
突出させる前記中空糸(1)の端部を前記中空糸(1)
を溶解又は膨潤させる溶液(4)中に浸漬させて各中空
糸の端部を閉塞させる工程、前記ケース(2)の端部を
前記結合剤(3)中に浸漬させて前記ケース(2)の内
壁と前記中空糸(1)の間及び各中空糸(1)間に前記
結合剤(3)を充填する工程及び前記結合剤(3)の固
化後に前記中空糸(1)の閉塞端部を切除する工程を含
む中空糸モジュールの製造
1. Insert a large number of hollow fibers (1) into a cylindrical case (2), and insert the case (2) at both ends of the case (2).
2) between the inner wall of the hollow fiber (1) and each hollow fiber (1)
In the method for manufacturing a hollow fiber module, the gap between the ends of the hollow fiber (1) that protrudes from the edge of the case (2) is filled with a binder (3).
a step of immersing the ends of each hollow fiber in a solution (4) that dissolves or swells the fibers, and immersing the ends of the case (2) in the binder (3) to close the ends of the case (2); filling the binder (3) between the inner wall of the hollow fiber (1) and each hollow fiber (1), and after solidifying the binder (3), the closed end of the hollow fiber (1). Manufacture of hollow fiber modules including the process of cutting out
JP61259469A 1986-10-30 1986-10-30 Production of hollow yarn module Pending JPS63111906A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61259469A JPS63111906A (en) 1986-10-30 1986-10-30 Production of hollow yarn module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61259469A JPS63111906A (en) 1986-10-30 1986-10-30 Production of hollow yarn module

Publications (1)

Publication Number Publication Date
JPS63111906A true JPS63111906A (en) 1988-05-17

Family

ID=17334508

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61259469A Pending JPS63111906A (en) 1986-10-30 1986-10-30 Production of hollow yarn module

Country Status (1)

Country Link
JP (1) JPS63111906A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012044441A1 (en) * 2010-09-28 2012-04-05 Dow Global Technologies Llc Tubesheet and method for making and using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5843205A (en) * 1981-09-09 1983-03-12 Sumitomo Bakelite Co Ltd Filter device
JPS5990605A (en) * 1982-11-13 1984-05-25 Nitto Electric Ind Co Ltd Terminal treatment of hollow fiber bundle

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5843205A (en) * 1981-09-09 1983-03-12 Sumitomo Bakelite Co Ltd Filter device
JPS5990605A (en) * 1982-11-13 1984-05-25 Nitto Electric Ind Co Ltd Terminal treatment of hollow fiber bundle

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012044441A1 (en) * 2010-09-28 2012-04-05 Dow Global Technologies Llc Tubesheet and method for making and using the same
CN103140277A (en) * 2010-09-28 2013-06-05 陶氏环球技术有限责任公司 Tubesheet and method for making and using the same
US8506808B2 (en) 2010-09-28 2013-08-13 Dow Global Technologies Llc Tubesheet and method for making and using the same

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