JPS63101402A - Purification of galactomannan - Google Patents
Purification of galactomannanInfo
- Publication number
- JPS63101402A JPS63101402A JP24538786A JP24538786A JPS63101402A JP S63101402 A JPS63101402 A JP S63101402A JP 24538786 A JP24538786 A JP 24538786A JP 24538786 A JP24538786 A JP 24538786A JP S63101402 A JPS63101402 A JP S63101402A
- Authority
- JP
- Japan
- Prior art keywords
- galactomannan
- crude
- aqueous solution
- added
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 title claims abstract description 40
- 229920000926 Galactomannan Polymers 0.000 title claims abstract description 40
- 238000000746 purification Methods 0.000 title 1
- 239000007864 aqueous solution Substances 0.000 claims abstract description 19
- 238000001914 filtration Methods 0.000 claims abstract description 11
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 9
- -1 alkaline earth metal salt Chemical class 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000001110 calcium chloride Substances 0.000 claims abstract description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 16
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 9
- 239000000243 solution Substances 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 238000013019 agitation Methods 0.000 abstract 1
- 235000011148 calcium chloride Nutrition 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910001562 pearlite Inorganic materials 0.000 abstract 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 229920000161 Locust bean gum Polymers 0.000 description 6
- 239000000711 locust bean gum Substances 0.000 description 6
- 235000010420 locust bean gum Nutrition 0.000 description 6
- 239000012264 purified product Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 235000010491 tara gum Nutrition 0.000 description 2
- 239000000213 tara gum Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000006116 Eucalyptus pauciflora Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001938 Vegetable gum Polymers 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical group OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 125000000311 mannosyl group Chemical group C1([C@@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明はガラクトマンナンの精製法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a method for purifying galactomannan.
ガラクトマンナンはマンノースな構成単位とする主鎖に
ガラクトース単位が側鎖として構成される中性多糖類で
あり、主として豆科植物の種子の胚乳部に多（含有され
ている。グア豆を原料とするグアガム、タラ豆を原料と
するタラガム及びローカストビーンを原料とするローカ
ストビーンガムは代表的なガラクトマンナンを主成分と
する植物ガム質である。Galactomannan is a neutral polysaccharide composed of a main chain consisting of mannose units and galactose units as side chains, and is mainly contained in the endosperm of seeds of leguminous plants. Guar gum, tara gum made from cod beans, and locust bean gum made from locust beans are representative vegetable gums containing galactomannan as a main component.
ガラクトマンナンは水に溶解したときに、きわめて高い
粘性を有し、その水溶液はｐＨ安定性及び共存塩安定性
に優れており、食品分野を中心に捺染、糊料等の諸工業
にも広く利用されている。Galactomannan has extremely high viscosity when dissolved in water, and its aqueous solution has excellent pH stability and coexisting salt stability, and is widely used in various industries such as textile printing and starch, mainly in the food field. has been done.
しかし通常のガラクトマンナンは、胚乳部の摘出に際し
て種皮、胚芽部（蛋白質、油分、繊維質）等の不純物が
混入するので、透明性及び品質安定性が劣ったものにな
る。そのため高純度、高透明性等の高度な品質を要求さ
れる用途においては精製ガラクトマンナンが要望されて
いる。However, normal galactomannan has poor transparency and quality stability because impurities such as seed coat and germ (protein, oil, fiber) are mixed in when the endosperm is extracted. Therefore, purified galactomannan is required for applications that require high quality such as high purity and high transparency.
ガラクトマンナンの精製法としては、通常粗製ガラクト
マンナンを熱水溶解したのち、蛋白質、繊維質等の不溶
解物質をｆ過除去し、ｆ液にメタノール、イソプロピル
アルコール、アセトン等の水親和性有機溶剤を加えてガ
ム質を析出させ、これを回収して乾燥、粉砕する方法が
用いられている。Galactomannan is usually purified by dissolving crude galactomannan in hot water, removing insoluble substances such as proteins and fibers by filtration, and adding a water-compatible organic solvent such as methanol, isopropyl alcohol, or acetone to the liquid. is added to precipitate a gummy substance, which is then collected, dried, and crushed.
しかし前記の工程においては、熱水溶解して得たガラク
トマンナン水溶液中に微細な粒子となった蛋白質等の不
溶解物質が含まれ、これが充分に除去できないため、水
溶液の透明性に優れた精製ガラクトマンナンが得られな
いという問題がある。またこの微細な不溶解物質をｒ過
によって除去するためには微小粒径のｒ過助剤を大量に
用い、さらにごく目開きの細かいｒ布を用いるか、何度
もｆ過を繰り返さなければならず生産性が低下する等の
問題点があり、より簡便に透明性の優れたガラクトマン
ナンを得る方法が要望されていた。However, in the above process, the galactomannan aqueous solution obtained by dissolving in hot water contains insoluble substances such as proteins in the form of fine particles, which cannot be removed sufficiently. There is a problem that galactomannan cannot be obtained. In addition, in order to remove these fine insoluble substances by r-filtration, it is necessary to use a large amount of r-filtering agent with a fine particle size, use a r-cloth with very fine openings, or repeat f-filtration many times. However, there are problems such as a decrease in productivity, and there has been a need for a simpler method for obtaining galactomannan with excellent transparency.
本発明者らは前記の状況に鑑み、生産性を低下させるこ
となく透明性に優れた精製ガラクトマンナンを得るべく
鋭意検討した結果、本発明に到達した。In view of the above-mentioned situation, the present inventors conducted intensive studies to obtain purified galactomannan with excellent transparency without reducing productivity, and as a result, they arrived at the present invention.
本発明は、アルカリ土類金属塩を含有する粗製ガラクト
マンナンの水溶液から不溶解物質を炉去し、Ｆｉｌから
ガラクトマンナンを回収することを特徴とする、ガラク
トマンナンの精製法である。The present invention is a method for purifying galactomannan, which is characterized by removing insoluble substances from an aqueous solution of crude galactomannan containing an alkaline earth metal salt, and recovering galactomannan from a filtrate.
本発明に用いられる粗製ガラクトマンナンとしては、ガ
ラクトマンナン含有種子から種皮や胚芽部を大まかに除
去して粉砕したものでもよく、あるいは不純物をある程
度除去し粗精製した粉砕品でもよい。グアガム、タラガ
ム、ローカストビーンガム等の市販品を用いることもで
きる。The crude galactomannan used in the present invention may be obtained by roughly removing the seed coat and germ from a galactomannan-containing seed and pulverizing it, or it may be a pulverized product obtained by removing impurities to some extent and roughly refining it. Commercially available products such as guar gum, tara gum, and locust bean gum can also be used.
本発明を実施するに際しては、まずアルカリ土類金属塩
を含有する粗製ガラクトマンナンの水溶液を調製する。In carrying out the present invention, first, an aqueous solution of crude galactomannan containing an alkaline earth metal salt is prepared.
粗製ガラクトマンナンを溶解させる水としては、７０〜
１００℃の熱水が用いられる。熱水の使用量は粗製ガラ
クトマンナン１部に対して７０〜１２５部である。熱水
に溶解させる方法としては、まず粗製ガラクトマンナン
粉体な２０℃前後の冷水中に充分に攪拌して分散させ、
攪拌を継続しながら所定の温度まで加温して溶解する方
法、又は所定の温度に保持した熱水を攪拌しながら徐々
に粗製ガラクトマンナン粉体を添加して溶解させる方法
があげられる。The water for dissolving crude galactomannan is 70~
100°C hot water is used. The amount of hot water used is 70 to 125 parts per part of crude galactomannan. To dissolve it in hot water, first, the crude galactomannan powder is thoroughly stirred and dispersed in cold water at around 20°C.
Examples include a method in which crude galactomannan powder is gradually added to and dissolved in hot water maintained at a predetermined temperature while stirring, or a method in which crude galactomannan powder is gradually added to and dissolved in hot water maintained at a predetermined temperature.
本発明に用いられるアルカリ土類金属塩としては、水溶
性のものであればどのようなものでもよいが、カルシウ
ム塩、マグネシウム塩特に塩化カルシウム、塩化マグネ
シウムが好ましい。The alkaline earth metal salt used in the present invention may be any water-soluble salt, but calcium salts and magnesium salts are preferred, particularly calcium chloride and magnesium chloride.
アルカリ土類金属塩の添加量は、粗製ガラクトマンナン
１ ｋｇに対し、カルシウム、マグネシウム換算として
０．０２〜１．０ｇ当量が好ましい。The amount of alkaline earth metal salt added is preferably 0.02 to 1.0 g equivalent in terms of calcium and magnesium per 1 kg of crude galactomannan.
添加量をこれより多くしても格別の効果はなく、得られ
る精製ガラクトマンナン水溶液の透、明性が低下する傾
向を生ずる。また添加量がこれより少ないと透明性向上
効果が充分でない。アルカリ土類金属塩は、粗製ガラク
トマンナンと一緒に水に溶解してもよく、粗製ガラクト
マンナンの溶解前又は溶解後に加えてもよい。Even if the amount added is larger than this, there is no particular effect, and the transparency and brightness of the purified galactomannan aqueous solution obtained tend to decrease. Furthermore, if the amount added is less than this, the effect of improving transparency will not be sufficient. The alkaline earth metal salt may be dissolved in water together with the crude galactomannan, or may be added before or after dissolving the crude galactomannan.
次いでアルカリ土類金属塩を含有するガラクトマンナン
水溶液をｒ遇する。ｒ過は７０℃以上の温度で行うこと
が好ましい。温度が下がると水溶液の粘度が高くなり、
ｒ過性が悪化し生産性が低下するので好ましくない。ｒ
遇する際にはｒ過助剤例えばパーライトを水溶液に対し
て０．５〜１．５％添加し、フィルタープレスでケーキ
層が充分に形成されたのち、Ｐ液を取り出す方法を用い
ることもできる。Then, an aqueous galactomannan solution containing an alkaline earth metal salt is added. The filtration is preferably carried out at a temperature of 70°C or higher. As the temperature decreases, the viscosity of the aqueous solution increases,
This is not preferable because it deteriorates the r-permeability and reduces productivity. r
If necessary, a method can be used in which a super-aiding agent such as perlite is added in an amount of 0.5 to 1.5% to the aqueous solution, and the P solution is taken out after a cake layer is sufficiently formed using a filter press. .
こうして得られた不純物を戸別した水溶液からガラクト
マンナンを回収する方法としては、メタノール、イソプ
ロピルアルコール、アセトン等の水親和性有機溶剤を添
加して沈殿を形成させ、これを回収する方法が用いられ
る。As a method for recovering galactomannan from the aqueous solution from which the impurities thus obtained are removed, a method is used in which a water-friendly organic solvent such as methanol, isopropyl alcohol, or acetone is added to form a precipitate, and then the precipitate is recovered.
本発明方法によれば、従来法に比較して、生産性を低下
させることなく、水溶液透明性の優れた精製ガラクトマ
ンナンを得ることができる。According to the method of the present invention, purified galactomannan with excellent aqueous solution transparency can be obtained without reducing productivity as compared to conventional methods.
下記実施例において製品の水溶液透明度は、精製ガラク
トマンナン４．０Ｉをイオン交換水４（３０ｒｒｔに冷
水分散し、８０℃で１時間攪拌して溶解し、水分補正し
て正確に全量４００Ｉとしたものを２５°Ｃに冷却して
サンプル液とし、分光光度計による６ ６０ ｎｍでの
蒸留水を対照とした透過率（Ｔ％）で示す。In the examples below, the aqueous solution clarity of the product was determined by dispersing purified galactomannan 4.0 I in cold water at 4 ml (30 rrt) of ion-exchanged water, dissolving it by stirring at 80°C for 1 hour, and correcting the moisture content to make the total amount exactly 400 I. The sample liquid was cooled to 25° C., and the transmittance (T%) at 6 60 nm measured with a spectrophotometer was measured with respect to distilled water.
実施例１
粗製ローカストビーンガム３．５ ｋｇ及び塩化カルシ
ウム５０ｇを水３００看に分散し、８５°Ｃで１時間攪
拌して溶解したのち、「過助剤のパーライト３．７ ｋ
ｙを添加混合し、フィルタープレスで加圧濾過した。こ
のときの平均濾過速度は１．６−ｅ／分・ｍ２であった
。次いでｒ液に同容量のイソプロピルアルコールを添加
して生成した沈殿を圧搾脱水し、乾燥、粉砕して精製ロ
ーカストビーンガムを得た。本命の水溶液透明度は９７
、０％であった。Example 1 3.5 kg of crude locust bean gum and 50 g of calcium chloride were dispersed in 300 g of water and stirred at 85°C for 1 hour to dissolve.
y was added and mixed, and filtered under pressure using a filter press. The average filtration rate at this time was 1.6-e/min·m2. Next, the same volume of isopropyl alcohol was added to the r liquid, and the resulting precipitate was dehydrated by pressing, dried, and ground to obtain purified locust bean gum. The favorite aqueous solution clarity is 97
, 0%.
実施例２
粗製ローカストビーンガム３．５ ｋｙ及び塩化マグネ
シウム１００ｇを水３００沼に分散し、８５°Ｃで１時
間攪拌して溶解したのち、実施例１と同様に濾過した。Example 2 3.5 ky of crude locust bean gum and 100 g of magnesium chloride were dispersed in 300 g of water, stirred at 85°C for 1 hour to dissolve, and then filtered in the same manner as in Example 1.
このときの平均濾過速度は１、’！ｒ−ｅ／分・ｍ２で
あった。次いで実施例１と同様に操作して精製品を得た
。この製品の水溶液透明度は９７．５％であった。The average filtration rate at this time is 1,'! It was r-e/min·m2. Then, the same procedure as in Example 1 was carried out to obtain a purified product. The aqueous solution transparency of this product was 97.5%.
比較例１
粗製ローカストビーンガム６．５ ｋｇを水３００２に
分散し、８５℃で１時間攪拌して溶解したのち、実施例
１と同様に濾過した。このときの平均「過速度は１．３
４７分・ｍ２であった。次いで実施例１と同様に操作し
て精製品を得た。この製品の水溶液透明度は９５．０％
であり実施例１及び２に比べて劣っていた。Comparative Example 1 6.5 kg of crude locust bean gum was dispersed in water 3002, stirred at 85° C. for 1 hour to dissolve, and then filtered in the same manner as in Example 1. The average "overspeed" at this time was 1.3
It was 47 minutes/m2. Then, the same procedure as in Example 1 was carried out to obtain a purified product. The aqueous solution transparency of this product is 95.0%
Therefore, it was inferior to Examples 1 and 2.
実施例６
粗製タラガム（富士化学社製スノーガム）３゜５ ｋｇ
を水３００２会表に分散し、８５℃で１時間攪拌して溶
解し、塩化マグネシウム１００ｇを添加したのち実施例
１と同様に濾過した。このときの平均濾過速度は１．２
Ａ／分・ｍ２であった。Example 6 Crude cod gum (snow gum manufactured by Fuji Chemical Co., Ltd.) 3°5 kg
was dispersed in water 3002, dissolved by stirring at 85° C. for 1 hour, and 100 g of magnesium chloride was added thereto, followed by filtration in the same manner as in Example 1. The average filtration rate at this time is 1.2
It was A/min·m2.
次いで実施例１と同様に操作して精製品を得た。Then, the same procedure as in Example 1 was carried out to obtain a purified product.
この製品の水溶液透明度は９８．５％であった。The aqueous solution transparency of this product was 98.5%.
比較例２
実施例３と同様にして得た水溶液に塩化マグネシウムを
添加しないで、実施例１と同様に濾過した。このときの
平均「過速度は１．２２／分＠ｍ２であった。次いで実
施例１と同様に操作して精製品を得た。この製品の水溶
液透明度は９６．０％であり、実施例６に比べて劣って
いた。Comparative Example 2 An aqueous solution obtained in the same manner as in Example 3 was filtered in the same manner as in Example 1 without adding magnesium chloride. The average overspeed at this time was 1.22/min@m2.Then, the same procedure as in Example 1 was carried out to obtain a purified product.The aqueous solution transparency of this product was 96.0%, and the It was inferior to 6.
Claims (1)
ンの水溶液から不溶解物質を濾去し、濾液からガラクト
マンナンを回収することを特徴とする、ガラクトマンナ
ンの精製法。 ２、アルカリ土類金属塩が塩化マグネシウム又は塩化カ
ルシウムであることを特徴とする、特許請求の範囲第１
項に記載の方法。[Scope of Claims] 1. A method for purifying galactomannan, which comprises filtering off insoluble substances from an aqueous solution of crude galatatomannan containing an alkaline earth metal salt and recovering galactomannan from the filtrate. 2. Claim 1, characterized in that the alkaline earth metal salt is magnesium chloride or calcium chloride.
The method described in section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24538786A JPS63101402A (en) | 1986-10-17 | 1986-10-17 | Purification of galactomannan |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24538786A JPS63101402A (en) | 1986-10-17 | 1986-10-17 | Purification of galactomannan |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63101402A true JPS63101402A (en) | 1988-05-06 |
| JPH05401B2 JPH05401B2 (en) | 1993-01-05 |
Family
ID=17132901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24538786A Granted JPS63101402A (en) | 1986-10-17 | 1986-10-17 | Purification of galactomannan |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63101402A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0686643A1 (en) * | 1994-06-09 | 1995-12-13 | Rhone-Poulenc Inc. | Guar gum composition and process for making it |
| US7408057B2 (en) | 2000-07-03 | 2008-08-05 | Marine Bioproducts Intenational | Clarified hydrocolloids of undiminished properties and method of producing same |
| US8536325B2 (en) | 2009-02-05 | 2013-09-17 | Alcon Research, Ltd. | Process for purifying guar |
| US9175249B2 (en) | 2009-07-07 | 2015-11-03 | Alcon Research, Ltd. | Ethyleneoxide butyleneoxide block copolymer compositions |
-
1986
- 1986-10-17 JP JP24538786A patent/JPS63101402A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0686643A1 (en) * | 1994-06-09 | 1995-12-13 | Rhone-Poulenc Inc. | Guar gum composition and process for making it |
| US7408057B2 (en) | 2000-07-03 | 2008-08-05 | Marine Bioproducts Intenational | Clarified hydrocolloids of undiminished properties and method of producing same |
| US8536325B2 (en) | 2009-02-05 | 2013-09-17 | Alcon Research, Ltd. | Process for purifying guar |
| US9175249B2 (en) | 2009-07-07 | 2015-11-03 | Alcon Research, Ltd. | Ethyleneoxide butyleneoxide block copolymer compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05401B2 (en) | 1993-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE69727162T2 (en) | Manufacture of inulin-containing products | |
| JPS5828247A (en) | Purifying method of stevioside solution | |
| CN104039893B (en) | The preparation method of phycocyanobilin | |
| DE3716509A1 (en) | METHOD FOR PRODUCING AND SEPARATING CYCLODEXTRINES | |
| US6162906A (en) | Clarified konjac glucomannan | |
| JPS63101402A (en) | Purification of galactomannan | |
| EP0705280B1 (en) | Cyclodextrin refining process | |
| CA2467510A1 (en) | Process for the production of alginate having a high mannuronic acid-content | |
| US2845363A (en) | Method of making stable cactus mucilage | |
| JPH027962B2 (en) | ||
| JPH02171185A (en) | Preparation of physiologically-active substance | |
| US6740249B1 (en) | Filtration aid for the bayer process | |
| JP2729722B2 (en) | Method for producing purified galactomannan | |
| CN107641159B (en) | Production process of low-viscosity whitening carrageenan | |
| KR20220090611A (en) | A method of manufacturing alginic acid and fucoidan | |
| EP0130946B1 (en) | Process for the preparation of a galactomannan rich thickening agent | |
| JPS63105004A (en) | Purification of locust beam gum | |
| JPH01197501A (en) | Preparation of refined cilium gum | |
| CN1062870C (en) | Method for purifying sun-flower seed low-ester pectine | |
| JP2605207B2 (en) | Purification method of beet saponin | |
| JPH0260597A (en) | Purification of xanthane gum | |
| CH691026A5 (en) | Process for the production of pure guar gum. | |
| JPH03122101A (en) | Clarification of gum arabic | |
| JP5522857B2 (en) | Method for producing collagen | |
| JPH05239105A (en) | Production of purified galactomannan |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |