JPS6267015A - Sunscreen cosmetic - Google Patents

Sunscreen cosmetic

Info

Publication number
JPS6267015A
JPS6267015A JP60207494A JP20749485A JPS6267015A JP S6267015 A JPS6267015 A JP S6267015A JP 60207494 A JP60207494 A JP 60207494A JP 20749485 A JP20749485 A JP 20749485A JP S6267015 A JPS6267015 A JP S6267015A
Authority
JP
Japan
Prior art keywords
cosmetic
weight
powder
cosmetics
silicone oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60207494A
Other languages
Japanese (ja)
Inventor
Takashi Umeno
高 梅野
Midori Ugawa
鵜川　みどり
Shigeru Hashimoto
繁 橋本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sunstar Inc
Original Assignee
Sunstar Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunstar Inc filed Critical Sunstar Inc
Priority to JP60207494A priority Critical patent/JPS6267015A/en
Publication of JPS6267015A publication Critical patent/JPS6267015A/en
Pending legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/11—Encapsulated compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns

Abstract

PURPOSE:The titled cosmetic, containing a low-viscosity silicone oil, powder for cosmetic and fine particulate titanium oxide treated with silicone, ethylene glycol ester of a fatty acid, etc., and capable of sufficiently satisfying required performances, e.g. extensibility to the skin, perspiration resistance, no stickiness, etc. CONSTITUTION:A sunscreen cosmetic obtained by incorporating (A) 1-50 wt.% low-viscosity silicone oil, expressed by the formula (R is H, lower alkyl or phenyl; n is 4-70) and having about 1-500 cSt viscosity at 25 deg.C with (B) 5-70 wt.% powder for cosmetic and 1-70 wt.% fine particulate titanium oxide treated with silicone, preferably fine powder having the surface treated with methylhydrogenpolysiloxane and 20-130m<2>/g specific surface area and (C) at least one component selected from 1-20 wt.% ethylene glycol ester of a fatty acid, 1-20 wt.% 12-hydroxystearic acid and 1-15 wt.% candelilla wax.

Description

【発明の詳細な説明】 魚班Δ立野 本発明は日焼は止め化粧料、さらに詳しくは、低粘度の
シリコーン油と化粧用粉体を主成分とす半固形状の日焼
は止め化粧料に関する。[Detailed Description of the Invention] The present invention relates to a sunscreen cosmetic, more specifically, a semi-solid sunscreen cosmetic containing low viscosity silicone oil and cosmetic powder as main ingredients. Regarding.

発明の背景 従来から、日焼けの原因となる紫外線から皮膚を保護す
る日焼は止め化粧料が種々提案されており、これらは、
紫外線吸収剤を配合するものと、化粧用粉体の配合によ
り紫外線を散乱するものの２つに大別される。しかし、
紫外線吸収剤は皮膚に対して刺激があり、その配合は必
ずしも満足できろものではない。また、化粧用粉体を配
合したらのら、日焼は止め化粧料に要求される、汗に強
いこと、使用か容易なこと、使用後、ベトッキがなく、
さっばりしていることなどの諸性能を満足するものはな
かな見当たらない。BACKGROUND OF THE INVENTION Various sunscreen cosmetics that protect the skin from ultraviolet rays that cause sunburn have been proposed.
There are two main categories: those that contain UV absorbers and those that scatter UV rays by incorporating cosmetic powder. but,
Ultraviolet absorbers are irritating to the skin, and their formulations are not always satisfactory. In addition, once the cosmetic powder is blended, it is resistant to sweat, easy to use, and does not leave sticky residue after use, which is required for sunscreen cosmetics.
It is difficult to find one that satisfies various performance requirements such as being lightweight.

このような事情にかんがみ、本発明者らは、要求される
諸性能を満足する、すぐれた日焼は止め化粧料を得るべ
く種々検討した。その結果、低粘度のシリコーン油と化
粧用粉体を主成分とする半固形状の形態の化粧料がその
目的に適することを見出した。In view of these circumstances, the present inventors conducted various studies in order to obtain an excellent sunscreen cosmetic that satisfies various required performances. As a result, they found that a semi-solid cosmetic containing low-viscosity silicone oil and cosmetic powder as the main ingredients is suitable for this purpose.

低粘度のシリコーン油が、皮膚に塗布したときに、ザラ
サラした感触を有し、メークアップ化粧料に配合すると
、大変良好な使用感を有する化粧料が得られることは、
すてに知られている（特開昭５４−１４５２８号）。し
かしながら、このようなシリコーン油に粉体を配合して
り１リーム状にすると、粉体が分離、沈降して満足な製
品が得られない。ところが、本発明によれば、該シリコ
ーン油と粉体を用いて良好な半固形状の形態の製品が得
られる。また、同時に処方される微粒子酸化チタンの表
面活性のため変臭、変色が生じる問題かあるが、本発明
によれば、これら防止することができる。The fact that low-viscosity silicone oil has a smooth feel when applied to the skin, and when incorporated into makeup cosmetics, results in cosmetics that have a very good feeling of use.
It is well known (Japanese Unexamined Patent Publication No. 14528/1983). However, when such silicone oil is blended with powder and made into a single ream, the powder separates and settles, making it impossible to obtain a satisfactory product. However, according to the present invention, a good semi-solid product can be obtained using the silicone oil and powder. In addition, there are problems with odor and discoloration due to the surface activity of the particulate titanium oxide that is simultaneously formulated, but according to the present invention, these problems can be prevented.

発明の概要 本発明は、低粘度シリコーン油１〜５０重量％、化粧用
粉体５〜７０重量％およびシリコーン処理微粒子酸化チ
タン１〜７０重徹％と、エチレングリコール脂肪酸エス
テル１〜２０重量％、１２−ヒドロキンステアリン酸１
〜２０重量％およびキャンデリラワックスｔ−１５重量
％からなる群から選ばれる少なくとも１種の成分を必須
成分として配合してなる半固形状の日焼は止め化粧料を
提供するものである。本発明の日焼は止め化粧料はクリ
ーム状、吹惜状等の半固形状で使用しやすく、肌へのの
び、耐汗性ヘトツキのなさなど、要求される諸性能を充
分に満足するらのである。Summary of the Invention The present invention comprises 1 to 50% by weight of low viscosity silicone oil, 5 to 70% by weight of cosmetic powder, 1 to 70% by weight of silicone-treated fine particle titanium oxide, 1 to 20% by weight of ethylene glycol fatty acid ester, 12-Hydroquine stearic acid 1
The present invention provides a semi-solid sunscreen cosmetic containing as an essential component at least one component selected from the group consisting of 15% by weight of candelilla wax and 15% by weight of candelilla wax. The sunscreen cosmetic of the present invention is easy to use in a semi-solid form such as cream or spray form, and fully satisfies various required performances such as spreadability on the skin, sweat resistance, and non-stickiness. It is.

発明の詳細 な説明の日焼は止め化粧料の必須成分として用いろ低粘
度シリコーン油は、式 （式中、Ｒは水素、低級アルキルまたはフェニル、ｎは
４〜７０を意味する） で示される２５℃における粘変が約１〜５００センチス
トークスのシリコーン油であり、商業的に人手可能であ
る。このシリコーン油は化粧料の性状および使用感等の
観点から、化粧料全量に基ついて、１〜５０重量％の割
合で配合する。Detailed Description of the Invention The low viscosity silicone oil used as an essential component of sunscreen cosmetics is represented by the formula (wherein R is hydrogen, lower alkyl or phenyl, and n means 4 to 70). The silicone oil has a viscosity change of about 1 to 500 centistokes at 25°C and is commercially available. This silicone oil is blended in an amount of 1 to 50% by weight based on the total amount of the cosmetic from the viewpoint of the properties and feel of the cosmetic.

化粧用粉体としては、シリコーン処理微粒子酸化チタン
以外の、化粧料配合用の、顔料等の無機および有機粉体
が挙げられ、ポリエチレン末、タルク、無水ケイ酸、黒
酸化鉄、ベンガラ、黄酸化鉄、酸化チタンなどが包含さ
れ、これらは単独でら二種以上を用いてもよい。化粧料
の性状、紫外線散乱効果等から、化粧用粉体は化粧料全
量に基づいて５〜７０重量％の割合で配合する。Cosmetic powders include inorganic and organic powders such as pigments for cosmetic formulations other than silicone-treated fine titanium oxide particles, such as polyethylene powder, talc, silicic anhydride, black iron oxide, red iron oxide, and yellow oxide. Iron, titanium oxide, etc. are included, and these may be used alone or in combination of two or more. The cosmetic powder is blended in an amount of 5 to 70% by weight based on the total amount of the cosmetic, depending on the properties of the cosmetic and the UV scattering effect.

シリコーン処理微粒子酸化チタンとしては、比表面積力
２０　ｙｔ”／９〜ｌ　３０　ｙ２／９０）微粒子（平
均粒径０．００５μｍ〜０．０７５μｍ）酸化チタンを
メチルハイドロジエンポリシロキサンで表面処理したら
のが挙げろれ、化粧料全量に基づいて１〜７０重量％の
割合で配合される。Silicone-treated fine particles of titanium oxide include specific surface area of 20 yt"/9 to 130 y2/90) fine particles (average particle size of 0.005 μm to 0.075 μm) that are surface-treated with methylhydrodiene polysiloxane. In particular, it is blended in an amount of 1 to 70% by weight based on the total amount of cosmetics.

エチレングリコール脂肪酸エステルとしては、式 ％式％ （式中、Ｒ１およびＲ２は、同一または異なって、各々
、炭素数１１〜３５のアルキル、ｎは１〜５をＣ味する
） で示されるエステルが挙げられ、これらも商業的に入手
可能である。このエステルは、化粧料の性状等の観点か
ら、化粧料全量に基づいて１〜２０重量％の割合で配合
する。エチレングリコール脂肪酸エステルは特に、クリ
ーム状の化粧料の製造に適している。Ethylene glycol fatty acid esters include esters represented by the formula % (wherein R1 and R2 are the same or different, each alkyl having 11 to 35 carbon atoms, and n represents 1 to 5). These are also commercially available. This ester is blended in an amount of 1 to 20% by weight based on the total amount of the cosmetic from the viewpoint of the properties of the cosmetic. Ethylene glycol fatty acid esters are particularly suitable for the production of creamy cosmetics.

１２−ヒドロキシステアリン酸は商業的に入手可能で、
本発明の化粧料においては、化粧料の性状等の観点から
化粧料全量に基づいて、１〜２０重量％の範囲で配合す
る。12-Hydroxystearic acid is commercially available;
In the cosmetic composition of the present invention, from the viewpoint of the properties of the cosmetic composition, etc., it is blended in an amount of 1 to 20% by weight based on the total amount of the cosmetic composition.

キャンデリラワックスは、本発明の化粧料においては、
化粧料全量に基づいて、１〜１５重量％の範囲で配合す
る。Candelilla wax is used in the cosmetics of the present invention.
It is blended in an amount of 1 to 15% by weight based on the total amount of the cosmetic.

これらのエチレングリコール脂肪酸エステル、１２−ヒ
ドロキシステアリン酸およびキャンデリラワックスは単
独でも、２種以上併用してらよい。These ethylene glycol fatty acid ester, 12-hydroxystearic acid and candelilla wax may be used alone or in combination of two or more.

本発明の日焼は止め化粧料は、通常の非水系軟膏状化粧
料と同様な方法で製造でき、さらに、流ｆｄ）ハラフィ
ン、脂肪酸、高級アルコール、エステル油、ラノリン、
ワセリン、パラフィンワックス、セレシンなどのような
、他の成分を配合することができる。The sunscreen cosmetic of the present invention can be produced in the same manner as ordinary non-aqueous ointment cosmetics, and further contains halafine, fatty acids, higher alcohols, ester oils, lanolin,
Other ingredients can be included, such as petrolatum, paraffin wax, ceresin, etc.

つぎに、実施例および参考例を挙げて、本発明をさらに
詳しく説明する。Next, the present invention will be explained in more detail with reference to Examples and Reference Examples.

実施例１および参考例１および２ 第１表に示す成分を用い、常法により、クリーム状の化
粧料を製造した。Example 1 and Reference Examples 1 and 2 Cream-like cosmetics were produced by a conventional method using the ingredients shown in Table 1.

第１表 得られた実施例１のクリームと、市販の、シリコーン油
を用いていない同様なりリーム（いずれらチューブ入り
）の性能を１００名のパネルにより、っぎの７段階の評
価方式により評価した。Table 1: The performance of the obtained cream of Example 1 and a commercially available similar cream without silicone oil (all in tubes) was evaluated by a panel of 100 people using the 7-level evaluation system. .

＋３：きわめて良好、＋２．良好、 ＋１：やや良好、０：普通、−Ｉ：やや劣る、＝２：劣
る、−３：非常に劣る 結果を第２表に示す。第２表中の数値は１００名のパネ
ル員による評価点の平均である。+3: Very good, +2. Table 2 shows the results: Good, +1: Slightly Good, 0: Fair, -I: Slightly Poor, =2: Poor, -3: Very Poor. The numerical values in Table 2 are the average scores of the 100 panel members.

第２表 第２表に示すごとく、本発明の日焼は止め化粧料は要求
される諸性能を満たし、きイつめてすくれた日−は止め
効果を発揮する。Table 2 As shown in Table 2, the sunscreen cosmetic composition of the present invention satisfies the various performance requirements and exhibits an intense sunscreen effect.

また、実施例１および参考例１のクリームを製造直後か
ら４０℃の恒温室で放置テストした結果、実施例Ｉのク
リームは１ケ月後ら何ら異常なく、３ケ月後に、わずか
に離液が認められたにの対し、参考例１のクリームは１
週間後、すでに著しい離液を生じた。In addition, as a result of leaving the creams of Example 1 and Reference Example 1 in a constant temperature room at 40°C immediately after production, the cream of Example I showed no abnormalities after 1 month, and slight syneresis was observed after 3 months. In contrast, the cream of Reference Example 1
After a week, significant syneresis had already occurred.

さらに、実施例１および参考例２のクリームを１ケ月（
４月１５日〜５月１５日）問屋外に放置したところ、参
考例２のクリームでは黒変、異臭が生じたが、実施例１
のクリームでは異常は認められなかった。Furthermore, the cream of Example 1 and Reference Example 2 was applied for 1 month (
(April 15th to May 15th) When left outside, the cream of Reference Example 2 turned black and developed a strange odor, but the cream of Example 1
No abnormalities were observed with the cream.

実施例２および参考例３および４ 第３表に示す成分を用い、常法により半固形状の化粧料
を製造した。Example 2 and Reference Examples 3 and 4 Semi-solid cosmetics were produced by a conventional method using the ingredients shown in Table 3.

第３表 得られた実施例２の化粧料と、市販の、シリコーン油を
用いていない同様な化粧料（いずれもチューブ入り）の
性能を９５名のパネルにより、つぎの７段階の評価方式
により評価した。Table 3 The performance of the obtained cosmetic of Example 2 and a commercially available similar cosmetic that does not use silicone oil (all in tubes) was evaluated by a panel of 95 people using the following 7-level evaluation method. evaluated.

＋３　きわめて良好、＋２：良好、 ＋１．やや良好、０：普通、−１：やや劣る、−２劣る
、−３：非常に劣る 結果の平均を第４表に示す。+3: Very good, +2: Good, +1. Table 4 shows the average of the results: Slightly good, 0: Fair, -1: Slightly poor, -2 Poor, -3: Very poor.

第４表 第４表に示すごとく、本発明の日焼は止め化粧料は要求
されろ諸性能を満たし、きわめてすぐれた日焼は止め効
果を発揮する。Table 4 As shown in Table 4, the sunscreen cosmetic composition of the present invention satisfies the required performance and exhibits an extremely excellent sunscreen effect.

また、実施例２および参考例３の化粧料を製造直後から
４０℃の恒温室で放置テストした結果、実施例２の化粧
料は１ケ月後ら何ら異常なく、３ケ月後に、イつずかに
離液が認められたにの対し、参考例３の化粧料は３日後
、すでに著しい離液を生じた。In addition, as a result of leaving the cosmetics of Example 2 and Reference Example 3 in a constant temperature room at 40°C immediately after production, the cosmetics of Example 2 showed no abnormality after 1 month, and after 3 months, On the other hand, the cosmetic of Reference Example 3 already caused significant syneresis after 3 days.

さらに、実施例２および参考例４の化粧料を１ケ月（４
月１５日〜５月１５日）問屋外に放置したところ、参考
例４の化粧料では黒変、異臭が生じたが、実血例２の化
粧料では異常は認められなかった。Furthermore, the cosmetics of Example 2 and Reference Example 4 were used for 1 month (4
(May 15th to May 15th) When the cosmetics of Reference Example 4 were left outside, black discoloration and a strange odor occurred, but no abnormality was observed in the cosmetics of Actual Example 2.

実施例３および参考例５および６ 第５表に示す成分を用い、常法により半固形状の化粧料
（ファンデーノヨン）を製造した。Example 3 and Reference Examples 5 and 6 A semi-solid cosmetic (foundation noyon) was produced using the ingredients shown in Table 5 by a conventional method.

第５表 ｉすられｆ二実施例３の化粧料と、市販の、ノリコーン
浦を用いていない同様な化粧料（いずれらチューブ入り
）の性能を９５名のパネルにより、つぎの７段階の評価
方式により評価した。Table 5: The performance of the cosmetic of Example 3 and a commercially available similar cosmetic that did not use Noricone Ura (all in tubes) was evaluated by a panel of 95 people on the following 7-level scale. Evaluation was made using the following method.

＋３　きわめて良好、＋２：良好、 −１やや良好、０．旨通、−１，やや劣る、−２劣る、
−３・非常に劣る 結果の平均を第６表に示す。+3 Very good, +2: Good, -1 Fairly good, 0. Utsutsu, -1, slightly inferior, -2 inferior,
-3.Very poor results are shown in Table 6.

第６表 第６表に示すごとく、本発明の日焼け１ヒめ化粧斗は要
求される諸性能を満たし、きイつめてすくれｔ日焼は止
め効果を発揮する。Table 6 As shown in Table 6, the sunburn makeup toner of the present invention satisfies the required performance and exhibits a tight sunscreen effect.

また、実施例３および参考例５の化粧料を〃造α後から
４０℃の恒温室で放置テストした結果、実施例３の化粧
料は１ケ月後ら何ら異常なく、３テ月後に、イつずかに
離液が認められｆ月この対し、参考例５の化粧料は２週
間後、慣でに杆しい＃液を生した。In addition, as a result of testing the cosmetics of Example 3 and Reference Example 5 after being left in a constant temperature room at 40°C after production, the cosmetics of Example 3 showed no abnormalities after 1 month, and after 3 months, On the other hand, the cosmetic of Reference Example 5 already produced a persistent liquid after two weeks.

さらに、実施例３および参考例６の化粧料を１ｒ月（４
月１５日〜５月１５０）問屋外に放置したところ、参考
例６の化粧料では黒変、異臭か生じたか、実施例３の化
粧料では異常は認められなかった。Furthermore, the cosmetics of Example 3 and Reference Example 6 were used for 1r month (4
(May 15th to May 150th) When the cosmetics were left outside, the cosmetics of Reference Example 6 produced black discoloration and a strange odor, while the cosmetics of Example 3 showed no abnormalities.

Claims (1)

【特許請求の範囲】[Claims] （１）低粘度シリコーン油１〜５０重量％、化粧用粉体
５〜７０重量％およびシリコーン処理微粒子酸化チタン
１〜７０重量％と、エチレングリコール脂肪酸エステル
１〜２０重量％、１２−ヒドロキシステアリン酸１〜２
０重量％およびキャンデリラワックス１〜１５重量％か
らなる群から選ばれる少なくとも１種の成分を必須成分
として配合したことを特徴とする半固形状の日焼け止め
化粧料。(1) 1 to 50% by weight of low viscosity silicone oil, 5 to 70% by weight of cosmetic powder, 1 to 70% by weight of silicone-treated fine particle titanium oxide, 1 to 20% by weight of ethylene glycol fatty acid ester, 12-hydroxystearic acid 1-2
A semi-solid sunscreen cosmetic comprising at least one component selected from the group consisting of 0% by weight and 1 to 15% by weight of candelilla wax as an essential component.
JP60207494A 1985-09-18 1985-09-18 Sunscreen cosmetic Pending JPS6267015A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60207494A JPS6267015A (en) 1985-09-18 1985-09-18 Sunscreen cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60207494A JPS6267015A (en) 1985-09-18 1985-09-18 Sunscreen cosmetic

Publications (1)

Publication Number Publication Date
JPS6267015A true JPS6267015A (en) 1987-03-26

Family

ID=16540648

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60207494A Pending JPS6267015A (en) 1985-09-18 1985-09-18 Sunscreen cosmetic

Country Status (1)

Country Link
JP (1) JPS6267015A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63287715A (en) * 1987-05-20 1988-11-24 Shiseido Co Ltd Oily suncare cosmetic
JPS6475416A (en) * 1987-09-17 1989-03-22 Shiseido Co Ltd Aerosol cosmetic
FR2716621A1 (en) * 1994-02-28 1995-09-01 Roussel Uclaf Cosmetic sunscreen compsns.
US5618522A (en) * 1995-01-20 1997-04-08 The Procter & Gamble Company Emulsion compositions
EP0704204A3 (en) * 1994-09-23 1997-06-18 Dow Corning Siloxane gels
EP0707845A3 (en) * 1994-10-17 1997-06-18 Dow Corning Alkylmethylsiloxane-containing gels
JP2009508920A (en) * 2005-09-23 2009-03-05 クローダ インターナショナル パブリック リミティド カンパニー Metal oxide dispersion

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63287715A (en) * 1987-05-20 1988-11-24 Shiseido Co Ltd Oily suncare cosmetic
JPS6475416A (en) * 1987-09-17 1989-03-22 Shiseido Co Ltd Aerosol cosmetic
FR2716621A1 (en) * 1994-02-28 1995-09-01 Roussel Uclaf Cosmetic sunscreen compsns.
EP0677287A2 (en) * 1994-02-28 1995-10-18 Roussel Uclaf Cosmetic composition for solar protection
EP0677287A3 (en) * 1994-02-28 1998-02-25 The Boots Company PLC Cosmetic composition for solar protection
EP0704204A3 (en) * 1994-09-23 1997-06-18 Dow Corning Siloxane gels
EP0707845A3 (en) * 1994-10-17 1997-06-18 Dow Corning Alkylmethylsiloxane-containing gels
US5618522A (en) * 1995-01-20 1997-04-08 The Procter & Gamble Company Emulsion compositions
JP2009508920A (en) * 2005-09-23 2009-03-05 クローダ インターナショナル パブリック リミティド カンパニー Metal oxide dispersion

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