JPS6261008A - Production of plastic optical fiber - Google Patents

Production of plastic optical fiber

Info

Publication number
JPS6261008A
JPS6261008A JP60201318A JP20131885A JPS6261008A JP S6261008 A JPS6261008 A JP S6261008A JP 60201318 A JP60201318 A JP 60201318A JP 20131885 A JP20131885 A JP 20131885A JP S6261008 A JPS6261008 A JP S6261008A
Authority
JP
Japan
Prior art keywords
resin
capillary
core
optical fiber
plastic optical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60201318A
Other languages
Japanese (ja)
Inventor
Masaaki Abe
阿部 公明
Haruki Yokono
春樹 横野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP60201318A priority Critical patent/JPS6261008A/en
Publication of JPS6261008A publication Critical patent/JPS6261008A/en
Pending legal-status Critical Current

Links

Landscapes

  • Multicomponent Fibers (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)

Abstract

PURPOSE:To permit simple and inexpensive production by filling a resin for core into a tube of a plastic capillary having the inside diameter corresponding to the diameter of the core and curing the resin. CONSTITUTION:A vinyl chloride capillary, PE capillary or 'Teflon(R)' capillary is utilized as the capillary for clad and a transparent thermoplastic epoxy resin is put into the capillary with a vacuum pump by putting one end of the capillary into the resin while the transparent thermosetting epoxy resin is kept heated to 20-50 deg.C to the decreased viscosity state and connecting the other end to the vacuum pump. The resin is then cured by a hot air dryer, by which a plastic optical fiber is obtd. The capillary which can be shrunk according to the shrinkage when the resin for the core cures is used.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、プラスチック光ファイバーの製造法に関する
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for manufacturing plastic optical fibers.

(従来の技術) プラスチック光ファイバーの製造法として所定のコアー
用樹脂を容器に入n1ノズル先端より引き出し加熱か冷
却して硬化させ、続いてクラッド用樹脂をコーティング
する方法が一般的である。
(Prior Art) A common method for manufacturing plastic optical fibers is to put a predetermined core resin in a container, pull it out from the tip of the n1 nozzle, heat or cool it to harden it, and then coat it with a cladding resin.

(発明が解決しようとする問題点) 従来の製造法では、所定のコアー径に調整するのに樹脂
の温度、粘度、容器の圧力、ノズル管理、製品の送り速
度、張力、周辺の温度、クリーン化等多くの管理項目を
コントロール必要があった。
(Problems to be Solved by the Invention) In conventional manufacturing methods, adjusting the core diameter to a predetermined core diameter requires a number of factors such as resin temperature, viscosity, container pressure, nozzle management, product feed rate, tension, surrounding temperature, and cleanliness. It was necessary to control many management items such as

その之め高度な計器類が必要で、細心の注意を払わねば
ならないので、高価となジ少量多品種の製造上不利であ
りto 本発明は、きわめて閏単で安価にグラスチック光ファイ
バーを製造する方法を提供するものである。
Therefore, sophisticated instruments are required and careful attention must be paid, which makes it expensive and disadvantageous for manufacturing a wide variety of products in small quantities.The present invention makes it possible to manufacture glass optical fibers in a very simple and inexpensive manner. The present invention provides a method.

(問題点を着決する之めの手段) 本発明は、コアー径に相当する円径を有するプラスチッ
ク細管、例えば、円径α1〜2. Q +nfllで、
塩化ビニル、ポリエチレン、ボリプQピレン、テフロン
等の熱可塑性樹脂またに熱硬化性樹脂で製造さfコアー
が熱硬化性樹脂の場合は不透明のものでもよいが、コア
ーが蓄外糎硬化樹脂の場合は、透明性のものがより良好
であるが、cILらの細管に圧縮ボンダ等により、コア
ー用樹脂全圧入する。また圧入が困難な場合には、細管
の一端を真空ボン7′につなぎ他端をコアー用樹脂容器
に差し込むことにより、細管の中にコアー用樹脂を簡単
に入n、ることができる。
(Means for resolving the problem) The present invention provides a plastic capillary tube having a circular diameter corresponding to the core diameter, for example, a circular diameter α1 to α2. Q + nflll,
Manufactured from thermoplastic or thermosetting resins such as vinyl chloride, polyethylene, polyethylene, Teflon, etc.If the core is made of thermosetting resin, it may be opaque, but if the core is made of thermosetting resin, it may be opaque. A transparent one is better, but the entire core resin is press-fitted into the thin tube of cIL using a compression bonder or the like. If press-fitting is difficult, the core resin can be easily inserted into the thin tube by connecting one end of the thin tube to the vacuum bong 7' and inserting the other end into the core resin container.

本発明によると、コアー径を一定にする方法として、あ
らかじめ既成プラスチック細管の円径が所定のコアー直
径となるものを選び使用す几ばよく、従来のようにコア
ー径を一定にするための装置や高度な技術を必要としな
いものである。しかも、この方法におけるコアー用樹脂
としてエポキシ系樹脂を便用するのが好ましいがエポキ
シ樹脂は硬化時間が長く、他のプラスチック光ファイバ
ーのコアー用樹脂例えばPMMA等では紡糸時コアー用
樹脂はノズルから取り出し冷却すると即時に硬化するた
め、紡糸が簡単に可能であったが、エポキシ系樹脂では
硬化に10分〜4時間と長くかかる之め、従来の方法で
は、紡糸不可能であった。本発明では硬化に長時間金寮
しても、コアー用樹脂は所定の外径をもつクラッド用細
管に入っている友め、時間に関係なく、硬化処理が可能
である。
According to the present invention, as a method for making the core diameter constant, it is sufficient to select and use a ready-made plastic capillary whose circular diameter has a predetermined core diameter. It does not require advanced technology. Moreover, it is preferable to use an epoxy resin as the core resin in this method, but epoxy resin takes a long time to harden, and when using other plastic optical fiber core resins such as PMMA, the core resin is removed from the nozzle and cooled during spinning. Since the resin cures instantly, it is easy to spin the resin. However, since the epoxy resin takes a long time to cure, from 10 minutes to 4 hours, it has not been possible to spin the resin using conventional methods. In the present invention, even if curing takes a long time, the core resin is contained in a thin tube for cladding having a predetermined outer diameter, so the curing process can be performed regardless of the time.

第1□□□は本発明により得らnるプラスチック光ファ
イバーの断面図であり、1はコア、2はクラッドとなる
プラスチックlll1管である。
The first □□□ is a cross-sectional view of a plastic optical fiber obtained according to the present invention, in which 1 is a core and 2 is a plastic tube serving as a cladding.

(実施例) クラッド用細管として円径1 mm、外径5市の塩化ビ
ニール細管、ポリエチレン細管、テンロン細管を利用し
央験用真空ポンプで真空圧500〜1.000ffll
l!Hgにより、熱硬化性透明エポキシ樹脂を20〜5
0℃に保温し粘度を下げた状態で細管の一端を樹脂の中
に入几、他端を具9ポンプに接続することにより細管の
中に熱硬化性透明エポキシ樹脂全人fした。次に熱に乾
燥器に50分〜3時間、100〜200℃の温度で硬化
させたところ、伝送損失1〜5dB/mのプラスチック
光ファイバーを得ることができた。
(Example) Using vinyl chloride tubes, polyethylene tubes, and Tenron tubes with a circular diameter of 1 mm and an outer diameter of 5 mm as cladding tubes, a vacuum pump for central testing was used to generate a vacuum pressure of 500 to 1.000 ffll.
l! Depending on Hg, the temperature of thermosetting transparent epoxy resin is 20-5
One end of the thin tube was put into the resin while keeping the temperature at 0° C. to lower the viscosity, and the other end was connected to a pump to fill the entire tube with thermosetting transparent epoxy resin. Next, when it was cured in a heat dryer for 50 minutes to 3 hours at a temperature of 100 to 200°C, a plastic optical fiber with a transmission loss of 1 to 5 dB/m could be obtained.

なお細管はコアー用樹脂の硬化時の収縮率に応じ収縮可
能なものがよい。また、同様の細管で同じよ5な方法で
紫外線硬化性エポキシ83 /J1を使って80 W/
cm、5〜1Q分紫外耐照射することにより、同じ程度
の性能のプラスチック光ファイバーを得ることができ之
Note that the thin tube is preferably one that can be contracted according to the shrinkage rate of the core resin upon curing. Also, using the same method in the same thin tube, use UV curable epoxy 83/J1 to 80 W/
By resisting ultraviolet irradiation for 5 to 1 Q cm, a plastic optical fiber with similar performance can be obtained.

(発明の効果) 本発明によると、コアー径が簡単に得らnること、また
従来不可能とさrしてい之エポキシ樹脂全コアー用樹脂
として使用可能となること、及び、硬化方法として熱硬
化及び紫外線硬化のいずnでも可能であジ、硬化時間に
制限さnず製造できる定め、きわめて簡単で安価にプラ
スチック光フアイバー全製造することが出来る。
(Effects of the Invention) According to the present invention, the core diameter can be easily obtained, the epoxy resin can be used as a resin for all cores, which was previously impossible, and the curing method is heat treatment. Both curing and ultraviolet curing are possible, and the manufacturing process is not limited to the curing time, making it possible to manufacture plastic optical fibers extremely simply and at low cost.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明のプラスチック光ファイバーの断面図で
ある。 符号のμシ明 1、 ファー、  2. プラスチック細管代坤人弁理
士 若 林 邦 彦 /コア 晃1図 手続補正書(自発) 昭和61年12 月lO日 昭和60年特許願第201318号 事件との関係  特許出願人 住所    東京都新宿区西新宿二丁目1番1号名称(
445)日立化成工業株式会社 代表者横山亮次 4、代理人 ■163 居所    東京都新宿区西新宿二丁目1番1号日立化
成工業株式会社内 〔電話 東京 346−3111 <大代表)〕明細書
の発明の詳細な説明の欄。 6、補正の内容 +l)明細書第2頁3行目〜4行目に「コントロール必
要があった。」とあるのを「コントロールする必要があ
った。」と訂正する。 (2)明細書筒2頁15行目に「テフロン」とあるのを
「フン素樹脂」と訂正する。 (3)明細書第2頁16行目に「製造されコアーが」と
あるのを「製造され、コアーが」と訂正する。 (4)明細書第4頁6行目〜7行目に「テフロン」とあ
るのを「フッ素樹脂」と訂正する。 (5)明細書第4頁17行目に「収縮可能なものがよイ
、」とあるのを「収縮可能なものがよい。このように熱
収縮細管の場合は加熱後収縮で円径が所定のコア径とな
るようにする。」と訂正する。 以    上
FIG. 1 is a cross-sectional view of the plastic optical fiber of the present invention. μ-shape of the code 1, Far, 2. Kunihiko Wakabayashi, Patent Attorney for Plastic Tubes / Core Kou 1 Procedural Amendment (Spontaneous) Date of December 1985 Relation to Patent Application No. 201318 of 1985 Patent Applicant Address Nishi, Shinjuku-ku, Tokyo Shinjuku 2-chome 1-1 name (
445) Hitachi Chemical Co., Ltd. Representative Ryoji Yokoyama 4, Agent 163 Address Hitachi Chemical Co., Ltd., 2-1-1 Nishi-Shinjuku, Shinjuku-ku, Tokyo [Telephone: Tokyo 346-3111 <Main representative)] Specification A column for a detailed description of the invention. 6. Contents of the amendment +l) In the third and fourth lines of page 2 of the specification, the phrase "control was necessary." should be corrected to "control was necessary." (2) On page 2, line 15 of the specification tube, the word "Teflon" has been corrected to "fluorine resin." (3) On page 2, line 16 of the specification, the phrase "manufactured and the core" is corrected to "manufactured and the core is". (4) On page 4, lines 6 and 7 of the specification, "Teflon" is corrected to "fluororesin." (5) On page 4, line 17 of the specification, the phrase ``Shrinkable is best.'' should be replaced with ``Shrinkable.'' In the case of heat-shrinkable tubes, the diameter can be reduced by shrinking after heating. Make sure that the core diameter is the specified value.''that's all

Claims (1)

【特許請求の範囲】[Claims] 1、コアー径に相当する円径のプラスチック細管の管内
に、コアー用樹脂を充填し硬化させることを特徴とする
プラスチック光ファイバーの製造法。
1. A method for producing a plastic optical fiber, which comprises filling a plastic thin tube with a circular diameter corresponding to the core diameter with a core resin and curing the resin.
JP60201318A 1985-09-11 1985-09-11 Production of plastic optical fiber Pending JPS6261008A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60201318A JPS6261008A (en) 1985-09-11 1985-09-11 Production of plastic optical fiber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60201318A JPS6261008A (en) 1985-09-11 1985-09-11 Production of plastic optical fiber

Publications (1)

Publication Number Publication Date
JPS6261008A true JPS6261008A (en) 1987-03-17

Family

ID=16439018

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60201318A Pending JPS6261008A (en) 1985-09-11 1985-09-11 Production of plastic optical fiber

Country Status (1)

Country Link
JP (1) JPS6261008A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600534A1 (en) * 2004-05-27 2005-11-30 Shenzhen Yang Qian Material Application Technology Co., Ltd. Process of manufacturing core-sheath composite fiber

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11126634A (en) * 1997-10-22 1999-05-11 Shinichi Mori Secondary battery performance improving device
JPH11307115A (en) * 1998-04-27 1999-11-05 Bio Techno:Kk Reinforcing agent for lead-acid battery
JP2001216999A (en) * 2000-02-03 2001-08-10 Hideaki Tanaka Activator in electrolytic diaphragm for battery fuel cell
JP2004214126A (en) * 2003-01-08 2004-07-29 Yukio Kojo Manufacturing method for deterioration prevention and recovery promotion sheet of rechargeable battery, and using method of the sheet
JP2008108511A (en) * 2006-10-24 2008-05-08 Kanji Hosokawa Lead-acid battery electrolyte
US20100015527A1 (en) * 2005-07-20 2010-01-21 Fuminori Yamaguchi Electromotive device
US20130015390A1 (en) * 2011-07-11 2013-01-17 Huang Hsueh-Hung Lead-acid accumulator material and a forming method thereof
JP2014056778A (en) * 2012-09-13 2014-03-27 Mitsuharu Maeda Energization method of secondary battery, energization device, secondary battery

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11126634A (en) * 1997-10-22 1999-05-11 Shinichi Mori Secondary battery performance improving device
JPH11307115A (en) * 1998-04-27 1999-11-05 Bio Techno:Kk Reinforcing agent for lead-acid battery
JP2001216999A (en) * 2000-02-03 2001-08-10 Hideaki Tanaka Activator in electrolytic diaphragm for battery fuel cell
JP2004214126A (en) * 2003-01-08 2004-07-29 Yukio Kojo Manufacturing method for deterioration prevention and recovery promotion sheet of rechargeable battery, and using method of the sheet
US20100015527A1 (en) * 2005-07-20 2010-01-21 Fuminori Yamaguchi Electromotive device
JP2008108511A (en) * 2006-10-24 2008-05-08 Kanji Hosokawa Lead-acid battery electrolyte
US20130015390A1 (en) * 2011-07-11 2013-01-17 Huang Hsueh-Hung Lead-acid accumulator material and a forming method thereof
JP2014056778A (en) * 2012-09-13 2014-03-27 Mitsuharu Maeda Energization method of secondary battery, energization device, secondary battery

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1600534A1 (en) * 2004-05-27 2005-11-30 Shenzhen Yang Qian Material Application Technology Co., Ltd. Process of manufacturing core-sheath composite fiber

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