JPS6245519A - Foamable bathing agent - Google Patents

Abstract

PURPOSE:To provide the titled bathing agent storable stably for a long period without using a stabilizer, and dissolving in water while rising and falling is water, by forming an organic acid and a carbonate in separate tablets, putting the tablets in a water- resistant synthetic resin bag having perforations, and sealing the bag in a moisture- resistant synthetic resin bag. CONSTITUTION:A tablet composed mainly of an organic acid such as succinic acid, citric acid anhydride, tartaric acid, etc., and a tablet composed mainly of a carbonate such as sodium bicarbonate, sodium carbonate, sodium sesquicarbonate, etc., are put into a perforated heat-resistant synthetic resin bag (preferably having about 100 holes of 300-400mu diameter per 1cm<2>), and the bag is further packaged and sealed in a moisture-resistant synthetic resin bag. The water-resistant bag is taken out of the moisture-resistant bag in use and thrown into bath. The organic acid is dissolved in hot water entering into the bag through the perforations to increase the acid concentration in the bag to the level sufficient for the reaction with the carbonate. Carbon dioxide gas is generated in the bag by this process. The bag rises according to the generation of carbon dioxide gas until the top end of the bag is exposed from the water surface into air, when the carbon dioxide gas is released to the atmosphere and the bag sinks in water. The bag moves up and down by this mechanism to discharge carbon dioxide gas in bath water.

Description

DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a foaming bath agent that does not require a stabilizer and dissolves in water while moving up and down.

(Prior art) Conventionally, bath additives generally contain salt, salt, and carbonic acid. ! It is a mixture of inorganic salts, etc., flavorings and colorants added to it, and organic acids etc. These foaming bath additives are a combination of carbonates and organic acids, which generate carbon dioxide gas in the bath. This enhances the refreshing feeling and makes bathing more enjoyable.

However, this foaming bath agent is a combination of anhydrous carbonate and anhydrous organic acid, and the presence of a slight amount of moisture causes the two to react and generate carbon dioxide gas.
WJ gas expands the packaging bag in which the bath agent is packaged, spoiling its appearance and lowering its commercial value, and has the disadvantage that a satisfactory foaming effect cannot be obtained.

Therefore, in recent years, in order to stabilize a mixture of anhydrous carbonate and anhydrous organic acid for a long period of time, a foaming bath agent containing magnesium oxide or sthorium aluminate as a stabilizer has been developed under Japanese Patent Application No. 57-180880. (Unexamined Japanese Patent Publication No. 59-706
10).

Conventional foaming bath additives as described above have the disadvantage that carbon dioxide gas causes the packaging bag to expand, spoiling its appearance and reducing its product value.

In addition, in the case where a stabilizer was blended, the bath agent did not have the property of dissolving in hot water while interlocking with the -1-de.

(Problems to be Solved by the Invention) In order to solve the above-mentioned drawbacks, the present invention does not mix an organic acid and a carbonate, which easily react with moisture, but molds the two into separate tablets, and then molds the two into separate tablets with holes. 11I)I Packaging in an aqueous synthetic resin bag, and further sealing the bag with a synthetic resin bag to prevent moisture from entering, and packaging the easily reactive organic acids and carbonates in a stable state. When in use, the outer moisture-proof synthetic resin bag is opened, and the 71 acid and carbonate packaged in the perforated synthetic resin bag are placed in bath water, and the bag is filled with water. The system reacts with the lentic acid and dissolves the 4R organic acid, generates carbonic acid residue, and dissolves the synthetic resin bag with holes in water while interlocking with the 4R acid.

(Failure to solve the problem) The foaming bath agent of the present invention has the following structure.

Molded organic acid tablets and carbonate tablets separately.

The product is placed in a synthetic resin bag having water-resistant holes, and then sealed and packaged with a moisture-proof synthetic resin bag.

(Operation of the invention) Tablets 1 containing the organic acid of the present invention as a main component and tablets 2 containing blown acid salt as one component are packaged in a water-resistant synthetic resin bag 4 having holes 3, and Since the bag 4 is sealed and packaged with a moisture-proof synthetic resin bag 5 on the outside, it can be stored stably for a long period of time without adding a stabilizer.

If tablets 1 containing an organic acid as a main component and tablets 2 containing a carbonate as a main component are put into the bath water 7 at the same time without putting them in a bag, this will save a lot of hot water and is suitable for the reaction. Carbonate does not react quickly because it does not reach acid concentration.

On the other hand, when tablets 1 containing an organic acid as a main component and tablets 2 containing a blown acid salt as a main component are placed in a water-resistant synthetic resin bag 4 having holes 3 and placed in the bath water 7, initially Perforated hole 3 of bag body 4
Hot water enters, dissolves the organic acid, increases the c degree of the acid in the bag body 4 relative to the hot water, reacts effectively with the carbonate, generates carbon dioxide gas 9 in the bag body 4, and the bag body 4 It rises from the bathwater,
The tip of the bag body 4 comes out from the water surface and releases carbon dioxide gas 9.

When the carbon dioxide gas 9 in the bag 4 decreases, the water pressure causes the bag 4 to
dents and sinks into the hot water, and charcoal M gas 9 accumulates in the bag body 4 (
It comes out from the water surface 8 and releases carbon dioxide scum 9.

In this way, the bag body 4 repeats the T motion while in the bath water 7.

(Example) In the first example of the present invention, the organic acid tablet contains succinic acid 4
g was molded into a tablet 1 with a diameter of about 20 mm and a thickness of 8 mm, and another carbonate tablet was prepared with 6 g of sodium bicarbonate and CMC.
0.8 g was mixed and molded into a tablet 2 with a diameter of about 20 mm and a thickness of 8 mm, and a water-resistant synthetic resin bag with a length of 12 cm and a width of 4 cm having about 100 holes 3 of 300-400 g per 1 cm1. The bag 4 is further hermetically sealed with a synthetic resin bag 5 having 1M resistance.

The second example is that the organic acid tablet contains 2.4 g of succinic acid.
1.6 g of salt was mixed and formed into tablets with a diameter of about 20 mm and a thickness of about 8 mm, and another carbonate tablet was prepared by
Mix 2.2g of sodium bicarbonate and 3.8g of salt to make about 1+'! A tablet 2 with a diameter of 20 mm and a thickness of 8 mm is formed into a tablet 2 with approximately 1 hole 3 of 300 to 400 g per 1 cm1.
00 pieces are packaged in a water-resistant synthetic resin bag 4 measuring 12 cm long and 4 cm wide, and the bag 4 is further sealed in a moisture-proof synthetic resin bag 5.

In the third example, 3 g of succinic acid and 1 g of anhydrous citric acid were mixed in an effervescent bath salt tablet and formed into a tablet with a diameter of about 20 mm and a thickness of 8 mm. Mix 3g of sodium carbonate and 3g of Glauber's salt to create a mixture with a diameter of about 20mm and a thickness of 8.
Molded into 2 mm tablets, 1-300 to 400
The pot is packaged in a water-resistant synthetic resin bag 4 with a length of 12 cm and a width of 4 cm having about 100 holes 3, and the bag 4 is further wrapped in a moisture-proof synthetic resin bag 5. be.

To explain how to use the present invention, the outer moisture-proof synthetic resin bag 5 is opened, and a tablet 1 containing an organic acid as a main ingredient and a tablet 2 containing a carbonate as a main ingredient are found. Hole 3
When the resin bag 4 is placed in a bath/vj7, it first sinks into the hot water, and then moisture enters through the holes 3 and converts the organic acid inside the bag 4 into a -L component. The tablet 1 dissolves and reacts with the tablet 2 whose main component is carbonate, generating carbon dioxide scum 9 in the bag body 4, and the bag body 4 rises from the water, with the tip of the bag body 4 above the water surface. and releases carbon dioxide gas 9.

Then, the carbon dioxide gas 9 in the bag body 4 is depressed by the water pressure and sinks into l4, and when the carbon dioxide gas 9 accumulates in the bag body 4, it tumbles out from the water surface 8 and releases carbon dioxide scum 9.

Thus, the contents inside the bag body 4 are 4j9. Acid-based tablet 1
Then, the tablet 2 whose main component is a salt of salt gradually reacts and dissolves while releasing carbon dioxide gas.

1. The organic acids used in the present invention include succinic acid, citric anhydride, tartaric acid, malic acid, etc., and one or more thereof may be selected and used.

Carbonic acid +11 is sodium bicarbonate (sodium bicarbonate A)
, J, sodium sesquicarbonate, potassium carbonate, sodium sesquicarbonate, etc. are selected and used.

In order to suppress the foaming property of carbonate, starch 7s;
MC may be added to foods as a solidifying agent.

41 Bicarbonate-resistant tablets may be molded into hollow tablets LA and 2A in order to have a wide surface area, and the molded shape of the tablets is free.

The water-resistant synthetic resin bag 4 used in the present invention is made of a water-resistant synthetic resin film such as polypropylene or polyethylene, and has about 100 holes 3 of 300 to 400 holes in the laj. However, a figure or the like 6 may be printed on the surface of the synthetic resin film in the hole 3, and the synthetic resin film may be either transparent or opaque.

For example, as the water-resistant synthetic resin bag 4, a perforated film HCOP#30 manufactured by Shinto Shichiguchi Shoji Co., Ltd. was used.

Furthermore, for molding into the above-mentioned tablets, metal manryo was added as a molding aid, and Shaozhou starch powder or CMC was added as a solidifying agent.

In addition, the carbonated ln tablets have a scent and color! Add citrus flavoring and coloring to make it more appealing.

(Effects of the Invention) In the present invention, tablets of organic acid and carbonate are sealed and packaged in a water-resistant synthetic resin bag 4 and a moisture-proof synthetic resin bag 5, so that they can be stored stably for a long period of time.

In the present invention, the organic acid in the bag body 4 is removed while repeating vertical movement.
Since the carbonate foams and dissolves, the carbonate diffuses well in the bath water 7.

In the present invention, by forming the organic acid in the bag 4 into a tablet, the organic acid can be slowly dissolved and the acid in the bag 4 can be maintained at an appropriate concentration.

Since the bag body 4 bubbles carbon dioxide gas 9 while moving up and down in the bath water, children can enjoy the a'<(L dissolved state with interest).

Also, if you print an animal figure, mangalo, etc. on the bag body 4, the animal figure or mangalo will float or sink in the bath water, and the bag body 4 will move downward, which will please the customer. You can take a bath.

[Brief explanation of the drawing]

Fig. 1 is an explanatory front view showing the foaming bath agent of the present invention in a partially opened state, Fig. 2 is a front view of a perforated water-resistant synthetic resin bag showing another embodiment, and Fig. 3 4 is a front view of only the perforated water-resistant synthetic resin bag, and FIG. 4 is an explanatory view showing the state of use. Tablets whose main ingredient is l...
...Charcoal M t1! Tablet 3 whose main ingredient is...
...... Hole 4 ... Water-resistant synthetic resin bag body 5 ...
...Moisture-proof synthetic resin bag Synthetic resin bag 6...
...Graphics etc. 7 ...Bath 8 ...Water surface 9 ...Carbon dioxide patent Applicant: King Chemical Co., Ltd.
Rijin Seki 1) Sadaji;, 1 other person °j Ω + Figure 9 "-Itosashiri Neichi -rImi Kadori (Effective in 1985)
J] 19th, 1985, 1st rule! No. 186213 Number 117'l!!i,,'
4'-1 (3198) jP Riju stone 1T1
Fixed next 1;, □゛゛□11? ? (06)94
Number 1-2295 (1 outsider) 5, Lottery 1! Subject specification, 1: Detailed description of the invention, brief description of drawings, each column 6, contents of Supplement II, Attachment 3 (as per.
7---Mt.Hen 1f-1't ■, Mingbutsu 1. I: 21'↓5th line (replace "in the water" with ",74. 1 hole 3'' is supplemented with 1F- as ``hole 3.'' 3, 4M11 Sword No. 6 J:j The 6th line says r6gj, and it is written as ``5.4 g J and negative 1i +l-. 4, l!II Mll, 1: 7th page, 14th I
From line ``Figure 1'' to line 16, ``Figure 1 is an explanatory diagram.''
Delete the space between (2) and add section 1 in F. Figure 3 is a front view of a synthetic resin bag with holes 1 and 1 for water resistance, and Figure 4 is a front view of only the synthetic resin bag with holes 1 and 2 for water resistance, and Figure 4 is a front view of the synthetic resin bag with holes 1 and 1 for water resistance. This is an explanatory diagram showing ``5... Moisture-proof synthetic resin bag, synthetic resin bag'' in the second line of page 11 of the Yo73 Specification. ...Moisture-proof synthetic resin bag". Patent applicant King Chemical Co., Ltd. Agent Ishi [11th stipulation]
1 person for the next work...

Claims (1)

[Claims] 1. A tablet 1 containing an organic acid as a main component and a tablet 2 containing a carbonate as a main component are packaged in a synthetic resin bag 4 having water-resistant holes 3, and 4 is sealed and packaged in a moisture-proof synthetic resin bag 5. 2. The effervescent bath agent according to claim 1, wherein the tablet 2 containing carbonate as a main component contains a fragrance and a coloring agent. 3. The effervescent bath agent according to claim 1 or 2, wherein the tablet 2 containing carbonate as a main component is mixed with Glauber's salt. 4. An effervescent bath agent according to claims 1 to 3, wherein the tablet 1 whose main component is an organic acid is mixed with Glauber's salt. 5. The effervescent bath agent according to claim 1, wherein the tablet 1 containing an organic acid as a main component is succinic acid. 6. The effervescent bath agent according to claim 1, wherein the tablet 2 whose main component is carbonate is sodium bicarbonate.