JPS6238233B2 - - Google Patents
Info
- Publication number
- JPS6238233B2 JPS6238233B2 JP52128909A JP12890977A JPS6238233B2 JP S6238233 B2 JPS6238233 B2 JP S6238233B2 JP 52128909 A JP52128909 A JP 52128909A JP 12890977 A JP12890977 A JP 12890977A JP S6238233 B2 JPS6238233 B2 JP S6238233B2
- Authority
- JP
- Japan
- Prior art keywords
- packaging
- desiccant
- oxygen
- plastic film
- breathable material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004806 packaging method and process Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000002274 desiccant Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002985 plastic film Substances 0.000 claims description 8
- 229920006255 plastic film Polymers 0.000 claims description 8
- 235000013305 food Nutrition 0.000 claims description 7
- 229940123973 Oxygen scavenger Drugs 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 235000013324 preserved food Nutrition 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 14
- 229910052760 oxygen Inorganic materials 0.000 description 14
- 239000001301 oxygen Substances 0.000 description 14
- 239000006096 absorbing agent Substances 0.000 description 11
- 241001474374 Blennius Species 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 238000005192 partition Methods 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 239000002648 laminated material Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000008476 powdered milk Nutrition 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 235000010265 sodium sulphite Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
Landscapes
- Packages (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Description
本発明は、乾燥海苔、ふりかけ等の乾燥食品の
保存包装方法に関するものである。
従来からいくつかの脱酸素剤があり、食品の保
存に用いられてきた。この脱酸素剤の反応は、反
応を開始させるためにある程度の水が必要であ
る。また脱酸素剤が酸素吸収と同時に水あるいは
水蒸気を発生するものであつた。
このため、乾燥海苔、ふりかけ食品、粉末乳等
の含水率が10%以下の乾燥食品は、これらの反応
による水または水蒸気を吸湿してしまい、商品価
値が低下してしまうため、脱酸素剤を使用できな
いのが現状であつた。
本発明はこのような反応により水または水蒸気
を発生する脱酸素剤を用い、乾燥食品の保存包装
方法を得ることを目的とするものである。
本発明は、含水率が10%以下である乾燥海苔ふ
りかけ食品、粉末乳等の乾燥食品を脱酸素剤と乾
燥剤を仕切つて、通気性材料で包装した包装保持
剤とを同時にプラスチツクフイルムで包装したこ
とを特徴とした乾燥食品の保存包装方法である。
本発明でいう包装保持剤1は第1図、第2図、
第3図に示すように、脱酸素剤2と乾燥剤3を仕
切つて通気性材料で包装したものである。
まず第1図に示すように、脱酸素剤2と乾燥剤
3をポリエチレン、ポリプロピレン等のプラスチ
ツクおよびアルミ箔からなる積層フイルムからな
る仕切壁5により仕切りこの両者を通気性材料
6,6により、外側を包装し、仕切壁5の端部を
通気性材料6,6の端部の間に挾み、熱接着して
なるものである。
また第2図に示すように脱酸素剤2を2枚の仕
切壁8,8により挾み、その外側に乾燥剤3を入
れ、さらにその外側を通気性材料9,9により包
装し、仕切壁8,8の端部を通気性材料9,9の
間に挾み熱接着したものである。
他には第3図に示すように、通気性材料10,
10の間に脱酸素剤2と乾燥剤3を両側に分けて
包装し、その間を熱接着した仕切壁11を設け、
さらに周囲を熱接着したものである。
本発明で使用する乾燥剤は、シリカゲル、活性
酸化アルミニウム、硫酸ナトリウム等である。
脱酸素剤は、結晶水を有する硫酸第一鉄等の鉄
族またはマンガンの第一塩、水酸化カルシウム等
のアルカリ性物質、亜硫酸ナトリウム等の亜硫酸
塩および必要な添加剤からなるものである。
必要な添加剤としては、鉄粉等の金属粉、活性
炭等の吸着剤および塩化マグネシウム、塩化カル
シウム等の潮解性物がある。
また保持剤を包装する通気性材料は、紙と穴の
あいたポリエチレンフイルムとの積層材料が好適
である。
全体を包装するプラスチツクフイルムは、耐気
体透過度の小さいものが適していて、エチレン―
酢酸ビニル共重合体ケン化物フイルムを含む積層
材料が好適である。
次に本発明の実施例について説明する。
<実施例 1>
坪量50〜70g/m2の上質紙の片面にポリエチレ
ンを塗布し、通気度が10000秒/100c.c.程度になる
ようにポリエチレンに孔をあけた通気性材料を一
辺が8cm角の方形状に熱接着する。この時厚さ60
μの低密度ポリエチレンフイルムを挾んで熱接着
する。そして2つに仕切られた一方に脱酸素剤
を、もう一方にも乾燥剤を封入し包装保持剤を作
成した。
ここで脱酸素剤は、硫酸第一鉄(7水塩)2.94
g、水酸化カルシウム0.79g、亜硫酸ナトリウム
0.27gからなるものである。
乾燥剤は、シリカゲル、無水硫酸ナトリウムお
よび硫酸アルミニウムをそれぞれ封入し、3種類
の包装保持剤を作成した。
そして乾燥食品として海苔10gを精秤して、そ
れぞれの包装保持剤とプラスチツクフイルムによ
り約200c.c.の空気と共に封入した。そして経時的
に海苔の重量増加率、袋内の酸素濃度および海苔
の官能評価を行なつた。その結果を表1に示す。
包装するプラスチツクフイルムは、延伸ポリプ
ロピレンフイルム(20μ)/エチレン―酢酸ビニ
ル共重合体ケン化物フイルム(17μ)/低密度ポ
リエチレンフイルム(60μ)からなる積層フイル
ムである。
The present invention relates to a method for preserving and packaging dried foods such as dried seaweed and furikake. There are several oxygen absorbers that have been used to preserve food. This oxygen scavenger reaction requires some water to initiate the reaction. In addition, the oxygen scavenger absorbs oxygen and simultaneously generates water or water vapor. For this reason, dried foods with a moisture content of 10% or less, such as dried seaweed, furikake foods, and powdered milk, absorb water or water vapor from these reactions and reduce their commercial value, so they should not be treated with oxygen absorbers. The current situation was that it could not be used. The object of the present invention is to provide a method for preserving and packaging dry foods using an oxygen absorber that generates water or steam through such a reaction. The present invention separates an oxygen absorber from a desiccant agent for dry foods such as dried seaweed furikake foods and powdered milk with a moisture content of 10% or less, and simultaneously wraps them in a plastic film with a packaging retainer packaged in an air-permeable material. This is a method for preserving and packaging dried foods. The packaging holding agent 1 according to the present invention is shown in FIGS.
As shown in FIG. 3, the oxygen absorber 2 and the desiccant 3 are separated and packaged with a breathable material. First, as shown in FIG. 1, an oxygen absorber 2 and a desiccant 3 are separated by a partition wall 5 made of a laminated film made of plastic such as polyethylene or polypropylene and aluminum foil, and both are separated from each other by air-permeable materials 6, 6 on the outside. The end portion of the partition wall 5 is sandwiched between the end portions of the breathable material 6, 6 and thermally bonded. Further, as shown in FIG. 2, the oxygen absorber 2 is sandwiched between two partition walls 8, 8, the desiccant 3 is placed on the outside of the deoxidizer 2, the outside is further wrapped with breathable material 9, and the partition wall The ends of 8, 8 are sandwiched between breathable materials 9, 9 and thermally bonded. In addition, as shown in FIG.
The oxygen absorber 2 and desiccant 3 are packaged separately on both sides between 10 and a partition wall 11 is provided between them which is thermally bonded.
Furthermore, the surrounding area is thermally bonded. The desiccant used in the present invention is silica gel, activated aluminum oxide, sodium sulfate, etc. The oxygen scavenger consists of a primary salt of iron group or manganese such as ferrous sulfate having water of crystallization, an alkaline substance such as calcium hydroxide, a sulfite such as sodium sulfite, and necessary additives. Necessary additives include metal powders such as iron powders, adsorbents such as activated carbon, and deliquescent substances such as magnesium chloride and calcium chloride. The breathable material for packaging the retention agent is preferably a laminated material of paper and perforated polyethylene film. A plastic film with low gas permeation resistance is suitable for the entire packaging, and an ethylene-
Laminated materials containing saponified vinyl acetate copolymer films are preferred. Next, examples of the present invention will be described. <Example 1> Polyethylene is coated on one side of high-quality paper with a basis weight of 50 to 70 g/m 2 , and a breathable material is made on one side by making holes in the polyethylene so that the air permeability is about 10,000 seconds/100 c.c. Hot glue into an 8cm square shape. At this time the thickness is 60
A low-density polyethylene film of μ is sandwiched and hot-bonded. Then, a package holding agent was created by enclosing an oxygen absorber in one of the two partitions and a desiccant in the other. Here, the oxygen absorber is ferrous sulfate (heptahydrate) 2.94
g, calcium hydroxide 0.79g, sodium sulfite
It consists of 0.27g. The desiccant contained silica gel, anhydrous sodium sulfate, and aluminum sulfate, respectively, and three types of packaging holding agents were created. Then, 10 g of seaweed was accurately weighed as a dry food and sealed with approximately 200 c.c. of air using the respective packaging holding agents and plastic film. Then, the weight increase rate of the seaweed, the oxygen concentration inside the bag, and the sensory evaluation of the seaweed were conducted over time. The results are shown in Table 1. The plastic film used for packaging is a laminated film consisting of stretched polypropylene film (20μ)/saponified ethylene-vinyl acetate copolymer film (17μ)/low-density polyethylene film (60μ).
【表】【table】
【表】
<実施例 2>
実施例1で用いた保持剤と同じ保持剤を2枚の
厚さ60μのポリエチレンフイルム間に封入し、そ
の両側に実施例1と同様に3種類の乾燥剤を実施
例1と同じ通気性材料により封入した。
保持剤および乾燥剤の使用量は、それぞれ4.0
gであつた。これを実施例1と同様海苔10gとと
もに封入し、実施例1と同様に経時的変化を測定
したその結果を表2に示す。
また包装プラスチツクフイルムは、実施例1に
用いたものと同じものである。[Table] <Example 2> The same retention agent used in Example 1 was sealed between two 60μ thick polyethylene films, and three types of desiccants were placed on both sides in the same manner as in Example 1. It was sealed with the same breathable material as in Example 1. The amount of holding agent and desiccant used is 4.0 each.
It was hot at g. This was sealed together with 10 g of seaweed as in Example 1, and the changes over time were measured in the same manner as in Example 1. The results are shown in Table 2. The packaging plastic film was the same as that used in Example 1.
【表】
<実施例 3>
実施例1で用いたものと同じ保持剤を用い、そ
れぞれの乾燥剤により3種類の包装保持剤を得
た。
包装保持剤の形態は第3図に示すとおりであ
る。そして用いる脱酸素剤および乾燥剤の量はそ
れぞれ4.0gおよび10gであつた。
これを海苔10gとともにプラスチツクフイルム
により封入し、実施例1,2と同様経時的変化を
測定した。その結果を表3に示す。
なおプラスチツクフイルムは、実施例1で用い
たものと同じである。[Table] <Example 3> Using the same holding agent as that used in Example 1, three types of packaging holding agents were obtained using each desiccant. The form of the packaging holding agent is as shown in FIG. The amounts of oxygen scavenger and desiccant used were 4.0 g and 10 g, respectively. This was enclosed in a plastic film together with 10 g of seaweed, and changes over time were measured in the same manner as in Examples 1 and 2. The results are shown in Table 3. Note that the plastic film is the same as that used in Example 1.
【表】【table】
【表】
実施例3の包装は、酸素吸収速度がはやく、し
かも重量の増加率も小さく良好であつた。
この保持剤の脱酸素剤と乾燥剤の割合は、乾燥
食品の含水率に応じ変えればよい。[Table] The packaging of Example 3 was good in that it had a fast oxygen absorption rate and a small weight increase rate. The ratio of oxygen scavenger and desiccant in this holding agent may be changed depending on the moisture content of the dried food.
第1図、第2図、第3図は本発明の包装方法に
おいて用いる包装保持剤の断面図である。
1…包装保持剤、2…脱酸素剤、3…乾燥剤、
5,8,11…仕切壁、6,9,10…通気性材
料。
FIG. 1, FIG. 2, and FIG. 3 are cross-sectional views of a packaging holding agent used in the packaging method of the present invention. 1...Package holding agent, 2...Oxygen absorber, 3...Drying agent,
5, 8, 11... Partition wall, 6, 9, 10... Breathable material.
Claims (1)
より水または水蒸気を発生する脱酸素剤と乾燥剤
を仕切り、両者を通気性材料で包装した包装保持
剤とを同時にプラスチツクフイルムで包装したこ
とを特徴とした乾燥食品の保存包装方法。1. Dried food with a moisture content of 10% or less is packaged with a plastic film at the same time as a packaging holding agent that separates the desiccant from the oxygen scavenger that generates water or water vapor through a deoxidizing reaction and wraps both with a breathable material. A storage packaging method for dry foods featuring:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12890977A JPS5462091A (en) | 1977-10-27 | 1977-10-27 | Method of preservative packaging of dried food |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12890977A JPS5462091A (en) | 1977-10-27 | 1977-10-27 | Method of preservative packaging of dried food |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5462091A JPS5462091A (en) | 1979-05-18 |
JPS6238233B2 true JPS6238233B2 (en) | 1987-08-17 |
Family
ID=14996351
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12890977A Granted JPS5462091A (en) | 1977-10-27 | 1977-10-27 | Method of preservative packaging of dried food |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5462091A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0751489Y2 (en) * | 1990-02-15 | 1995-11-22 | 株式会社タイヘイ産商 | Packaging sheet |
CN104431904A (en) * | 2014-12-08 | 2015-03-25 | 魏权 | Fresh daylily pickling method |
-
1977
- 1977-10-27 JP JP12890977A patent/JPS5462091A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5462091A (en) | 1979-05-18 |
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