JPS6229947A - Production of gel containing hardly digestible polysaccharide - Google Patents

Production of gel containing hardly digestible polysaccharide

Info

Publication number
JPS6229947A
JPS6229947A JP60169327A JP16932785A JPS6229947A JP S6229947 A JPS6229947 A JP S6229947A JP 60169327 A JP60169327 A JP 60169327A JP 16932785 A JP16932785 A JP 16932785A JP S6229947 A JPS6229947 A JP S6229947A
Authority
JP
Japan
Prior art keywords
gel
oil
pressure
polysaccharide
indigestible polysaccharide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60169327A
Other languages
Japanese (ja)
Inventor
Shigeru Toba
茂 鳥羽
Haruo Harada
原田 春士
Yutaka Nishimura
豊 西村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ajinomoto Co Inc
Original Assignee
Ajinomoto Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ajinomoto Co Inc filed Critical Ajinomoto Co Inc
Priority to JP60169327A priority Critical patent/JPS6229947A/en
Publication of JPS6229947A publication Critical patent/JPS6229947A/en
Pending legal-status Critical Current

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  • Grain Derivatives (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Preparation Of Fruits And Vegetables (AREA)
  • Coloring Foods And Improving Nutritive Qualities (AREA)

Abstract

PURPOSE:To produce the titled gel having stable gel property, excellent freeze- resistance and high water-content, by applying shearing stress to a substance containing hardly digestible polysaccharide with an extruder under high temperature and pressure and extruding the substance under the condition to attain a water content falling within a specific range. CONSTITUTION:One or more kinds of substances containing hardly digestible polysaccharide and selected from (A) a mixture of 95-65wt% KONJAK mannan and 5-35wt% xanthan gum, a hardly digestible polysaccharide such as carrageenan, pectin, etc., and proteins such as soybean protein, egg protein, etc., (B) cereal flour or starch such as rice flour, soybean flour, etc., (C) an oil or fat such as palm oil, rice oil, soybean oil, cottonseed oil, etc., and (D) a seasoning, flavor, nutrient, etc., such as sodium glutamate, etc., are supplied to an extruder at a rate to give a gel having a water-content of 50-99%, applied with a shearing stress under high temperature and pressure condition at the optimum heating temperature of 50-200 deg.C and a pressure of <=36kg/cm<2> to effect the swelling and dissolution of the components in a short time. The swollen and dissolved components are extruded to obtain the objective gel.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、高水分の難消化性多糖含有グルを極めて短時
間に得る製造法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a production method for obtaining a high moisture indigestible polysaccharide-containing glucose in an extremely short period of time.

〔従来の技術〕[Conventional technology]

従来よりコンニャクマンナン、カラ)−ナン、アルギン
酸ナトリウムの如き離油化性多糖類は。
Conventionally, oil-releasing polysaccharides such as konjac mannan, cara-naan, and sodium alginate have been used.

ダイエタリーツーPとして知られ、胃腸の働きを調整し
、血清コレステロールを低下させ、解毒する等の作用が
報告されている。また、コンニャクマンナン等の多糖類
は解消化性であり、1oO〜200倍にも及ぶ大量の水
を抱水し、グルを形成するので、多量の水と共に服用さ
せ、満腹感を出させ肥満防止を計る低力四り一食品とし
て注目をあびている。
Known as Dietary Two P, it has been reported to have effects such as regulating gastrointestinal function, lowering serum cholesterol, and detoxifying. In addition, polysaccharides such as konnyaku mannan are soluble and hold a large amount of water ranging from 100 to 200 times, forming glutes, so they should be taken with a large amount of water to create a feeling of fullness and prevent obesity. It is attracting attention as a low-strength food that measures the body's health.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

17かし、これらの難消化性多糖類は、一般に高分子量
のため膨潤、溶解に時間がかかり、短時間に均一々ゲル
を得ることはでキ力い一方難消化性多糖類を加熱加圧処
理できる押出機を用いて処理する方法が知られているが
(特公昭5B−51750号公報)、水分含量が低い為
ゲル化物とはいえず、押出処理によシ膨化しかきもち風
のスナック食品が得られていた。
17 However, these indigestible polysaccharides generally take time to swell and dissolve due to their high molecular weight, and it is difficult to obtain a uniform gel in a short period of time. A processing method using an extruder capable of processing is known (Japanese Patent Publication No. 5B-51750), but due to its low water content, it cannot be said to be a gelatinized product, and it puffs up during the extrusion process, resulting in a rice cake-like snack. Food was available.

〔問題点を解決するための手段〕[Means for solving problems]

本発明者らは上記問題点について種々検討した結果、高
水分の難消化性多糖類に加熱加圧状態で剪断応力を加え
ることによυ極めて短時間で多糖類を膨潤、溶解するこ
とができること、高水分の多糖類をサージング等の現象
を起こさずに安定吐出するには二軸押出機を用いること
によりこの問題点を解決できることを見い出し本発明を
完成した。
As a result of various studies on the above-mentioned problems, the present inventors found that by applying shear stress to a high moisture indigestible polysaccharide under heat and pressure, it is possible to swell and dissolve the polysaccharide in an extremely short time. The inventors have discovered that this problem can be solved by using a twin-screw extruder to stably discharge high-moisture polysaccharides without causing phenomena such as surging, and have completed the present invention.

即ち本発明は難消化性多糖含有物質を水分含量50%な
いし99%になるように、押出機に供給し加熱加圧状態
で剪断応力を加えて押出すことを特徴とする難消化性多
糖含有ゲルの製造法である。
That is, the present invention provides an indigestible polysaccharide-containing material, which is characterized by supplying the indigestible polysaccharide-containing substance to an extruder so that the moisture content is 50% to 99%, and extruding it under heating and pressure while applying shear stress. This is a method for producing gel.

本発明で用いることのできる難消化性多糖としては、グ
ル形成能のあるもので、コンニャクマンナンとキサンタ
ンガムとの混合物、ローカストビーンがムとキサンタン
ガムとの混合物、寒天、カラギーナン、アルギン酸塩、
ペクチン、タマリンドがム、カードランの如きものであ
り、又、その他のゲル形成能のない多糖も併用して使用
することができる。
Indigestible polysaccharides that can be used in the present invention include those that have glue-forming ability, such as a mixture of konjac mannan and xanthan gum, a mixture of locust bean gum and xanthan gum, agar, carrageenan, alginate,
Pectin, tamarind, curdlan, and other polysaccharides without gel-forming ability can also be used in combination.

蛋白質としては大豆たん白、小麦たん白、乳たん白、卵
たん白、魚肉たん白、畜肉たん白等が、穀粉類及び澱粉
類としては、米粉、麦粉等の穀粉、大豆粉、とうもろこ
し粉、高梁粉等の麹穀粉、甘蔗澱粉、馬鈴薯澱粉、コー
ンスターチ等が、また油脂類としてはパーム油、米油、
大豆油、コーン油、綿実油などの植物油、ラード、タロ
ーなどの動物脂及びこれらの分別油、水添脂などの加工
油脂が使用できる。
Proteins include soybean protein, wheat protein, milk protein, egg protein, fish protein, livestock protein, etc., and flours and starches include rice flour, wheat flour, soybean flour, corn flour, etc. Koji grain flour such as Takahashi flour, cane starch, potato starch, corn starch, etc., and oils and fats such as palm oil, rice oil,
Vegetable oils such as soybean oil, corn oil, and cottonseed oil, animal fats such as lard and tallow, and processed oils and fats such as their fractionated oils and hydrogenated fats can be used.

更に、呈味料として具体的には、調味料(グルタミン酸
、グルタミン酸ナトリウムその他のアミノ酸、アミノ酸
塩、5′−り叶?ヌクレオチド類、食塩、塩化カリウム
等)、酸味料(各種有機酸、ビネガー類)、甘味料(蔗
糖その他の糖、ソルビトール、マルチトールその他の糖
7A、コ−A/、 7ス/ぐルテーム、アセサルファム
、サイクラメート、サッカリン、サッカリンナトリウム
、ステビオサイド、グリコジルステビオサイドその他)
、その他の呈味料、各種エキス類(動植物エキス、Ir
AP 。
Furthermore, specific examples of flavoring agents include seasonings (glutamic acid, monosodium glutamate and other amino acids, amino acid salts, 5'-riwan nucleotides, salt, potassium chloride, etc.), acidulants (various organic acids, vinegars, etc.). ), sweeteners (sucrose and other sugars, sorbitol, maltitol and other sugars, 7A, Co-A/, 7S/glutame, acesulfame, cyclamate, saccharin, sodium saccharin, stevioside, glycodylstevioside, etc.)
, other flavoring agents, various extracts (animal and plant extracts, Ir.
A.P.

HVP、酵母エキス等)をあげることができる。風味料
としては、フレーバー、香辛料、等の風味料などをあげ
ることができる。その他、乳化剤、保存料、着香料、ビ
タミン類、その他の栄養強化成分、各種の医薬成分、着
色料等の粉末素材の中から選ばれた1種以上を併用する
ことができる。
HVP, yeast extract, etc.). Examples of flavoring agents include flavors, spices, and the like. In addition, one or more types selected from powder materials such as emulsifiers, preservatives, flavoring agents, vitamins, other nutritious ingredients, various pharmaceutical ingredients, and coloring agents can be used in combination.

本発明においては、特にコンニャクマンナンとキサンタ
ンガムの混合物の重量比率が95:5〜65:35であ
る時、加熱加圧後冷却するだけで容易にグル化し強い弾
力のあるゲル化物が得られる。
In the present invention, especially when the weight ratio of the mixture of konjac mannan and xanthan gum is 95:5 to 65:35, a gelled product with strong elasticity can be easily obtained by simply cooling after heating and pressurizing.

これら難消化性多糖含有物質を水分50係ないし99チ
になるように押出機に供給し、加熱加圧状態で剪断応力
を加え短時間で膨潤、醒解させ所望のゲル形成能を持っ
た物質を押出す。この時、あらかじめ上記の水分含量に
なるようにした混合物を供給してもよいし、難消化性多
糖含有物質の粉体を供給し押出機内に注水することによ
シ上記の水分含量になるようにして加熱加圧状態にして
押出すこともできる。この時の最適加熱温度は原料の種
類及び水、添加物の混合割合によυ異方るが、一般的に
は50℃ないし200℃、よシ好ましくは通常80℃な
いし150℃である。この時の圧力は、加熱された混合
物を移動せしめるに必要な圧力以上であればよく、特に
高圧である必要はない。その上限は加熱温度及びノズル
形状と相関関係を有するが、通常は36kvcIn2以
下の圧力、より好ましくは1kg/crn2ないし25
 k177m2の圧力に【処理したものが好適である。
These indigestible polysaccharide-containing substances are supplied to an extruder with a water content of 50 to 99 degrees, and shear stress is applied under heating and pressure to swell and dissolve in a short period of time, resulting in a substance with the desired gel-forming ability. extrude. At this time, it is possible to supply a mixture that has been adjusted to have the above moisture content in advance, or by supplying powder of an indigestible polysaccharide-containing substance and injecting water into the extruder, the moisture content can be adjusted to the above moisture content. It can also be extruded by heating and pressurizing it. The optimum heating temperature at this time varies depending on the type of raw materials and the mixing ratio of water and additives, but is generally 50°C to 200°C, preferably 80°C to 150°C. The pressure at this time does not need to be particularly high as long as it is at least the pressure necessary to move the heated mixture. The upper limit has a correlation with the heating temperature and nozzle shape, but it is usually a pressure of 36 kvcIn2 or less, more preferably 1 kg/crn2 to 25 kvcIn2.
Preferably, the material has been treated to a pressure of 177 m2.

押出機としては一軸よシも二軸押出機の方が好ましく原
料投入口、二本のスクリー−、バレル、加熱または冷却
ジャケット、駆動装置およびこれらの付随する装置を備
えたものであれば、一般的な二軸押出機で充分である。
Either a single-screw extruder or a twin-screw extruder is preferred, and as long as it is equipped with a raw material inlet, two screens, a barrel, a heating or cooling jacket, a drive device, and these accompanying devices, it is generally suitable. A standard twin screw extruder is sufficient.

バレルは一体型のものであっても、複数のバレルを一体
的に取付けたものでありてもよい。バレルの外周には原
料を冷却または加熱するための複数のジャケットを備え
ることもできる。押出機にはダイおよび/またはノズル
を必要によシ具備することもできる。押出す時の圧力及
び温度は適宜調整することができる。
The barrel may be of a one-piece type or may be a plurality of barrels attached together. The outer periphery of the barrel can also be provided with a plurality of jackets for cooling or heating the raw material. The extruder may also be equipped with a die and/or nozzle as required. The pressure and temperature during extrusion can be adjusted as appropriate.

〔発明の効果〕〔Effect of the invention〕

本発明による難消化性多糖含有グルの製造法は、従来か
ら膨潤、加熱等のプロセスに時間がかかっていたものを
極めて短時間に処理し、所望のグル形成能を引出す方法
であり、その中でもコンニャクマンナンとキサンタンガ
ムによるグルは、熱可逆性を有し、アルカリ臭がなく、
酸性〜中性域で安定なゲル物性を呈し、又、保存時の離
水が少なく凍結耐性が優れているという効果を呈する。
The method for producing indigestible polysaccharide-containing glue according to the present invention is a method that brings out the desired glue-forming ability by processing in an extremely short time the processes that conventionally took time such as swelling and heating. Glue made from konjac mannan and xanthan gum is thermoreversible and has no alkaline odor.
It exhibits stable gel properties in the acidic to neutral range, and also exhibits the effects of less syneresis during storage and excellent freezing resistance.

従って低カロリー、整腸作用等の健康食品イメージ金具
備した新しい難消化性多糖含有グルの提供が可能であシ
、その有用性は明らかである。
Therefore, it is possible to provide a new indigestible polysaccharide-containing glue that has the image of a health food, such as low calorie and intestinal regulation effect, and its usefulness is obvious.

実施例1゜ 実験用二軸エクストルーダー(Werner & Pf
lelder社製C−58型、ノズル3φ唾)を用いて
、コンニャクマンナンとキサンタンガムの3:1の混合
粉体並びに水をそれぞれ1 k17/hr及び49 k
g/ hrのフィード量で処理した。
Example 1゜Experimental twin-screw extruder (Werner & Pf.
A 3:1 mixed powder of konjac mannan and xanthan gum and water were added at 1k17/hr and 49k using a Lelder C-58 model with a 3φ nozzle.
It was treated with a feed rate of g/hr.

なおエクストルーダーの操作条件は次の通υであった。The operating conditions for the extruder were as follows.

温 度     投入口付近  水 冷中央部 120
℃ 吐出口付近  100℃ スクリュー回転数            200 r
pn吐出物は均一に加熱混練された流動物で冷却するこ
とにより容易にグル化した。グルは非常に弾力があり、
レオメータ−で測定した所2809/cm2のグル強度
を有していた。
Temperature Near the inlet Water Cold center 120
℃ Near the discharge port 100℃ Screw rotation speed 200 r
The pn discharged material was easily glued by cooling with a uniformly heated and kneaded fluid. Guru is very elastic;
It had a glue strength of 2809/cm2 when measured with a rheometer.

実施例2゜ 実施例1と同様の二軸エクストルーダーを用いて、コン
ニャクマンナン、キサンタンガム、カゼイネート及び馬
澱の3:1:2:4の混合粉体並びに水をそれぞれ4 
kvhr及び46kg/hrのフィード量で処理した。
Example 2 Using the same twin-screw extruder as in Example 1, a 3:1:2:4 mixed powder of konjac mannan, xanthan gum, caseinate, and horse lees and 4 ml of water were each added.
kvhr and a feed rate of 46 kg/hr.

操作条件は次の通シであった。The operating conditions were as follows.

温 度     投入口付近  水 冷中央部 150
℃ 吐出口付近  120℃ スクリュー回転数            30Orp
mなお、ダイは断面が5wmX20mのスリットダイを
使用し、先端を水冷した。
Temperature Near the inlet Water Cold center 150
℃ Near the discharge port 120℃ Screw rotation speed 30Orp
Note that a slit die with a cross section of 5wm x 20m was used, and the tip was water-cooled.

吐出物は均一に成型されたチーズ様のゲル化物で強い弾
力を有していた。
The discharged product was a uniformly shaped cheese-like gelled product with strong elasticity.

参考例1゜ 実施例1において使用したものと同じ難消化性多糖含有
物質を、実験用−軸エクストルーダー(い=20.D=
30φ■;ノズル2φ■)を用いて30に9/hr の
フィード量で処理した。なお操作条件は次の通ヤであっ
た。
Reference Example 1゜The same indigestible polysaccharide-containing substance used in Example 1 was added to an experimental shaft extruder (I=20.D=
The treatment was carried out using a 30 mm nozzle (2 mm diameter) and a feed rate of 9/hr. The operating conditions were as follows.

温 度     投入口付近  水 冷中央部 120
℃ 吐出口付近  100℃ スクリュー回転数             15Or
pm吐出は、不安定で断続的にサージングを繰返した。
Temperature Near the inlet Water Cold center 120
℃ Near the discharge port 100℃ Screw rotation speed 15Or
PM discharge was unstable and repeated intermittent surging.

又、吐出物もやや不均一で冷却後のグルは非常に弱くゲ
ル強度は35 g/cm2であった。
Further, the discharged material was also somewhat non-uniform, and the gel after cooling was very weak, with a gel strength of 35 g/cm2.

Claims (4)

【特許請求の範囲】[Claims] (1)難消化性多糖含有物質を水分含量50%ないし9
9%になるように、押出機に供給し加熱加圧状態で剪断
応力を加えて押出すことを特徴とする難消化性多糖含有
ゲルの製造法。
(1) Indigestible polysaccharide-containing substances with a water content of 50% to 9%
A method for producing an indigestible polysaccharide-containing gel, which comprises supplying the gel to an extruder and extruding it by applying shear stress under heat and pressure so that the gel has a concentration of 9%.
(2)難消化性多糖含有物質が、難消化性多糖と、蛋白
質の第1成分、穀粉類及び澱粉類から選ばれた1種以上
の第2成分、油脂類の第3成分、呈味料、風味料、栄養
強化成分、着香料、着色料及び乳化剤から選ばれた1種
以上の第4成分の中から選ばれた1種以上の成分とから
成ることを特徴とする特許請求範囲第1項記載の製造法
(2) The indigestible polysaccharide-containing substance includes an indigestible polysaccharide, a first component of protein, one or more second components selected from flours and starches, a third component of fats and oils, and a flavoring agent. , and one or more components selected from one or more fourth components selected from flavorants, nutritional enrichment ingredients, flavorants, colorants, and emulsifiers. Manufacturing method described in section.
(3)難消化性多糖が、コンニャクマンナンとキサンタ
ンガムとの混合物、ローカストビーンガムとキサンタン
ガムとの混合物、寒天、カラギーナン、アルギン酸塩、
ペクチン、タマリンドガム及びカードランの1種あるい
は2種以上であることを特徴とする特許請求範囲第1項
記載の製造法。
(3) The indigestible polysaccharide is a mixture of konjac mannan and xanthan gum, a mixture of locust bean gum and xanthan gum, agar, carrageenan, alginate,
The manufacturing method according to claim 1, characterized in that one or more of pectin, tamarind gum, and curdlan are used.
(4)難消化性多糖が、コンニャクマンナンとキサンタ
ンガムとの混合物で、その重量比率が95:5〜65:
35であることを特徴とする特許請求範囲第1項記載の
製造法。
(4) The indigestible polysaccharide is a mixture of konjac mannan and xanthan gum, with a weight ratio of 95:5 to 65:
35. The manufacturing method according to claim 1, characterized in that:
JP60169327A 1985-07-31 1985-07-31 Production of gel containing hardly digestible polysaccharide Pending JPS6229947A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60169327A JPS6229947A (en) 1985-07-31 1985-07-31 Production of gel containing hardly digestible polysaccharide

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60169327A JPS6229947A (en) 1985-07-31 1985-07-31 Production of gel containing hardly digestible polysaccharide

Publications (1)

Publication Number Publication Date
JPS6229947A true JPS6229947A (en) 1987-02-07

Family

ID=15884490

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60169327A Pending JPS6229947A (en) 1985-07-31 1985-07-31 Production of gel containing hardly digestible polysaccharide

Country Status (1)

Country Link
JP (1) JPS6229947A (en)

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JPH0191759A (en) * 1987-10-01 1989-04-11 Terumo Corp Gelatinous food
JPH02142449A (en) * 1988-10-11 1990-05-31 Holgates Nutritional Foods Ltd Edible composition
WO1997033593A1 (en) * 1996-03-15 1997-09-18 Takara Shuzo Co., Ltd. A product of heat treatment of uronic acid, food, drink or drug including the product
EP1198991A1 (en) * 2000-10-20 2002-04-24 Nutriz N.V: Non-dairy products derived from rice
US6479649B1 (en) 2000-12-13 2002-11-12 Fmc Corporation Production of carrageenan and carrageenan products
WO2008130252A1 (en) * 2007-04-24 2008-10-30 Fonterra Co-Operative Group Limited Dairy product and process
US8062686B2 (en) 2005-04-12 2011-11-22 InovoBiologics, Inc. Dietary supplement, and methods of use
EP2355803A4 (en) * 2008-11-14 2012-04-25 Archer Daniels Midland Co Organogel compositions and processes for producing
JP2013013359A (en) * 2011-07-04 2013-01-24 En Otsuka Pharmaceutical Co Ltd Frozen egg processed food
US8597709B2 (en) 2005-04-12 2013-12-03 Inovobiologic Inc. Dietary supplement and methods of use
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JPH02142449A (en) * 1988-10-11 1990-05-31 Holgates Nutritional Foods Ltd Edible composition
WO1997033593A1 (en) * 1996-03-15 1997-09-18 Takara Shuzo Co., Ltd. A product of heat treatment of uronic acid, food, drink or drug including the product
US6482806B1 (en) 1996-03-15 2002-11-19 Takara Shuzo Co., Ltd. Product of heat treatment of uronic acid, food, drink, or drug including the product
US7435442B2 (en) 2000-10-20 2008-10-14 Nutriz N.V. Non-dairy products derived from rice and method of making
EP1198991A1 (en) * 2000-10-20 2002-04-24 Nutriz N.V: Non-dairy products derived from rice
US6479649B1 (en) 2000-12-13 2002-11-12 Fmc Corporation Production of carrageenan and carrageenan products
US7018635B2 (en) 2000-12-13 2006-03-28 Fmc Corporation Semi-refined carrageenan
US7189843B2 (en) 2000-12-13 2007-03-13 Fmc Corporation Production of carrageenan and carrageenan products
JP2005506389A (en) * 2000-12-13 2005-03-03 エフ エム シー コーポレーション Production of carrageenan and carrageenan products
US7772211B2 (en) 2000-12-13 2010-08-10 Fmc Corporation Production of carrageenan and carrageenan products
JP4776867B2 (en) * 2000-12-13 2011-09-21 エフ エム シー コーポレーション Production of carrageenan and carrageenan products
US8062686B2 (en) 2005-04-12 2011-11-22 InovoBiologics, Inc. Dietary supplement, and methods of use
US8597709B2 (en) 2005-04-12 2013-12-03 Inovobiologic Inc. Dietary supplement and methods of use
US10010102B2 (en) 2005-04-12 2018-07-03 Inovobiologic Inc. Dietary supplement and methods of use
WO2008130252A1 (en) * 2007-04-24 2008-10-30 Fonterra Co-Operative Group Limited Dairy product and process
EP2355803A4 (en) * 2008-11-14 2012-04-25 Archer Daniels Midland Co Organogel compositions and processes for producing
JP2013013359A (en) * 2011-07-04 2013-01-24 En Otsuka Pharmaceutical Co Ltd Frozen egg processed food
CN111317124A (en) * 2020-04-22 2020-06-23 苏州罗得威尔生物科技有限公司 Method for preparing slowly digestible starch by compounding food colloid and starch and combining physical treatment

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