JPS62295983A - Filler material for spiral gasket - Google Patents

Filler material for spiral gasket

Info

Publication number
JPS62295983A
JPS62295983A JP13988686A JP13988686A JPS62295983A JP S62295983 A JPS62295983 A JP S62295983A JP 13988686 A JP13988686 A JP 13988686A JP 13988686 A JP13988686 A JP 13988686A JP S62295983 A JPS62295983 A JP S62295983A
Authority
JP
Japan
Prior art keywords
filler material
filler
vibration
glass
fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13988686A
Other languages
Japanese (ja)
Other versions
JPH0315952B2 (en
Inventor
Satoru Hashimoto
哲 橋本
Masahiko Takaoka
高岡 昌彦
Hidenobu Tei
鄭 秀信
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Pillar Packing Co Ltd
Original Assignee
Nippon Pillar Packing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Pillar Packing Co Ltd filed Critical Nippon Pillar Packing Co Ltd
Priority to JP13988686A priority Critical patent/JPS62295983A/en
Publication of JPS62295983A publication Critical patent/JPS62295983A/en
Publication of JPH0315952B2 publication Critical patent/JPH0315952B2/ja
Granted legal-status Critical Current

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  • Gasket Seals (AREA)
  • Sealing Material Composition (AREA)
  • Paper (AREA)

Abstract

PURPOSE:To obtain the title filler material having excellent resistance to heat and vibration, by blending a fiber base material composed of a combination of at least two types of glass fibers having different fiber diameters with a clay mineral and a binder and then molding the blend. CONSTITUTION:A fiber base material composed of a combination of at least two types of glass fibers having fiber diameters of 2mum or less and 2mum or more is blended with a filler such as a clay mineral (e.g., talc) and a binder (e.g., acrylonitrile.butadiene rubber). The blend is formed into sheet and cut into a tape form. This provides a filler material for spiral gasket which exhibits little performance degradation against heating at a medium to high temp. range (400-700 deg.C) and vibration and which can be suitably employed in pipe joints through which high-temp. sealed fluid is fed.

Description

【発明の詳細な説明】 3、発明の詳細な説明 (イ)発明の分野 この発明は、例えば、水、LNG、、N2ガス、特に自
動車の排気管の如く排気ガス等の高温密封流体を送給す
る配管継手部に配設して用いるようなうず巻層ガスケッ
トのフィラー材に関する。
Detailed Description of the Invention 3. Detailed Description of the Invention (a) Field of the Invention The present invention is applicable to high-temperature sealed fluids such as water, LNG, N2 gas, and especially exhaust gas such as in the exhaust pipes of automobiles. The present invention relates to a filler material for a spiral layer gasket that is used by being disposed at a pipe joint for supplying water.

(ロ)発明の背景 従来、上述例のうず巻層ガスケットとしては、例えば、
特公昭47−42426号公報に記載のガスケットがあ
る。
(b) Background of the Invention Conventionally, the spirally wound layer gasket of the above-mentioned example has, for example,
There is a gasket described in Japanese Patent Publication No. 47-42426.

すなわち、断面形状をv字状もしくは波形等の屈曲形状
とした金属帯板(フープ材)と、帯状のフィラー材とを
複数回うず巻状に巻回して構成したうず巻層ガスケット
である。
That is, it is a spiral layer gasket constructed by winding a metal strip (hoop material) with a bent shape such as a V-shape or wave shape in cross section and a strip-shaped filler material multiple times in a spiral shape.

しかし、上述のうず巻層ガスケットのフィラー材には、
アスベスト繊維が用いられているので、良好なシール特
性を有する反面、次のような斯生上の問題点があった。
However, the filler material of the spiral layer gasket mentioned above has
Since asbestos fibers are used, although they have good sealing properties, they have the following production problems.

つまり、アスベスト(石綿)はその性質上取扱い時に多
足の粉塵を発生しやすく、この粉塵を長期に亘って吸入
し続けると肺臓にアスベスト粉塵が沈着したり、またア
スベストの長期使用により皮膚にアスベスト粉塵が付着
して、アスベスト病、中皮腫、肺ガンその他となり、衛
生上極めて好ましくない問題点があった。
In other words, due to its nature, asbestos tends to generate a lot of dust when handled, and if this dust is continued to be inhaled over a long period of time, asbestos dust may be deposited in the lungs, and long-term use of asbestos may cause asbestos dust to be deposited on the skin. Dust adhesion caused asbestos disease, mesothelioma, lung cancer, and other problems, which were extremely unfavorable from a sanitary standpoint.

このような問題点を所間するために、例えば特願昭60
−62286号に示ず如き、アスベスト誠雑以外の無機
繊維を用いたアスベストフリー(脱石線)のフィラー材
がある。
In order to solve these problems, for example, the patent application filed in 1983
As shown in No. 62286, there is an asbestos-free filler material using inorganic fibers other than asbestos fibers.

上述のフィラー材は、アスベスト繊維以外の無機楳雑を
基材として、セビオライトを配合さ「たうず巻層ガスケ
ットのフィラー材であり、アスベスト類のフィラー材の
代替品として十分好適に使用できると共に、アスベスト
製フィラー材よりも優れた特性を有する利点がある。
The above-mentioned filler material is a filler material for spiral wound layer gaskets, which is made of inorganic materials other than asbestos fibers as a base material and contains Seviolite, and can be used suitably as a substitute for asbestos filler materials. It has the advantage of having better properties than asbestos filler materials.

しかし、上述のフィラー材においては、特に中高温度域
たとえば400〜700℃での使用時および取付箇所が
振動する場合において特性の劣化が生ずる問題点があっ
た。
However, the above-mentioned filler materials have a problem in that their properties deteriorate, especially when used in a medium to high temperature range, for example, 400 to 700° C., and when the attachment location vibrates.

(ハ)発明の目的 この発明は、特に中高温度域(400〜700℃)の加
熱および振動に対しても特性の劣化が極めて僅少で、耐
熱性、耐振性に優れたうず巻層ガスケットのフィラー材
の提供を目的とする。
(c) Purpose of the Invention The present invention provides a filler for spiral-wound layer gaskets that exhibits very little deterioration in characteristics even when subjected to heating and vibration, particularly in the medium-to-high temperature range (400 to 700°C), and has excellent heat resistance and vibration resistance. The purpose is to provide materials.

(ニ)発明の要約 この発明は、2μm以下の繊維径を有するガラスII維
と、2μmを超過する繊維径のガラス繊維とを、2種以
上組合けた繊N基材を、粘土鉱物などの充填材および結
合剤と配合して抄造したうず巻層ガスケツl−のフィラ
ー材であることを特徴とする。
(d) Summary of the Invention This invention provides a fiber N base material that is a combination of two or more types of glass II fibers having a fiber diameter of 2 μm or less and glass fibers having a fiber diameter exceeding 2 μm, filled with clay minerals, etc. The present invention is characterized in that it is a filler material for a spirally wound layered gasket l-, which is made by blending it with a material and a binder.

(ホ)発明の効果 この発明によれば、フィラー材のuutt基uとして、
2μm以下の繊維径を071るガラスvaNと、2μm
を超過する繊維径のガラス繊維とを組合せているので、
上述の2μmを超過する繊維径のガラス繊維が、加熱時
の強度の低下を防止し、また2μm以下の繊維径のガラ
ス繊維が振動による充la日詰材としての粘土鉱物の脱
落を防止するので、特に400〜700℃の中高温度域
の加熱および振動に対しても特性の劣化が極めて僅少で
、耐熱性、耐振性に優れる効果がある。
(e) Effect of the invention According to this invention, as the uutt base u of the filler material,
Glass vaN with a fiber diameter of 2 μm or less and 2 μm
Because it is combined with glass fiber with a fiber diameter exceeding
The above-mentioned glass fibers with a fiber diameter exceeding 2 μm prevent the strength from decreasing during heating, and the glass fibers with a fiber diameter of 2 μm or less prevent clay minerals used as a filling material from falling off due to vibration. In particular, there is very little deterioration of the characteristics even when subjected to heating and vibration in the medium-to-high temperature range of 400 to 700°C, and there is an effect of excellent heat resistance and vibration resistance.

(へ)発明の実施例 この実施例のフィラー材は、2μm以ドの繊維径を有す
るガラス繊維とし、1!雑径0.6μmのマイクロガラ
スを7重量パーセント、2μmを超過する繊維径のガラ
スw4紺として、繊維径6μmのガラス繊維を10重量
パーセント、粘土鉱物としてタルク(天然の含水ケイ酸
マグネシウムで、紙の充填材、隣片状物)を45虫8パ
ーセント、同じく粘土鉱物としてのセビオライト(ケイ
酸おにび酸化マグネシウムを主成分とする天然の粘土鉱
物)を25重量パーセント、セルローズバルブをア徂吊
パーセント、結合剤としてアクリロ・ニリトル・ブタジ
ェン・ラバーいわゆるNBRを5重量バーセン1〜、凝
集剤を1重量パーセントの割合で配合して抄造(she
et formir+g ) L/、厚さ0゜4I!u
R1かさ密度(bulk density、充NL[の
こと>約0.7g/cm3の無n ta ヲ(!? タ
ウ、t、コ0) fR機紙を幅15#Iのテープ状に裁
断したものである。
(F) Embodiment of the Invention The filler material in this embodiment is glass fiber having a fiber diameter of 2 μm or more. 7% by weight of micro glass with a diameter of 0.6 μm, 10% by weight of glass fiber with a fiber diameter of 6 μm as glass w4 navy blue with a fiber diameter exceeding 2 μm, talc as a clay mineral (natural hydrous magnesium silicate, paper 45% by weight of 45% of filler, 25% of clay mineral, Seviolite (a natural clay mineral whose main components are silicate and magnesium oxide), and cellulose bulb were suspended. 5% by weight of acrylo-nitributadiene-butadiene rubber (NBR) as a binder and 1% by weight of a coagulant.
et formir+g) L/, thickness 0°4I! u
R1 bulk density (about 0.7g/cm3) is made from fR machine paper cut into a tape with a width of 15 #I. be.

なJ3、上述のマイクロガラスとしては、日本板硝子株
式会社製のrMLF3AJの繊維径0.6μ7nのバル
ク状のEガラスを使用し、6μmガラスとしては、ユニ
チノJニーエムグラス株式会社製の繊維長ざ3HnのE
ガラスを使用し、タルクとしては、日本タルク株式会社
製の「ND」のタルク粉体を使用し、 セビオライトとしては、武III品工業株式会礼製の[
ニードプラスSPJの粉体をそれぞれ使用し IC。
J3, bulk E glass with a fiber diameter of 0.6μ7n manufactured by Nippon Sheet Glass Co., Ltd., rMLF3AJ, manufactured by Nippon Sheet Glass Co., Ltd., is used as the above-mentioned microglass, and as the 6μm glass, RMLF3AJ manufactured by Nippon Sheet Glass Co., Ltd., with a fiber length of 3Hn, is used as the 6μm glass. E
Glass was used, the talc used was ``ND'' talc powder manufactured by Nippon Talc Co., Ltd., and the Seviolite was ``ND'' talc powder manufactured by Take III Products Co., Ltd.
IC using Needplus SPJ powder.

また、実施例のフィラー材と従来品のそれとの特性を比
較対比するため下表1に示すようにマイクロガラスを配
合しない比較量Aと、6μ面ガラス繊維を配合しない比
較量Bとをそれぞれ形成した。
In addition, in order to compare and contrast the characteristics of the filler material of the example and that of the conventional product, we prepared a comparison amount A that does not contain microglass and a comparison amount B that does not contain 6μ glass fiber, as shown in Table 1 below. did.

く表1〉 上述の実施例のフィラー材および比較量A、Bに対して
、機械的強度、特に引張強度試験を行ない下表2に示す
結果が得られた。
Table 1> Mechanical strength, particularly tensile strength, tests were conducted on the filler materials of the above-mentioned examples and comparative amounts A and B, and the results shown in Table 2 below were obtained.

なお、この引張強度試験は、各フィラー材を引張速度2
00I!a/l1linで引張ることにより行なったも
のである。また、温度条件を変えるため、常温の各フィ
ラー材および400℃、600℃にそれぞれ加熱した後
に、これら各温度に維持した状態で10時間を経過した
直後の各フィラー材をそれぞれ用いて引張強度試験を行
なった。
In addition, this tensile strength test was conducted at a tensile rate of 2 for each filler material.
00I! This was done by pulling at a/l1lin. In addition, in order to change the temperature conditions, we conducted a tensile strength test using each filler material at room temperature and after heating to 400°C and 600°C, and immediately after 10 hours had passed while maintaining these temperatures. I did it.

く表2〉 この試験結果から、実施例のフィラー材は、温度条件に
かかわらず、2μ7n以下の繊維径を右づ゛るガラス繊
維を含まない比較量A、2μ瓦を超過する繊維径のガラ
ス繊維を含まない比較量Bのいずれと比べても、引張強
度延いては機械的強度に優れていることが理解でき、ま
た比較量△、Bでは加速温度が高温になるのに従って引
張強度が急激に低下するのに対して、実流例のフィラー
材ではこのような変化がないことから、この実施例のフ
ィラー材は耐熱性に優れていることが確認された。これ
は2μmを越えるガラスJMItとしての6μmガラス
繊維が加熱時の強度低下を防止することによるものと考
えられる。
Table 2 From this test result, regardless of the temperature conditions, the filler material of the example has a comparative amount A that does not contain glass fibers with a fiber diameter of 2μ7n or less, and a glass fiber with a fiber diameter exceeding 2μ7n. It can be seen that the tensile strength and mechanical strength are superior when compared to either of the comparison amounts B, which does not contain fibers, and the tensile strength of the comparison amounts △ and B increases rapidly as the acceleration temperature increases. In contrast, there was no such change in the filler material of the actual flow example, confirming that the filler material of this example has excellent heat resistance. This is thought to be due to the fact that the 6 μm glass fiber as the glass JMIt exceeding 2 μm prevents the strength from decreasing during heating.

また、上述の実施例のフィラー材を用いて所定内径およ
び所定外径のうず巻ガスケットを製作すると共に、これ
と同一のフープ材および上述の比較量A、8のフィラー
材を用いて同一寸法のうず巻ガスケットを製作して振動
後の流体漏洩量を比較試験したところ表3に示す結果が
得られた。
In addition, a spiral wound gasket with a predetermined inner diameter and a predetermined outer diameter was manufactured using the filler material of the above-mentioned example, and a spiral gasket with the same dimensions was manufactured using the same hoop material and the filler material of the comparative amount A and 8 described above. When a spiral gasket was manufactured and a comparative test was conducted on the amount of fluid leakage after vibration, the results shown in Table 3 were obtained.

なお、この性能試験は、50トン万能試験機により締付
圧力200 Kgf / ciに加圧し、1箭封流体と
して0.5に3/ciのN2ガスを使用し、かつ漏洩m
測定器としてメスシリンダを用いて行なったものである
。また温度条件を変えるために、初期締付時の常温の各
うず巻ガスケットおよび600℃に温度加熱した状態を
3時間経過した直後の各うず巻ガスケットを用いて漏洩
量を測定した。さらに振動周波数66.7112.振動
加速度110゜7m/s2で合計4時間加娠した直後の
それぞれのうず巻ガスケットを用いて漏洩はを測定した
This performance test was conducted using a 50-ton universal testing machine with a clamping pressure of 200 Kgf/ci, using N2 gas at a rate of 0.5 to 3/ci as a sealing fluid, and measuring leakage m.
A measuring cylinder was used as the measuring device. In addition, in order to change the temperature conditions, the amount of leakage was measured using each spiral gasket at room temperature at the time of initial tightening and each spiral gasket immediately after heating to 600° C. for 3 hours. Furthermore, the vibration frequency is 66.7112. Leakage was measured using each spiral-wound gasket immediately after being subjected to vibration acceleration of 110°7 m/s2 for a total of 4 hours.

く表3〉 この試験結果から、比較量Aのフィラー材を用いたうず
巻ガスケツ]へでは振動に対して漏洩量が急増し、また
比較量Bのフィラー材を用いたうず巻ガスケットでは加
熱および振動に対して漏洩ωがいずれも急増16が、実
施例のフィラー材を用ちいたうず巻ガスケットは、中高
温加熱および撮動のいずれに対しても漏洩aの茗るしい
増加がなく、加熱、振動に対して優れた効果があること
が確ルΣされた。
Table 3 From this test result, the amount of leakage in the spiral gasket using comparative amount A of filler material increased rapidly due to vibration, and the spiral gasket using comparative amount B of filler material showed a rapid increase in the amount of leakage due to vibration. The leakage ω increases rapidly in response to vibration16, but the spiral-wound gasket using the filler material of the example does not exhibit a sharp increase in the leakage a in both medium and high temperature heating and imaging. It was confirmed that it has an excellent effect on vibration.

ここで、撮動に対する上述の特性は、2μm以下の繊維
径をもつガラス繊維としての0.6μmマイクロガラス
が振動による充填日詰材(粘土鉱物)の脱落を防止する
ためである。
Here, the above-mentioned characteristics for imaging are due to the fact that 0.6 μm microglass as glass fiber having a fiber diameter of 2 μm or less prevents the filling material (clay mineral) from falling off due to vibration.

つまり、上述のマイクロガラスは加熱されることにより
、繊維表面積を小ざくする傾向があり、このマイクロガ
ラスが加熱されて収縮することで、充填材としての粘土
鉱物を捕捉する能力を])1強ザる。
In other words, when the above-mentioned microglass is heated, it tends to reduce the fiber surface area, and when this microglass is heated and shrinks, the ability to capture clay minerals as a filler decreases. Zaru.

このためマイクロガラスをtHI 73 Uとして使用
することにより、耐振性の優れたフィラー材を1’7る
ことができる。
Therefore, by using microglass as tHI 73 U, a filler material with excellent vibration resistance can be obtained.

また6μIrL径のガラスIIは上述のマイクロガラス
に比較して熱劣化が小さく、このため2μm以上の径を
もつガラスlJ&雑を繊維基材として使用することによ
り、耐熱性の優れたフィラー材を得ることができ、上述
のマイクロガラスと2μm以上の径のガラス繊維とを組
合せることにより、加熱および撮動に強いフィラー材を
(ワることができる。
Furthermore, glass II with a diameter of 6μIrL has less thermal deterioration than the above-mentioned microglass, so by using glass II with a diameter of 2μm or more as a fiber base material, a filler material with excellent heat resistance can be obtained. By combining the above-mentioned microglass with glass fibers having a diameter of 2 μm or more, it is possible to create a filler material that is resistant to heating and imaging.

なお、各種試験データに基づく使用温度400〜700
℃に対するガラス錫維の望ましい組合せを示すと下表4
の通りである。
In addition, the operating temperature is 400 to 700 based on various test data.
Table 4 below shows the desirable combination of glass tin fibers with respect to °C.
It is as follows.

く表4〉 なお、粘土鉱物としては上述したタルク、セビオライト
の他にカオリン(カオリナイトを主成分とする白色粘土
で、約800℃でレラミツク状になる耐熱部材)を所定
重量%だ(プ配合してもよいことは勿論である。
Table 4: As clay minerals, in addition to the above-mentioned talc and seviolite, kaolin (a white clay whose main component is kaolinite, a heat-resistant material that becomes relami-like at about 800°C) was added at a predetermined weight percent (preparation). Of course, you can do it.

Claims (1)

【特許請求の範囲】[Claims] 1.2μm以下の繊維径を有するガラス繊維と、2μm
を超過する繊維径のガラス繊維とを、2種以上組合せた
繊維基材を、粘土鉱物な どの充填材および結合剤と配合して抄造し た うず巻層ガスケットのフィラー材。
Glass fibers with a fiber diameter of 1.2 μm or less and 2 μm
A filler material for a spiral-wound layer gasket made by mixing a fiber base material, which is a combination of two or more types of glass fibers with a fiber diameter exceeding , with a filler such as a clay mineral and a binder.
JP13988686A 1986-06-16 1986-06-16 Filler material for spiral gasket Granted JPS62295983A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13988686A JPS62295983A (en) 1986-06-16 1986-06-16 Filler material for spiral gasket

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13988686A JPS62295983A (en) 1986-06-16 1986-06-16 Filler material for spiral gasket

Publications (2)

Publication Number Publication Date
JPS62295983A true JPS62295983A (en) 1987-12-23
JPH0315952B2 JPH0315952B2 (en) 1991-03-04

Family

ID=15255880

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13988686A Granted JPS62295983A (en) 1986-06-16 1986-06-16 Filler material for spiral gasket

Country Status (1)

Country Link
JP (1) JPS62295983A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03259988A (en) * 1990-03-09 1991-11-20 Nippon Pillar Packing Co Ltd Filler material for spiral gasket
JPH04314778A (en) * 1991-04-11 1992-11-05 Nippon Pillar Packing Co Ltd Filter for spiral wound gasket

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03259988A (en) * 1990-03-09 1991-11-20 Nippon Pillar Packing Co Ltd Filler material for spiral gasket
JPH04314778A (en) * 1991-04-11 1992-11-05 Nippon Pillar Packing Co Ltd Filter for spiral wound gasket

Also Published As

Publication number Publication date
JPH0315952B2 (en) 1991-03-04

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