JPS62295960A - Electrically conductive coating agent composition - Google Patents
Electrically conductive coating agent compositionInfo
- Publication number
- JPS62295960A JPS62295960A JP13829086A JP13829086A JPS62295960A JP S62295960 A JPS62295960 A JP S62295960A JP 13829086 A JP13829086 A JP 13829086A JP 13829086 A JP13829086 A JP 13829086A JP S62295960 A JPS62295960 A JP S62295960A
- Authority
- JP
- Japan
- Prior art keywords
- group
- member selected
- tables
- formulas
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 title abstract 2
- 239000012799 electrically-conductive coating Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000005977 Ethylene Substances 0.000 claims abstract description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 3
- 239000008199 coating composition Substances 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims 8
- -1 polyoxyethylene nonylphenyl ether phosphate Polymers 0.000 abstract description 24
- 239000004094 surface-active agent Substances 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003760 tallow Substances 0.000 abstract description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 5
- 235000015278 beef Nutrition 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 229910019142 PO4 Inorganic materials 0.000 description 9
- 239000010452 phosphate Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 3
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 3
- 229920001281 polyalkylene Polymers 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- XMMDVXFQGOEOKH-UHFFFAOYSA-N n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCN XMMDVXFQGOEOKH-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
- 229940087291 tridecyl alcohol Drugs 0.000 description 2
- 229960001124 trientine Drugs 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
- AOFLVNRYYFHDPU-UHFFFAOYSA-N 18-aminooctadecan-1-ol Chemical compound NCCCCCCCCCCCCCCCCCCO AOFLVNRYYFHDPU-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000013066 combination product Substances 0.000 description 1
- 229940127555 combination product Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- VPNOHCYAOXWMAR-UHFFFAOYSA-N docosan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCCCCCN VPNOHCYAOXWMAR-UHFFFAOYSA-N 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- BPTZEQZDELJZTL-UHFFFAOYSA-N nonoxybenzene;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCOC1=CC=CC=C1 BPTZEQZDELJZTL-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- UVBBCQLPTZEDHT-UHFFFAOYSA-N pent-4-en-1-amine Chemical group NCCCC=C UVBBCQLPTZEDHT-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000009291 secondary effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Abstract
Description
イ１発明の目的
（産業上の利用分野）
本発明は高分子材料の導電性を改良するための導電性塗
布剤組成物更に詳しくは経済性及び導電効果に優れた導
電性塗布剤組成物に関するものである。
（従来の技術）
従来高分子材料の絶縁性に起因する電子部品の取扱いの
トラブルを防止するための最も普遍的な手段としては金
屑粉末、グラファイト、金属識維、カーボンブラックな
どのフィラーをバインダー溶液中に分散せしめた導電性
塗布剤を塗布する方策がとられてきている。またこれら
は導電回路の製造にも使用されてきている。
（発明が解決しようとする間Ｊ点）
しかしながらこれらの塗布剤によって目的の導電性を得
るためにはフィラーの量を°極端に多くする必要があり
、例えば最も優れた銀粉末分散型の導電性塗布剤の場合
バインダーの固形分の４倍量の銀粉末を使用しないと目
的の導電性が得られず、このため製品の価格が著しく高
価なものになると同時に、バインダーの配合割合が少な
いために塗膜の物性が劣る結果となり、大きな間圧とし
て指摘されてきた。
口０発明の構成
（間朋点を解決するための手段）
本発明者等はかかる観点から従来の導電性塗布剤の欠点
を克服すべく種々研究の結果、本発明に到達したもので
あり、本発明は導電性塗布剤を製造するに際し、一般式
（１）または一般式（２）Ｒ，０−Ｐ−ＯＨ・・・・・
・・（１）Ｒ２
（但しＲ３は炭素数８〜２２のアルキル基、アルケニル
基、Ｒ２はＯＨまたはＲ，Ｏである。）○
Ｒ２Ｏ−Ｐ−ＯＨ・・・・・・・（２）（但しＲ１は炭
素数８〜２２のアルキル基、アルケニル基を有する高級
アルコールまたは炭素数４〜１２のアルキル基を有する
アルキルフェノール１モルにエチレンオキサイドまたは
／およびプロピレンオキサイドを１〜１００モル付加さ
せた残基、Ｒ４はＯＨまたはＲ，Ｏである。）に示され
る化合物少くとも１種１００重量部に対し一般式％式％
（５）
（ＲｓはＲ１と同様、または炭素数８〜２２のヒドロキ
シアルキル基、Ｒ１は水素原子またはメチル基、Ｒ７は
エチレン、プロピレン、Ｘは０または１〜５の整数であ
る。）
Ｒ１A1 Object of the invention (industrial application field) The present invention relates to a conductive coating composition for improving the conductivity of polymeric materials, and more particularly to a conductive coating composition that is economical and has excellent conductivity. It is something. (Prior art) Conventionally, the most universal means to prevent handling troubles of electronic parts caused by the insulating properties of polymer materials is to use fillers such as gold powder, graphite, metal fibers, and carbon black as binders. Approaches have been taken to apply conductive coatings dispersed in solutions. They have also been used to make conductive circuits. (Point J while the invention is trying to solve the problem) However, in order to obtain the desired conductivity with these coating agents, it is necessary to extremely increase the amount of filler.For example, the most excellent conductivity of silver powder dispersed type In the case of coating agents, the desired electrical conductivity cannot be obtained unless silver powder is used in an amount four times the solid content of the binder, which makes the product extremely expensive, and at the same time, because the proportion of the binder is small, This results in poor physical properties of the coating film, and has been pointed out as a large pressure. Structure of the Invention (Means for Solving the Shortcomings) From this perspective, the present inventors have arrived at the present invention as a result of various studies to overcome the drawbacks of conventional conductive coating agents. In the present invention, when manufacturing a conductive coating agent, general formula (1) or general formula (2) R,0-P-OH...
...(1) R2 (However, R3 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, and R2 is OH or R, O.) ○ R2O-P-OH... (2) ( However, R1 is a residue obtained by adding 1 to 100 moles of ethylene oxide or/and propylene oxide to 1 mole of a higher alcohol having an alkyl group or alkenyl group having 8 to 22 carbon atoms or an alkylphenol having an alkyl group having 4 to 12 carbon atoms. , R4 is OH or R, O.
(5) (Rs is the same as R1 or a hydroxyalkyl group having 8 to 22 carbon atoms, R1 is a hydrogen atom or a methyl group, R7 is ethylene or propylene, and X is 0 or an integer of 1 to 5.) R1
【
Ｒ，Ｃ０ＮＨ−Ｒ，−（Ｎ−Ｒ，）ｙ−ＮＨＲ，・・（
４）（但しＲ１は炭素数７〜２１のアルキル基、アルケ
ニル基、ヒドロキシアルキルまたはアルケニル基、ｙは
○または１〜３の整数、Ｒ５は水素原子、またはＲ，Ｃ
ｏである。）
Ｒ８゜
〔但しＲ１゜は水素原子、または
［
Ｒ、−Ｎ Ｒ、。
（但しＲＩ １は水素原子、Ｒｔ（Ｎ −Ｒ，）ｚＲ，
、、ｚは０または１〜２の整数、ＲＩ ＩはＮＨ，また
はに示される化合物少なくとも１種１０〜３００重量部
を配合した配合物（以下本発明の配合物と称する。）を
少量添加することによって、従来の導電性塗布剤よりも
フィラニの含量が少なくても優れた導電効果を示し、更
には副次的な効果として塗布剤の粘度を低下させる事が
できるという新たな発見に基づく新規な導電性塗布剤を
提供するものである１本発明の配合物は下記の如くして
得られる。
まず一般式（１）および（２）で示されるリン酸エステ
ル型界面活性剤はデシルアルコール、ラウリルアルコー
ル、トリデシルアルコール、ミリスチルアルコール、ス
テアリルアルコール、セチルアルコール、オレイルアル
コール、オキソ法からの炭素数１１〜１５の混合アルコ
ール、炭素数１２〜１３のセカンダリ−アルコール、お
よびこれらの高級アルコール１モルに公知の方法でエチ
レンオキサイドまたは／およびプロピレンオキサイドを
１〜１００モル付加させた非イオン界面活性剤、ブチル
フェノール、オクチルフェノール。
ノニルフェノール、ドデシルフェノール、ジノニルフェ
ノール１モルに公知の方法でエチレンオキサイド、また
は／およびプロピレンオキサイドをｌ°〜１００モル付
加させた非イオン界面活性剤などを原料として、これら
原料１モルにオキシ塩化リン、五酸化リン、好ましくは
五酸化リンを公知の方法で０．３モル−１，０モル反応
させて得られるものであって、通常モノエステルとジエ
ステルとの混合物で得られる。性能上好ましくは、ラウ
リルアルコール、トリデシルアルコール、オレイルアル
コール、オキソ法からの炭素数１１〜１５の混合アルコ
ール、オクチルフェノール、ノニルフェノール１モルに
エチレンオキサイドを５〜１５モル付加させた非イオン
界面活性剤を原料としたリン酸エステル型界面活性剤を
使用する二とが好ましい。
一般式（３）、 （４）、および（５）に示されるアミ
ノ化合物はデシルアミン、ドデシルアミン、ミリスチル
アミン、バルミチルアミン、セチルアミン、ステアリル
アミン、牛脂アミン、ベヘニルアミン、ラウリルアミノ
プロピルアミン、牛脂アミノプロピルアミン、ヒドロキ
システアリルアミン、とマ脂肪アミン、アルキルハライ
ドやαまたはインナーオレフィンとエチレンジアミン、
ジエチレントリアミン、トリエチレンテトラミン、テト
ラエチレンペンタミン、アミノプロピルエチレンジアミ
ンなどのポリアルキレンポリアミンとを反応させて得ら
れる（ヒドロキシ）アルキル化ポリアルキレンポリアミ
ン、およびこれらのアミンの水素原子をメチル基で一部
または全部を置換したアミノ化合物、さらにはラウリン
酸、ミリスチン酸、バルミチン酸、ステアリン酸、オレ
イン酸、イソステアリン酸、エルカ酸、にマ脂肪酸、１
２ヒドロキシステアリン酸など１〜２モルと上記のポリ
アルキレンポリアミンとを公知の方法で反応させること
によって得られるアマイド化合物およびイミダシリン化
合物などを挙げることができ、性能上および経済性より
好ましくは牛脂アミノプロピルアミン、ラウリルアミノ
プロピルアミン。
オレイン酸、ラウリン酸、ステアリン酸とジエチレント
リアミン、トリエチレンテトラミン、テトラエチレンペ
ンタミンとを反応させて得られるアマイド化合物または
イミダシリン化合物を使用すべきである。本発明におい
て、上記に示したリン酸エステル型界面活性剤とアミノ
化合物は１：０゜１〜１：３の範囲で配合して使用され
るが、好ましくは、リン酸エステル型界面活性剤の酸価
当量と、アミノ化合物のアミン価当量とが中和されるべ
く混合するか、または金属の酸化防止を期待する場合に
はアミノ化合物を中和当量よりや八多く混合するのが好
ましく、シュ比で云えば１：０゜２〜１・１．６の範囲
である。本発明の導電性塗布剤はフィラーとして公知の
銀、白金、銅、鉄、スズ、アルミニウム、ニッケル、カ
ーボンブラックなどが使用され、バインダーとして公知
のフェノール樹脂、ポリエステル樹脂、アクリル樹脂、
ウレタン樹脂、アルキッド樹脂、エポキシ樹脂などが使
用される。本発明の配合物は通常フィラーに対して０．
５〜５％程度使用され塗布剤製造時に添加されるか事前
にフィラーを本発明の配合物の溶液中で処理し乾燥した
ものを使用してもよい。
さらには本発明のリン酸エステル型界面活性剤とアミノ
化合物を別々に所定量加えることもできる。
（実施例）
次に本発明を実施例で説明する。
実施例１〜実施例２゜
【リン酸エステル型界面活性剤（１）の合成ｊノニルフ
ェノール１モルにエチレンオキサイド８モルを公知の方
法で付加したポリ （８）オキシエチレンノニルフェニ
ルエーテル１モル５７２ｇを四ツロコルベンに取り、五
酸化リン０．４モル５７ｇを徐々に常温で攪拌しながら
加え、後９０℃にて５時間反応させ、フェノールフタリ
ン指示薬を用いて測定した酸価１２０の淡黄色粘稠油状
のポリ（８）オギシエチレンノニルフェニルエーテルフ
オスフエートを得た。
【アミノ化合物（１）］
工業用牛脂アルキルジアミンをアミノ化合物（１）とす
る。本品はアミン価３７２の黄褐色ペースト状であった
。
【本発明の配合品（１）の製造】
ポリ（８）オキシエチレンノニルフェニルエーテルフォ
スフニート〔リン酸エステル型界面活性ｍ（１）１１°
ＯＯｇと牛脂アルキルジアミン〔アミノ化合物（１））
３７ｇとを６０℃で混合し、黄褐色ペースト状の本発明
の配合品（１）を得た。
本品については、後記のテストに供する。[R,C0NH-R,-(N-R,)y-NHR,...(
4) (However, R1 is an alkyl group, alkenyl group, hydroxyalkyl or alkenyl group having 7 to 21 carbon atoms, y is ○ or an integer of 1 to 3, R5 is a hydrogen atom, or R, C
It is o. ) R8゜ [However, R1゜ is a hydrogen atom, or [ R, -NR,. (However, RI 1 is a hydrogen atom, Rt(N −R,)zR,
, , z is an integer of 0 or 1 to 2, RRI I is NH, or a small amount of a blend containing 10 to 300 parts by weight of at least one of the compounds shown in (hereinafter referred to as the blend of the present invention) is added. This is a novel product based on the new discovery that it shows superior conductivity even with a lower content of filani than conventional conductive coatings, and can also reduce the viscosity of coatings as a secondary effect. One formulation of the present invention, which provides a conductive coating agent, is obtained as follows. First, the phosphoric acid ester type surfactants represented by general formulas (1) and (2) are decyl alcohol, lauryl alcohol, tridecyl alcohol, myristyl alcohol, stearyl alcohol, cetyl alcohol, oleyl alcohol, and carbon number 11 from the oxo method. ~15 mixed alcohols, secondary alcohols with 12 to 13 carbon atoms, and 1 to 100 moles of ethylene oxide or/and propylene oxide added to 1 mole of these higher alcohols by a known method, a nonionic surfactant, butyl phenol. , octylphenol. Using a nonionic surfactant made by adding l° to 100 moles of ethylene oxide or/and propylene oxide to 1 mole of nonylphenol, dodecylphenol, or dinonylphenol by a known method as a raw material, phosphorus oxychloride, phosphorus oxychloride, etc. are added to 1 mole of these raw materials. It is obtained by reacting phosphorus pentoxide, preferably phosphorus pentoxide, from 0.3 mol to 1.0 mol by a known method, and is usually obtained as a mixture of a monoester and a diester. In terms of performance, preferred nonionic surfactants include lauryl alcohol, tridecyl alcohol, oleyl alcohol, mixed alcohols having 11 to 15 carbon atoms from the oxo method, octylphenol, and nonionic surfactants in which 5 to 15 moles of ethylene oxide are added to 1 mole of nonylphenol. It is preferable to use a phosphate ester type surfactant as a raw material. Amino compounds represented by general formulas (3), (4), and (5) include decylamine, dodecylamine, myristylamine, valmitylamine, cetylamine, stearylamine, tallow amine, behenylamine, lauryl aminopropylamine, tallow amino Propylamine, hydroxystearylamine, fatty amines, alkyl halides and alpha or inner olefins and ethylenediamine,
(Hydroxy)alkylated polyalkylene polyamines obtained by reacting with polyalkylene polyamines such as diethylene triamine, triethylene tetramine, tetraethylene pentamine, and aminopropyl ethylene diamine, and some or all of the hydrogen atoms of these amines are replaced with methyl groups. Amino compounds substituted with
Examples include amide compounds and imidacillin compounds obtained by reacting 1 to 2 moles of 2-hydroxystearic acid with the above-mentioned polyalkylene polyamines by a known method, and beef tallow aminopropyl is preferred from the viewpoint of performance and economy. Amine, lauryl aminopropylamine. Amide or imidacilline compounds obtained by reacting oleic acid, lauric acid, stearic acid with diethylenetriamine, triethylenetetramine, tetraethylenepentamine should be used. In the present invention, the above-mentioned phosphate ester type surfactant and amino compound are used in a ratio of 1:0°1 to 1:3, but it is preferable that the phosphate ester type surfactant It is preferable to mix so that the acid value equivalent and the amine value equivalent of the amino compound are neutralized, or to mix the amino compound in an amount slightly more than the neutralization equivalent when antioxidation of the metal is expected. In terms of ratio, it is in the range of 1:0°2 to 1.1.6. The conductive coating agent of the present invention uses well-known fillers such as silver, platinum, copper, iron, tin, aluminum, nickel, carbon black, etc., and binders such as well-known phenol resins, polyester resins, acrylic resins,
Urethane resin, alkyd resin, epoxy resin, etc. are used. The formulations of the present invention typically have a 0.0.
The filler may be used in an amount of about 5 to 5% and added at the time of manufacturing the coating agent, or the filler may be treated in advance in a solution of the formulation of the present invention and dried. Furthermore, the phosphate ester type surfactant of the present invention and the amino compound can be added separately in predetermined amounts. (Example) Next, the present invention will be explained with examples. Examples 1 to 2 [Synthesis of phosphate ester type surfactant (1)] 572 g of 1 mole of poly(8)oxyethylene nonylphenyl ether prepared by adding 8 moles of ethylene oxide to 1 mole of nonylphenol by a known method was added. Add 57 g of 0.4 mol of phosphorus pentoxide to Yotsurokolbene gradually at room temperature while stirring, and then react at 90°C for 5 hours to obtain a pale yellow viscous substance with an acid value of 120 as measured using a phenolphthalin indicator. Oily poly(8) ethylene nonylphenyl ether phosphate was obtained. [Amino Compound (1)] Industrial beef tallow alkyl diamine is used as an amino compound (1). This product was in the form of a yellowish brown paste with an amine value of 372. [Production of compounded product (1) of the present invention] Poly(8) oxyethylene nonyl phenyl ether phosphinate [phosphate ester type surface active m(1) 11°
OOg and tallow alkyldiamine [amino compound (1)]
37 g at 60° C. to obtain a yellow-brown paste-like blended product (1) of the present invention. This product will be subjected to the tests described below.
【リン酸エステル型界面活性剤（２）〜（９）の合成】
リン酸エステル型界面活性剤（１）の合成と同様にリン
酸エステル型界面活性剤（２）〜（９）を合成し第１表
に示す結果を得た。[Synthesis of phosphate ester type surfactants (2) to (9)]
Phosphate ester type surfactants (2) to (9) were synthesized in the same manner as the synthesis of phosphate ester type surfactant (1), and the results shown in Table 1 were obtained.
【アミノ化合物（２）〜（９）】
アミノ化合物（２）〜（９）について第２表に示す。
〔本発明の塗布剤組成物］
平均粒径０．３ミクロンの銀粉１００ｇ、本発明の配合
品（１）〜（２０＞１．５ｇ、アクリル系バインダー、
コダックスＬＫ−７０４（固型分５０％、東し製）ｔｏ
ｏｇ、キシレン１００ｇをミキサーで混合し本発明の塗
布剤組成物（１）〜（２０）を得た。また同様に銀粉Ｌ
ＯＯｇ、コダックスＬＫ−７０４１００ｇ、溶剤１００
ｇより成る比較例（１）および銀粉１００ｇ、コダック
スＬＫ−７０４７０ｇ、溶剤１３０ｇより成る比較例（
２）の塗布剤組成物を得た。
これらの塗布剤組成物をポリエステルフィルムに膜厚２
ｏミクロンに塗布し常温で１日風乾後の面積電気抵抗を
測定した所第４表の如き結果が得られた。また本発明の
塗布剤組成物（１）〜（２０）と比較例（１）は比較例
（２）に比べて塗膜の強度が優れていた。
第４表
本発明の導電性塗布剤と比較例の導電効果（１）第４表
に示される如く本発明の塗布剤組成物は９Ｂ粉の配合量
が少ないのにも拘らず優れた導電性を示した。
［実施例２１〜２６］
チャネルカーボンブラック １００ｇ、本発明の配合品
（１）、（５）、（ブ）、（１０）、（１６）及び（１
９）を１．２ｇ、ウレタン系バインダー ＵＣＸ−９０
１（固型分３０％、地雷化製）３３０ ｇをミキサーで
混合し、本発明の塗布剤組成物（２１）〜（２６）を得
た。また同様にカーボンブラック １００ｇ、 ＵＣ
Ｘ−９０１３３０ｇよｌＪ成ル比較例（３）の塗布剤組
成物を得た。これらの塗布剤組成物をポリビリニデン樹
脂に膜厚２ｏミクロンに塗布し常温で１日風乾後の面積
電気抵抗を測定した所、第５表の如き結果を得た。
第５表
本発明の４電性塗布剤と比較例の導電効果（２）第５表
に示された如く本発明の塗布剤組成物は比較例より優れ
た導電性を示した。
［実施例（２７）〜（３０）］
平均粒径２ｏミリミクロンの％粉 １００ｇ、本発明の
配合品（２）、（８）、（１２）、及び（２０）を３ｇ
、ポリエステル系バインダーバイロン２００（固型分１
００％、東洋紡製）５０ｇ、トルエン２００ｇ、ＭＩＢ
Ｋ １００ｇをミキサーテ混合し本発明の塗布剤組成
物（２７）〜（３０）を得た。
また同様に銅粉１００ｇ、バイロン２００ ５０ｇ、溶
剤３００ｇより成る比較例（４）を得た。これらの塗布
剤組成物をポリエステルフィルムに２０ミクロシの膜厚
に塗布し常温で１日、虱乾後の面積電気抵抗を測定した
所第６表の如き結果を得た。
第６表
本発明の導電性塗布剤と比較例の導電効果（３）【実施
例（３１）〜（３３）］
平均粒径２ミクロンのニッケル粉 ５０ｇ、２０ミリミ
クロンのニッケル粉５０ｇ、本発明の配合品（３）、（
４）、（１３）を２ｇ、ポリエステル系バインダーバイ
ロン２００を５０ｇ、トルエン ２００ｇ、アセトン
ｌｏｏｇをミキサーで混合し本発明の塗布剤組成物（３
１）〜（３３）を得た。また同様にニッケル粉１００ｇ
、バイロン２００５０ｇ、溶剤３００ｇより成る比較例
（５）を得た。
これらの塗布剤組成物をＡＢＳ板に２０ミクロンの膜厚
に塗布し常温で１日、虱乾後の面積電気抵抗を測定した
所第７表の如き結果を得た。
また本発明の塗布剤組成物を４０°Ｃ１１ケ月処理して
導電効果を測定したが殆ど変化がなかった。
第７表
本発明の導電性塗布剤と比較例の導電効果（４）ハ１発
明の効果
以上の実施例に示したように本発明による導電性塗布剤
を泪いることによって従来の塗布剤に、くらべ著るしく
導電性を改良するとともに経済性、記入性においても従
来法に優ることは明らかである。[Amino compounds (2) to (9)] Amino compounds (2) to (9) are shown in Table 2. [Coating composition of the present invention] 100 g of silver powder with an average particle size of 0.3 microns, blended products (1) to (20>1.5 g) of the present invention, acrylic binder,
Kodax LK-704 (solid content 50%, manufactured by Toshi) to
og and 100 g of xylene were mixed in a mixer to obtain coating compositions (1) to (20) of the present invention. Similarly, silver powder L
OOg, Kodax LK-704 100g, solvent 100
Comparative example (1) consisting of g and Comparative example (1) consisting of 100 g of silver powder, Kodax LK-70470 g, and 130 g of solvent.
A coating composition 2) was obtained. These coating compositions were applied to a polyester film with a film thickness of 2
The area electrical resistance was measured after applying the coating to an area of 0.0 microns and air-drying it at room temperature for one day, and the results shown in Table 4 were obtained. Moreover, coating compositions (1) to (20) of the present invention and Comparative Example (1) had superior coating film strength compared to Comparative Example (2). Table 4 Conductive effects of the conductive coating agent of the present invention and comparative examples (1) As shown in Table 4, the coating composition of the present invention has excellent conductivity despite the small amount of 9B powder blended. showed that. [Examples 21 to 26] 100 g of channel carbon black, blended products (1), (5), (b), (10), (16) and (1) of the present invention
9) 1.2g, urethane binder UCX-90
1 (solid content: 30%, manufactured by Jimika) were mixed in a mixer to obtain coating compositions (21) to (26) of the present invention. Similarly, 100g of carbon black, UC
A coating composition of Comparative Example (3) of X-901330g was obtained. These coating compositions were coated on polyvinidene resin to a film thickness of 20 microns, and after air-drying at room temperature for one day, the area electrical resistance was measured, and the results shown in Table 5 were obtained. Table 5 Conductive effect of the tetraelectric coating composition of the present invention and comparative example (2) As shown in Table 5, the coating composition of the present invention exhibited superior conductivity compared to the comparative example. [Examples (27) to (30)] 100g of powder with an average particle size of 2o millimicrons, 3g of blended products (2), (8), (12), and (20) of the present invention
, polyester binder Vylon 200 (solid content 1
00%, manufactured by Toyobo) 50g, toluene 200g, MIB
100 g of K was mixed in a mixer to obtain coating compositions (27) to (30) of the present invention. Similarly, a comparative example (4) consisting of 100 g of copper powder, 50 g of Vylon 200, and 300 g of solvent was obtained. These coating compositions were coated on a polyester film to a thickness of 20 microns, dried at room temperature for one day, and then the area electrical resistance was measured, and the results shown in Table 6 were obtained. Table 6 Conductive effect of the conductive coating agent of the present invention and comparative examples (3) [Examples (31) to (33)] 50 g of nickel powder with an average particle size of 2 microns, 50 g of nickel powder with an average particle size of 20 mm, the present invention Combination product (3), (
4), 2g of (13), 50g of polyester binder Vylon 200, 200g of toluene, acetone
LOOG was mixed with a mixer to form the coating composition (3) of the present invention.
1) to (33) were obtained. Similarly, 100g of nickel powder
Comparative Example (5) was obtained, consisting of 20,050 g of Vylon and 300 g of solvent. These coating compositions were coated on an ABS board to a thickness of 20 microns, dried at room temperature for one day, and then the area electrical resistance was measured, and the results shown in Table 7 were obtained. Furthermore, when the coating composition of the present invention was treated at 40° C. for 11 months and the conductive effect was measured, there was almost no change. Table 7 Conductive effect of the conductive coating agent of the present invention and comparative examples (4) C1 Effect of the invention As shown in the above examples, the conductive coating agent of the present invention can be applied to a conventional coating agent. It is clear that this method significantly improves the conductivity and is superior to the conventional method in terms of economy and ease of writing.
Claims (1)
（１） （但しＲ＿１は炭素数８〜２２のアルキル基、アルケニ
ル基、Ｒ＿２はＯＨまたはＲ＿１Ｏである）▲数式、化
学式、表等があります▼・・・・・・・・・（２） （但しＲ＿３は炭素数８〜２２のアルキル基、アルケニ
ル基を有する高級アルコールまたは炭素数４〜１２のア
ルキル基を有するアルキルフェノール１モルにエチレン
オキサイドまたは／およびプロピレンオキサイドを１〜
１００モル付加させた残基、Ｒ＿４はＯＨまたはＲ＿３
Ｏである。）に示される化合物少くとも１種１００重量
部に対し 一般式（３）、（４）、または（５） ▲数式、化学式、表等があります▼・・・・・・・・・
（３） （Ｒ＿５はＲと同様、または炭素数８〜２２のヒドロキ
シアルキル基、Ｒ＿６は水素原子またはメチル基、Ｒ＿
７はエチレン、プロピレン、ｘは０または１〜５の整数
である。） ▲数式、化学式、表等があります▼・・（４） （但しＲ＿８は炭素数７〜２１のアルキル基、アルケニ
ル基、ヒドロキシアルキルまたはアルケニル基、ｙは０
または１〜３の整数、Ｒ＿９は水素原子、またはＲ＿９
ＣＯである。） ▲数式、化学式、表等があります▼・・・・・・（５） 〔但しＲ＿１＿０は水素原子、または ▲数式、化学式、表等があります▼ （但しＲ＿１＿１は水素原子、▲数式、化学式、表等が
あります▼、ｚ は０または１〜２の整数、Ｒ＿１＿２はＮＨ＿２または
▲数式、化学式、表等があります▼である。）〕 に示される化合物少なくとも１種１０〜３００重量部を
配合した配合物を含有することからなる導電性塗布剤組
成物。[Claims] 1. General formula (1) or general formula (2) ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・
(1) (However, R_1 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, and R_2 is OH or R_1O.) ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・・・・(2) ( However, R_3 is an alkyl group having 8 to 22 carbon atoms, a higher alcohol having an alkenyl group, or an alkylphenol having an alkyl group having 4 to 12 carbon atoms, and 1 to 1 to 1 mol of ethylene oxide or/and propylene oxide.
100 mol added residue, R_4 is OH or R_3
It is O. ) General formula (3), (4), or (5) ▲ Numerical formula, chemical formula, table, etc. are included for 100 parts by weight of at least one compound shown in ).
(3) (R_5 is the same as R or a hydroxyalkyl group having 8 to 22 carbon atoms, R_6 is a hydrogen atom or a methyl group, R_
7 is ethylene or propylene, and x is 0 or an integer from 1 to 5. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(4) (However, R_8 is an alkyl group, alkenyl group, hydroxyalkyl group, or alkenyl group with 7 to 21 carbon atoms, and y is 0
or an integer from 1 to 3, R_9 is a hydrogen atom, or R_9
It is CO. ) ▲There are mathematical formulas, chemical formulas, tables, etc.▼・・・・・・(5) [However, R_1_0 is a hydrogen atom, or ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (However, R_1_1 is a hydrogen atom, ▲Mathematical formulas, chemical formulas, (There are tables, etc.▼, z is 0 or an integer from 1 to 2, R_1_2 is NH_2 or ▲There are mathematical formulas, chemical formulas, tables, etc.▼.)] Contains 10 to 300 parts by weight of at least one of the compounds shown in A conductive coating composition comprising:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13829086A JPS62295960A (en) | 1986-06-16 | 1986-06-16 | Electrically conductive coating agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13829086A JPS62295960A (en) | 1986-06-16 | 1986-06-16 | Electrically conductive coating agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62295960A true JPS62295960A (en) | 1987-12-23 |
Family
ID=15218433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13829086A Pending JPS62295960A (en) | 1986-06-16 | 1986-06-16 | Electrically conductive coating agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62295960A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008078102A3 (en) * | 2006-12-22 | 2008-11-20 | Imuthes Ltd | Lipids and their use as non-viral delivery vehicle |
| CN111511489A (en) * | 2017-10-31 | 2020-08-07 | LS-Nikko铜制炼株式会社 | Surface-treated silver powder and method for producing same |
-
1986
- 1986-06-16 JP JP13829086A patent/JPS62295960A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008078102A3 (en) * | 2006-12-22 | 2008-11-20 | Imuthes Ltd | Lipids and their use as non-viral delivery vehicle |
| CN111511489A (en) * | 2017-10-31 | 2020-08-07 | LS-Nikko铜制炼株式会社 | Surface-treated silver powder and method for producing same |
| JP2021501266A (en) * | 2017-10-31 | 2021-01-14 | エルエスニッコカッパー インコーポレイテッドＬｓ−Ｎｉｋｋｏ Ｃｏｐｐｅｒ Ｉｎｃ． | Surface-treated silver powder and its manufacturing method |
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