JPS62289802A - Bronze-colored antifogging mirror - Google Patents
Bronze-colored antifogging mirrorInfo
- Publication number
- JPS62289802A JPS62289802A JP13416886A JP13416886A JPS62289802A JP S62289802 A JPS62289802 A JP S62289802A JP 13416886 A JP13416886 A JP 13416886A JP 13416886 A JP13416886 A JP 13416886A JP S62289802 A JPS62289802 A JP S62289802A
- Authority
- JP
- Japan
- Prior art keywords
- bronze
- thin film
- mirror
- color
- copper alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010409 thin film Substances 0.000 claims abstract description 27
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 15
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 229910000906 Bronze Inorganic materials 0.000 abstract description 13
- 239000010974 bronze Substances 0.000 abstract description 13
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract description 13
- 239000010408 film Substances 0.000 abstract description 8
- 239000011521 glass Substances 0.000 abstract description 4
- 239000010949 copper Substances 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 229910002482 Cu–Ni Inorganic materials 0.000 abstract description 2
- 229910045601 alloy Inorganic materials 0.000 abstract description 2
- 239000000956 alloy Substances 0.000 abstract description 2
- 229910052802 copper Inorganic materials 0.000 abstract description 2
- 238000002310 reflectometry Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 238000004040 coloring Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910010280 TiOH Inorganic materials 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 229910001120 nichrome Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Landscapes
- Optical Elements Other Than Lenses (AREA)
- Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
- Surface Heating Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
３、発明の詳細な説明
技術分野
本発明は、一般に、ブロンズ色防曇鏡に関し、特に、自
動車用後写鏡として好適なブロンズ色防曇鏡に関する。DETAILED DESCRIPTION OF THE INVENTION 3. Detailed Description of the Invention Technical Field The present invention generally relates to a bronze-colored anti-fog mirror, and more particularly to a bronze-colored anti-fog mirror suitable as a rear view mirror for automobiles.
従来技術
近年、自動車用後写鏡の分野においては、鏡をブロンズ
色に着色することにより防眩効果を達成するとともに、
製品に高級感を与える着色技術が提供されている。一方
、同分野において、雨水等が原因で生ずる鏡面曇りを防
止する防曇技術が提供されている。そして、また、上記
両者の技術を併せ有する技術ら提供されている。PRIOR ART In recent years, in the field of automobile rearview mirrors, an anti-glare effect has been achieved by coloring the mirrors in a bronze color.
Coloring techniques are provided that give products a luxurious feel. On the other hand, in the same field, anti-fog technology has been provided to prevent mirror fogging caused by rainwater or the like. Furthermore, technologies that combine both of the above-mentioned technologies have also been provided.
第５．６図に、上記両技術を組み合わせてなる自動車用
後写鏡の従来例を示している。第５．６図において、ｌ
は後写鏡全体を示しており、この後耳鏡ｌは、ガラス等
の透明基板２に、Ｔｉ０ｈ。Fig. 5.6 shows a conventional example of an automobile rearview mirror that combines both of the above-mentioned technologies. In Figure 5.6, l
1 shows the entire rear otoscope, and this rear otoscope 1 has a transparent substrate 2 made of glass or the like made of TiOH.
Ｃｅｎ２．Ｚｒ０ｙ、５ｎＯｚ、ＺｎＳ等の透明誘電体
薄膜３と、Ｃｒ、Ａｌ１．Ｔｉ、Ｎｉ−Ｃｒ等の金属反
射薄膜５とを真空蒸着等の方法で順に積層するとともに
、金属反射薄膜５を通電加熱するための手段、すなわち
、■対の電極６及び各電極に接続するリード線７を備え
ている。Cen2. A transparent dielectric thin film 3 made of Zr0y, 5nOz, ZnS, etc., and Cr, Al1. The metal reflective thin film 5 made of Ti, Ni-Cr, etc. is laminated in order by a method such as vacuum evaporation, and the metal reflective thin film 5 is heated by electricity, i.e., a pair of electrodes 6 and a lead connected to each electrode. It has line 7.
上記構造において、今、透明誘電体薄膜３としてＴ ｉ
Ｏｔを使用したとすれば、この先学膜厚を６００Å以
下にすると、入射光と反射光との干渉が原因でブロンズ
色を呈するようになる。ま１こ、１対の電極６間に通電
すれば、金属反射薄膜の電気抵抗により発熱が生じ、そ
の結果、鏡面に発生した曇りが除去されろ。In the above structure, now the transparent dielectric thin film 3 is T i
If Ot is used, if the film thickness is reduced to 600 Å or less, it will take on a bronze color due to interference between incident light and reflected light. First, if electricity is applied between the pair of electrodes 6, heat will be generated due to the electrical resistance of the metal reflective thin film, and as a result, the fogging that has occurred on the mirror surface will be removed.
ところで、上記従来例においては、ＮｉＣｒ等の金属反
射薄膜５自体は、通常無彩色である。すなわち、後写鏡
ｌの着色は、透明誘電体薄膜３のみにより、換言すれば
光の干渉効果のみにより、ブロンズ色を発色せしめてい
るのである。Incidentally, in the conventional example described above, the metal reflective thin film 5 itself made of NiCr or the like is usually achromatic. In other words, the rear view mirror 1 is colored only by the transparent dielectric thin film 3, in other words, by only the light interference effect, to produce a bronze color.
したがって、上記従来例は次のような問題がある。すな
わち、ブロンズ色の濃淡と反射率とは分光特性として相
関関係があり、ブロンズ色が淡い場合は反射率が高く、
一方、ブロンズ色が濃い場合は反射率が低い。ところで
、自動車用後写鏡においては、視認性の点から、規格上
反射率は３８％以上は必要とされている。ここで、上記
従来例において、反射率を３８％以上にしようとすれば
、十分満足できる濃度のブロンズ色が得られないのであ
る。また、光の干渉効果により発色せしめる場合は色の
バラツキが生ずるという問題がある。Therefore, the above conventional example has the following problems. In other words, there is a correlation between the shade of bronze and the reflectance as spectral characteristics; when the bronze color is light, the reflectance is high;
On the other hand, when the bronze color is deep, the reflectance is low. By the way, from the viewpoint of visibility, standards for rear view mirrors for automobiles require a reflectance of 38% or more. In the conventional example described above, if the reflectance is increased to 38% or more, a bronze color with a sufficiently satisfactory density cannot be obtained. Further, when coloring is caused by the interference effect of light, there is a problem that color variation occurs.
さらに、この場合は透明誘電体薄膜と金属反射薄膜との
２眉の薄膜が必要で構造も複雑となり、したがって製造
コストが高いという問題がある。Furthermore, in this case, two thin films, a transparent dielectric thin film and a metal reflective thin film, are required, resulting in a complicated structure and, therefore, a problem of high manufacturing costs.
本発明の技術的課題
従って、本発明が解決すべき技術的課題は、上記自動車
用後写鏡のようにブロンズ色着色鏡であってかつ防曇手
段の施されている鏡において、反射率を比較的高く保つ
と同時に適度の濃度でかつ色のバラツキのないブロンズ
色の着色を得るようにするとともに、構造を簡単にする
ことである。Technical Problems of the Present Invention Accordingly, the technical problem to be solved by the present invention is to improve the reflectance of a bronze-colored mirror such as the above-mentioned automobile rearview mirror and equipped with an anti-fog means. The objective is to maintain a relatively high concentration and at the same time obtain a bronze color with an appropriate density and no color variation, and to simplify the structure.
本発明の構成
上記技術的課題を解決するために、本発明は次のように
構成した。これを第１．２図に従って説明する。Configuration of the present invention In order to solve the above technical problem, the present invention was configured as follows. This will be explained according to Fig. 1.2.
本発明に係るブロンズ色防曇鏡は、透明基板１２の片面
に、膜厚２００Å以上好ましくは５００Å以上であって
かつ銅を主成分とする銅合金反射薄膜１３を形成すると
ともに、銅合金反射薄膜１３を通電加熱するための手段
１６．１７を装着してなることを特徴としている。The bronze-colored anti-fog mirror according to the present invention has a copper alloy reflective thin film 13 having a film thickness of 200 Å or more, preferably 500 Å or more and containing copper as a main component, formed on one side of a transparent substrate 12. 13 is equipped with means 16 and 17 for heating with electricity.
透明基板【２はガラス或いはプラスチックにより構成さ
れる。The transparent substrate [2 is made of glass or plastic.
銅合金反射薄膜１３は例えばＣｕ−Ｎｉ合金が好ましい
。The copper alloy reflective thin film 13 is preferably made of, for example, a Cu-Ni alloy.
通電加熱手段１６．１７は、銅合金反射薄膜１４の表面
の両側に固着した１対の電極１６．１６並びに各電極１
６に接続したリード線１７で構成される。The energization heating means 16.17 includes a pair of electrodes 16.16 fixed to both sides of the surface of the copper alloy reflective thin film 14 and each electrode 1.
It consists of a lead wire 17 connected to 6.
実施例 本発明者等は次の条件で本発明を実施した。Example The present inventors implemented the present invention under the following conditions.
（条件）
透明基板１２： 透明ガラス
銅合金反射薄膜１４： Ｃｕ Ｎｉ合金、Ｃｕ７０
％・Ｎｉ３０％（原子比率）。(Conditions) Transparent substrate 12: Transparent glass copper alloy reflective thin film 14: Cu Ni alloy, Cu70
%・Ni30% (atomic ratio).
膜厚６００人 電ｔ！６ 銀ペースト 電源電圧： １２Ｖ 結果は次のとおりてあった。Film thickness: 600 people Electric T! 6 Silver paste Power supply voltage: 12V The results were as follows.
（結果）
第２図に示すように自然光りを透明基板１２側から入射
させると、反射率は５５％を示した。これは前記自動車
後写鏡・規格値３８％以上を満足している。また、第３
図のＣＩＥ色度座標図に示すように、本実施例に相当す
る■は従来例に比較して十分農い色調のブロンズ色を呈
していることが分かる。第３図では反射薄膜１４のＣｕ
−Ｎｉ含打率を種々変化させた例■〜■を示しているが
、何れの場合も従来例と同程度若しくはより濃い色調で
あることを示している。尚、■〜■の何れの場合も反射
率は５０％以上である。尚又、ＣＩＥ色度座標図におい
ては、中心の印「＋」の部分は白色を表し、この部分よ
り離れるに従って色調か濃くなる。(Results) As shown in FIG. 2, when natural light was applied from the transparent substrate 12 side, the reflectance was 55%. This satisfies the standard value of 38% or more for automobile rear view mirrors. Also, the third
As shown in the CIE chromaticity coordinate diagram of the figure, it can be seen that the color (2) corresponding to this example exhibits a bronze color with a sufficiently dark tone compared to the conventional example. In FIG. 3, the reflective thin film 14 is made of Cu.
-Examples (1) to (2) are shown in which the Ni-containing batting percentage was variously changed, and in each case, the color tone is the same as or darker than the conventional example. In addition, the reflectance is 50% or more in any case of (1) to (2). Furthermore, in the CIE chromaticity coordinate diagram, the center mark "+" represents white, and the color tone becomes darker as the distance from this part increases.
室温２０℃下で通電加熱すると銅合金反射薄膜１４のシ
ート抵抗は４（Ω／ｓｑ）、電極両端の抵抗は８Ω、出
力は１８Ｗとなり、鏡面は６０°Ｃ以上になった。これ
は曇止めをするために十分な温度である。When heated with electricity at a room temperature of 20°C, the sheet resistance of the copper alloy reflective thin film 14 was 4 (Ω/sq), the resistance at both ends of the electrode was 8Ω, the output was 18W, and the mirror surface became 60°C or higher. This is a sufficient temperature to prevent fogging.
第４図に、上記原子比率のＣｕ−Ｎｉ合金反射薄膜を使
用した場合の膜厚とシート抵抗及び反射率との関係を示
している。この図より、鏡として充分な反射率（３８％
以上）を安定して得るためには、銅合金反射薄膜の膜厚
は２００Å以上好ましくは５００Å以上が必要であり、
この場合、シート抵抗は約ｌ〜５Ω／ｓｑの範囲で制御
できることが分かる。FIG. 4 shows the relationship between film thickness, sheet resistance, and reflectance when a Cu--Ni alloy reflective thin film having the above atomic ratio is used. From this figure, we can see that the reflectance is sufficient (38%) as a mirror.
In order to stably obtain the above), the thickness of the copper alloy reflective thin film needs to be 200 Å or more, preferably 500 Å or more,
In this case, it can be seen that the sheet resistance can be controlled within a range of about 1 to 5 Ω/sq.
本発明の作用・効果
本発明の前記構成においては、銅合金反射薄膜１４固有
の反射光のブロンズ色着色により十分濃いブロンズ色を
得ることができるとともに色のバラツキもほととんどな
い。また、銅合金反射薄膜１４一層であるため構造が簡
単で製造コストが低置となる。そして、通電加熱手段で
ある銅合金反射薄膜１４は防曇効果も十分である。Effects and Effects of the Present Invention In the above configuration of the present invention, a sufficiently deep bronze color can be obtained due to the bronze coloring of the reflected light unique to the copper alloy reflective thin film 14, and there is almost no variation in color. Furthermore, since the copper alloy reflective thin film 14 is a single layer, the structure is simple and the manufacturing cost is low. The copper alloy reflective thin film 14, which is the electrical heating means, also has a sufficient antifogging effect.
第１図は本発明の実施例に係るブロンズ色防曇鏡の裏面
図、第２図は第１図Ｂ−Ｂ’線断面図、第３図は本発明
の実施例と従来例との比較を示すＣＩＥ色度座標図、第
４図は銅合金反射薄膜と反射率及びシート抵抗との関係
を示すグラフ、第５図は従来例に係るブロンズ色防曇鏡
の裏面図、第６図は第５図Ａ−Ａ’線断面図である。
１１・・・ブロンズ色防曇鏡、 １２・・・透明基板
、１３・・・銅合金反射薄膜、 １６・・・電極、
１７・・・リード線。
１図
窮３図Fig. 1 is a back view of a bronze-colored anti-fog mirror according to an embodiment of the present invention, Fig. 2 is a sectional view taken along line B-B' in Fig. 1, and Fig. 3 is a comparison between an embodiment of the present invention and a conventional example. FIG. 4 is a graph showing the relationship between the copper alloy reflective thin film, reflectance, and sheet resistance. FIG. 5 is a back view of a conventional bronze-colored antifogging mirror. FIG. FIG. 5 is a sectional view taken along line A-A'. 11... Bronze color anti-fog mirror, 12... Transparent substrate, 13... Copper alloy reflective thin film, 16... Electrode,
17... Lead wire. Figure 1 Figure 3
Claims (1)
であってかつ、銅を主成分とする銅合金反射薄膜（１３
）を形成するとともに、銅合金反射薄膜（１３）を通電
加熱するための手段（１６、１７）を装着してなること
を特徴とするブロンズ色防曇鏡。(1) On one side of the transparent substrate (12), a copper alloy reflective thin film (13
) and is equipped with means (16, 17) for electrically heating the copper alloy reflective thin film (13).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13416886A JPS62289802A (en) | 1986-06-09 | 1986-06-09 | Bronze-colored antifogging mirror |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13416886A JPS62289802A (en) | 1986-06-09 | 1986-06-09 | Bronze-colored antifogging mirror |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62289802A true JPS62289802A (en) | 1987-12-16 |
Family
ID=15122037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13416886A Pending JPS62289802A (en) | 1986-06-09 | 1986-06-09 | Bronze-colored antifogging mirror |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62289802A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007181557A (en) * | 2006-01-06 | 2007-07-19 | Ryoko:Kk | Synthetic resin mirror |
-
1986
- 1986-06-09 JP JP13416886A patent/JPS62289802A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007181557A (en) * | 2006-01-06 | 2007-07-19 | Ryoko:Kk | Synthetic resin mirror |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4786784A (en) | Method for producing an electrically heated window assembly and resulting article | |
| US5099105A (en) | Electrically heated automobile glazing with electrically conductive decorative frame | |
| US5902505A (en) | Heat load reduction windshield | |
| JP2018123053A (en) | Pane having electric heating layer and production method thereof | |
| US4878743A (en) | Automotive mirror using electrochromic element | |
| US4546050A (en) | Coated glass article as a new article of manufacture | |
| JP2007512218A (en) | Transparent substrates that can be used alternatively or progressively for thermal control, electromagnetic shielding, and heating windows | |
| JP2009502703A (en) | Heatable windshield | |
| JP2003507305A (en) | Window glass | |
| US4778732A (en) | Electrically conductive glass sheet | |
| EP0673590A1 (en) | Sunlight viewable thin film electroluminescent display having darkened metal electrodes | |
| JPH11116280A (en) | Transparent base having transparent low-resistance coating | |
| JPS62289802A (en) | Bronze-colored antifogging mirror | |
| JPH07125575A (en) | Electronic control glare-proof mirror | |
| JPH0515242B2 (en) | ||
| JPH09207723A (en) | Heater for defogging and defrosting of mirror for vehicle and its manufacture | |
| JPH0640746A (en) | Window glass for automobile | |
| JPH02151838A (en) | Fully solid-state electrochromic element | |
| JPH0517061B2 (en) | ||
| JPS6053448A (en) | Light permeable film heater | |
| CN112677586B (en) | Heatable light-adjusting glass and preparation method thereof | |
| JPS6047745A (en) | Outside mirror for automobile | |
| JPH0682840A (en) | Antidazzle mirror | |
| JPH08293379A (en) | Transparent laminated body | |
| US20230065516A1 (en) | Method for busbar hiding of a laminated glazing |