JPS6228381B2 - - Google Patents
Info
- Publication number
- JPS6228381B2 JPS6228381B2 JP4625279A JP4625279A JPS6228381B2 JP S6228381 B2 JPS6228381 B2 JP S6228381B2 JP 4625279 A JP4625279 A JP 4625279A JP 4625279 A JP4625279 A JP 4625279A JP S6228381 B2 JPS6228381 B2 JP S6228381B2
- Authority
- JP
- Japan
- Prior art keywords
- freon
- frozen
- ethylene glycol
- brine
- freezing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000007710 freezing Methods 0.000 claims description 9
- 230000008014 freezing Effects 0.000 claims description 9
- 239000012267 brine Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 27
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 for example Chemical compound 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Heat Treatment Of Articles (AREA)
Description
【発明の詳細な説明】
この発明は、冷凍液を経済的に使用できるよう
にした冷凍方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a freezing method that allows economical use of freezing fluid.
被冷凍物を−30度以下の冷凍液中に浸漬して凍
結せしめるときに使用する冷凍液には、塩化カル
シウム、メタノール、メチレンクロライド、エチ
レングリコール、トリクロロエチレン、フレオン
11等があるが、危険性とか、これらの冷凍液を入
れたタンクの腐蝕性等の点から考慮すると、エチ
レングリコールまたはフレオン11が望ましい冷凍
液となる。 The freezing liquid used when freezing items by immersing them in freezing liquid at -30 degrees or below contains calcium chloride, methanol, methylene chloride, ethylene glycol, trichloroethylene, and freon.
11, etc., but ethylene glycol or Freon 11 is preferable from the viewpoint of danger and corrosiveness of tanks containing these refrigeration liquids.
しかし、エチレングリコールは沸点が105℃位
で、常温では殆ど蒸発しないという利点がある
が、−30℃以下になると粘度が非常に大となり、
ために熱交換効率が低下するという欠点がある。
これに反し、フレオン11は、沸点が23.7℃と低い
が、−30℃以下でも粘度が小で、熱交換効率の低
下を来たすことがないという利点がある。 However, ethylene glycol has a boiling point of around 105℃, and although it has the advantage of hardly evaporating at room temperature, it becomes very viscous at temperatures below -30℃.
Therefore, there is a drawback that heat exchange efficiency decreases.
On the other hand, Freon 11 has a low boiling point of 23.7°C, but has the advantage that it has a small viscosity even below -30°C and does not cause a decrease in heat exchange efficiency.
本発明は、エチレングリコールとフレオン11と
の長短を利用し、しかもエチレングリコールの比
重は1.093とフレオン11の比重1.608よりも小なる
点にも着目して、蒸発しにくく、かつ低温にて効
果的に冷凍できる方法を提供できるようにした。 The present invention takes advantage of the advantages and disadvantages of ethylene glycol and Freon 11, and also focuses on the fact that ethylene glycol has a specific gravity of 1.093, which is lower than Freon 11's specific gravity of 1.608, making it difficult to evaporate and effective at low temperatures. We are now able to provide a method for freezing food.
しかして本発明の冷凍方法は、被冷凍物を入れ
た容器４を、タンク１内のフレオン系ブライン３
の液面上にエチレン系ブライン層２を形成した前
記フレオン系ブライン内へ浸漬して被冷凍物を凍
結せしめることを特徴とする。 Therefore, in the freezing method of the present invention, the container 4 containing the object to be frozen is transferred to the Freon brine 3 in the tank 1.
The object to be frozen is frozen by being immersed in the Freon brine having an ethylene brine layer 2 formed on the liquid surface thereof.
本発明の方法は、被冷凍物を入れた容器、例え
ここで、エチレン系ブラインにはエチレングリ
コールが、フレオン系ブラインにはフレオン11が
好適であり、フレオン11の温度は−30℃以下であ
る。 In the method of the present invention, a container containing an object to be frozen, e.g. .
上述した本発明においては、被冷凍物（例えば
水）を入れた容器４（例えばパイプ）をフレオン
系ブライン、例えばフレオン11のブライン中に浸
漬して被冷凍物たる水を凍結せしめるが、−30℃
以下であつても粘度が大となることのない反面、
沸点が23.7℃と低いフレオン11の液面は、エチレ
ン系の例えば沸点が105℃位と高いエチレングリ
コール層３によつて覆われているので、フレオン
11の蒸発はエチレングリコールによつて妨げられ
る。 In the present invention described above, the container 4 (e.g., a pipe) containing the object to be frozen (e.g., water) is immersed in Freon-based brine, for example, Freon 11 brine to freeze the object to be frozen, water. ℃
On the other hand, the viscosity does not become large even if the
The liquid surface of Freon 11, which has a low boiling point of 23.7°C, is covered with an ethylene-based ethylene glycol layer 3, which has a high boiling point of about 105°C.
Evaporation of 11 is inhibited by ethylene glycol.
しかもフレオン11は−30℃以下の低温でも粘度
が大となることはないので、熱交換効率が低下す
ることはなく、容器４内の被冷凍物を効果的に凍
結できる。 Moreover, since Freon 11 does not have a large viscosity even at low temperatures of −30° C. or lower, the heat exchange efficiency does not decrease, and the object to be frozen in the container 4 can be effectively frozen.
また、フレオンはエチレングリコールによつて
液面がカバーされているので、フレオンの蒸発は
阻止され、したがつてタンク１は密閉製のもので
ある必要はなく、開放タンクでよくて、常圧下で
の開放タンクで作業性に優れた冷凍を行える。 In addition, since the liquid surface of Freon is covered with ethylene glycol, evaporation of Freon is prevented.Therefore, the tank 1 does not need to be a sealed one, and an open tank may be sufficient. The open tank allows for highly efficient refrigeration.
しかもフレオンは前記のごとく蒸発を阻止され
ているので、蒸発するものと異なつて頻繁にフレ
オンを補充する必要はなく、被冷凍物に付着して
取去られた消耗分だけ補充すればよいことと、フ
レオンは加熱されることがなくして変質による老
化ということも殆どないこととから永年使用に供
することができ、高価なフレオンは節約できて経
済的な冷凍を行えるという作用、効果を奏しうる
利点がある。 Moreover, since Freon is prevented from evaporating as mentioned above, unlike Freon that evaporates, there is no need to replenish Freon frequently, and only the amount of Freon that has adhered to the object to be frozen and has been removed can be replenished. Since Freon is not heated and there is almost no aging due to deterioration, it can be used for many years, and expensive Freon can be saved and economical refrigeration can be performed. There is.
なお、本発明は、例えばエンジン用排気管など
の各種パイプを冷間加工する際に好適であり、パ
イプに、本発明によつて凍結せしめた後曲げ加工
等を施す。 The present invention is suitable for cold working various types of pipes such as engine exhaust pipes, and the pipes are subjected to bending work after being frozen according to the present invention.
また、容器たるパイプは単管に限らず、各管内
に被冷凍物たる水を入れた２重管その他の多重管
とするばあいもある。 Further, the pipe serving as the container is not limited to a single pipe, but may be a double pipe or other multiple pipes in which each pipe contains water, which is the object to be frozen.
第１図は本発明方法を実施するための冷凍装置
の一例を示す図である。
図中、１…タンク、２…エチレングリコール
層、３…フレオン11の液、４…被凍結物。
FIG. 1 is a diagram showing an example of a refrigeration apparatus for carrying out the method of the present invention. In the figure, 1...Tank, 2...Ethylene glycol layer, 3...Freon 11 liquid, 4...Object to be frozen.
Claims (1)
ン系ブラインの液面上にエチレン系ブライン層を
形成した前記フレオン系ブライン内へ浸漬して被
冷凍物を凍結せしめることを特徴とする冷凍方
法。1. A freezing method characterized by freezing the object by immersing a container containing the object to be frozen into the Freon brine in which an ethylene brine layer is formed on the liquid surface of the Freon brine in a tank. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4625279A JPS55137465A (en) | 1979-04-16 | 1979-04-16 | Refrigerator method and apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4625279A JPS55137465A (en) | 1979-04-16 | 1979-04-16 | Refrigerator method and apparatus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55137465A JPS55137465A (en) | 1980-10-27 |
| JPS6228381B2 true JPS6228381B2 (en) | 1987-06-19 |
Family
ID=12741974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4625279A Granted JPS55137465A (en) | 1979-04-16 | 1979-04-16 | Refrigerator method and apparatus |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55137465A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0512956Y2 (en) * | 1987-09-08 | 1993-04-05 | ||
| JPH0621173U (en) * | 1992-03-13 | 1994-03-18 | 富士通テン株式会社 | Connector structure |
-
1979
- 1979-04-16 JP JP4625279A patent/JPS55137465A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0512956Y2 (en) * | 1987-09-08 | 1993-04-05 | ||
| JPH0621173U (en) * | 1992-03-13 | 1994-03-18 | 富士通テン株式会社 | Connector structure |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55137465A (en) | 1980-10-27 |
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