JPS6227351B2 - - Google Patents
Info
- Publication number
- JPS6227351B2 JPS6227351B2 JP56127630A JP12763081A JPS6227351B2 JP S6227351 B2 JPS6227351 B2 JP S6227351B2 JP 56127630 A JP56127630 A JP 56127630A JP 12763081 A JP12763081 A JP 12763081A JP S6227351 B2 JPS6227351 B2 JP S6227351B2
- Authority
- JP
- Japan
- Prior art keywords
- heat storage
- storage tank
- heat
- wall
- storage material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005338 heat storage Methods 0.000 claims description 55
- 239000011232 storage material Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 230000035699 permeability Effects 0.000 claims description 3
- 239000012466 permeate Substances 0.000 claims 1
- 230000001568 sexual effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- -1 Polyfluoroethylene Polymers 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Building Environments (AREA)
- Thermotherapy And Cooling Therapy Devices (AREA)
Description
【発明の詳細な説明】
本発明は、無機水化物を含有する蓄熱材を収納
する蓄熱槽に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heat storage tank containing a heat storage material containing an inorganic hydrate.
一般的に蓄熱材には、物質の顕熱を利用したも
のと、潜熱を利用したものとが知られている。潜
熱を利用した蓄熱材は、顕熱を利用した蓄熱材に
比較して、単位重量当り、また単位体積当りの蓄
熱量が大きく、必要量の熱を蓄熱しておくのに少
量の蓄熱材でよく、そのため蓄熱装置を小型化す
ることができる。潜熱を利用した蓄熱材は、顕熱
を利用した蓄熱材のように、放熱とともに温度が
低下してしまわずに、転移点において一定温度の
熱を放熱するという特徴を有する。特に無機水化
物の融解潜熱を利用した蓄熱材は、単位体積当り
の蓄熱量の大きなことが知られている。 In general, there are two types of heat storage materials: those that utilize the sensible heat of substances and those that utilize latent heat. Heat storage materials that use latent heat have a larger amount of heat storage per unit weight and unit volume than heat storage materials that use sensible heat, and require only a small amount of heat storage material to store the required amount of heat. Therefore, the heat storage device can be downsized. A heat storage material that uses latent heat has the characteristic that, unlike a heat storage material that uses sensible heat, the temperature does not drop as heat is released, and instead radiates heat at a constant temperature at a transition point. In particular, heat storage materials that utilize the latent heat of fusion of inorganic hydrates are known to have a large amount of heat storage per unit volume.
ところが、無機水化物およびこれらの混合物
は、その中の水分が蒸発する風解性または水分を
吸収する潮解性を有し、さらに水分蒸発量は温度
の上昇とともに増加する。このために、蓄熱槽は
密閉構造として、水分の出入を避けなければなら
なかつた。 However, inorganic hydrates and mixtures thereof have efflorescence properties in which water in them evaporates or deliquescent properties in which they absorb water, and the amount of water evaporation increases as the temperature rises. For this reason, the heat storage tank had to have a sealed structure to prevent moisture from entering and exiting.
しかし、蓄熱槽を密閉構造とすれば、蓄熱材の
収納に不便が生ずるだけでなく、生産コストの上
昇にもつながるという実用上の欠点がある。ま
た、完全な密閉構造にすれば、温度による内部の
気体の膨張などに起因する爆発の危険性もあり、
保安上の問題点もあつた。 However, if the heat storage tank has a sealed structure, there are practical drawbacks in that it not only causes inconvenience in storing the heat storage material, but also leads to an increase in production costs. Additionally, if the structure is completely sealed, there is a risk of explosion due to expansion of internal gas due to temperature.
There were also security issues.
本発明は、水分の蒸発や吸収による蓄熱材の劣
化がおこらない安価で、安全性の高い蓄熱槽を提
供するものである。この蓄熱槽の特徴は、その少
なくとも一部分にガス透過性が良好で水分を通し
にくい物質を構成した半透性部を設けた点にあ
る。このような半透性を有する物質としてはポリ
フツ化エチレン樹脂が知られている。 The present invention provides an inexpensive and highly safe heat storage tank in which the heat storage material does not deteriorate due to evaporation or absorption of moisture. A feature of this heat storage tank is that at least a portion thereof is provided with a semipermeable portion made of a material that has good gas permeability and does not easily allow moisture to pass through. Polyfluorinated ethylene resin is known as a material having such semipermeability.
ポリフツ化エチレン樹脂は、吸水率0.00%、透
湿率0.06g/m2・dayと非常に小さく、空気を容
易に通過させるという特性を有し、最適な材料の
一つである。 Polyfluoroethylene resin has a very low water absorption rate of 0.00% and a moisture permeability rate of 0.06 g/m 2 ·day, and has the characteristics of allowing air to pass through easily, making it one of the most suitable materials.
以下、本発明の蓄熱槽について詳細に説明す
る。 Hereinafter, the heat storage tank of the present invention will be explained in detail.
図は本発明の蓄熱槽の一実施例を示す断面図で
ある。 The figure is a sectional view showing an embodiment of the heat storage tank of the present invention.
図において、1は空気を容易に通し、水蒸気を
通しにくい物質からなる半透性部、2は蓄熱槽壁
部、3は蓄熱槽内部に収納されている無機水化物
系蓄熱材、4は蓄熱槽内部の空気である。 In the figure, 1 is a semipermeable part made of a substance that allows air to pass through easily but water vapor does not easily pass through, 2 is a wall of the heat storage tank, 3 is an inorganic hydrate-based heat storage material stored inside the heat storage tank, and 4 is a heat storage material. This is the air inside the tank.
無機水化物系蓄熱材として暖戻用蓄熱材を用い
た場合を例に、この蓄熱槽の原理を説明する。ま
ず蓄熱時蓄熱材3を加熱し、融解させる。この融
解時に、蓄熱材3の体積は融解に伴つて大きくな
り、また蓄熱材が液体になることによつて水蒸気
圧も高くなる。さらに蓄熱槽内の空気も当然加熱
されるため膨張する。そのため、蓄熱槽の少なく
とも一部分に、上述のような半透性部が設けられ
ていない場合には、蓄熱槽内部が高圧になり、さ
らに、異常に加熱されたような場合には、爆発の
危険性もある。しかし、この実施例では、図に示
したように、蓄熱槽の一部分に半透性部1を設け
ているので、空気に関しては、蓄熱槽の内部と外
部とはつながつているため、蓄熱槽内部の圧力は
周囲と同じ圧力になり、そのため蓄熱槽内に異常
に高い圧力が発生するようなことはなく、蓄熱槽
にかかる荷重が密閉型の蓄熱槽に比較して大幅に
低減される。さらに、本発明の蓄熱槽では、内部
の水蒸気が密閉されることになり、蓄熱、放熱を
繰り返しても、蓄熱槽内の水分量は一定に保たれ
るため、水分の蒸散や吸収による蓄熱材の劣化が
なく、蓄熱材はきわめて安定に機能する。 The principle of this heat storage tank will be explained by taking as an example a case where a warming heat storage material is used as an inorganic hydrate-based heat storage material. First, during heat storage, the heat storage material 3 is heated and melted. At the time of this melting, the volume of the heat storage material 3 increases as it melts, and the water vapor pressure also increases as the heat storage material becomes liquid. Furthermore, the air in the heat storage tank is naturally heated and expands. Therefore, if at least a portion of the heat storage tank is not provided with a semi-permeable part as described above, the inside of the heat storage tank will be under high pressure, and if it is heated abnormally, there is a risk of explosion. There is also gender. However, in this embodiment, as shown in the figure, since the semi-permeable part 1 is provided in a part of the heat storage tank, the inside and outside of the heat storage tank are connected with respect to air, so the inside of the heat storage tank is The pressure in the heat storage tank is the same as the surrounding pressure, so there is no abnormally high pressure inside the heat storage tank, and the load on the heat storage tank is significantly reduced compared to a closed type heat storage tank. Furthermore, in the heat storage tank of the present invention, the water vapor inside is sealed, and even if heat storage and heat radiation are repeated, the amount of moisture in the heat storage tank is kept constant. There is no deterioration, and the heat storage material functions extremely stably.
なお、空気は容易に通すが、水蒸気は通しにく
い物質としては、前述したポリフツ化エチレン樹
脂が好適であるが、空気は容易に通すが、水蒸気
は通しくいという機能を有する物質であれば、使
用することができる。 The above-mentioned polyfluorinated ethylene resin is suitable as a material that allows air to pass through easily but does not allow water vapor to pass through, but any material that has the function of allowing air to pass through easily but preventing water vapor from passing through may be used. can do.
また、上記実施例では、空気は容易に通すが、
水分は通しにくい半透性部を蓄熱槽上部に1個設
けた場合について示したが、この部分の大きさや
数、さらに形状や位置が、水分の蒸散や吸収を防
ぐ目的に合致していさえすれば、任意でよいのは
言うまでもない。また、実際に使用するにあつて
は、蓄熱槽壁は、内壁と外壁の間に断熱物質など
を介在させた構造とする。したがつて、半透性部
が内壁または外壁のいずれか一方に設けてあつて
もよいのは勿論である。 In addition, in the above embodiment, air can easily pass through, but
We have shown the case where one semi-permeable part, which is difficult for moisture to pass through, is provided at the top of the heat storage tank, but as long as the size, number, shape, and position of this part match the purpose of preventing moisture evaporation and absorption. Needless to say, it can be optional. Furthermore, in actual use, the heat storage tank wall has a structure in which a heat insulating material or the like is interposed between the inner wall and the outer wall. Therefore, it goes without saying that the semi-permeable portion may be provided on either the inner wall or the outer wall.
以上のように、本発明の蓄熱槽は、その一部分
が空気を容易に通すものの、水蒸気を通しにくい
物質から半透性部で構成されているため、比較的
簡単な構造で、水分の蒸散や吸入による蓄熱材の
劣化が防止され、結果として、安価で安全性の高
いものである。 As described above, the heat storage tank of the present invention has a relatively simple structure and has a relatively simple structure that prevents water evaporation. Deterioration of the heat storage material due to inhalation is prevented, and as a result, it is inexpensive and highly safe.
図は本発明の一実施例の蓄熱槽の断面図であ
る。
1……半透性部、2……蓄熱槽壁部、3……蓄
熱材、4……空気。
The figure is a sectional view of a heat storage tank according to an embodiment of the present invention. 1... Semi-permeable part, 2... Heat storage tank wall, 3... Heat storage material, 4... Air.
Claims (1)
部の少なくとも一部分にガス通気性は良好である
が、水分は透過しにくい物質を用いて構成された
半透性部を有することを特徴とする蓄熱槽。 2 半透性部がポリフツ化エチレン樹脂で構成さ
れていることを特徴とする特許請求の範囲第1項
に記載の蓄熱槽。[Scope of Claims] 1. A semi-transparent wall that houses a heat storage material mainly composed of inorganic hydrate, and that has good gas permeability in at least a portion of the wall, but is made of a material that is difficult for moisture to permeate. A heat storage tank characterized by having a sexual part. 2. The heat storage tank according to claim 1, wherein the semipermeable portion is made of polyfluorinated ethylene resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56127630A JPS5828988A (en) | 1981-08-13 | 1981-08-13 | Heat accumulator |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56127630A JPS5828988A (en) | 1981-08-13 | 1981-08-13 | Heat accumulator |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5828988A JPS5828988A (en) | 1983-02-21 |
JPS6227351B2 true JPS6227351B2 (en) | 1987-06-13 |
Family
ID=14964835
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56127630A Granted JPS5828988A (en) | 1981-08-13 | 1981-08-13 | Heat accumulator |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5828988A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6349549U (en) * | 1986-09-19 | 1988-04-04 | ||
JPS6349551U (en) * | 1986-09-19 | 1988-04-04 | ||
JPS6349550U (en) * | 1986-09-19 | 1988-04-04 | ||
JPH01270071A (en) * | 1988-04-22 | 1989-10-27 | Ricoh Co Ltd | Operation display controller for copying machine |
CN101963468A (en) * | 2009-07-24 | 2011-02-02 | J·埃贝斯佩歇合资公司 | Latent heat storage and process for manufacturing same |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2014020663A (en) * | 2012-07-18 | 2014-02-03 | Denso Corp | Cold storage heat exchanger |
JP6434867B2 (en) * | 2015-06-30 | 2018-12-05 | 東邦瓦斯株式会社 | Heat storage material filling container and heat storage tank |
-
1981
- 1981-08-13 JP JP56127630A patent/JPS5828988A/en active Granted
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6349549U (en) * | 1986-09-19 | 1988-04-04 | ||
JPS6349551U (en) * | 1986-09-19 | 1988-04-04 | ||
JPS6349550U (en) * | 1986-09-19 | 1988-04-04 | ||
JPH01270071A (en) * | 1988-04-22 | 1989-10-27 | Ricoh Co Ltd | Operation display controller for copying machine |
CN101963468A (en) * | 2009-07-24 | 2011-02-02 | J·埃贝斯佩歇合资公司 | Latent heat storage and process for manufacturing same |
Also Published As
Publication number | Publication date |
---|---|
JPS5828988A (en) | 1983-02-21 |
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