JPS62271857A - Protective material - Google Patents
Protective materialInfo
- Publication number
- JPS62271857A JPS62271857A JP10678686A JP10678686A JPS62271857A JP S62271857 A JPS62271857 A JP S62271857A JP 10678686 A JP10678686 A JP 10678686A JP 10678686 A JP10678686 A JP 10678686A JP S62271857 A JPS62271857 A JP S62271857A
- Authority
- JP
- Japan
- Prior art keywords
- protective material
- rust
- substance
- sheet
- impregnated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims description 37
- 230000001681 protective effect Effects 0.000 title claims description 14
- 239000000126 substance Substances 0.000 claims description 21
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 19
- 229920005992 thermoplastic resin Polymers 0.000 claims description 9
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- 230000003449 preventive effect Effects 0.000 claims description 5
- 238000005470 impregnation Methods 0.000 claims description 4
- 239000000077 insect repellent Substances 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims description 3
- 239000002781 deodorant agent Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims 1
- 230000002265 prevention Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- ZFAKTZXUUNBLEB-UHFFFAOYSA-N dicyclohexylazanium;nitrite Chemical compound [O-]N=O.C1CCCCC1[NH2+]C1CCCCC1 ZFAKTZXUUNBLEB-UHFFFAOYSA-N 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- WUGCLPOLOCIDHW-UHFFFAOYSA-N 2-aminoethanol;benzoic acid Chemical compound [NH3+]CCO.[O-]C(=O)C1=CC=CC=C1 WUGCLPOLOCIDHW-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- RIBMRDXQOWISQN-UHFFFAOYSA-N cyclohexanamine;cyclohexanecarboxylic acid Chemical compound NC1CCCCC1.OC(=O)C1CCCCC1 RIBMRDXQOWISQN-UHFFFAOYSA-N 0.000 description 1
- FNPGYAQZEUKTCV-UHFFFAOYSA-N cyclohexanamine;prop-2-enoic acid Chemical compound OC(=O)C=C.NC1CCCCC1 FNPGYAQZEUKTCV-UHFFFAOYSA-N 0.000 description 1
- CIFYUXXXOJJPOL-UHFFFAOYSA-N cyclohexylazanium;benzoate Chemical compound [NH3+]C1CCCCC1.[O-]C(=O)C1=CC=CC=C1 CIFYUXXXOJJPOL-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- QNNPHOLOYSXYNU-UHFFFAOYSA-N dicyclohexylazanium;benzoate Chemical compound OC(=O)C1=CC=CC=C1.C1CCCCC1NC1CCCCC1 QNNPHOLOYSXYNU-UHFFFAOYSA-N 0.000 description 1
- CYYRAVBQFCQGFE-UHFFFAOYSA-N dicyclohexylazanium;prop-2-enoate Chemical compound [O-]C(=O)C=C.C1CCCCC1[NH2+]C1CCCCC1 CYYRAVBQFCQGFE-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000005001 laminate film Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 ３、発明の詳細な説明 ［発明の目的］ （産業上の利用分野） この発明は、物品包装用の保護材に関する。[Detailed description of the invention] 3. Detailed description of the invention [Purpose of the invention] (Industrial application field) The present invention relates to a protective material for packaging articles.
（従来の技術）
例えば機械部品等を梱包し、輸送、保管する場合、それ
ら部品に錆が発生するという問題があった。そこで従来
は、部品そのものに防錆油を塗布したり、気化性防錆紙
で梱包したりしていた。(Prior Art) For example, when mechanical parts and the like are packaged, transported, and stored, there is a problem in that the parts rust. Conventionally, the parts themselves were coated with anti-rust oil or wrapped in volatile anti-rust paper.
しかし前者の対策では防錆油が直接部品に付着するため
、使用する際に必ず洗浄しなければならないという不便
さがあり、また後者の対策では、防錆剤が周囲に拡散す
るため、効果が長く保たれず、不十分であった。さらに
、外部からの湿気の浸入に対しても、十分対応できない
問題があった。However, with the former measure, the rust preventive oil adheres directly to the parts, which is inconvenient as they must be cleaned before use, and with the latter measure, the rust preventive oil spreads into the surrounding area, making it ineffective. It was not maintained for long and was insufficient. Furthermore, there was a problem in that it was not possible to adequately deal with the infiltration of moisture from the outside.
（発明が解決しようとする問題点）
上記のように従来の防錆対策では、防錆油の洗浄の手間
がかかる不便さや、防錆効果が十分長く保てない問題が
あった。(Problems to be Solved by the Invention) As described above, the conventional rust prevention measures have the inconvenience of having to clean the rust prevention oil and the problem that the rust prevention effect cannot be maintained for a sufficiently long time.
この発明は、このような従来の問題を解決するもので、
気化性物質の防錆、防虫、あるいは消臭効果を長期間に
亘って持続できる保護材を提供することを目的とする。This invention solves these conventional problems.
The purpose of the present invention is to provide a protective material that can maintain the rust-proofing, insect-proofing, and deodorizing effects of volatile substances over a long period of time.
［発明の構成］
（問題点を解決するための手段）
この発明の保護材は、熱可塑性含浸用組材に熱可塑性樹
脂フィルムをラミネートしたシート状基材に気化性物質
を含浸させたものであ゛る。[Structure of the Invention] (Means for Solving the Problems) The protective material of the present invention is a sheet-like base material obtained by laminating a thermoplastic resin film on a thermoplastic impregnation assembly and impregnated with a vaporizable substance. Aaru.
（作用）
この発明の保護材では、気化性物質の含浸されている熱
可塑性含浸用組材を内側にして、物品を包装し、あるい
はヒートシールによって袋体にして物品を収容すること
により、気化性物質の防錆、防虫、あるいは消臭剤とし
ての本来の効果を長期に亘って発揮させるものである。(Function) In the protective material of the present invention, the article is packaged with the thermoplastic impregnated assembly material impregnated with the vaporizable substance inside, or the article is housed in a bag by heat sealing. This allows the substance to exhibit its original effects as a rust preventive, insect repellent, or deodorant over a long period of time.
（実施例）
以下、この発明の実施例を図に基づいて詳説する。図に
示すように、保護材は熱可塑性含浸用組材１に熱可塑性
樹脂フィルム３をラミネートしたシート状基材５に対し
、気化性物質を含浸、乾燥させて成るものである。(Example) Hereinafter, an example of the present invention will be explained in detail based on the drawings. As shown in the figure, the protective material is made by impregnating a sheet-like base material 5 in which a thermoplastic resin film 3 is laminated onto a thermoplastic impregnating assembly 1 with a vaporizable substance and drying the same.
熱可塑性含浸用組材１には、ナイロン、ポリエステル、
ポリエチレンのような熱可塑性樹脂の不織布や織布が用
いられる。The thermoplastic impregnation material 1 includes nylon, polyester,
Nonwoven or woven fabrics made of thermoplastic resin such as polyethylene are used.
熱可塑性樹脂フィルム３は、前記熱可塑性含浸用組材１
に対してラミネートできる素材であれば良くて、例えば
ナイロン、ポリエステル、ポリエチレン等が用いられる
。The thermoplastic resin film 3 is the thermoplastic impregnated assembly material 1
Any material can be used as long as it can be laminated to the material, such as nylon, polyester, polyethylene, etc.
気化性物質は、気化性又は昇華性の物質であり、機械部
品や電子部品の防錆を目的とするときには、例えばモノ
エタノールアミンベンゾエート、ジシクロヘキシルアン
モニウムベンゾエート、シクロヘキシルアミンベンゾエ
ート、シクロヘキシルアミンシクロヘキシルカルボキシ
レート
ヘキシルアンモニウムサリチレート、ジシクロヘキシル
アンモニウムシクロヘキシルカルポキシレート，ジシク
ロヘキシルアミンアクリレート、シクロヘキシルアミン
アクリレート、ベンゾトリアゾール、ジシクロヘキシル
アンモニウムナイトライト等の防錆剤が用いられる。The vaporizable substance is a vaporizable or sublimable substance, and when the purpose is to prevent rust of mechanical parts or electronic parts, for example, monoethanolamine benzoate, dicyclohexylammonium benzoate, cyclohexylamine benzoate, cyclohexylamine cyclohexyl carboxylate hexylammonium Rust inhibitors such as salicylate, dicyclohexylammonium cyclohexylcarpoxylate, dicyclohexylamine acrylate, cyclohexylamine acrylate, benzotriazole, and dicyclohexylammonium nitrite are used.
また気化性物質として、殺虫又は防虫を目的とする場合
には、樟脳、ナフタレン、パラジクロルベンゼン等の防
虫剤や殺虫剤が適宜用いられる。Further, as the vaporizable substance, when the purpose is to kill or repel insects, insect repellents and insecticides such as camphor, naphthalene, and paradichlorobenzene are appropriately used.
さらに消臭を目的とする場合には、芳香族炭化水素系の
気化性芳香剤が適宜に用いられる。Further, when the purpose is deodorization, an aromatic hydrocarbon-based volatile aromatic agent is appropriately used.
保護材の製造に際しては、まず気化性物質の含浸液槽中
に組材１を連続的に通して気化性物質を含浸させ、その
後、乾燥室に通して組材１の含浸剤を乾燥させる。In manufacturing the protective material, first, the assembly 1 is continuously passed through a vaporizable substance impregnating liquid tank to be impregnated with the vaporizable substance, and then passed through a drying chamber to dry the impregnating agent in the assembly 1.
続いて、この気化性物質の含浸、乾燥された組材１に対
して熱可塑性樹脂フィルム３を熱圧着してラミネートす
る。Subsequently, a thermoplastic resin film 3 is thermocompression bonded to the assembled material 1 which has been impregnated with the vaporizable substance and dried to be laminated.
このラミネート処理の際、図に示すようにエンボスロー
ルにより両シート材１，３に熱圧着部７を形成すると、
両者の結合は強固なものにできる。During this lamination process, as shown in the figure, if a thermocompression bonding part 7 is formed on both sheet materials 1 and 3 using an embossing roll,
The bond between the two can be made stronger.
このようにして製造されたシート状の保護材は、直接に
シート材として物品の包装に用いることができる。また
、ヒートシール処理により袋体に形成し、物品の収容後
、開口部もヒートシールするならば、物品を完全に密封
することができる。The sheet-like protective material produced in this manner can be used directly as a sheet material for packaging articles. Moreover, if the bag is formed by heat-sealing and the opening is also heat-sealed after storing the article, the article can be completely sealed.
このようにして、物品を包装、あるいは密封するとき、
ラミネートした外側の熱可塑性樹脂フィルム３が内外の
通気を遮断し、内部の組材１中に含浸されている気化性
物質が外部に拡散することがなく、内部の物品に対して
のみ長時間、防錆、防虫あるいは消臭の効果を発揮する
。When packaging or sealing items in this way,
The laminated outer thermoplastic resin film 3 blocks ventilation between the inside and outside, preventing the vaporizable substances impregnated into the inner assembly 1 from diffusing to the outside, and allowing only the inner articles to be exposed for a long time. Demonstrates rust-proofing, insect-proofing, and deodorizing effects.
また特に、防錆を目的とする気化性物質を用いている場
合、ラミネートフィルム３が外部からの湿気の浸入を防
止するため、防錆効果を一層高めることができる。In particular, when a volatile substance is used for the purpose of rust prevention, the laminate film 3 prevents moisture from entering from the outside, so that the rust prevention effect can be further enhanced.
次に、気化性物質として防錆剤を用いた保護材について
、その防錆効果を試した実験例を示す。Next, an experimental example will be shown in which the antirust effect of a protective material using a rust preventive agent as a volatile substance was tested.
（実施例１）
スパンボンドＥ５０３０ （材質ポリエステル、厚さ０
．１６ｍｍ，旭化成工業株式会社製）の不織布の片面に
２０μのポリエチレンフィルムをラミネートしたシート
状基材に、ジシクロヘキシルアンモニウムナイトライト
を２．１（１／＋１１２の割合で含浸した保護材で、２
０ｃｍｘ １ ０ｃｍの袋を作った． （実施例
２）
実施例１と同じシート状基材に対し、ベンゾトリアゾー
ルを２．１／ｍ２の割合で含浸したもので、２ ０ｃｍ
ｘ １ ０ｃｍの袋を作った。(Example 1) Spunbond E5030 (Material: Polyester, Thickness: 0
．． A protective material impregnated with dicyclohexylammonium nitrite at a ratio of 2.1 (1/+112) on a sheet-like base material made by laminating a 20 μm polyethylene film on one side of a 16 mm nonwoven fabric (manufactured by Asahi Kasei Corporation).
I made a bag measuring 0cm x 10cm. (Example 2) The same sheet-like base material as in Example 1 was impregnated with benzotriazole at a ratio of 2.1/m2.
I made a bag of x10cm.
（実施例３）
スパンボンドＮ５０３０ （材質ナイロン、厚さ０．１
６ｍｍ、旭化成工業株式会社製）の不織布の片面に２０
μのポリエチレンフィルムをラミネートシたシート状基
材に、ジシクロヘキシルアンモニウムナイトライトを２
．１ｏ／ｍ２の割合で含浸したもので、２０ｃｍｘ １
Ｑｃｍの袋を作った。(Example 3) Spunbond N5030 (Material: nylon, thickness: 0.1
20 on one side of a nonwoven fabric of 6 mm (manufactured by Asahi Kasei Corporation).
Two dicyclohexylammonium nitrites were applied to a sheet-like base material laminated with μ polyethylene film.
．． Impregnated at a rate of 1o/m2, 20cm x 1
I made a Qcm bag.
（実施例４）
実施例３と同じシート状基材に対し、シクロヘキシルア
ミンシクロヘキサンカルボキシレートを２．１９／ｍ２
の割合で含浸したもので、２゜ｃ＋ｎｘ１ｏｃｍの袋を
作った。(Example 4) Cyclohexylamine cyclohexane carboxylate was added at 2.19/m2 to the same sheet-like base material as in Example 3.
A bag of 2°C + n x 1ocm was made by impregnating it at the ratio of
（比較例１）
実施例１と同材質のシート状基材で、同サイズの袋を作
った。(Comparative Example 1) A bag of the same size as in Example 1 was made using the same sheet-like base material.
（比較例２）
実施例３と同材質のシート状基材で、同サイズの袋を作
った。(Comparative Example 2) A bag of the same size as in Example 3 was made using the same sheet-like base material.
（試験方法）
２０℃、９５ＲＨ％に調整された槽内に上記各個の袋を
２４時間静置しておき、その後、多装に脱脂処理済みの
テストピース（１５０ｘ７０ｘＱ、８ｍｍ、日本テスト
パネル社製）を入れて、直らにヒートシールして密封し
た。そして、この多装を２０”Ｃ，９５ＲＨ％の槽内に
入れて静置し、錆の発生状況を調べた。(Test method) Each of the above bags was left standing in a tank adjusted to 20°C and 95RH% for 24 hours, and then a degreased test piece (150x70xQ, 8mm, manufactured by Nippon Test Panel Co., Ltd.) ) and heat-sealed it immediately. Then, this multi-pack was placed in a tank at 20"C and 95RH% and allowed to stand, and the state of rust formation was examined.
この試験の結果は、次表のようになり、比較例１．２の
ものでは２４時間以内にテストピースに発錆が見られた
が、実施例１〜４のものでは、１年経過してもいずれの
テストピースにも発錆が見られなかった。The results of this test are as shown in the table below. In Comparative Example 1.2, rust was observed on the test piece within 24 hours, but in Examples 1 to 4, after one year had passed. No rust was observed on any of the test pieces.
［発明の効果］
この発明は上記構成を有するため、気化性物質の含浸さ
れた組材を内側にして物品の包装を行なうとき、気化性
物質が外部に拡散することがなくて有効に物品に対して
働き、防錆、防虫あるいは消臭などの気化性物質の特性
を長期に亘り、十分に発揮させることができる。 。[Effects of the Invention] Since the present invention has the above configuration, when an article is packaged with the material impregnated with a vaporizable substance inside, the vaporizable substance does not diffuse to the outside and the article is effectively packaged. It can fully exhibit the properties of volatile substances such as rust prevention, insect prevention, and deodorization over a long period of time. .
またこの発明では、組材が熱可塑性樹脂製であるため、
物品の包装に当り、ヒートシールにより密封することが
でき、物品の保護を一層確実に行なえる。In addition, in this invention, since the assembly material is made of thermoplastic resin,
When packaging an article, it can be sealed by heat sealing, and the article can be more securely protected.
図面はこの発明の一実施例の部分断面図である。 １・・・熱可塑性含浸用組材 ３・・・熱可塑性樹脂フィルム ５・・・シート状基材 The drawing is a partial cross-sectional view of one embodiment of the invention. 1... Thermoplastic impregnation material 3...Thermoplastic resin film 5... Sheet-like base material
Claims (4)
ミネートしたシート状基材に対して、気化性物質を含浸
させて成る保護材。(1) A protective material made by impregnating a sheet-like base material, which is made by laminating a thermoplastic resin film onto a thermoplastic impregnation assembly, with a vaporizable substance.
る特許請求の範囲第１項に記載の保護材。(2) The protective material according to claim 1, wherein the volatile substance is a rust preventive.
を特徴とする特許請求の範囲第１項に記載の保護材。(3) The protective material according to claim 1, wherein the vaporizable substance is an insecticide or an insect repellent.
を特徴とする特許請求の範囲第１項に記載の保護材。(4) The protective material according to claim 1, wherein the vaporizable substance is a deodorant or a fragrance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10678686A JPS62271857A (en) | 1986-05-12 | 1986-05-12 | Protective material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10678686A JPS62271857A (en) | 1986-05-12 | 1986-05-12 | Protective material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62271857A true JPS62271857A (en) | 1987-11-26 |
Family
ID=14442582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10678686A Pending JPS62271857A (en) | 1986-05-12 | 1986-05-12 | Protective material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62271857A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996017764A1 (en) * | 1994-12-09 | 1996-06-13 | Shs Technische Verpackungen Gmbh I. Gr. | Protective device for a two-wheeled vehicle |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52101195A (en) * | 1976-02-21 | 1977-08-24 | Shigekazu Takeda | Rustproof skin wrapping film |
-
1986
- 1986-05-12 JP JP10678686A patent/JPS62271857A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52101195A (en) * | 1976-02-21 | 1977-08-24 | Shigekazu Takeda | Rustproof skin wrapping film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996017764A1 (en) * | 1994-12-09 | 1996-06-13 | Shs Technische Verpackungen Gmbh I. Gr. | Protective device for a two-wheeled vehicle |
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