JPS62264601A - Plastic magnet conposite - Google Patents
Plastic magnet conpositeInfo
- Publication number
- JPS62264601A JPS62264601A JP61108262A JP10826286A JPS62264601A JP S62264601 A JPS62264601 A JP S62264601A JP 61108262 A JP61108262 A JP 61108262A JP 10826286 A JP10826286 A JP 10826286A JP S62264601 A JPS62264601 A JP S62264601A
- Authority
- JP
- Japan
- Prior art keywords
- extrusion
- mixture
- orientation
- powder
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004033 plastic Substances 0.000 title claims description 4
- 229920003023 plastic Polymers 0.000 title claims description 4
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000003831 antifriction material Substances 0.000 claims abstract description 6
- 239000011230 binding agent Substances 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 abstract description 17
- 230000000694 effects Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 150000002910 rare earth metals Chemical class 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000218645 Cedrus Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001684 chronic effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 101150096059 lipC gene Proteins 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔雄菜J:■利用分野〕 本発明はグラスチック磁石組成物に係る。[Detailed description of the invention] [Yuna J: ■Field of use] The present invention relates to a glasstic magnet composition.
従来Oプラスチック龜石組成物はし1jえば、特開昭5
9−12783号0様に樹脂マグネット成形表置などに
用いられるグラスチック樹脂組成物などが知られている
。Conventional O plastic amulet composition has been disclosed in Japanese Unexamined Patent Publication No. 1973
No. 9-12783 No. 0 discloses a glasstic resin composition used for resin magnet molding and the like.
しかし乍ら前述わ従来技術は強@注粉末なりQτ又’1
1 B r 7工ライト磁石粉末で、そZa[U、2μ
’m〜5μmと大変細かい、また酸化物な■でバインダ
ー0ポリアミド樹脂と混合的250℃近辺に加熱し押出
成形する方法である。ここでステアリン酸カルシウムな
どt−a形動剤として加えているが、こFLはあくまで
フェライト51石O金截外磁場成形方法である。しかし
ながら希土類F11石O押出伐形りよ5に、押出圧力が
高く配向磁場の大きβも■Vcは不向きである。粉末粒
度は3μm〜150μmと大変中が広くなるOで、微粉
末〜粗い粉末筒で金型中を通過するって、吸杉注を阻害
し易い問題があった。そこで本発明μこOような問題点
を解決するも■で、七O目的とするところは。However, as mentioned above, the conventional technology is a strong @Note powder Qτ or '1
1 B r 7-grade light magnet powder, so Za[U, 2μ
This is a method of extrusion molding by heating to around 250° C. in a mixture with a binder-free polyamide resin using very fine particles of 5 μm to 5 μm and oxides. Although calcium stearate and the like are added here as a t-a type moving agent, this FL is only a method of external magnetic field forming of 51 stone O ferrite. However, due to the high extrusion pressure and large orientation magnetic field β, ■Vc is unsuitable for rare earth F11 stone O extrusion cutting shapes. The powder particle size is 3 μm to 150 μm, which is very large, and there is a problem that passing through the mold as a fine powder to coarse powder can easily hinder suction pouring. Therefore, the purpose of the present invention is to solve these problems.
押出成彩性を改善することであり、又韻O目的は配向度
を高めることである。The purpose is to improve the extrusion colorability, and the purpose is to increase the degree of orientation.
本発明υプラスチック磁石組成物は、永久磁石粉末と結
合剤である[ lfi ’+B樹)jdからなる混合物
(コンパウンド) VCo、01〜4重量%7)減卆材
を加えたことをffIRとTる。ここで永久墓石は、希
土類磁石で1−5系、2−47系1尺−?8−B系を対
象とする。好まし^材質は、列えばF3mc O@系a
m(Co baJ Cu6.@ 1’#O,l Zfo
、oz)74 j ’mo、s Yo、a CCo b
aJCu6@o7 I’g O,15Z?”0.0!
)7.4 、 Bm(Co b(Lip c
sa、Oy ’g MI Tt o、ot)7.4
Ndts F’$77 Ba (Ceo、*
Pro、s Hdha )ts FetrBsなど
0希土類伍石を対象とする。ここで前記希土類磁石O粉
末粒度は1−5系では、3−54m。The plastic magnet composition of the present invention is a mixture (compound) consisting of permanent magnet powder and a binder [lfi' + Ru. Here, the permanent gravestone is made of rare earth magnets, 1-5 series, 2-47 series, 1 shaku? Targets 8-B series. Preferable material is F3mc O@ series a
m(Co baJ Cu6.@1'#O,l Zfo
, oz) 74 j 'mo, s Yo, a CCo b
aJCu6@o7 I'g O,15Z? “0.0!
)7.4, Bm(Co b(Lip c
sa, Oy 'g MI Tt o, ot) 7.4
Ndts F'$77 Ba (Ceo, *
Targets 0 rare earths such as Pro, s Hdha ) ts FetrBs, etc. Here, the rare earth magnet O powder particle size is 3-54 m in the 1-5 series.
2−17系ri3 A m 〜150 A rn 、
R−’!! # −B系は、5〜200μmである。ま
たバインダーは。2-17 series ri3 A m ~150 A rn,
R-'! ! #-B series has a thickness of 5 to 200 μm. Also a binder.
ポリアミド、垣素比ポリエチレン、ポリエステル。Polyamide, polyethylene, polyester.
FVAボリグロピレ/などを剛いる。また減摩材は、窒
化ホウ素% (Bll二硫化モリブデン、(M、)s
t) 、黒鉛(C)、ステアリン酸、ステアリン酸カル
シウム、ステアリン酸亜鉛、炭酸カルシウム7:11f
iもしくl−!26i以上混合しても良い、添加徽は0
.01wt%以下では、収形注向上効果が少い。FVA Boliguropyre/etc. In addition, the anti-friction material is boron nitride% (Bll molybdenum disulfide, (M,)s
t), graphite (C), stearic acid, calcium stearate, zinc stearate, calcium carbonate 7:11f
i or l-! 26i or more may be mixed, the addition amount is 0
.. If the amount is less than 0.01 wt%, the effect of improving mold fit is small.
4 wtチをこえると、非ら注物質が増えるのでミ気性
能が低くなることおよび、結合強度をはめるためこれま
でとした。When the weight exceeds 4 wt, the amount of non-injected substances increases, resulting in poor air permeability and bonding strength.
なお磁場押出成形装置により、シート状、バイク状り円
柱状、その他異形状■希土類樹脂磁石を提供できる。By using the magnetic field extrusion molding equipment, we can provide rare earth resin magnets in sheet shapes, bike shapes, cylinder shapes, and other irregular shapes.
〔実施列−1〕
[1図は本発明及び比較列に用β九、ミ場押出成彩裟賀
を示す、原料コンパランド3は、27)バレル内でスク
リュー1を介して前方へ送出され。[Implementation row-1] [Figure 1 shows the β9 used in the present invention and the comparison row, and the completion of extrusion in the field. The raw material comparand 3 is fed forward through the screw 1 in the barrel. .
50ヨーク、67)コイルにより磁場は8Vc集中し約
8〜l0KO#であつ之、7は押出型でBUJ−2材で
出来てハる。9は中子でやはり5Uy−,2材でできて
いる1次に戎杉物は11■ノズルで空冷され固化する。50 yoke, 67) The magnetic field is concentrated at 8Vc by the coil and is about 8 to 10 KO#.7 is an extrusion mold and is made of BUJ-2 material. 9 is the core, which is also made of 5Uy-2 materials, and the primary Ebisu cedar material is air-cooled and solidified by the 11-inch nozzle.
ここで磁石粉末は、S惧5(CObαI/C%。0.ガ
5.32デ・、0冨)7.1組成■2−17系合金粉末
で七O粒度は3μm−関μmである。この粉末′に一荏
股チ(VQi、%)、残部塩素比ポリエチレン及び減摩
剤とからなる混合物を混練機で混合コンパウンドとした
。嘉1図Q押出成形吸にてパイグ状り永久磁石をりくっ
た。婿2図μ、円筒伏伍石O概峻図で外匝φα)×内径
18 X 30 m (長さ)であった。Here, the magnet powder is a 2-17 series alloy powder with a 7.1 composition (CObαI/C%. 0.5.32 de., 0.0) and a grain size of 3 μm-7.1 μm. This powder was mixed with a mixture of one part (VQi, %), the rest being polyethylene with a chlorine ratio, and a lubricant, and a compound was prepared using a kneader. Figure 1: Pig-shaped permanent magnet was cut out using an extrusion molding tool. The outline of the cylindrical stone was φα) x inner diameter 18 x 30 m (length).
なお比較列は、減摩剤は入っていないもっである。The comparative row contains no anti-friction agent.
一方本発明法は、減肇剤として、窒化硼素(BN)でそ
υ粒度は、0.5μ〜1.5μWLo超微粉末のも■を
0.1 u$〜5wt%加えた。On the other hand, in the method of the present invention, 0.1 u$ to 5 wt % of ultrafine powder of boron nitride (BN) with a grain size of 0.5 μ to 1.5 μ is added as a deodorizing agent.
第3図に磁気特性(BT)■変化を記載した。粉末り配
向度はBT(残留磁束密度)O変化としてとらえること
ができるからである。そtLKよれば本発明法は、比較
列に比べBfは5.8KGから最大5.3KGまで向上
する効果を得られた。Figure 3 shows changes in magnetic properties (BT). This is because the powder orientation degree can be understood as a change in BT (residual magnetic flux density) O. According to SotLK, the method of the present invention had the effect of improving Bf from 5.8 KG to a maximum of 5.3 KG compared to the comparison train.
〔実施列−2〕
磁石粉末d 、RB(Co b(LIpC%h011P
aD−mτi o、ot ) t、aなる2−17系組
成り合金t−彫解、磁気硬比υためO熱処@を施したも
υを使用しな、そO粉末粒度は、!−均で加μmであっ
た。[Implementation row-2] Magnet powder d, RB(Co b(LIpC%h011P
aD-mτi o,ot) t, a 2-17 composition alloy t-engraving, magnetic hardness ratio υ, even if O heat treatment @ is applied, υ is not used, so O powder particle size is,! - The average value was in μm.
第1炎Vc原料コンパウンド■製危条沖1円容を記載。1st flame Vc raw material compound■ The volume of Seikyoki 1 yen is listed.
釘 2 表 なおそれぞれυ組成比率は1重−チで擬している。Nail 2 Front Note that the υ composition ratio in each case is simulated as one layer.
押出成形条件は、嬉工図に承丁展酋で行い侍られ友試料
形状it醜2図とは同様υも■である。The extrusion molding conditions were as follows: The shape of the sample was the same as that of the two figures, and υ was also ■.
第 3 我
wXa表は、実施列により優られた磁石O磁気特性及び
°吻理″¥j性を示した9本発明O減摩剤添加効果は、
綴気曲能r高め且つ物理特注も改讐出来るなどυ利点が
ある。そ7)理由な、FiBL場押出戎形における妃と
コンパウンドの1#擦係数O減小、流動性改質効果に起
因するもっである。′爵に本実施列からもわかるように
、固体状り減摩剤が有効であるがこれは押出成彩■よう
に耐熱性が盛装とされる(約120〜300℃で成彩す
るため)ことに大戻胃効であることがわかった。The 3rd wXa table shows that the 9 magnets exhibited excellent magnetic properties and mechanical properties.The effect of adding the lubricant of the present invention is as follows:
It has advantages such as increasing the ability to perform music and improving physical customization. 7) The reason is that the 1# friction coefficient O of the compound and the compound in the FiBL extrusion process is reduced, which is due to the fluidity modification effect. As can be seen from this example, solid lubricants are effective, but they are heat resistant like extrusion molding (because they mold at about 120 to 300°C). It was found that it had a great effect on the stomach.
〔発明D5ehMk)
以と述べ友ように本発明法によれば、罎場押出吠杉迅石
〇−気特注O尚注能fヒ、並びに物理特注。[Invention D5ehMk] As mentioned above, according to the method of the present invention, it is possible to create a custom-made product, a custom-made product, and a special-order physical product.
中でも慢械的注質を高められるとθう効果?胃する。Among them, is it effective to increase chronic attention? I feel sick to my stomach.
磁気椿8:υ高曲能化は、出湯中配向度き高められたこ
とおよび高密度比効果である。これは潤滑効束=減摩剤
0添77EIによるも■である。Magnetic Tsubaki 8: υ The high bendability is due to the increased orientation during tapping and the high density ratio effect. This is also due to the lubricating flux = 0 addition of anti-friction agent 77EI.
瀉1図は本発明VCおけるm場押出装置0断面図第2図
は、押出成形磁石り概観図
呉3図は、実tM列11’Cおける減早剤添加駄と磁気
¥’il:i:DBrD相関?示す図1日・スクリュー
2111バレル
3・・・コンパウンド
4 * 11 @ヒーター
5・働・ヨーク(継鉄)
6・コイル
7・・・金型
8・・・磁場配向部
9@・・中子
10−・・円筒−石
11・・−冷却エアーノズル
以 と
出願人 セイコーエプソン味式会肚
第2図
トtXcr)
01ユ34ダ
運屋」h資縫〜う幻
第3図Figure 1 is a cross-sectional view of the m-field extrusion device in the VC of the present invention. Figure 2 is an overview of the extrusion molding magnet. Figure 3 is a diagram showing the speed reducer addition and magnetism in the actual tM column 11'C. :DBrD correlation? Figure 1 shows: Screw 2111 Barrel 3 Compound 4 * 11 @ Heater 5 Work Yoke 6 Coil 7 Mold 8 Magnetic field orientation part 9 @ Core 10 -... Cylinder - Stone 11... - Cooling air nozzle and Applicant Seiko Epson Aji Shikikai (Fig. 2)
Claims (1)
物(コンパウンド)に0.01%〜4重量%の減摩材を
加えたことを特徴とするプラスチツク磁石組成物。A plastic magnet composition characterized in that 0.01% to 4% by weight of an anti-friction material is added to a mixture (compound) of permanent magnet powder and an organic resin as a binder.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61108262A JPS62264601A (en) | 1986-05-12 | 1986-05-12 | Plastic magnet conposite |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61108262A JPS62264601A (en) | 1986-05-12 | 1986-05-12 | Plastic magnet conposite |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS62264601A true JPS62264601A (en) | 1987-11-17 |
Family
ID=14480192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61108262A Pending JPS62264601A (en) | 1986-05-12 | 1986-05-12 | Plastic magnet conposite |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62264601A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0548952A2 (en) * | 1991-12-25 | 1993-06-30 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Method for producing a magnet roll |
US5888416A (en) * | 1992-05-12 | 1999-03-30 | Seiko Epson Corporation | Rare-earth bonded magnet composition, rare-earth bonded magnet and process for producing said rare-earth bonded magnet |
-
1986
- 1986-05-12 JP JP61108262A patent/JPS62264601A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0548952A2 (en) * | 1991-12-25 | 1993-06-30 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Method for producing a magnet roll |
US5888416A (en) * | 1992-05-12 | 1999-03-30 | Seiko Epson Corporation | Rare-earth bonded magnet composition, rare-earth bonded magnet and process for producing said rare-earth bonded magnet |
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