JPS62252302A - Production of aqueous solution of titanium hydroperoxide of high purity - Google Patents
Production of aqueous solution of titanium hydroperoxide of high purityInfo
- Publication number
- JPS62252302A JPS62252302A JP9358486A JP9358486A JPS62252302A JP S62252302 A JPS62252302 A JP S62252302A JP 9358486 A JP9358486 A JP 9358486A JP 9358486 A JP9358486 A JP 9358486A JP S62252302 A JPS62252302 A JP S62252302A
- Authority
- JP
- Japan
- Prior art keywords
- titanium
- hydrogen peroxide
- aqueous solution
- purity
- high purity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007864 aqueous solution Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- UYFXJSBYTIMJAH-UHFFFAOYSA-J [Ti+4].[O-]O.[O-]O.[O-]O.[O-]O Chemical compound [Ti+4].[O-]O.[O-]O.[O-]O.[O-]O UYFXJSBYTIMJAH-UHFFFAOYSA-J 0.000 title abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims abstract description 17
- 229910000048 titanium hydride Inorganic materials 0.000 claims abstract description 13
- -1 titanium hydride Chemical compound 0.000 claims abstract description 12
- DJGLQWCKPYQFJG-UHFFFAOYSA-N hydrogen peroxide;titanium Chemical compound [Ti].OO DJGLQWCKPYQFJG-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 19
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 14
- 239000012535 impurity Substances 0.000 abstract description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001257 hydrogen Substances 0.000 abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 4
- 239000010936 titanium Substances 0.000 abstract description 4
- 229910052719 titanium Inorganic materials 0.000 abstract description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006482 condensation reaction Methods 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 11
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 10
- 239000000047 product Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 229910000348 titanium sulfate Inorganic materials 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は高純度酸化チタンの粉末、膜、繊維構造体を作
るのに有用な高純度過酸化水素化チタン水溶液の製造法
に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for producing a high-purity titanium hydrogen peroxide aqueous solution useful for producing high-purity titanium oxide powder, membranes, and fibrous structures.
従来技術
従来の水酸化チタン又は酸化チタンの製造法としては、
塩化チタン、硫酸チタン或いはアルコキシチタン等のチ
タン塩を原料に用いて、加水分解する方法、又は酸化す
る方法、もしくは両者の併用が知られている。これらの
方法によると水酸化チタン或いは酸化チタンの生成の場
に於いて、不純分の原因となる成分即ち硫酸塩、塩化物
、塩素。Prior Art Conventional methods for producing titanium hydroxide or titanium oxide include:
A method of hydrolyzing or oxidizing a titanium salt such as titanium chloride, titanium sulfate, or alkoxytitanium as a raw material, or a combination of both is known. According to these methods, in the production of titanium hydroxide or titanium oxide, components that cause impurities, such as sulfates, chlorides, and chlorine, are removed.
或いはアルコールのいずれかが存在している。そのため
、これらの物質は水酸化チタン又は酸化チタンに取り込
まれて、これらを不純にしていた。or alcohol is present. Therefore, these substances were incorporated into titanium hydroxide or titanium oxide, making them impure.
又過酸化水素化チタン水溶液としては高濃度塩酸酸性の
塩化チタンおよび高濃度硫酸酸性硫酸チタンに過酸化水
素水を加えたものが知られているが、これらを分解して
も前記と同じ理由で、不純な水酸化チタンが得られる。In addition, titanium hydrogen peroxide aqueous solutions are known to include highly concentrated hydrochloric acid acidic titanium chloride and highly concentrated sulfuric acid acidic titanium sulfate with hydrogen peroxide solution added, but even if these are decomposed, it will not work for the same reason as above. , impure titanium hydroxide is obtained.
発明の目的
本発明は従来法における欠点を解消するために行ったも
ので、第一の目的は高純度水酸化チタンおよび高純度酸
化チタンを得るために、不純物の原因となる成分を含ま
ない原料としての高純度の過酸化水素化チタン水溶液の
製造法を提供することである。第二の目的は高純度水酸
化チタンおよび高純度酸化チタンを得るにさいして、環
境を汚染する物質を発生しない原料としての高純度の過
酸化水素化チタン水溶液の製造法を提供することである
。第三の目的は高純度水酸化チタンおよび高純度酸化チ
タンを得るにさいして、これらの形状を膜状、繊維状、
微粉末状に容易に得ることが出来る高純度過酸化水素化
チタン水溶液の製造法を提供することである。Purpose of the Invention The present invention was carried out to eliminate the drawbacks of conventional methods, and the first purpose is to produce raw materials that do not contain components that cause impurities, in order to obtain high-purity titanium hydroxide and high-purity titanium oxide. An object of the present invention is to provide a method for producing a highly pure aqueous titanium peroxide solution. The second purpose is to provide a method for producing a high-purity titanium peroxide aqueous solution as a raw material that does not generate substances that pollute the environment when obtaining high-purity titanium hydroxide and high-purity titanium oxide. . The third purpose is to obtain high-purity titanium hydroxide and high-purity titanium oxide, which can be shaped into membranes, fibers, or
An object of the present invention is to provide a method for producing a high-purity titanium hydrogen peroxide aqueous solution that can be easily obtained in the form of a fine powder.
発明の構成
本発明者は、前記目的を達成するために研究した結果、
水素化チタン微粉末と過酸化水素水溶液とを混合して、
溶解させると、高純度の水酸化チタン並びに高純度酸化
チタンの製造原料として好適な高純度過酸化水素化チタ
ン水溶液が得られることを見出した。この知見に基づい
て本発明を完成したものである。Structure of the Invention As a result of research to achieve the above object, the present inventor has discovered that
Mix titanium hydride fine powder and hydrogen peroxide aqueous solution,
It has been found that when dissolved, a high-purity titanium hydrogen peroxide aqueous solution suitable as a raw material for producing high-purity titanium hydroxide and high-purity titanium oxide can be obtained. The present invention was completed based on this knowledge.
本発明の要旨は、
水素化チタン微粉末と過酸化水素水溶液とを混合して、
溶解させることを特徴とする高純度過酸化水素化チタン
水溶液の製造法にある。The gist of the present invention is to mix titanium hydride fine powder and a hydrogen peroxide aqueous solution,
The present invention provides a method for producing a high-purity titanium hydrogen peroxide aqueous solution, which is characterized by dissolving it.
本発明で使用する水素化チタン微粉末は通常入手出来る
塊状乃至粗粒状の水素化チタンを非酸化性雰囲気下、例
えば水中で粉砕し、微粉の泥状として得るか、或いは常
温で泥状を風乾して乾燥微粉末として得る。なお、水素
化チタンは非常に砕は易く、粉砕して容易に微粉末とす
ることが出来るが、同時に酸化も容易である。なお、水
素化チタンは高純度スポンヂチタンに高純度水素を約４
００ ’Ｃで接触させても容易に得ることが出来る。The fine titanium hydride powder used in the present invention is obtained by grinding normally available lump or coarse titanium hydride in a non-oxidizing atmosphere, for example in water, or by air-drying the slurry at room temperature. It is obtained as a dry fine powder. Incidentally, titanium hydride is very easily crushed and can be easily ground into fine powder, but at the same time it is easily oxidized. In addition, titanium hydride is made by adding about 4% of high-purity hydrogen to high-purity sponge titanium.
It can be easily obtained by contacting at 00'C.
本発明で使用する過酸化水素水は市販品でよく、これに
は多種の純度品があるが、最も好ましくは安定剤の入っ
ていない最高純度品であるが、これに限るものではない
。過酸化水素濃度は０．１％以上で溶解出来るが、濃度
が高いほど溶解速度は早くなり、また分解する分もある
ので、３０％程度が好ましく、溶解後は水で稀釈しても
差し支えがない。The hydrogen peroxide solution used in the present invention may be a commercially available product, and there are various purity products, but the most preferred is the highest purity product that does not contain stabilizers, but it is not limited to this. Hydrogen peroxide can be dissolved at a concentration of 0.1% or more, but the higher the concentration, the faster the dissolution rate, and some decomposition occurs, so a hydrogen peroxide concentration of about 30% is preferable, and after dissolution it can be diluted with water. do not have.
水素化チタン微粉末と過酸化水素水とを混合して、けん
濁させると、常温以下で容易に溶解して、黄色系色調の
高純度過酸化水素化チタン水溶液が得られる。When fine titanium hydride powder and aqueous hydrogen peroxide are mixed and suspended, they are easily dissolved at room temperature or below, yielding a yellowish-colored high-purity aqueous titanium peroxide solution.
なお、水素化チタンは過酸化水素水との溶解反応以外に
、過酸化水素の分解反応および先に生じた過酸化水素化
チタンの縮合反応に触媒作用を持ち、両反応を促進する
。溶解反応を優先させるために、微粉末として使用する
ことが高濃度溶液を得るためには必要で、且つ室温以下
で攪拌して速やかに溶解させて、不要の水素化チタンは
出来るだけ系中に存在させないことが好ましい。In addition to the dissolution reaction with the hydrogen peroxide solution, titanium hydride has a catalytic effect on the decomposition reaction of hydrogen peroxide and the condensation reaction of titanium hydrogen peroxide that occurs previously, promoting both reactions. In order to give priority to the dissolution reaction, it is necessary to use it as a fine powder to obtain a highly concentrated solution, and to quickly dissolve it by stirring at room temperature or below, as much as possible of unnecessary titanium hydride is removed from the system. Preferably, it is not present.
得られた高純度過酸化水素化チタン水溶液から熱分解に
よって高純度過酸化水素化チタンおよび高純度酸化チタ
ンを得ることが出来る。その過程は以下の通りである。High purity titanium hydrogen peroxide and high purity titanium oxide can be obtained from the obtained high purity titanium hydrogen peroxide aqueous solution by thermal decomposition. The process is as follows.
高純度過酸化水素化チタン水溶液は冷温下では準安定で
あるが、室温程度では、最初に遊離の過酸化水素を分解
して多量の酸素ガスを放出する。High-purity titanium hydrogen peroxide aqueous solution is metastable at cold temperatures, but at room temperature it first decomposes free hydrogen peroxide and releases a large amount of oxygen gas.
同時に膣液の色調の黄色は時間と共に薄くなる。At the same time, the yellow color of the vaginal fluid becomes lighter over time.
続いて過酸化水素化チタンの縮合が生じ、その縮合度を
徐々に増して行き、粘ちょう性の増加として見られ、ゼ
リー状を示すようになる。一般的には、室温下では数時
間から数日間、或いは１００℃下では数分間から数時間
にわたって、この状態が続く。遂には縮合過酸化水素化
チタンが沈降する、最終的には沈降物は水酸化チタンに
変化する。Subsequently, condensation of titanium hydrogen peroxide occurs, and the degree of condensation gradually increases, which is seen as an increase in viscosity and a jelly-like appearance. Generally, this state continues for several hours to several days at room temperature, or for several minutes to several hours at 100°C. Eventually, condensed titanium hydrogen peroxide precipitates, and finally the precipitate changes to titanium hydroxide.
低濃度、低縮合度のゲルを固体上に付着させて、これを
風乾すると被膜が形成される。ゲルを急速に凍結乾燥す
ると空隙を持った立体構造体が出来る。また、ゲルを徐
々に凍結すると粗大粒となる。A film is formed by depositing a low concentration, low degree of condensation gel on a solid and air drying it. Rapid freeze-drying of the gel creates a three-dimensional structure with voids. Furthermore, when the gel is gradually frozen, it becomes coarse particles.
縮合過酸化水素化チタンのゲル液を乾燥したものを徐々
に昇温しでいくと、約１００℃で脱水、吸熱が生じ、約
２５０〜３２０℃で脱水、脱酸素および発熱が生じ、４
５０℃以上で加熱前の形状を保った酸化チタンとなる。When the temperature of a dried gel solution of condensed titanium hydrogen peroxide is gradually raised, dehydration and endotherm occur at about 100°C, dehydration, deoxygenation, and heat generation occur at about 250 to 320°C.
At 50°C or higher, titanium oxide becomes titanium oxide that maintains its shape before heating.
急速に加熱すると、脱ガスによって以前の形状は壊れて
粉状となる。When heated rapidly, degassing causes the former shape to collapse and become powder-like.
発明の効果
本発明の方法によるときは酸化チタンの製造原料として
、次ような優れた効果を有する。Effects of the Invention The method of the present invention has the following excellent effects as a raw material for producing titanium oxide.
第一に、原料中に、チタン、水素、および酸素以外の元
素を含まないので、原料自体から不純物を発生しない、
また該原料に添加物を加える必要がなく、ただ熱的に分
解するだけでよいので、不純物の混入が避けられて、高
純度品が得られる。第二に、原料中に、チタン、水素、
および酸素以外の元素を含まないので、原料自体から不
純物を発生しない、また該原料に添加物を加える必要が
なく、ただ熱的に分解するだけでよいので、環境を汚染
する物質を発生しない。第三に高純度を保ちながら、形
状を膜状、繊維状、微粉末状に容易に得ることが出来る
。First, the raw materials do not contain any elements other than titanium, hydrogen, and oxygen, so the raw materials themselves do not generate impurities.
Furthermore, since there is no need to add additives to the raw material and only thermal decomposition is required, contamination with impurities can be avoided and a highly pure product can be obtained. Second, the raw materials contain titanium, hydrogen,
Since it does not contain any elements other than oxygen, it does not generate impurities from the raw material itself, and there is no need to add additives to the raw material, and it only needs to be thermally decomposed, so it does not generate substances that pollute the environment. Thirdly, it can be easily formed into a film, fiber, or fine powder form while maintaining high purity.
実施例
塊状の水素化チタンを少量の水に浸しながら乳鉢中で粉
砕して、微粉の泥状として、これを風乾して乾燥微粉末
として、その微粉４７■を１０ｍ１の３０％高純度酸化
水素水に加え、混合して、しばらくすると溶解して、黄
色の高純度過酸化水素化チタン水溶液を得た。Example: A block of titanium hydride is crushed in a mortar while soaked in a small amount of water to form a fine powder slurry, which is air-dried to form a dry fine powder. 47 cm of the fine powder is added to 10 ml of 30% high purity hydrogen oxide. It was added to water, mixed, and dissolved after a while to obtain a yellow high-purity titanium hydrogen peroxide aqueous solution.
手続補正書
昭和６２年２月々り
特許庁長官 小 川 邦 夫 殿
１、事件の表示
昭和６１年特許願第９３５８４号
２、発明の名称
高純度過酸化水素化チタン水溶液の製造法３、補正をす
る者
事件との関係 特許出願人
瀬 高 信 ａｉ、、゛ ・５、補
正により増加する発明の数 なし６、補正の対象
明細書の発明の詳細な説明の欄
７、補正の内容
別紙
（１）明細書第２頁６行「過酸化水素水」を「過酸化水
素水溶液」と訂正する。Procedural amendment filed in February 1988 Kunio Ogawa, Commissioner of the Patent Office1, Indication of the case Patent Application No. 93584 filed in 19882, Name of the invention Process for producing a high-purity titanium hydrogen peroxide aqueous solution3, Amendment Relationship with the patent applicant Takanobu Sase ai,,゛・5, Number of inventions increased by the amendment None6, Detailed explanation of the invention in the specification subject to the amendment 7, Contents of the amendment attached sheet (1) ) On page 2 of the specification, line 6, "Hydrogen peroxide solution" is corrected to "Hydrogen peroxide solution."
（２）同第２頁１１行「行ったもので、」を［行ったも
のである。］と訂正する。(2) Page 2, line 11, “I did it,” means “I did it.” ] Correct.
（３）同第４頁５〜６行「過酸化水素水は市販品で・・
・・・・があるが」を「過酸化水素水溶液は市販品でよ
いが、これには多種の純度品があり、」と訂正する。(3) Page 4, lines 5-6 “Hydrogen peroxide is a commercially available product...
``There is...'' was corrected to ``A commercially available hydrogen peroxide solution is fine, but there are many different purity products.''
（４）同第４真下から８行、同上から４行「過酸化水素
水」を「過酸化水素水溶液」と訂正する。(4) Correct "hydrogen peroxide solution" to "hydrogen peroxide solution" in the 8th line from the bottom of the 4th line and the 4th line from the top.
（５）同第５頁６行「高純度過酸化水素化チタン」を「
高純度水酸化チタン」と訂正する。(5) Page 5, line 6 “High purity titanium hydrogen peroxide”
"High purity titanium hydroxide".
（６）同第６頁１２行「次ような」を「次のような」と
訂正する。(6) On page 6, line 12, ``like the following'' is corrected to ``like the following''.
（７）同第６頁１５行、および路行「添加物」を「分解
剤」と訂正する。(7) On page 6, line 15, the word "additive" is corrected to "decomposer."
（８）同第７頁９行「高純度酸化水素水」を［高純度過
酸化水素水溶液］と訂正する。(8) On page 7, line 9, "High purity hydrogen oxide solution" is corrected to "High purity hydrogen peroxide solution."
Claims (1)
溶解させることを特徴とする高純度過酸化水素化チタン
水溶液の製造法。Mix titanium hydride fine powder and hydrogen peroxide aqueous solution,
A method for producing a high-purity titanium hydrogen peroxide aqueous solution, which is characterized by dissolving it.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9358486A JPS62252302A (en) | 1986-04-23 | 1986-04-23 | Production of aqueous solution of titanium hydroperoxide of high purity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9358486A JPS62252302A (en) | 1986-04-23 | 1986-04-23 | Production of aqueous solution of titanium hydroperoxide of high purity |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62252302A true JPS62252302A (en) | 1987-11-04 |
| JPH0369843B2 JPH0369843B2 (en) | 1991-11-05 |
Family
ID=14086329
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9358486A Granted JPS62252302A (en) | 1986-04-23 | 1986-04-23 | Production of aqueous solution of titanium hydroperoxide of high purity |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62252302A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004196647A (en) * | 2003-09-09 | 2004-07-15 | Monet Associates:Kk | Method of manufacturing titanium hydroperoxide solution |
-
1986
- 1986-04-23 JP JP9358486A patent/JPS62252302A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004196647A (en) * | 2003-09-09 | 2004-07-15 | Monet Associates:Kk | Method of manufacturing titanium hydroperoxide solution |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0369843B2 (en) | 1991-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |