JPS62248618A - Manufacture of thermoplastic polymer sheet - Google Patents

Manufacture of thermoplastic polymer sheet

Info

Publication number
JPS62248618A
JPS62248618A JP61091999A JP9199986A JPS62248618A JP S62248618 A JPS62248618 A JP S62248618A JP 61091999 A JP61091999 A JP 61091999A JP 9199986 A JP9199986 A JP 9199986A JP S62248618 A JPS62248618 A JP S62248618A
Authority
JP
Japan
Prior art keywords
cooling member
mobile cooling
cooling body
slit
plate electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61091999A
Other languages
Japanese (ja)
Inventor
Takatoshi Kuratsuji
倉辻 孝俊
Hideyori Kurihara
英資 栗原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP61091999A priority Critical patent/JPS62248618A/en
Publication of JPS62248618A publication Critical patent/JPS62248618A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/915Cooling of flat articles, e.g. using specially adapted supporting means with means for improving the adhesion to the supporting means
    • B29C48/9165Electrostatic pinning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/305Extrusion nozzles or dies having a wide opening, e.g. for forming sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • B29C48/914Cooling of flat articles, e.g. using specially adapted supporting means cooling drums

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To efficiently manufacture a high-quality sheet, by a method wherein a plate electrode is made to protrude to a mobile cooling member side from the inside of a slit of a mouth piece and DC voltage is applied between the said electrode and the mobile cooling member. CONSTITUTION:A mouth piece extruding a molten polymer into a shetlilke state and a mobile cooling member are provided and a plate electrode 3 is made to protrude to a mobile cooling member side through the inside of a slit 1 of the mouth piece, which is desirably in an insulated state from the inside of the slit 1. The tip part (mobile cooling member side) of the plate electrode is n parallel with an axial direction of a mobile cooling member face. The plate electrode is preferably composed of a material having conductivity such as a metal or carbon and it is desirable that a form of a side of the same facing to the mobile cooling member is in a knifelike state. Then a cooling drum, cooling roller and cooling belt can be exemplified as the mobile cooling member. Composite member of them is included also in the exemplification. Then quality of the material of the surface of the mobile cooling member must have the conductivity as the mobile cooling member forms a pair to the plate electrode protruded through the slit of the mouth piece.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は熱可摺性重合体シートの製造方法に関し、*に
鈴しく【エロ金から押出した熱可塑性重合体のシート状
烙融物1!i’に、静電荷の作用を利用して、移動冷却
体にしっかりと接触させて冷却固化する熱可塑性重合体
シートの製造方法に関する。
[Detailed Description of the Invention] Industrial Application Field The present invention relates to a method for producing a thermoplastic polymer sheet. The present invention relates to a method for producing a thermoplastic polymer sheet, which is cooled and solidified by firmly contacting a moving cooling body by utilizing the action of electrostatic charge.

従来技術 熱oll注性重合体らシートを製造する方法は、通常、
該重合体を熔融連続流として押出し口金を通してシート
状に押出し%次いでこれをドラムのような移動冷却体と
接触させて冷却固化することKよりなされる。しかし、
この方法にはい(つかの1大な問題点かある。その一つ
は。
Prior Art The method for producing sheets from hot-rolling polymers usually involves the following steps:
The polymer is extruded as a continuous molten stream through an extrusion die into a sheet, and then brought into contact with a moving cooling body such as a drum to cool and solidify. but,
Yes, there is one major problem with this method, one of which is.

口金と移動冷却体の間で、JRは移動冷却体上でシート
状熔融物流の幅が着しく諷少する傾向にあり、シート幅
が不規則になることである1、他の問題点は、シート状
重合体流かW11@体流と移動冷却体表thIg)間に
9気を捕捉することにより生じる冷却斑の現象である°
。多くの場合、シート状熔融物流の線速度より速いI!
!而速面で移動冷却体の表面は5IIhするので、これ
らの問題点は更に助長される。
Between the nozzle and the moving cooling body, JR has a tendency for the width of the sheet-like melt flow to become narrow on the moving cooling body, making the sheet width irregular1.Other problems are as follows: This is a phenomenon of cooling spots caused by the trapping of air between the sheet-like polymer flow (W11@body flow and the moving cooling body surface thIg).
. In many cases, I! is faster than the linear velocity of the sheet melt flow.
! Since the surface of the moving cooling body has a speed of 5IIh, these problems are further aggravated.

これらの問題を牌決する方法として、押出されたシート
状熔融物流の表面上に帝″RLKよる静電荷を析出させ
、該シート状熔融物流を移動冷却体表面にしっかりと&
j着させる方法は公知である・。この方法にも各種の方
法が従来から知られている。例えは、+11熱可シ性連
台体のシート状熔融物が移動冷却体に接する近傍で月つ
該熔融物の移動冷却体に接しない餞の面上にワイヤ電極
を設け、この電極と移動冷却体との間に直流電圧を印加
する方法(特公昭37−ti142号)。
As a method to solve these problems, an electrostatic charge is deposited on the surface of the extruded sheet-like molten stream by Teijin RLK, and the sheet-like molten stream is firmly attached to the surface of the moving cooling body.
The method of attaching the material is well known. Various methods have been known for this method. For example, a wire electrode is provided on the surface of the melt near where the sheet-like melt of the +11 thermoplastic series is in contact with the movable cooling body, but not in contact with the movable cooling body for the melt, and the wire electrode is moved with this electrode. A method of applying a DC voltage between the cooling body (Japanese Patent Publication No. 37-ti142).

(2)口金を電極とし、該口金と移動冷却体との間に直
a電圧を印加する方法(特開昭5〇−69166号) 
、f3+移動冷却体の表面に電気絶縁皮膜を設け、−万
シート状58融物が接する的の皮膜の向上Km極を設け
、この電極と移動冷却体との間に直流電圧を印加する方
法(%公昭48−14784号) 、 +41上記も方
法においてシート状熔融物の移動冷却体との接触点近傍
を。
(2) A method in which the cap is used as an electrode and a direct voltage is applied between the cap and the moving cooling body (Japanese Patent Laid-Open No. 50-69166)
, A method of providing an electrically insulating film on the surface of the f3+ moving cooling body, providing a Km electrode for improving the film in contact with the -10,000-sheet-like 58 melt, and applying a DC voltage between this electrode and the moving cooling body ( % Publication No. 48-14784), +41 In the above method, the area near the point of contact of the sheet-shaped melt with the moving cooling body.

9気より電気絶縁性の商いガスの雰囲気に保つ7i法(
特開昭59−185627号)等が知らIしている。こ
れらの方法によってフィルムの冷却斑が大幅に数置され
る。
7i method (which maintains an atmosphere of commercial gas that is more electrically insulating than 9qi)
JP-A No. 59-185627) etc. are known. These methods significantly reduce cooling spots in the film.

しかし、シート製造の速度を速め、或い(工より高品負
の7−トを製造1′るに曝工、これら方法も充分でない
However, these methods are not sufficient to increase the speed of sheet production or to produce high quality sheets.

発明の目的 本発明の目的4工、従来技術の欠点を改良し、より高速
で且つ安定してノートを製造jる方法を提供することに
ある。
OBJECTS OF THE INVENTION The fourth object of the present invention is to provide a method for manufacturing notebooks faster and more stably by improving the drawbacks of the prior art.

発明の構成・効果 本発明の目的は1本発明によれは1口金から押出した熱
可塑性重合体のソート状熔融*aを移動冷却体に接触さ
せて冷却固化1°るシートの製造方法において、該口金
のスリット内部から平板電極を移動冷却体側に突出させ
、かつ該電極と移動冷却体との間に直流電圧を印加する
ことを特徴とする熱可塑性重合体シートの製造力泳によ
って達成される。
Structure and effect of the invention The object of the present invention is 1. According to the present invention, there is provided a method for producing a sheet in which a sorted melt*a of a thermoplastic polymer extruded from one die is brought into contact with a moving cooling body and cooled and solidified 1°. This is achieved by a thermoplastic polymer sheet production process characterized by protruding a flat plate electrode from inside the slit of the base toward the moving cooling body and applying a DC voltage between the electrode and the moving cooling body.

本発明に通用されるkt!tは、熔融ポリマーをシート
状に押出す口金と移動冷却体とケ少な(とも具備し、&
fO金のスリット内部かり、好ましくはこれとは絶縁状
態で、平板[他を移動冷却体側に突出させていることt
特徴とてるものである。この平板電極はその先端fil
l(移動冷却体側)が移動冷却体面の#m方向と平行に
なっている。平板電極は金−、カーボン等の導電性を有
する素材からなるものであれは艮(、その形状は移動冷
却体に向かった側がナイフ状VCなっていることが好ま
しい。
kt applicable to the present invention! t is equipped with a die for extruding the molten polymer into a sheet, a moving cooling body, and a
The inside of the gold slit is preferably insulated from the flat plate [the other part should protrude toward the moving cooling body side].
It is a distinctive feature. This flat plate electrode has its tip fil
l (moving cooling body side) is parallel to #m direction of the moving cooling body surface. The flat plate electrode may be made of a conductive material such as gold or carbon, but it is preferable that its shape be a knife-shaped VC on the side facing the moving cooling body.

また、移動冷却体として奢工、冷却ドラム、冷却ローラ
、冷却ベルト等が例示できる。これらの複合体も含まれ
る。移動冷却体は口金のスリットから突出した平板電極
の対電他となるので。
Furthermore, examples of the moving cooling body include luxury goods, cooling drums, cooling rollers, cooling belts, and the like. Complexes of these are also included. The moving cooling body serves as a counter current for the flat plate electrode that protrudes from the slit in the base.

その表面材質は導電性を有するものである必賛がある。The surface material must be conductive.

本発明で蚤工、口金のスリット内部から突出した平板電
極と移動冷却体との間に直流電圧を印加するが、一方な
アースし、他方に十又は−の電圧を印加してもよ(、又
一方を+、他万を−に印加してもよ(、更に双方兵士又
は−として、その間に電位差をつ&jる方法でもよい。
In the present invention, a DC voltage is applied between the flat plate electrode protruding from inside the slit of the cap and the moving cooling body, but one side may be grounded and a voltage of 10 or - may be applied to the other. Alternatively, one may be applied to + and the other to - (or, furthermore, both may be soldiers or - and a potential difference may be applied between them).

両電極間にかけ61!位差は、下記式(1)で与えられ
る臨界電圧Vcより商い電圧である。
61 between both electrodes! The potential difference is a voltage less than the critical voltage Vc given by the following equation (1).

ここで、D=口金のスリット巾、 L:口金のランド長。Here, D = slit width of the cap, L: Land length of the cap.

H:平板を他の下地と移動冷却体と の距離 r:熱可塑性重合体の表面張力 である。H: Flat plate with other substrate and moving cooling body distance of r: surface tension of thermoplastic polymer It is.

例えは、熔融製腺時の温度における表面張力23 dy
n/cs+のポリエチレンを用いた場合、スリット巾2
.2mlランド長40 m ! H= 30 mmの条
件下では、 Vc = 10.I KVとなる。
For example, the surface tension at the temperature during melt gland production is 23 dy
When using n/cs+ polyethylene, slit width 2
.. 2ml land length 40m! Under the condition of H = 30 mm, Vc = 10. It becomes I KV.

このaが電圧より高い電圧をかけれは、本発明における
熱可m1!f宜合体は自動的に口金から移動冷却体に向
って引っばられる。印加する電圧は、it接熱司1gI
性重合体に働く引力VC影響するため、電圧変動率は±
1516以下、好ましくは±0.5X以、下とするのが
望ましい。
If this a is applied with a voltage higher than the voltage, the thermoplastic m1! in the present invention is applied. The coalesce is automatically pulled from the cap towards the moving cooling body. The voltage to be applied is 1gI
Due to the attractive force VC acting on the polymer, the voltage fluctuation rate is ±
It is desirable that it be below 1516, preferably below ±0.5X.

本発明におtする#I可塑性に8体は、下記式(2)。The #I plasticity according to the present invention is expressed by the following formula (2).

131でそれぞれ示さ八る1ζ、qのj@ (g−q 
)がlより小さい重合体である。
1ζ, q's j@ (g-q
) is smaller than l.

R=X、/X、      ・・・・・・・・・・・・
・・・(2!q ” K+/ Kt      ・・・
・・・・・・・・・・・(31かかる重合体としては1
例えはポリエチレン。
R=X, /X, ・・・・・・・・・・・・
・・・(2!q ” K+/Kt ・・・
・・・・・・・・・・・・(31 As such a polymer, 1
An example is polyethylene.

ポリプルピレン、ポリオキシメチレン、ホリアミド、ポ
リエステル等、或いはこれらの共m0体や混合体があげ
られる3゜ 重合体のR−qが1であると下記式(41で示されるポ
リマーの電荷密度σは0となり、電圧をかけても重合体
シエ電気的力を受げなt・。又R・qか]より大である
とポリマーの荷[密度か負となり、電圧をかザるとN合
体はtm惚の陽亀側に+、陰他側に−の帯電をし、重合
体と移動冷却体とが互に反発し合ってm合体はノート状
にならない。−万、1<・pか1より小さい場合、ポリ
マーの荷電密度σは正となり、電圧をかけると重合体は
陽極側か−、陰極側が十に帯電することから、#]1[
合体を裏対他の移動冷却体に引力を受けて@看し、均一
ノート状となる4、a=goKIX、 l E=E6C
OI!WL+ vr=2tv+to=  s、gsxx
o−12(Ji’/ m〕、  R=Xt/X* 。
Polypropylene, polyoxymethylene, holamide, polyester, etc., or their co-m0 forms or mixtures can be mentioned.If R-q of the 3° polymer is 1, the charge density σ of the polymer represented by the following formula (41) is 0. Therefore, even if a voltage is applied, the polymer will not receive any electrical force.If it is larger than t. The yang-kame side of the yang-kame side is charged with + and the yin-other side is charged with -, and the polymer and the moving cooling body repel each other, so that the m-combination does not become note-like.From -10,000, 1<・p or 1 When it is small, the charge density σ of the polymer is positive, and when a voltage is applied, the polymer is charged to either the anode side or the cathode side, so #]1[
The merging is caused by the attraction of the other moving cooling body and becomes a uniform notebook shape 4, a=goKIX, l E=E6C
OI! WL+vr=2tv+to=s, gsxx
o-12(Ji'/m], R=Xt/X*.

q=に、/K。q=ni, /K.

なお1式(41のiil)mはPhilog、 i”r
ans+ R,Soc。
In addition, formula 1 (41 iil) m is Philog, i”r
ans+ R, Soc.

London、 5erA+ 269 、295 (1
971)  を参照さnたい。
London, 5erA+ 269, 295 (1
Please refer to 971).

本発明における熱可M1性重合体は、易滑剤り顔料、各
種安定剤等の如き添加剤が含有さnたものであっても、
前記R・qが1より小さいものならば何でもよい。又、
口金から押出されたシート状熔融物は、単層でも多層に
積層されたものであってもよい。
The thermoplastic M1 polymer in the present invention may contain additives such as lubricants, pigments, various stabilizers, etc.
Any material may be used as long as the R.q is smaller than 1. or,
The sheet-like melt extruded from the die may be a single layer or a multi-layer stack.

本発明の方法によれは2口金と移動冷却体との間隔を、
突出平板電極によって、実質的に極で移動してもvf看
性はすぐれ、高速且つ安定したシートの製造が出来ると
いう利点が得られる。
According to the method of the present invention, the distance between the two caps and the moving cooling body is
The protruding flat plate electrode provides excellent VF visibility even if it moves substantially at the poles, and has the advantage of allowing high-speed and stable sheet production.

実施例 以下、実施例を掲けて本発明を説明する。Example The present invention will be described below with reference to Examples.

実り例1〜4及び比較例1.2 35℃のオルンクーーフェノールpM液粘度から算出し
た固有粘度が0.62であるポリエチレンテレフタレー
トチップを180℃で真を乾燥したfi、90snφ直
径のスクリューを有する押出機で、280℃で熔融し、
次いでスリット巾2.5mtランド長15mの口金を有
するタイに送り、シートとして押し出し、冷却ドラムで
冷却固化してシート1に製造した。その際、口金のスリ
ット内部から、論1図のように、厚さ0.2Uの平板電
極をスリット下端に突出させ、ドラムとの間隔(電他間
距蛾)及び印加電圧を一々変えた9、また、実施例3で
は口金下にsi+’、ガスな117分の割合で供給した
Fruitful Examples 1 to 4 and Comparative Example 1.2 A polyethylene terephthalate chip with an intrinsic viscosity of 0.62 calculated from the viscosity of Orunkuphenol pM liquid at 35°C was dried at 180°C, and a screw with a diameter of 90 snφ was used. Melt at 280°C in an extruder with
Next, it was sent to a tie having a slit width of 2.5 m and a land length of 15 m, extruded as a sheet, and cooled and solidified in a cooling drum to produce Sheet 1. At that time, a flat plate electrode with a thickness of 0.2U was protruded from inside the slit of the cap to the lower end of the slit, as shown in Figure 1, and the distance from the drum (interval distance) and applied voltage were changed one by one9. Further, in Example 3, si+' and gas were supplied under the cap at a rate of 117 minutes.

一万、比較として、平板電極なしで口金に直接印加して
、または印加を中止した以外は実施例と同様に行ってシ
ーI・を製造した。
For comparison, Sea I was manufactured in the same manner as in the example except that the voltage was applied directly to the cap without a flat electrode or the application was stopped.

これらの結果をtnl衣に示す。These results are shown in tnl clothing.

第 1 表 *)重着不良な起こさずに安定して引取れる速度Table 1 *) Speed at which it can be taken off stably without causing poor loading.

【図面の簡単な説明】[Brief explanation of drawings]

図は平板電像の突出状況?例示する概略図である。 1:口金スリット部、 2:キャスデイングトラム。 3:平板1!他、    4:高電圧直流電源。 5:重合体 Is the figure showing the protrusion of the flat plate image? FIG. 2 is an illustrative schematic diagram. 1: Cap slit part, 2: Casting tram. 3: Flat plate 1! Others, 4: High voltage DC power supply. 5: Polymer

Claims (1)

【特許請求の範囲】[Claims] 口金から押出した熱可塑性重合体のシート状熔融物流を
移動冷却体に接触させて冷却固化するシートの製造方法
において、該口金のスリット内部から平板電極を移動冷
却体側に突出させ、かつ該電極と移動冷却体との間に直
流電圧を印加することを特徴とする熱可塑性重合体シー
トの製造方法。
A method for manufacturing a sheet in which a sheet-shaped molten flow of a thermoplastic polymer extruded from a die is brought into contact with a moving cooling body to cool and solidify, in which a flat plate electrode is protruded from inside the slit of the die towards the moving cooling body; 1. A method for producing a thermoplastic polymer sheet, comprising applying a DC voltage between the moving cooling body and the moving cooling body.
JP61091999A 1986-04-23 1986-04-23 Manufacture of thermoplastic polymer sheet Pending JPS62248618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61091999A JPS62248618A (en) 1986-04-23 1986-04-23 Manufacture of thermoplastic polymer sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61091999A JPS62248618A (en) 1986-04-23 1986-04-23 Manufacture of thermoplastic polymer sheet

Publications (1)

Publication Number Publication Date
JPS62248618A true JPS62248618A (en) 1987-10-29

Family

ID=14042115

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61091999A Pending JPS62248618A (en) 1986-04-23 1986-04-23 Manufacture of thermoplastic polymer sheet

Country Status (1)

Country Link
JP (1) JPS62248618A (en)

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