JPS62241977A - Water-based ink composition - Google Patents
Water-based ink compositionInfo
- Publication number
- JPS62241977A JPS62241977A JP61085177A JP8517786A JPS62241977A JP S62241977 A JPS62241977 A JP S62241977A JP 61085177 A JP61085177 A JP 61085177A JP 8517786 A JP8517786 A JP 8517786A JP S62241977 A JPS62241977 A JP S62241977A
- Authority
- JP
- Japan
- Prior art keywords
- water
- dye
- ink composition
- based ink
- ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000000975 dye Substances 0.000 claims abstract description 24
- VTDOEFXTVHCAAM-UHFFFAOYSA-N 4-methylpent-3-ene-1,2,3-triol Chemical compound CC(C)=C(O)C(O)CO VTDOEFXTVHCAAM-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000981 basic dye Substances 0.000 claims abstract description 3
- 239000000982 direct dye Substances 0.000 claims abstract description 3
- 239000000980 acid dye Substances 0.000 claims abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 239000000976 ink Substances 0.000 description 26
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002314 glycerols Chemical class 0.000 description 2
- -1 glycol ethers Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 2
- 235000012756 tartrazine Nutrition 0.000 description 2
- 239000004149 tartrazine Substances 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- AVERNFJXXRIVQN-XSDYUOFFSA-N 5-[(4-ethoxyphenyl)diazenyl]-2-[(e)-2-[4-[(4-ethoxyphenyl)diazenyl]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C1=CC(OCC)=CC=C1N=NC(C=C1S(O)(=O)=O)=CC=C1\C=C\C1=CC=C(N=NC=2C=CC(OCC)=CC=2)C=C1S(O)(=O)=O AVERNFJXXRIVQN-XSDYUOFFSA-N 0.000 description 1
- IURGIPVDZKDLIX-UHFFFAOYSA-M [7-(diethylamino)phenoxazin-3-ylidene]-diethylazanium;chloride Chemical compound [Cl-].C1=CC(=[N+](CC)CC)C=C2OC3=CC(N(CC)CC)=CC=C3N=C21 IURGIPVDZKDLIX-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- UZZFFIUHUDOYPS-UHFFFAOYSA-L disodium 4-amino-3,6-bis[[4-[(2,4-diaminophenyl)diazenyl]phenyl]diazenyl]-5-oxido-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Nc1ccc(N=Nc2ccc(cc2)N=Nc2c(N)c3c(O)c(N=Nc4ccc(cc4)N=Nc4ccc(N)cc4N)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(N)c1 UZZFFIUHUDOYPS-UHFFFAOYSA-L 0.000 description 1
- AOMZHDJXSYHPKS-UHFFFAOYSA-L disodium 4-amino-5-hydroxy-3-[(4-nitrophenyl)diazenyl]-6-phenyldiazenylnaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(N=NC=3C=CC=CC=3)C(O)=C2C(N)=C1N=NC1=CC=C([N+]([O-])=O)C=C1 AOMZHDJXSYHPKS-UHFFFAOYSA-L 0.000 description 1
- OOYIOIOOWUGAHD-UHFFFAOYSA-L disodium;2',4',5',7'-tetrabromo-4,5,6,7-tetrachloro-3-oxospiro[2-benzofuran-1,9'-xanthene]-3',6'-diolate Chemical compound [Na+].[Na+].O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(Br)=C([O-])C(Br)=C1OC1=C(Br)C([O-])=C(Br)C=C21 OOYIOIOOWUGAHD-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は水性インキ組成物に関するものである。[Detailed description of the invention] [Industrial application field] The present invention relates to a water-based ink composition.
従来、インクジェット、サインペン、ボールペン、フェ
ルトペン等に使用されている水性インキ組成物には、染
料の溶解性を高めて目詰りを防止するため、あるいは保
湿性を高めてインキの急速な乾燥を防止するために、エ
チレングリコール。Conventionally, water-based ink compositions used in inkjet pens, felt-tip pens, ballpoint pens, felt-tip pens, etc. have been designed to increase dye solubility to prevent clogging, or to increase moisture retention to prevent ink from drying out quickly. to ethylene glycol.
プロピレングリコール、グリセリン等の多価アルコール
類、ジエチレングリコール、トリエチレングリコール、
ポリエチレングリコール等のポリグリコール類、メチル
セロソルブ、メチルカルピトール、メチルトリグリコー
ル類のグリコールエーテル類ならびに塩基性のオキシア
ルキレン誘導体が使用されてきた（特開昭６０−２２４
８４号）。Polyhydric alcohols such as propylene glycol and glycerin, diethylene glycol, triethylene glycol,
Polyglycols such as polyethylene glycol, glycol ethers of methyl cellosolve, methyl calpitol, and methyl triglycols, and basic oxyalkylene derivatives have been used (JP-A-60-224).
No. 84).
しかしながら、このような従来の水性インキ組成物に使
用されている溶剤のうち、多価アルコール類、ポリグリ
コール類およびグリコールエーテル類は水によく溶け、
沸点が高いという特徴を持っているが、染料の溶解性が
十分ではなく、水溶液の粘度の温度による変化が大きく
て、使用する温度によっては、にじみ、かすれ、紙への
ひっかかり過ぎが起こるなどの問題点があった。However, among the solvents used in such conventional water-based ink compositions, polyhydric alcohols, polyglycols, and glycol ethers are highly soluble in water;
Although it has the characteristic of a high boiling point, the solubility of the dye is not sufficient, and the viscosity of the aqueous solution changes greatly depending on the temperature. There was a problem.
またオキシアルキレン誘導体はこれらの問題点を解決す
るものであるが、塩基性であるため、染料の種類によっ
ては溶解性が十分でなく、水性インキ組成物に使用でき
ない場合があるという問題点があった。Oxyalkylene derivatives solve these problems, but because they are basic, they do not have sufficient solubility depending on the type of dye and may not be able to be used in water-based ink compositions. Ta.
本発明は以上のような従来のものの問題点を解決するた
めになされたもので、特定のグリセリン誘導体を含有さ
せることにより、広範囲の染料に対する溶解性が高く、
また温度による粘度変化が少なく、このため季節、地域
が変ってもほとんど同じような書き味を示し、にじみ、
かすれ、紙へのひっかかり過ぎなどがない水性インキ組
成物を提供することを目的としている。The present invention was made to solve the problems of the conventional products as described above, and by containing a specific glycerin derivative, it has high solubility for a wide range of dyes.
In addition, there is little change in viscosity due to temperature, so even if the season or region changes, the writing taste remains almost the same, and there is no smudging or smudging.
The purpose of the present invention is to provide an aqueous ink composition that does not fade or stick to paper too much.
本発明はイソプロピリデングリセロールおよび水溶性染
料を含有することを特徴とする水性インキ組成物である
。The present invention is an aqueous ink composition characterized by containing isopropylidene glycerol and a water-soluble dye.
本発明において使用するイソプロピリデングリセロール
は水溶性染料の溶剤として使用されるもので、中性であ
るため広範囲の水溶性染料に対する溶解性が高い。Isopropylidene glycerol used in the present invention is used as a solvent for water-soluble dyes, and since it is neutral, it has high solubility for a wide range of water-soluble dyes.
本発明に使用する染料としては、水溶性染料であれぽい
かなる染料も使用可能である。このような水溶性染料を
例示すると、直接染料としては、Ｃ，１，ダイレクトブ
ラック１９．５１．１０８．１９４、Ｃ，Ｉ。As the dye used in the present invention, any water-soluble dye can be used. Examples of such water-soluble dyes include C,1, Direct Black 19.51.108.194, and C,I as direct dyes.
ダイレクトブルー２．８６．９３．９８、Ｃ，１，ダイ
レクトレッドｌ、 １７．２８． Ｃ，１，ダイレクト
イエロー１２゜２４、酸性染料としては、 Ｃ，１，ア
シッドブラック２゜３１、５２、Ｃ，１，アシッドブル
ー９．５９．９３．１０３． Ｃ。Direct Blue 2.86.93.98, C, 1, Direct Red L, 17.28. C,1, Direct Yellow 12°24, Acidic dyes include: C,1, Acid Black 2°31,52, C,1, Acid Blue 9.59.93.103. C.
■、アシッドレッド８７．９２．１５５、Ｃ，１，アシ
ッドイエロー２３．塩基性染料としては、Ｃ，１，ベー
シックブラック２，８、Ｃ，１，ベーシックブルー３，
７、Ｃ０工、ベーシックレッド１８．５２等があげられ
る。■, Acid Red 87.92.155, C, 1, Acid Yellow 23. Basic dyes include C,1, Basic Black 2,8, C,1, Basic Blue 3,
7, C0 work, Basic Red 18.52, etc.
本発明の水性インキ組成物は、イソプロピリデングリセ
ロールおよび水溶性染料を含む組成物であり、通常はさ
らに水を含む組成物とされる。このような組成物中の各
成分の含有量は、イソプロピリデングリセロールが２〜
６０重量％、水溶性染料が２〜１０重量％、水が３０〜
９６重量％であるのが好ましい。The aqueous ink composition of the present invention is a composition containing isopropylidene glycerol and a water-soluble dye, and usually further contains water. The content of each component in such a composition ranges from 2 to 20% isopropylidene glycerol.
60% by weight, 2 to 10% by weight of water-soluble dye, 30 to 10% of water
Preferably it is 96% by weight.
本発明の水性インキ組成物には、上記各成分のほか安定
剤、殺菌剤、表面張力調整剤などの他の添加剤を配合す
ることも可能である。また溶剤としては、イソプロピリ
デングリセロールと他の水溶性溶剤の併用も可能である
。In addition to the above-mentioned components, the aqueous ink composition of the present invention can also contain other additives such as stabilizers, bactericides, and surface tension regulators. Further, as the solvent, isopropylidene glycerol and other water-soluble solvents can be used in combination.
本発明はインクジェット、サインペン、ボールペン、フ
ェルトペン、その他の用途に使用される水性インキ組成
物に広く適用可能である。The present invention is widely applicable to aqueous ink compositions used for inkjet, felt-tip pens, ballpoint pens, felt-tip pens, and other applications.
本発明の水性インキ組成物は中性のグリセリン誘導体を
含むため、広範囲の染料に対する溶解性がよく、また温
度による粘度変化が少ないので、季節、地域が変っても
、使用感は一定しており。Since the water-based ink composition of the present invention contains a neutral glycerin derivative, it has good solubility for a wide range of dyes, and its viscosity does not change much with temperature, so the feeling of use remains constant even when the season or region changes. .
にじみ、かすれ、紙へのひっかかり過ぎがないなどの効
果がある。It has the effect of preventing bleeding, blurring, and excessive catching on the paper.
以下、本発明を実施例によりさらに詳細に説明する。 Hereinafter, the present invention will be explained in more detail with reference to Examples.
実施例１ 表１に示す化合物の２５重量％水溶液について。Example 1 Regarding a 25% by weight aqueous solution of the compounds shown in Table 1.
０〜４０℃の範囲で粘度を測定した。その結果を図面の
グラフおよび表２に示す。The viscosity was measured in the range of 0 to 40°C. The results are shown in the graph of the drawing and in Table 2.
表１
図面および表２の結果より、本発明品の水溶液の粘度の
温度変化が少ないことが明らかである。Table 1 From the results shown in the drawings and Table 2, it is clear that the viscosity of the aqueous solution of the product of the present invention changes little with temperature.
実施例２
Ｃ，１，ダイレクトブラック１９ ５．０重
量％インプロピリデングリセロール ２５．ＯＩＩ
イオン交換水 ７０．０ ＩＩ
上述の組成物を常温で混合して黒色インキを得た。比較
例としてイソプロピリデングリセロールの代りにグリセ
リンを用いて黒色インキを作った。Example 2 C,1, Direct Black 19 5.0% by weight Impropylidene Glycerol 25. OII
Ion exchange water 70.0 II
A black ink was obtained by mixing the above composition at room temperature. As a comparative example, a black ink was prepared using glycerin instead of isopropylidene glycerol.
得られた２種のインキの粘度を測定した結果は表３の通
りであり、実施例のインキの粘度の変化は小さかった。The results of measuring the viscosity of the two types of ink obtained are shown in Table 3, and the change in viscosity of the ink of Example was small.
また実施例のインキはにじんだり、かすれたりすること
はなく、優れた書き味であった。Furthermore, the ink of the example did not bleed or fade, and had an excellent writing quality.
表 ３
実施例３
Ｃ，１，アシッドレッド９２ ７．０重
量％イソプロピリデングリセロール ２３．０
＃イオン交換水 ７０．ＯＩＩ
上述の組成物、および比較例としてイソプロピリデング
リセロールの代りに、ポリエチレングリコール（平均分
子量２００）を使用し、５０℃で２種の赤色インキを得
た。−５℃まで冷却した結果、実施例のインキは何の変
化も示さなかったが、比較例のインキは染料が析出した
。実施例のインキの粘度は０℃で４ 、３ｃＳｔ、４０
℃で１，７ｃＳｔであり、粘度の変化は小さかった。ま
た実施例のインキはにじんだり、かすれたりすることは
なく、優れた書き味であった。Table 3 Example 3 C,1, Acid Red 92 7.0% by weight Isopropylidene glycerol 23.0
#Ion exchange water 70. OII
Two types of red inks were obtained at 50° C. using the above composition and polyethylene glycol (average molecular weight 200) instead of isopropylidene glycerol as a comparative example. As a result of cooling to -5°C, the ink of the example did not show any change, but the ink of the comparative example precipitated the dye. The viscosity of the ink of the example is 4.3 cSt at 0°C, 40
℃, and the change in viscosity was small. Furthermore, the ink of the example did not bleed or fade, and had an excellent writing quality.
実施例４
Ｃ，１，アシッドイエロー２３ ６．０重
量％イソプロピリデングリセロール ２２．Ｏｆｔ
イオン交換水 ７２．ＯＩｔ上
述の組成物、および比較例としてイソプロピリデングリ
セロールの代りにプロピレングリコールを使用し、実施
例２と同様にして２種の黄色インキを得た。２種の黄色
インキの粘度は表４に示す通りであり、実施例によるも
のの粘度の変化は小さかった。また実施例のインキはに
じんだり、かすれたりすることはなく、優れた書き味で
あった。Example 4 C,1, Acid Yellow 23 6.0% by weight isopropylidene glycerol 22. Oft
Ion exchange water 72. OIt Two yellow inks were obtained in the same manner as in Example 2, using the above composition and propylene glycol instead of isopropylidene glycerol as a comparative example. The viscosity of the two types of yellow inks is as shown in Table 4, and the change in viscosity of the ink according to the example was small. Furthermore, the ink of the example did not bleed or fade, and had an excellent writing quality.
表 ４
以上の結果より１本発明の水性インキ組成物は温度によ
る粘度変化が少なくて、染料の溶解性がよく、にじみ、
かすれ等がなくて優れた書き味であることがｂかる。Table 4 From the above results, 1 the water-based ink composition of the present invention shows little change in viscosity due to temperature, good solubility of dyes, and no bleeding.
It can be seen that there is no blurring and the writing quality is excellent.
図面は実施例１における温度と粘度の関係を示するグラ
フである。
代理人 弁理士 柳 原 成
二 面
温度（”Ｃ）The drawing is a graph showing the relationship between temperature and viscosity in Example 1. Agent Patent attorney Seiji Yanagihara Surface temperature (“C”)
Claims (3)
を含有することを特徴とする水性インキ組成物。(1) A water-based ink composition characterized by containing isopropylidene glycerol and a water-soluble dye.
中２〜６０重量％である特許請求の範囲第１項記載の水
性インキ組成物。(2) The aqueous ink composition according to claim 1, wherein the content of isopropylidene glycerol in the composition is 2 to 60% by weight.
料である特許請求の範囲第１項または第２項記載の水性
インキ組成物。(3) The water-based ink composition according to claim 1 or 2, wherein the water-soluble dye is a direct dye, an acid dye, or a basic dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61085177A JPS62241977A (en) | 1986-04-15 | 1986-04-15 | Water-based ink composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61085177A JPS62241977A (en) | 1986-04-15 | 1986-04-15 | Water-based ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62241977A true JPS62241977A (en) | 1987-10-22 |
| JPH0588872B2 JPH0588872B2 (en) | 1993-12-24 |
Family
ID=13851379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61085177A Granted JPS62241977A (en) | 1986-04-15 | 1986-04-15 | Water-based ink composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62241977A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008163238A (en) * | 2006-12-28 | 2008-07-17 | Ricoh Co Ltd | Recording ink, ink media set, ink cartridge, inkjet recording method, inkjet recording apparatus and ink recorded matter |
| WO2013115344A1 (en) * | 2012-02-03 | 2013-08-08 | Ricoh Company, Ltd. | Inkjet ink and inkjet recording device |
| US8906994B2 (en) | 2007-02-05 | 2014-12-09 | Rhodia Poliamida E Especialdades LTDA | Coating systems comprising dioxolane film-forming agents |
-
1986
- 1986-04-15 JP JP61085177A patent/JPS62241977A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008163238A (en) * | 2006-12-28 | 2008-07-17 | Ricoh Co Ltd | Recording ink, ink media set, ink cartridge, inkjet recording method, inkjet recording apparatus and ink recorded matter |
| US8906994B2 (en) | 2007-02-05 | 2014-12-09 | Rhodia Poliamida E Especialdades LTDA | Coating systems comprising dioxolane film-forming agents |
| WO2013115344A1 (en) * | 2012-02-03 | 2013-08-08 | Ricoh Company, Ltd. | Inkjet ink and inkjet recording device |
| US9528017B2 (en) | 2012-02-03 | 2016-12-27 | Ricoh Company, Ltd. | Inkjet ink and inkjet recording device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0588872B2 (en) | 1993-12-24 |
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