JPS62241616A - Liquid for wire-cut electrodischarge machining - Google Patents

Liquid for wire-cut electrodischarge machining

Info

Publication number
JPS62241616A
JPS62241616A JP8388886A JP8388886A JPS62241616A JP S62241616 A JPS62241616 A JP S62241616A JP 8388886 A JP8388886 A JP 8388886A JP 8388886 A JP8388886 A JP 8388886A JP S62241616 A JPS62241616 A JP S62241616A
Authority
JP
Japan
Prior art keywords
succaroid
reduced
machining
liquid
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8388886A
Other languages
Japanese (ja)
Inventor
Takahiko Uchida
隆彦 内田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kurita Water Industries Ltd
Original Assignee
Kurita Water Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kurita Water Industries Ltd filed Critical Kurita Water Industries Ltd
Priority to JP8388886A priority Critical patent/JPS62241616A/en
Publication of JPS62241616A publication Critical patent/JPS62241616A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To enhance anti-rust and anti-corrosion characteristics for the machined surfaces by forming the base liquid from pure water and using a machining liquid containing reduced succaroid and reduced succaroid alcohol and non-ionic interface active agent. CONSTITUTION:The processing liquid shall contain 0.01-2wt% reduced succaroid and reduced succaroid alcohol, and approx. 0.00005-0.001wt% non-ionic interface active agent. Thus the reduced succaroid or reduced succaroid alcohol suppresses oxidation of the whole work to be processed caused by dissolved oxygen in the machining liquid or abrupt oxidation of the processing surface due to discharge during machining to lead to prevention of rusts. Rusting of a work often derives from deposition of processing chips onto the surface of the liquid machining body, but the non-ionic interface active agent interacts with the reduced succaroid and reduced succaroid alcohol to provide effective prevention of deposition of the machining chips.

Description

【発明の詳細な説明】 [産業上の利用分野] られる加工液に係り、特に、防錆・防食作用を有するワ
イヤカット用放電加工液に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a machining fluid, particularly an electric discharge machining fluid for wire cutting that has antirust and anticorrosion effects.

[従来の技術] ワイヤカット方式放電加工は、被加工体と僅か′な1?
11隔(10数IL)を設けてワイヤ状の71!極を設
こし、加工液を噴射させながら被加工体を移動させて加
工したい所に至ったときに、間欠的に放電させ、その熱
で被加工体を局部的に軟化、溶融すると共に、加工液の
一部が放電柱で急激に蒸発。
[Conventional technology] Wire-cut electric discharge machining requires only a small distance from the workpiece.
71 wire-shaped with 11 intervals (10-odd IL)! A pole is installed, the workpiece is moved while spraying machining fluid, and when it reaches the desired location, it is intermittently discharged, and the heat locally softens and melts the workpiece, and the workpiece is machined. Part of the liquid evaporates rapidly in the discharge column.

気化し、その強圧力で溶融部分を吹き飛ばすと同時に被
加工体微粉末を冷却し、系外に排出するものである。ワ
イヤカット方式放電加工では、被加工体を加工液中に浸
漬した状態で加工する型彫方式とは異なり、加工液を大
気中で被加工体に局部的に噴射させるため、被加工液に
よる乾潤状態が繰り返されることが多い。
It vaporizes, blows off the molten part with its strong pressure, and at the same time cools the fine powder of the workpiece and discharges it out of the system. Unlike the die-sinking method, in which the workpiece is machined while immersed in the machining fluid, wire-cut electric discharge machining uses the machining fluid to be sprayed locally onto the workpiece in the atmosphere, so the drying process caused by the workpiece fluid is prevented. The wet state is often repeated.

従来、放電加工液としては、炭化水素油が使用されてい
たが、着火の問題があるため、近年、純水系の不燃性加
工液が主流となりつつある。
Conventionally, hydrocarbon oil has been used as the electrical discharge machining fluid, but due to the problem of ignition, pure water-based nonflammable machining fluids have become mainstream in recent years.

通常、この加工液は排出後、*過によりSS*分を除去
した後、再使用するが、その電気伝導度に応じて、伝導
度が高い場合には、濾過水を更に混床式イオン交換樹脂
塔に通水し、液中の溶解性不純物を除去したのち、再使
用する(通常、加工液の電気伝導度は1o−iooルS
 / c m程度とされる。)。これは、加工液の電気
伝導度が上昇すると、加工精度の良好な放電加工が望め
なくなるためであり、イオン交換処理により加工液の電
気伝導度が調整される。
Normally, this processing fluid is reused after being drained and the SS* component is removed by *filtration. Water is passed through the resin tower to remove soluble impurities in the liquid, and then reused (normally, the electrical conductivity of the processing liquid is 1o-ioolS).
/ cm. ). This is because if the electrical conductivity of the machining fluid increases, electrical discharge machining with good machining accuracy cannot be expected, and the electrical conductivity of the machining fluid is adjusted by the ion exchange treatment.

ところで、ワイヤカット方式放電加工では、被加工体は
前述の如く加工液により乾潤状態が繰返される厳しい腐
食環境下にさらされ、しかも、この方式では細い溝状の
間隙が形成されるため、加工時に発生する被加工体や電
極、ワイヤ等の切り屑等の加工チップが付着(残留)し
易くなる。しかして、一旦、加工チップが付着すると、
そこに酸素濃淡電池が形成され、被加工体、特に鋼材等
の金属被加工体は極めて発錆し易くなる0発錆は、単に
被加工体の外観を悪くするばかりでなく、加工精度を低
下させ、仕上げのための高次加工を阻害するなど多くの
問題を生ずることとなる。
By the way, in wire-cut electrical discharge machining, the workpiece is exposed to a severe corrosive environment in which the workpiece is repeatedly wetted by the machining fluid as described above.Moreover, in this method, narrow groove-like gaps are formed, making the machining difficult. Machining chips such as chips from the workpiece, electrodes, wires, etc. that are sometimes generated tend to adhere (remain). However, once the processed chip is attached,
An oxygen concentration cell is formed there, and the workpiece, especially metal workpieces such as steel, is extremely susceptible to rust. Zero rusting not only deteriorates the appearance of the workpiece, but also reduces machining accuracy. This causes many problems such as inhibiting high-order processing for finishing.

このため、従来より被加工体の防錆のために、純水に防
錆剤を添加した加工液が使用されており、亜硝酸塩やり
ん酸塩などの既知のイオン性防錆剤を添加すること(特
開昭5l−147096)が提案された。しかしながら
、イオン性防錆剤の添加は、加工液の電気伝導度を上昇
させ、加工精度が低下すると共に、常時イオン交換樹脂
塔が運転されることとなり、加工液中の防錆剤濃度の低
下、イオン交換樹脂の寿命短縮、その他樹脂塔の稼動コ
スト等の面で極めて不経済となる。
For this reason, machining fluids made by adding rust preventive agents to pure water have traditionally been used to prevent rust on workpieces, and known ionic rust preventive agents such as nitrites and phosphates have been added It was proposed (Japanese Unexamined Patent Publication No. 51-147096). However, the addition of ionic rust inhibitors increases the electrical conductivity of the machining fluid, reducing machining accuracy, and requires the ion exchange resin tower to be constantly operated, resulting in a decrease in the rust inhibitor concentration in the machining fluid. This is extremely uneconomical in terms of shortening the life of the ion exchange resin and increasing operating costs of the resin tower.

このようなことなから、非イオン系の防錆剤として例え
ば、糖類(特開昭56−107843号)、グリコール
類(特開昭56−107844号)、多価アルコール(
同57−132931号)等が提案されている。
For this reason, nonionic rust preventives such as sugars (Japanese Unexamined Patent Publication No. 56-107843), glycols (Japanese Unexamined Patent Application No. 56-107844), polyhydric alcohols (
No. 57-132931), etc. have been proposed.

[発明が解決しようとする問題点] しかしながら、従来の防錆剤ではいずれも十分に満足し
得る効果が得られない、上記従来の防錆剤のうち、糖類
は比較的好ましいものと言えるが、糖類のみで前述の加
工中の加工チップの付着した被加工体の発錆を防ぐため
には、多量添加が必要となる。この場合には、糖類等の
非イオン系防錆剤を高濃度に含有する加工液の飛沫によ
り、加工機周辺がベトつくなどの新たな問題が生起する
こととなる。
[Problems to be Solved by the Invention] However, none of the conventional rust preventive agents achieves a sufficiently satisfactory effect.Among the above conventional rust preventive agents, sugars can be said to be relatively preferable; In order to prevent rusting of the workpiece to which processed chips are attached during the above-mentioned processing using only sugars, it is necessary to add a large amount. In this case, new problems arise such as the area around the processing machine becoming sticky due to splashes of the processing fluid containing a high concentration of nonionic rust preventives such as sugars.

[問題点を解決するための手段] 本発明は上記従来の問題点を解決し、低い非イオン系防
錆剤濃度で著しく優れた防錆、防食効果を奏するワイヤ
カット用放電加工液を提供するものであって、 純水をベース液とし、かつ還元糖及び/又は還元糖アル
コールと非イオン性界面活性剤とを含むことを特徴とす
るワイヤカット用放電加工液、を要旨とするものである
[Means for Solving the Problems] The present invention solves the above-mentioned conventional problems and provides an electrical discharge machining fluid for wire cutting that exhibits extremely excellent antirust and anticorrosion effects with a low concentration of nonionic rust inhibitor. The gist of the present invention is an electric discharge machining fluid for wire cutting, which uses pure water as a base liquid and contains reducing sugar and/or reducing sugar alcohol and a nonionic surfactant. .

以下に本発明の詳細な説明する。The present invention will be explained in detail below.

本発明のワイヤカット用放電加工液は、還元糖及び/又
は還元糖アルコールと非イオン性界面活性剤とを含むも
のである− 還元糖としては、一般式 %式% (ただし、n=2〜工0の整数) で表わされる単糖類、その他マルトース型二糖類、三糖
類等が挙げられ、これらの還元糖は1種を単独で、ある
いは2種以上を混合して用いることができる。還元糖と
してはブドウ糖(D−グルコース)が好適である。
The electrical discharge machining fluid for wire cutting of the present invention contains reducing sugar and/or reducing sugar alcohol and a nonionic surfactant. monosaccharides represented by (an integer of ) and other maltose-type disaccharides, trisaccharides, etc., and these reducing sugars can be used singly or in a mixture of two or more. Glucose (D-glucose) is suitable as the reducing sugar.

また、還元糖アルコールとしては、D−グルコース等の
還元により得られるD−ソルビトールが好ましい。
Moreover, as the reducing sugar alcohol, D-sorbitol obtained by reduction of D-glucose or the like is preferable.

非イオン性界面活性剤としては、エチレンオキサイド残
基(以下rEOJと略記する。)を含むHLB8〜12
の非イオン性エーテル系界面活性剤が好ましく1例えば
、EOとプロピレンオキサイド“(以下「PO」と略記
する。)の共重合体系のものが挙げられる。その他、非
イオン性界面活性剤としては、下記■、■も使用するこ
とができる。
Nonionic surfactants include HLB8-12 containing ethylene oxide residue (hereinafter abbreviated as rEOJ).
Preferred nonionic ether surfactants include those based on a copolymer of EO and propylene oxide (hereinafter abbreviated as "PO"). In addition, as nonionic surfactants, the following (1) and (2) can also be used.

■ ポリオキシエチレンアルキルフェニルエーテル系界
面活性剤 例えば、ポリオキシエチレンドデシルフェニルエーテル
、ポリオキシエチレンノニルフェニルエーテル等 ■ ポリオキシエチレンアルキルエーテル系界面活性剤 RO(CH2CH20)nH 例えばポリオキシエチレンオレイルエーテル(HLB8
)等 これらの非イオン系界面活性剤はEO含有量が5〜50
モル%であることが好ましく、またその分子量は500
〜10000、特に1000〜5000であることが好
ましい。
■ Polyoxyethylene alkyl phenyl ether surfactant, such as polyoxyethylene dodecyl phenyl ether, polyoxyethylene nonylphenyl ether, etc. ■ Polyoxyethylene alkyl ether surfactant RO (CH2CH20)nH For example, polyoxyethylene oleyl ether (HLB8
) etc. These nonionic surfactants have an EO content of 5 to 50
It is preferable that the molecular weight is 500 mol%.
-10,000, particularly preferably 1,000-5,000.

なお、非イオン性界面活性剤のうち、エステル系のもの
は、加工中にスカムを発生する難点があり、好ましくな
い。
Note that among nonionic surfactants, ester-based surfactants are not preferred because they generate scum during processing.

本発明の加工液は、このような還元糖及び/又は還元糖
アルコールと非イオン系界面活性剤を純水に混合して容
易に調整されるが、加工液は、これらの添加剤の低濃度
添加で著しく優れた防錆、防食効果を奏することから、
一般には、加工液中の還元糖及び/又は還元糖アルコー
ルの濃度は0、O1〜2重量%程度、非イオン系界面活
性剤の濃度は、o、oooos〜o、ooi重量%とな
るようにするのが好ましい。
The processing fluid of the present invention is easily prepared by mixing such reducing sugars and/or reducing sugar alcohols and nonionic surfactants with pure water, but the processing fluid has low concentrations of these additives. Because its addition provides extremely excellent anti-rust and anti-corrosion effects,
In general, the concentration of reducing sugar and/or reducing sugar alcohol in the processing liquid is about 0, 1 to 2% by weight, and the concentration of nonionic surfactant is about o, oooos to o, ooi % by weight. It is preferable to do so.

[作用] 本発明のワイヤカット用放電加工液は、還元糖や還元糖
アルコールと非イオン性界面活性剤とにより、良好な発
錆、防食効果を奏する。
[Function] The electrical discharge machining fluid for wire cutting of the present invention exhibits good rust and corrosion prevention effects due to the reducing sugar or reducing sugar alcohol and the nonionic surfactant.

即ち、還元糖や還元糖アルコールは、加工時の放電によ
る加工表面の急激な酸化や加工液中に含まれる溶存酸素
による被加工体全体の酸化を抑制することにより、発錆
を防止する機能を有している。
In other words, reducing sugars and reducing sugar alcohols have the function of preventing rust by suppressing the rapid oxidation of the machined surface due to electric discharge during machining and the oxidation of the entire workpiece due to dissolved oxygen contained in the machining fluid. have.

一方、被加工体の発錆は、前述の如く、加工チップの被
加工体表面への沈着に起因することが多いが、非イオン
性界面活性剤は、還元糖及び/又は還元糖アルコールと
の相乗効果で、この加工チップの沈着を効率的に防止す
る。
On the other hand, as mentioned above, rusting of the workpiece is often caused by the deposition of processed chips on the surface of the workpiece, but nonionic surfactants are The synergistic effect effectively prevents the deposition of processed chips.

[実施例] 以下、実施例及び比較例を挙げて本発明をより具体的に
説明するが、本発明はその要旨を超えない限り、以下の
実施例に限定されるものではない。
[Examples] Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to the following Examples unless it exceeds the gist thereof.

実施例1〜4、比較例1〜6 鋼材(S55C: loOX250X40mm)を、ワ
イヤカット方式放電加工機によりワイヤ径0.2mmの
真鍮ワイヤを用い、第1表に示す加工液を水圧2 k 
g / c m″で給水して、1mm/minの加工速
度でコの字型(5X80X40mmX 2)に加工し、
その後15時間放置した。
Examples 1 to 4, Comparative Examples 1 to 6 Steel materials (S55C: loOX250X40 mm) were processed using a wire-cut electric discharge machine using a brass wire with a wire diameter of 0.2 mm, and the machining fluid shown in Table 1 was heated to a water pressure of 2 k.
Supply water at a rate of g/cm'' and process into a U-shape (5 x 80 x 40 mm x 2) at a processing speed of 1 mm/min.
After that, it was left to stand for 15 hours.

放置後、各5X80X40mmの2枚に切り出して初期
重量(Wi)を測定した。そ゛の後、各々の加工物をイ
ンヒビター入り塩酸により脱錆後、後玉ff1(Wf)
を測定した。この2枚の平均重量差(Wi−Wf)及び
加工物の発錆状況を第1表に示す。
After standing, it was cut into two pieces each measuring 5 x 80 x 40 mm, and the initial weight (Wi) was measured. After that, after derusting each workpiece with hydrochloric acid containing an inhibitor, the second ball ff1 (Wf)
was measured. Table 1 shows the average weight difference (Wi-Wf) between the two sheets and the rusting state of the workpiece.

W i −W fは、加工チップの付着物量と発錆した
場合の重量との和を表し、W i −W fが少ないほ
ど加工面に加工チップの付着および発錆が少ないことを
表している。なお、W i −W fは外観上全く付着
物がない場合でも約30mg/76crn’程度はあり
、40〜60mg/76crn’であれば十分に実用的
である。
W i −W f represents the sum of the amount of deposits on the processed chip and the weight when rust occurs, and the smaller W i −W f represents the less adhesion of the processed chip to the processed surface and the less rust formation. . In addition, W i -W f is about 30 mg/76 crn' even when there is no deposit at all in appearance, and 40 to 60 mg/76 crn' is sufficiently practical.

なお、第1表中※1〜※4のA−Dは各々、下記に示す
分子量、EO含量(残部PO)のEO−PO共重合体系
非イオン性界面活性剤である。
Note that A-D in *1 to *4 in Table 1 are EO-PO copolymer type nonionic surfactants having the molecular weights and EO contents (remaining PO) shown below.

第1表より、本発明の加工液によれば、被加工体への加
工チップのイ、1着を防ぎ、発錆を効果的に防止するこ
とができることが明らかである。
From Table 1, it is clear that the machining liquid of the present invention can prevent machining chips from sticking to the workpiece and can effectively prevent rusting.

第1表 [発明の効果] 以]二詳述した通り、本発明のワイヤカット用放電加工
液は、純水に還元糖及び/又は還元糖アルコールと非イ
オン性界面活性剤を含むものであって、優れた防錆、防
食効果を有すると共に、■ 非イオン性であるため加工
液の電気伝導度を上げることがないので、イオン交換塔
の負荷を増加させることがなく、また精密加工が可能で
ある。
Table 1 [Effects of the Invention] As described in detail below, the electrical discharge machining fluid for wire cutting of the present invention contains reducing sugar and/or reducing sugar alcohol and a nonionic surfactant in pure water. It has excellent anti-rust and anti-corrosion effects, and ■ Since it is non-ionic, it does not increase the electrical conductivity of the machining fluid, so it does not increase the load on the ion exchange tower and allows precision machining. It is.

■ 二元糖や還元糖アルコールの必要添加量を大幅に低
減することができる。
■ The required amount of binary sugars and reducing sugar alcohols can be significantly reduced.

■ このため、加工液飛沫による加工機周辺のベトつき
を防止することができる。
- Therefore, it is possible to prevent the area around the processing machine from becoming sticky due to splashes of processing fluid.

等の利点を有する。It has the following advantages.

このため本発明のワイヤカット用放電加工液によれば、
経済的かつ高い加工精度のもとに、良好な加工を行うこ
とが可能とされる。
Therefore, according to the electrical discharge machining liquid for wire cutting of the present invention,
It is possible to perform good machining economically and with high machining accuracy.

Claims (4)

【特許請求の範囲】[Claims] (1)純水をベース液とし、かつ還元糖及び/又は還元
糖アルコールと非イオン性界面活性剤とを含むことを特
徴とするワイヤカット用放電加工液。
(1) An electric discharge machining fluid for wire cutting, which uses pure water as a base liquid and contains reducing sugar and/or reducing sugar alcohol and a nonionic surfactant.
(2)還元糖がブドウ糖であることを特徴する特許請求
の範囲第1項に記載の放電加工液。
(2) The electrical discharge machining fluid according to claim 1, wherein the reducing sugar is glucose.
(3)還元糖アルコールがD−ソルビトールであること
を特徴とする特許請求の範囲第1項又は第2項に記載の
放電加工液。
(3) The electric discharge machining fluid according to claim 1 or 2, wherein the reducing sugar alcohol is D-sorbitol.
(4)非イオン性界面活性剤はエチレンオキサイド残基
を5〜50モル%含むものであることを特徴とする特許
請求の範囲第1項ないし第3項のいずれか1項に記載の
放電加工液。
(4) The electric discharge machining fluid according to any one of claims 1 to 3, wherein the nonionic surfactant contains 5 to 50 mol% of ethylene oxide residue.
JP8388886A 1986-04-11 1986-04-11 Liquid for wire-cut electrodischarge machining Pending JPS62241616A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8388886A JPS62241616A (en) 1986-04-11 1986-04-11 Liquid for wire-cut electrodischarge machining

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8388886A JPS62241616A (en) 1986-04-11 1986-04-11 Liquid for wire-cut electrodischarge machining

Publications (1)

Publication Number Publication Date
JPS62241616A true JPS62241616A (en) 1987-10-22

Family

ID=13815190

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8388886A Pending JPS62241616A (en) 1986-04-11 1986-04-11 Liquid for wire-cut electrodischarge machining

Country Status (1)

Country Link
JP (1) JPS62241616A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5081333A (en) * 1989-03-17 1992-01-14 Mitsubishi Denki Kabushiki Kaisha Electric discharge machining fluid with a fatty acid amide additive for rust inhibition
US5349149A (en) * 1989-10-04 1994-09-20 Castrol Limited Burmah Castrol House Dual-purpose fluid for cutting and electrical discharge machining
CN103386520A (en) * 2013-07-15 2013-11-13 北京东兴润滑剂有限公司 Recyclable electric-spark drilling fluid of electrode without conicity and with low loss

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5081333A (en) * 1989-03-17 1992-01-14 Mitsubishi Denki Kabushiki Kaisha Electric discharge machining fluid with a fatty acid amide additive for rust inhibition
US5349149A (en) * 1989-10-04 1994-09-20 Castrol Limited Burmah Castrol House Dual-purpose fluid for cutting and electrical discharge machining
CN103386520A (en) * 2013-07-15 2013-11-13 北京东兴润滑剂有限公司 Recyclable electric-spark drilling fluid of electrode without conicity and with low loss

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