JPS62224261A - Prevention of fading of meat food - Google Patents
Prevention of fading of meat foodInfo
- Publication number
- JPS62224261A JPS62224261A JP61066666A JP6666686A JPS62224261A JP S62224261 A JPS62224261 A JP S62224261A JP 61066666 A JP61066666 A JP 61066666A JP 6666686 A JP6666686 A JP 6666686A JP S62224261 A JPS62224261 A JP S62224261A
- Authority
- JP
- Japan
- Prior art keywords
- meat
- sodium
- fading
- ascorbate
- kojic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013372 meat Nutrition 0.000 title claims abstract description 26
- 235000013305 food Nutrition 0.000 title claims abstract description 17
- 238000005562 fading Methods 0.000 title abstract description 5
- 230000002265 prevention Effects 0.000 title 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229960004705 kojic acid Drugs 0.000 claims abstract description 12
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 claims abstract description 11
- 239000011755 sodium-L-ascorbate Substances 0.000 claims abstract description 8
- 235000019187 sodium-L-ascorbate Nutrition 0.000 claims abstract description 8
- 238000002845 discoloration Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- 235000013580 sausages Nutrition 0.000 abstract description 5
- 241000251468 Actinopterygii Species 0.000 abstract description 4
- 241001465754 Metazoa Species 0.000 abstract description 4
- 235000015241 bacon Nutrition 0.000 abstract description 3
- 239000003112 inhibitor Substances 0.000 abstract description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000002211 L-ascorbic acid Substances 0.000 description 5
- 235000000069 L-ascorbic acid Nutrition 0.000 description 5
- 229960005070 ascorbic acid Drugs 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000015277 pork Nutrition 0.000 description 3
- PPASLZSBLFJQEF-RKJRWTFHSA-M sodium ascorbate Substances [Na+].OC[C@@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RKJRWTFHSA-M 0.000 description 3
- 229960005055 sodium ascorbate Drugs 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000019688 fish Nutrition 0.000 description 2
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- 150000002826 nitrites Chemical class 0.000 description 2
- 235000013594 poultry meat Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 235000021067 refined food Nutrition 0.000 description 2
- 235000010378 sodium ascorbate Nutrition 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- 241000271566 Aves Species 0.000 description 1
- 235000019542 Cured Meats Nutrition 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-araboascorbic acid Natural products OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- 101100136092 Drosophila melanogaster peng gene Proteins 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 108010024636 Glutathione Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- 235000015429 Mirabilis expansa Nutrition 0.000 description 1
- 244000294411 Mirabilis expansa Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000010350 erythorbic acid Nutrition 0.000 description 1
- 239000004318 erythorbic acid Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229960003180 glutathione Drugs 0.000 description 1
- 235000003969 glutathione Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013536 miso Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 235000005152 nicotinamide Nutrition 0.000 description 1
- 239000011570 nicotinamide Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000020995 raw meat Nutrition 0.000 description 1
- 235000019992 sake Nutrition 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は肉類食品の退色防止方法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a method for preventing discoloration of meat foods.
獣肉類、鳥肉類、魚肉類またはそれらの食肉類を原料と
するハム、ソーセージ、ベーコン等の加工食品の商品価
値はそれらの鮮かな色調が保持されるか否かによって著
しく左右されるものである。The commercial value of animal meat, poultry, fish, or processed foods made from these meats, such as ham, sausage, and bacon, is significantly influenced by whether or not their bright colors are maintained. .
そのため、従来から亜硝酸塩、硝酸塩などを使用して肉
類食品に美しい色調を付与する等の工夫が行われて来た
。また発色助剤、退色防止剤としては、L−アスコルビ
ン酸、エリソルビン酸、ニコチン酸アミド、またはシス
ティン、グルタチオン等の添加を行うことが知られてい
た。For this reason, efforts have been made to impart beautiful colors to meat foods using nitrites, nitrates, and the like. It has also been known to add L-ascorbic acid, erythorbic acid, nicotinic acid amide, cysteine, glutathione, etc. as a color development aid and a discoloration inhibitor.
しかしながら、これまでの退色防止方法はまだ十分な効
果を有するものではなく、より長時間退色を防止する経
済的な方法が望まれていた。However, conventional methods for preventing discoloration have not yet been sufficiently effective, and an economical method for preventing discoloration for a longer period of time has been desired.
本発明者は、肉類食品の色調改良剤として有効な物質に
ついて安全(無害)で水溶性しかも微量で有効なものを
、種々の天然成分中に探索した。The present inventors searched for substances in various natural ingredients that are safe (harmless), water-soluble, and effective in trace amounts as color improvers for meat foods.
その結果、日本酒、味噌、醤油等の製造に用いられるコ
ウジに含まれているコウジ酸と、既知発色助剤あるいは
退色防止剤であるし一アスコルビン酸ナトリウムとを併
用すると、それら2剤の相乗効果により極めて有効に肉
類食品の退色が防止されることを発見し、本発明を完成
するに至った。As a result, when kojic acid contained in koji, which is used in the production of sake, miso, soy sauce, etc., is used in combination with sodium monoascorbate, which is a known color development aid or anti-fading agent, the synergistic effect of the two agents was found. The present inventors have discovered that discoloration of meat foods can be extremely effectively prevented by this method, and have completed the present invention.
すなわち本発明は、コウジ酸及びL−アスコルビン酸す
) IJウムを肉類食品に含有せしめることを特徴とす
る肉類食品の退色防止方法である。That is, the present invention is a method for preventing discoloration of meat foods, which comprises incorporating kojic acid and L-ascorbic acid into the meat foods.
本発明において、肉類食品とは、獣肉類、鳥肉頌、魚肉
類等の生肉並びにそれらを原材料として製造される塩漬
肉や、ハム、ソーセージ、ベーコン等の加工製品を言う
。また肉類食品の退色とは、肉類が未加工の状態で有す
る赤味や、亜硝酸塩、硝酸塩等の使用によって発色した
赤味が、光の作用や酸化等によって外観主群かさを失う
ことを言う。In the present invention, the term "meat food" refers to raw meat such as animal meat, poultry meat, and fish meat, as well as cured meat produced using these as raw materials, and processed products such as ham, sausage, and bacon. Discoloration of meat foods refers to the redness that meat has in its unprocessed state, or the redness that develops due to the use of nitrites, nitrates, etc., that loses its appearance and bulk due to the action of light, oxidation, etc. .
本発明の実施に際しては、コウジ酸及びL−アスコルビ
ン酸ナトリウムが人体に無害であることから、その使用
量を厳しく限定する必要はないが、添加する肉類食品の
総量に対して、コウジ酸及びL−アスコルビン酸ナトリ
ウムは合計量で0.01〜1.0重量%を添加すること
が望ましい。またコウジ酸とL−アスコルビン酸ナトリ
ウムとの重量比は、コウジ酸11 g iに対してL−
アスコルビン酸ナトリウムが、0,1〜20重1部、好
ましくは0.5〜2重量部であることが望ましい。コウ
ジ酸とL−アスコルビン酸ナトリウムとは、1剤に混合
し、または2剤のままで同時に使用してもよ(、あるい
は2剤を別々の工程で使用し、最終的に2剤を含有する
肉類食品を形成せしめてもよい。When carrying out the present invention, there is no need to strictly limit the amount of kojic acid and sodium L-ascorbate used, as they are harmless to the human body. - It is desirable to add sodium ascorbate in a total amount of 0.01 to 1.0% by weight. The weight ratio of kojic acid to sodium L-ascorbate is 11 g of kojic acid to L-sodium ascorbate.
The amount of sodium ascorbate is preferably 0.1 to 20 parts by weight, preferably 0.5 to 2 parts by weight. Kojic acid and sodium L-ascorbate may be mixed into one agent or used simultaneously as two agents (or the two agents may be used in separate steps and the final product containing the two agents may be used simultaneously). Meat foods may also be formed.
まず、獣類、鳥類、魚類等の解体時には、洗浄用水とし
てコウジ酸及びL−アスコルビン酸ナトリウムの水溶液
を使用したり、または高濃度の水溶液として、あるいは
粉末のままで2剤を解体した肉にすり込む等の方法で使
用することができる。First, when dissecting animals, birds, fish, etc., an aqueous solution of kojic acid and sodium L-ascorbate is used as washing water, or the two agents are rubbed into the dissected meat as a highly concentrated aqueous solution or as a powder. It can be used in the following ways.
コストの面から考えれば、噴霧機を用いて、解体、水洗
後の各工程において該水溶液を噴霧することが最も有効
な利用方法である。加工食品として製造する場合も、同
様の方法で塩漬時または練合時等に随時添加することが
できる。From a cost standpoint, the most effective method is to use a sprayer to spray the aqueous solution in each step after dismantling and washing with water. When producing a processed food, it can be added at any time during salting or kneading using the same method.
本発明の肉類食品の退色防止方法を使用することによっ
て、肉類食品の退色を有効に防止することができる。By using the method for preventing discoloration of meat foods of the present invention, discoloration of meat foods can be effectively prevented.
〔実施例−1〕
豚赤身ひき肉60重里部、塩化ナトリウム3.2玉量部
、ポリリン酸ナトリウム0.5重量部、亜硝酸す)IJ
ウム0.1重1部、でんぷん3.5重里部、水33重量
部および第1表に示す混合割合の添加物を加えて練合し
、4℃で20時間キユアリングし、75℃で65分間加
熱した。これを4℃で24時間保存後、それらの外観を
色差計〔日本1色工業ND−101D型〕でL(明度)
、a(赤身と緑色)、b(黄色味と青味)を測定した。[Example-1] 60 parts by weight of lean pork minced meat, 3.2 parts by weight of sodium chloride, 0.5 parts by weight of sodium polyphosphate, IJ
0.1 parts by weight of starch, 3.5 parts by weight of starch, 33 parts by weight of water, and the additives in the mixing ratio shown in Table 1 were added and kneaded, cured at 4°C for 20 hours, and then cured at 75°C for 65 minutes. Heated. After storing this at 4℃ for 24 hours, their appearance was measured using a color difference meter [Nippon Isshoku Kogyo ND-101D model] as L (lightness).
, a (red and green), and b (yellow and bluish) were measured.
この検体を4℃で12時時間先灯照射(40ルツクス)
したのち色差計にてり、、a、bを測定した。This specimen was irradiated with a headlight for 12 hours at 4℃ (40 lux).
Thereafter, a and b were measured using a color difference meter.
保存後の保存前に対するa値の残存率を求め第1表に示
した。The residual rate of a value after storage compared to before storage was determined and shown in Table 1.
第1表
〔実施例−2〕
豚ひき肉400 g、牛ひき肉130g、豚脂150g
、食塩30g、亜硝酸ナトリウム0.1 g 。Table 1 [Example-2] 400 g of ground pork, 130 g of ground beef, 150 g of pork fat
, 30 g of table salt, 0.1 g of sodium nitrite.
メクリン酸ナトリウム2.5g、ポリリン酸ナトリウム
2.5 g 、氷、水230g、砂u4g、グルタミン
酸ナトリウム2g1卵白粉末10gおよびでんぷん35
gに、L−アスコルビン酸ナトリウム1.0g(対照)
またはコウジ酸およびL−アスコルビン酸を1.0gを
加えたものを、それぞれ練合し、折径3. Q c鵬の
塩化ビニリデン系ケーシングに充填し、80℃(で40
分間加熱後、冷却してソーセージを製造した。2.5 g of sodium meclate, 2.5 g of sodium polyphosphate, ice, 230 g of water, 4 g of sand, 2 g of sodium glutamate, 10 g of egg white powder, and 35 g of starch.
g, 1.0 g of sodium L-ascorbate (control)
Alternatively, 1.0 g of kojic acid and L-ascorbic acid are kneaded, and the folded size is 3.0 g. Filled in Qc Peng's vinylidene chloride casing and heated to 80℃ (40℃)
After heating for a minute, the mixture was cooled to produce sausages.
このソーセー ジをスライスして、室内散乱光下に4時
間放置して外観を観察したところ、L−アスコルビン酸
添加物(対照)に比べて、コウジ酸とL−アスコルビン
酸の添加物の外観は赤く、退色が少なく良好であった。When this sausage was sliced and left under indoor scattered light for 4 hours to observe its appearance, it was found that the appearance of the kojic acid and L-ascorbic acid additives was lower than that of the L-ascorbic acid additive (control). It was red and in good condition with little fading.
Claims (1)
に含有せしめることを特徴とする肉類食品の退色防止方
法。A method for preventing discoloration of meat foods, which comprises incorporating kojic acid and sodium L-ascorbate into the meat foods.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61066666A JPS62224261A (en) | 1986-03-25 | 1986-03-25 | Prevention of fading of meat food |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61066666A JPS62224261A (en) | 1986-03-25 | 1986-03-25 | Prevention of fading of meat food |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62224261A true JPS62224261A (en) | 1987-10-02 |
JPH0525463B2 JPH0525463B2 (en) | 1993-04-13 |
Family
ID=13322452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61066666A Granted JPS62224261A (en) | 1986-03-25 | 1986-03-25 | Prevention of fading of meat food |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62224261A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63269942A (en) * | 1987-04-28 | 1988-11-08 | Seiwa Kasei Kk | Tyrosinase inhibitor for food |
-
1986
- 1986-03-25 JP JP61066666A patent/JPS62224261A/en active Granted
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63269942A (en) * | 1987-04-28 | 1988-11-08 | Seiwa Kasei Kk | Tyrosinase inhibitor for food |
JPH0455660B2 (en) * | 1987-04-28 | 1992-09-04 | Seiwa Kasei Kk |
Also Published As
Publication number | Publication date |
---|---|
JPH0525463B2 (en) | 1993-04-13 |
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