JPS62184086A - Antifog agent - Google Patents
Antifog agentInfo
- Publication number
- JPS62184086A JPS62184086A JP2573386A JP2573386A JPS62184086A JP S62184086 A JPS62184086 A JP S62184086A JP 2573386 A JP2573386 A JP 2573386A JP 2573386 A JP2573386 A JP 2573386A JP S62184086 A JPS62184086 A JP S62184086A
- Authority
- JP
- Japan
- Prior art keywords
- water
- type
- polyhydric alcohol
- nonionic surfactant
- anionic surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 8
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004480 active ingredient Substances 0.000 claims abstract 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000003021 water soluble solvent Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims 1
- 239000011521 glass Substances 0.000 abstract description 13
- 229920003023 plastic Polymers 0.000 abstract description 12
- 239000004033 plastic Substances 0.000 abstract description 11
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000005871 repellent Substances 0.000 description 10
- -1 Polyoxyethylene Polymers 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000002940 repellent Effects 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Abstract
Description
【発明の詳細な説明】
本発明はガラス、プラスチック等の表面の凝結水による
曇りを防止するのり防止剤に関し、ガラス、プラスチッ
ク等の表面が撥水性を有しても防曇効果を有する曇り防
止剤に関する。Detailed Description of the Invention The present invention relates to an anti-slip agent that prevents fogging caused by condensed water on the surface of glass, plastic, etc., and an anti-fog agent that has an anti-fog effect even if the surface of glass, plastic, etc. is water repellent. Regarding drugs.
従来自動車等の車輛等のガラス、ヘルメットの風防プラ
スチック、眼鏡、レンズ等の曇り防止剤（ま種々提案さ
れているが、これらのガラスやプラスチックがシリコー
ン、ワックス、その他の撥水性材料で加工されていたり
、車体等に塗布されたワックス等の影響で汚染されて撥
水性になったりしていると、その上に前記の曇り防止剤
を噴霧等により塗布してもその表面に防曇性のすぐれた
皮膜が形成できず、曇り性を防止できない。Conventionally, anti-fogging agents are used for glass of vehicles such as automobiles, windshield plastic of helmets, glasses, lenses, etc. (Various kinds of anti-fogging agents have been proposed, but these agents have been used to prevent these glasses and plastics from being treated with silicone, wax, or other water-repellent materials. If the surface becomes water repellent due to contamination or water repellency due to the influence of wax applied to the car body, etc., even if the above-mentioned anti-fogging agent is applied by spraying etc., the surface will not have excellent anti-fog properties. A clear film cannot be formed and fogging cannot be prevented.
本発明者等は上記の点に鑑み種々研究の結果、撥水性を
有しないガラスやプラスチックは勿ａ、強い撥水性を有
するガラスやプラスチック面に対してもすぐれた防曇効
果を容易に奏する皮膜を形成するものを見出し、本発明
に到達した。即ち本発明は多価アルコールとエチレンオ
キサイド系非イオン界面活性剤と弗素系またはスルホコ
ハク酸ジアルキルエステル系アニオン界面活性剤を併用
するもので、これを水または水とアルコール混合液に溶
解し所要濃度にし、これを所要の防萌面に適当な方法に
より塗布するようにすれば、その防曇作用が極めてすぐ
れ、塗布面に汚点等も残さない０
配合される多価アルコールには、エチレングリコール、
プロピレングリコール、ホリエチレングリコール、グリ
セリン等の親水性化合物があり、７種または一種以上混
合して使用できる。In view of the above points, the inventors of the present invention have conducted various studies and found that a film that easily exhibits an excellent anti-fog effect not only on non-water repellent glass and plastic surfaces but also on highly water-repellent glass and plastic surfaces. The present invention was achieved by discovering something that forms the following. That is, the present invention uses a polyhydric alcohol, an ethylene oxide-based nonionic surfactant, and a fluorine-based or sulfosuccinic acid dialkyl ester-based anionic surfactant in combination, which is dissolved in water or a mixture of water and alcohol to a desired concentration. If this is applied to the desired anti-sprouting surface using an appropriate method, its anti-fogging effect will be extremely good and it will not leave any stains on the applied surface.The polyhydric alcohols include ethylene glycol,
There are hydrophilic compounds such as propylene glycol, polyethylene glycol, and glycerin, and seven types or a mixture of one or more types can be used.
エチレンオキサイド系非イオン界面活性剤には、０１２
〜０１８のプライマリ−アルコール１モルに約７〜２モ
ルのエチレンオキサイドが付加したポリオキシエチレン
ラウリルエーテル、ポリオキシエチレン七チルエーテル
、ポリオキシエチレンオレイルｘ −テＡｔ 等のポリ
オキシエチレンアルキルエーテル若しくは、Ｃ８２〜０
１４のセカンダリ−アルコール１モル当り約７〜２モル
のエチレンオキサイド力付加したポリオキシエチレンア
ルキルエーテルで、例えば、ソフタノール７θ、ソフタ
ノールタθ（何れも日本触媒化学工業に、に、の商品名
で、前者はＣ１３アルコールに７モル、後者はＣ１３ア
ルコールに２モルのそれぞれエチレンオキサイドを付加
したもの）の商品名で市販されているもの、あるいはポ
リオキシエチレンオクチルフェノールエーテル（例えば
トライトンＸ−／θθロームアンドへ−ス社商品名、エ
チレンオキサイド約２〜／θモル付加したもの）および
ポリオキシエチレンノニルフェノールエーテル等のポリ
オキシエチレンアルキルフェノールエーテルカアル。Ethylene oxide nonionic surfactants include 012
Polyoxyethylene alkyl ether such as polyoxyethylene lauryl ether, polyoxyethylene heptyl ether, polyoxyethylene oleyl ~0
A polyoxyethylene alkyl ether to which approximately 7 to 2 moles of ethylene oxide have been added per mole of the secondary alcohol of No. 14, for example, Softanol 7θ, Softanol TAθ (both manufactured by Nippon Shokubai Chemical Co., Ltd., under the trade names of Ni, the former; The latter is commercially available under the trade name of 7 moles of ethylene oxide added to C13 alcohol, and the latter is obtained by adding 2 moles of ethylene oxide to C13 alcohol), or polyoxyethylene octylphenol ether (e.g. Triton and polyoxyethylene alkylphenol ethers such as polyoxyethylene nonylphenol ether (trade name, product name of S.A. Co., Ltd., containing about 2 to θ moles of ethylene oxide) and polyoxyethylene nonylphenol ether.
また、上記弗素系アニオン界面活性剤にＣｔ例えば、エ
フトップＥＦ−／１、２（東北化成Ｋ 、 Ｋ、商品名
）、ｐｃ−ｉｒｇおよびＰＣ−／３’ｌ （何れも住友
スリーエムに、に、商品名）の名称で市販されているも
のがあり、スルホコハク酸ジアルキルエステル系アニオ
ン界面活性剤には、ニアロールＯＰ、およびニアロール
ＣＰ（何れも東邦化学工業に、に、 ｉ８ｉ品名）の名
称で市販されているものその他がある。In addition, the above-mentioned fluorine-based anionic surfactants include Ct, for example, FTOP EF-/1, 2 (Tohoku Kasei K, K, trade name), pc-irg and PC-/3'l (all of which are sold by Sumitomo 3M). Some sulfosuccinic acid dialkyl ester-based anionic surfactants are commercially available under the names of Nyalol OP and Nyallol CP (both manufactured by Toho Chemical Industry Co., Ltd., i8i product name). There are other things that have been done.
上記の多価アルコール、非イオン界面活性剤およびアニ
オン界面活性剤はそれぞれ単独若しくは２種以上を選択
して配合し、水または水とアルコール：非イオン界面活
性剤：アニオン界面活性剤の配合割合は重量比で、ｊ〜
／θ：ｊ〜１０：θ、ｊ〜１、３程度にして好ましい場
合が多い。またこれら配合薬剤は水またはアルコール例
えばメタノール、エタノール、イソプロピルアルコール
その他の水溶性溶剤を含有する水に溶解する。薬剤濃度
は多くの場合約／θ〜コｊ％（重量）に調整している。The above polyhydric alcohol, nonionic surfactant, and anionic surfactant are selected individually or in combination of two or more, and the blending ratio of water or water and alcohol: nonionic surfactant: anionic surfactant is In weight ratio, j~
/θ:j~10:θ,j~1, 3 is often preferred. These compounded drugs are also soluble in water or water containing alcohols such as methanol, ethanol, isopropyl alcohol, and other water-soluble solvents. The drug concentration is often adjusted to about /θ to coj% (by weight).
上記溶解液にアルコール等の水溶性溶剤含有水を使用す
ると塗布された溶液の乾燥性が著しく良好になる。この
場合溶液中の溶剤の濃度は約１０〜．２ｊ％（重量）程
度が好ましい。If water containing a water-soluble solvent such as alcohol is used as the solution, the drying properties of the applied solution will be significantly improved. In this case, the concentration of the solvent in the solution is approximately 10-. About 2j% (weight) is preferable.
次に本発明の配合例の若干を次表に示す。Next, some formulation examples of the present invention are shown in the following table.
（以下余白）
上記各配合例の曇り防止剤をシリコーン撥水剤で処理し
たおよび処理しない透明なガラス面、プラスチック面に
噴霧した結果、撥水剤の有無、強弱には関係なく一様に
塗布できると共に何れもすぐれた防曇効果を得ることが
できた。(Margins below) As a result of spraying the anti-fogging agent of each formulation example above onto transparent glass and plastic surfaces treated with and without silicone water repellent, it was uniformly applied regardless of the presence or absence of water repellent and the strength of the water repellent. It was possible to obtain an excellent anti-fog effect in both cases.
上記の如く調整された曇り防止剤は、その一定世例えば
／θθ俣、２θθＣ・・・・・・Ｓθθ印・・・・・・
を噴霧機付缶、瓶、プラスチック容器に詰め、あるいは
噴射剤と共に加圧容器に詰めて、自動車その他乗物の窓
ガラス、ヘルメットの風防プラスチック、眼鏡や写真機
等のレンズ、家屋その他建造物の窓ガラス、温室のプラ
スチックフィルムやガラス等、水滴凝縮により生ずる曇
りを防止する要ある場合に噴霧して容易に曇りを防止で
き、特にヘルメットの風防用プラスチック等の如くシリ
コーン、その他の薬剤により撥水加工された透明なプラ
スチック面、ワ゛矛りス等により汚染された自動車の窓
ガラス等の撥水性を有する透明なプラスチック、ガラス
等に対しすぐれた防Ω効果を発揮できた。The anti-fogging agent prepared as described above has a certain lifespan, for example, /θθmata, 2θθC...Sθθ mark...
It can be packed in cans, bottles, plastic containers with a sprayer, or in pressurized containers with propellants to be used for the window glass of automobiles and other vehicles, the windshield plastic of helmets, the lenses of glasses and camera lenses, and the windows of houses and other buildings. When it is necessary to prevent fogging caused by condensation of water droplets on glass, greenhouse plastic films, glass, etc., it can be easily sprayed to prevent fogging.In particular, it can be treated with silicone and other chemicals to make it water repellent, such as on the windshield plastic of helmets. Excellent anti-ohm effect was demonstrated on water-repellent transparent plastic surfaces, glass, etc., which have water repellency, such as automobile window glass contaminated by scratches, etc.
Claims (1)
面活性剤と弗素系またはスルホコハク酸ジアルキルエス
テル系アニオン界面活性剤を有効成分として含み、水ま
たは水溶性溶剤含有水に溶解した曇り防止剤。 ２、多価アルコールと非イオン界面活性剤とアニオン界
面活性剤の配合重量比が５〜１０：５〜１０：０．５〜
１．５である特許請求範囲第１項記載の曇り防止剤。[Scope of Claims] 1. A haze containing a polyhydric alcohol, an ethylene oxide nonionic surfactant, and a fluorine-based or sulfosuccinic acid dialkyl ester-based anionic surfactant as active ingredients, dissolved in water or water containing a water-soluble solvent. Inhibitor. 2. The blending weight ratio of polyhydric alcohol, nonionic surfactant, and anionic surfactant is 5 to 10:5 to 10:0.5
1.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2573386A JPS62184086A (en) | 1986-02-10 | 1986-02-10 | Antifog agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2573386A JPS62184086A (en) | 1986-02-10 | 1986-02-10 | Antifog agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62184086A true JPS62184086A (en) | 1987-08-12 |
Family
ID=12174015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2573386A Pending JPS62184086A (en) | 1986-02-10 | 1986-02-10 | Antifog agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62184086A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02263836A (en) * | 1989-04-03 | 1990-10-26 | Chisso Corp | Production of anti-fogging sheet |
| CN105368400A (en) * | 2015-10-08 | 2016-03-02 | 岳建华 | Antifogging glasses cloth |
-
1986
- 1986-02-10 JP JP2573386A patent/JPS62184086A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02263836A (en) * | 1989-04-03 | 1990-10-26 | Chisso Corp | Production of anti-fogging sheet |
| CN105368400A (en) * | 2015-10-08 | 2016-03-02 | 岳建华 | Antifogging glasses cloth |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4128394B2 (en) | Hydrophilic accelerator and hydrophilic maintenance agent for polysilazane-containing coating film | |
| EP1444290B1 (en) | Compositions for aqueous delivery of fluorinated silanes | |
| CA2500810A1 (en) | Cleaning composition for handling water hardness and methods for manufacturing and using | |
| JPH10510576A (en) | Paint with anti-reflective and anti-fog properties | |
| US6809072B2 (en) | Water repellent composition and windscreen washer comprising a siloxane, ether alcohol, and cationic surfactant | |
| EP0630395A1 (en) | Cleaner compositions | |
| AU1766992A (en) | Removing stains from carpet | |
| EP0358984A2 (en) | Floor polishing composition | |
| US6296694B1 (en) | Transparent anti-fog anti-splash coating compositions | |
| JP2004123830A (en) | Discoloration removal detergent for titanium and titanium alloy building material and discoloration removal cleaning method | |
| KR20190004206A (en) | Protective film material for laser processing | |
| JP2006265462A (en) | Hydrophilic stain-proof coating composition, method for forming coating film using the same and use using the same | |
| US4615738A (en) | Transparent antifog compositions | |
| JPS62184086A (en) | Antifog agent | |
| US5385604A (en) | Germicide resistant floor finish | |
| JP2018032781A (en) | Etchant and etching method | |
| US20080171835A1 (en) | Method of sulfonation of polymer substrate to impart a hydrophilic layer in said substrate with improvement in at least one of anti-fog, anti-static, wettability, lubricity anti-microbial properties, and articles made thereby | |
| CN104388047A (en) | Anti-fogging agent for glassware instrument and preparation method thereof | |
| CN107955762A (en) | A kind of vehicle window wash liquid | |
| JP2642157B2 (en) | Coating solution | |
| JP2000345106A (en) | Coating composition | |
| TW200916968A (en) | Composition for antireflection film formation and method for resist pattern formation using the composition | |
| JPH0220678B2 (en) | ||
| GB2203162A (en) | Anti-static compositions | |
| JPH08143795A (en) | Near-infrared/ultraviolet absorbing coating agent |