JPS62181138A - Laminated molded shape (1) having shock resistance - Google Patents
Laminated molded shape (1) having shock resistanceInfo
- Publication number
- JPS62181138A JPS62181138A JP2458486A JP2458486A JPS62181138A JP S62181138 A JPS62181138 A JP S62181138A JP 2458486 A JP2458486 A JP 2458486A JP 2458486 A JP2458486 A JP 2458486A JP S62181138 A JPS62181138 A JP S62181138A
- Authority
- JP
- Japan
- Prior art keywords
- molded product
- impact
- resistant laminate
- skin
- product according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000035939 shock Effects 0.000 title 1
- 239000002649 leather substitute Substances 0.000 claims description 15
- 241001465754 Metazoa Species 0.000 claims description 14
- 239000002759 woven fabric Substances 0.000 claims description 12
- 239000004922 lacquer Substances 0.000 claims description 10
- 239000004745 nonwoven fabric Substances 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 241000251730 Chondrichthyes Species 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 7
- 239000004677 Nylon Substances 0.000 claims description 6
- 229920001778 nylon Polymers 0.000 claims description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 5
- 238000004026 adhesive bonding Methods 0.000 claims description 5
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 4
- 239000004417 polycarbonate Substances 0.000 claims description 4
- 229930182556 Polyacetal Natural products 0.000 claims description 3
- 229920006324 polyoxymethylene Polymers 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims 2
- 238000000576 coating method Methods 0.000 claims 2
- 239000010985 leather Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000003365 glass fiber Substances 0.000 description 6
- -1 various whiskers Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 239000011256 inorganic filler Substances 0.000 description 4
- 229910003475 inorganic filler Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 241000283690 Bos taurus Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000283086 Equidae Species 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- HNPDNOZNULJJDL-UHFFFAOYSA-N ethyl n-ethenylcarbamate Chemical compound CCOC(=O)NC=C HNPDNOZNULJJDL-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 本発明は耐衝撃性の積層成形物に関するものである。[Detailed description of the invention] The present invention relates to impact-resistant laminate molded products.
動物の生皮または鮫皮または合成皮革は強度・耐衝撃が
大きく、しかも表面に強い打撃を受けても傷がつきにく
い等の優れた性質をもっている上に、さらに染色または
漆塗装が容易であり、表面の美観を保ち易い等のため従
来性・木等に接着して剣道の防具用の胴とか防護用の循
環各種の用途に使用されていた。Animal rawhide, sharkskin, or synthetic leather has excellent properties such as high strength and impact resistance, and is resistant to scratches even when subjected to strong blows, and is also easy to dye or lacquer coat. Because it is easy to maintain the aesthetic appearance of the surface, it has traditionally been used by gluing it to wood, etc., for use as body parts for Kendo armor and for various purposes as protective circulation.
然るに合成樹脂は軽くてしかも加工し易いため、最近で
は剣道防具用の胴等にも合成樹脂単体の製品が一部置替
わろうとしている。However, synthetic resins are lightweight and easy to process, so recently, products made of synthetic resin alone have begun to replace some parts of bodies such as kendo armor.
ただ、合成樹脂製品は一般に強い打撃に対して表面に傷
がつき易く、また表面に対する染色または漆塗装が難し
い等の欠点をもっている。However, synthetic resin products generally have drawbacks such as the surface being easily damaged by strong blows and the surface being difficult to dye or lacquer.
このため本発明者らはこれらの欠点を改善するため種々
検討した結果、ポリオレフィンまたは強化ポリオレフィ
ン（ガラス繊維または炭素繊維・金属繊維・各種ホイス
カー・無機充填剤等のフィラーによる強化）またはナイ
ロン・ポリカーボネート・ポリアセタール・ＡＢＳ樹脂
のうちいづれか一種の樹脂またはその強化樹脂（ガラス
繊維または炭素繊維・金属繊維・各種ホイスカー・無機
充填剤等のフィラーによる強化）の成形物に動物の生皮
または鮫皮または合成皮革を接着することにより、軽く
てしかも優れた性能の剣道防具用の胴、防護用の楯等が
容易に能率よく製作出来ることを見いだした。For this reason, the present inventors conducted various studies to improve these drawbacks, and found that polyolefin or reinforced polyolefin (reinforced with fillers such as glass fiber, carbon fiber, metal fiber, various whiskers, and inorganic fillers), nylon, polycarbonate, Animal rawhide, sharkskin, or synthetic leather is added to a molded product of polyacetal or ABS resin or its reinforced resin (reinforced with fillers such as glass fiber, carbon fiber, metal fiber, various whiskers, and inorganic fillers). It has been discovered that by bonding, lightweight and highly functional kendo armor bodies, protective shields, etc. can be easily and efficiently produced.
本発明はポリオレフィンまたは強化ポリオレフィン（ガ
ラス繊維または炭素繊維・金属繊維・各種ホイスカー・
無機充填剤等のフィラーによる強化）またはナイロン・
ポリカーボネート・ポリアセクール・ＡＢＳ樹脂のうち
いづれか一種の樹脂またはその強化樹脂（ガラス繊維ま
たは炭素繊維・金属繊維・各種ホイスカー・無機充填剤
のフィラーによる強化）に動物の生皮または鮫皮または
合成皮革を接着することよりなる耐衝撃性の積層成形物
を提供しようとするものである。The present invention uses polyolefin or reinforced polyolefin (glass fiber or carbon fiber, metal fiber, various whiskers,
(reinforced with fillers such as inorganic fillers) or nylon
Gluing animal rawhide, shark skin, or synthetic leather to any one of polycarbonate, polyacecool, and ABS resin or its reinforced resin (reinforced with glass fiber, carbon fiber, metal fiber, various whiskers, and inorganic fillers). It is an object of the present invention to provide a laminate molded product having high impact resistance.
成形物の材料のうちポリオレフィンはナイロン・ポリカ
ーボネート・ポリアセタール・ＡＢＳ樹脂等に較べて軽
いので、成形物の軽量化には特に優れているのであるが
、皮との接着が難しいので、樹脂表面を酸化処理すると
か、塗料用プライマーの下塗りや・成形物の表面に接着
のアンカーの役目をする切込みの溝入れが有効である。Among the materials for molded products, polyolefin is lighter than nylon, polycarbonate, polyacetal, ABS resin, etc., so it is particularly good at reducing the weight of molded products, but it is difficult to adhere to the skin, so it is difficult to oxidize the resin surface. Treatment, undercoating with a paint primer, and making grooves on the surface of molded parts to serve as anchors for adhesion are effective.
また成形物にまず織布または不織布を接着したあと皮を
接着すると、接着剤の塗りむらが減少し、接着強度が向
上する等の効果がある。樹脂表面の酸化処理・プライマ
ーの使用・成形物の表面に切込みの溝を入れること・繊
布または不織布の使用は勿論性の樹脂の場合にも同様の
効果をもっている。Furthermore, if a woven or nonwoven fabric is first adhered to the molded article and then the skin is attached, there are effects such as reducing uneven application of the adhesive and improving adhesive strength. Similar effects can be obtained not only by oxidizing the resin surface, using a primer, making grooves on the surface of the molded product, and using textile or nonwoven fabrics, but also in the case of plastic resins.
動物の生皮の主なものとしては牛、馬、豚、羊、鹿等の
生皮をあげることが出来る。合成皮革としてはクラレ（
株）製のクラリーノのように表面が銀皮状の合成皮革が
好ましい。The main types of animal rawhide include those of cows, horses, pigs, sheep, deer, etc. As for synthetic leather, Kuraray (
Synthetic leather with a silver-skinned surface, such as Clarino manufactured by Co., Ltd., is preferable.
使用する接着剤の主なものとしてはエポキシ系、ビニー
ル系、ウレタン系、ビニールウレタン系、アクリル系、
酢ビ糸環各種の接着剤をあげることが出来るが、接着剤
の選択に当たっては成形物に使用する原料樹脂の種類に
、また織布または不織布を用いる場合には織布または不
織布の種類によって通したものを選ぶ必要がある。The main adhesives used are epoxy, vinyl, urethane, vinyl urethane, acrylic,
Various types of adhesives can be used, but when selecting an adhesive, it depends on the type of raw material resin used for the molded product, and when using woven or non-woven fabric, the type of woven or non-woven fabric. You need to choose the one you have.
使用する織布または不織布の材料の主なものとしては綿
・麻・毛等の天然繊維、人絹・スフ・ナイロン・ポリエ
ステル・ポリアクリロニトリル・ポリビニールアルコー
ル・ポリプロピレン等をあげることが出来る。The main materials used for the woven or nonwoven fabric include natural fibers such as cotton, hemp, and wool, human silk, cotton wool, nylon, polyester, polyacrylonitrile, polyvinyl alcohol, and polypropylene.
なお、成形物の原料樹脂には必要に応じて、各種の安定
剤・着色剤のほか、各種の他の添加剤を加えても差支え
ない。Note that, in addition to various stabilizers and colorants, various other additives may be added to the raw material resin of the molded product as necessary.
以下に実施例によって本発明をさらに詳しく説明するが
、本発明はこれらによって限定されるものではない。The present invention will be explained in more detail below with reference to Examples, but the present invention is not limited thereto.
実施例１
宇部日東化成工業製の黒色のガラス繊維強化ポリプロピ
レン（ガラス繊維４０％）Ａｚｄｅｌ−１１３７を２０
０℃、１００気圧、３０秒なるプレス条件で、剣道防具
用の胴形の金型により厚さ約４．５ ｍｍの成形物をま
ずつくり、これに三井石油化学製の塗装用プライマーユ
ニストールＰを下塗りしたあと、予め７日間の水浸しに
より軟化・水洗し、木型によって上述の胴形の成形物表
面に密着しうるよう成形・乾燥した黒色の牛の生皮を中
央理化工業製のエポキシ系の接着剤・リカボンドＥＸ−
ＬＡおよびリカボンドＥＸ−ＩＢ （硬化剤）によって
接着した。Example 1 20% of black glass fiber reinforced polypropylene (40% glass fiber) Azdel-1137 manufactured by Ube Nitto Kasei Kogyo Co., Ltd.
Using press conditions of 0°C, 100 atm, and 30 seconds, a molded product with a thickness of approximately 4.5 mm was first made using a body-shaped mold for kendo armor, and then coated with Unistol P, a paint primer manufactured by Mitsui Petrochemicals. After applying the undercoat, the black cowhide was softened and washed by soaking in water for 7 days, then molded and dried using a wooden mold so that it could adhere to the surface of the above-mentioned torso-shaped molded product. Adhesive/Ricabond EX-
It was adhered with LA and Ricabond EX-IB (curing agent).
牛皮をはりつけていないＡｚｄｅｌ−１１３７製の胴形
の成形物と上述の牛皮をはりつけたＡｚｄｅｌ−１１３
７製の胴形の成形物について竹刀で打撃してみたところ
、牛皮をはりつけていないＡｚｄｅｌ−１１３７製およ
びＡＢＳ樹脂製のものは１回の打撃だけで表面に軽い傷
がついたのに対して、牛皮をはったＡｚｄｅｌ製のもの
は２〜３回の打撃でも傷がつかなかった。A trunk-shaped molded product made of Azdel-1137 with no cowhide pasted on it and Azdel-113 with the above-mentioned cowhide pasted on it.
When I hit a body-shaped molded product made by No. 7 with a bamboo sword, I found that the Azdel-1137 and ABS resin products without cowhide had slight scratches on the surface after just one hit. The one made by Azdel and covered with cowhide did not get scratched even after being hit two or three times.
実施例２
実施例１の方法によって成形した。Ａｚｄｅｌ−１１３
７製の胴形の成形物に、まずユニｌ−−ルＰを下塗りし
たあと、リカボンドＥＸ−Ｌ ＡおよびＥＸ−Ｉ Ｂに
より市販のナイロン製織布を接着後、さらに実施例１の
方法により成形・乾燥した牛の生皮を同じ接着剤で接着
した。Example 2 Molding was performed by the method of Example 1. Azdel-113
7 was first coated with UNIL-P, and then a commercially available nylon woven fabric was bonded with RIKABOND EX-LA and EX-I B, and further by the method of Example 1. Shaped and dried cow hides were glued together using the same adhesive.
次いでこれを十分乾燥した後、接着した牛の生皮を成形
物からはがして、織布を使用した場合と使用しない実施
例１の場合について成形物と牛皮との接着の状態を較べ
てみたところ、織布を使用した本実施例の成形物および
牛皮の表面における接着剤の付着状態は織布を使用しな
い場合の状態に較べて■接着剤の塗りむらが少ない、■
接着強度が大きいという結果を得た。After thoroughly drying this, the bonded cowhide was peeled off from the molded product, and the state of adhesion between the molded product and the cowhide was compared between the case where woven fabric was used and the case of Example 1 where woven fabric was not used. The adhesion state of the adhesive on the surface of the molded product and cowhide of this example using woven fabric is as follows: ■ There is less uneven application of the adhesive, ■
The results showed that the adhesive strength was high.
Claims (16)
ナイロン・ポリカーボネート・ポリアセタール・ＡＢＳ
樹脂のうちいづれか一種の樹脂またはその強化樹脂の成
形物に動物の生皮または鮫皮または合成皮革を接着する
ことよりなる耐衝撃性の積層成形物。(1) Polyolefin or reinforced polyolefin or nylon, polycarbonate, polyacetal, ABS
An impact-resistant laminate molded product made by adhering animal rawhide, shark skin, or synthetic leather to a molded product of any one of the resins or its reinforced resin.
場合の特許請求の範囲第１項記載の耐衝撃性の積層成形
物。(2) The impact-resistant laminate molded product according to claim 1, wherein the “molded product” is a “molded product in the shape of a body for Kendo armor.”
と、」の場合の特許請求の範囲第１項記載の耐衝撃性の
積層成形物。(3) The impact-resistant laminate molded product according to claim 1, where "on the molded product" is replaced with "after the molded product is coated with a primer."
と、」の場合の特許請求の範囲第２項記載の耐衝撃性の
積層成形物。(4) The impact-resistant laminate molded product according to claim 2, where "on the molded product" is replaced with "after the molded product is coated with a primer."
着、」の場合の特許請求の範囲第１項記載の耐衝撃性の
積層成形物。(5) The impact-resistant laminate molded product according to claim 1, where “on the molded product” is replaced with “adhering a woven or nonwoven fabric to the molded product”.
着、」の場合の特許請求の範囲第２項記載の耐衝撃性の
積層成形物。(6) The impact-resistant laminate molded product according to claim 2, where “on the molded product” is replaced with “adhering a woven or nonwoven fabric to the molded product”.
と、織布または不織布を接着、」の場合の特許請求の範
囲第１項記載の耐衝撃性の積層成形物。(7) The impact-resistant laminate molded product according to claim 1, in which "on the molded product" is replaced with "the molded product is coated with a primer, and then a woven fabric or nonwoven fabric is bonded."
と、織布または不織布を接着、」の場合の特許請求の範
囲第２項記載の耐衝撃性の積層成形物。(8) The impact-resistant laminate molded product according to claim 2, where "on the molded product" is replaced with "the molded product is coated with a primer, and then a woven or nonwoven fabric is bonded."
る」を「動物の生皮または鮫皮または合成皮革を接着、
皮の表面に漆塗装をする」の場合の特許請求の範囲第１
項記載の耐衝撃性の積層成形物。(9) "Gluing animal rawhide, sharkskin, or synthetic leather" to "gluing animal rawhide, sharkskin, or synthetic leather,"
Claim 1 for “lacquer coating on the surface of leather”
The impact-resistant laminate molded product described in .
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
２項記載の耐衝撃性の積層成形物。(10) The impact-resistant laminate molded product according to claim 2, in which "animal rawhide, sharkskin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
３項記載の耐衝撃性の積層成形物。(11) The impact-resistant laminate molded product according to claim 3, in which "animal rawhide, sharkskin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
４項記載の耐衝撃性の積層成形物。(12) The impact-resistant laminate molded product according to claim 4, in which "animal rawhide, shark skin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
５項記載の耐衝撃性の積層成形物。(13) The impact-resistant laminate molded product according to claim 5, in which "animal rawhide, shark skin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
６項記載の耐衝撃性の積層成形物。(14) The impact-resistant laminate molded product according to claim 6, in which "animal rawhide, shark skin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
７項記載の耐衝撃性の積層成形物。(15) The impact-resistant laminate molded product according to claim 7, in which "animal rawhide, shark skin, or synthetic leather is bonded and the surface of the skin is coated with lacquer."
、皮の表面に漆塗装をする」の場合の特許請求の範囲第
８項記載の耐衝撃性の積層成形物(16) Impact-resistant laminate molded product according to claim 8 in the case of "gluing animal rawhide, shark skin, or synthetic leather and coating the surface of the skin with lacquer"
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2458486A JPS62181138A (en) | 1986-02-06 | 1986-02-06 | Laminated molded shape (1) having shock resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2458486A JPS62181138A (en) | 1986-02-06 | 1986-02-06 | Laminated molded shape (1) having shock resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62181138A true JPS62181138A (en) | 1987-08-08 |
Family
ID=12142207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2458486A Pending JPS62181138A (en) | 1986-02-06 | 1986-02-06 | Laminated molded shape (1) having shock resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62181138A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778401A (en) * | 2014-12-18 | 2016-07-20 | 神华集团有限责任公司 | Polyformaldehyde foam composition, preparation method thereof, and structural foam material containing polyformaldehyde foam composition |
| JP6384938B1 (en) * | 2017-10-03 | 2018-09-05 | 創造技術株式会社 | Leather composite material |
-
1986
- 1986-02-06 JP JP2458486A patent/JPS62181138A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778401A (en) * | 2014-12-18 | 2016-07-20 | 神华集团有限责任公司 | Polyformaldehyde foam composition, preparation method thereof, and structural foam material containing polyformaldehyde foam composition |
| JP6384938B1 (en) * | 2017-10-03 | 2018-09-05 | 創造技術株式会社 | Leather composite material |
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