JPS62179812A - Manufacture of composite cylindrical material - Google Patents

Manufacture of composite cylindrical material

Info

Publication number
JPS62179812A
JPS62179812A JP2327586A JP2327586A JPS62179812A JP S62179812 A JPS62179812 A JP S62179812A JP 2327586 A JP2327586 A JP 2327586A JP 2327586 A JP2327586 A JP 2327586A JP S62179812 A JPS62179812 A JP S62179812A
Authority
JP
Japan
Prior art keywords
powder
metal plate
metal sheet
metal powder
composite cylindrical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2327586A
Other languages
Japanese (ja)
Inventor
Kazuyuki Yoshimoto
吉本 和幸
Yasusato Ishida
恭聡 石田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mazda Motor Corp
Original Assignee
Mazda Motor Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mazda Motor Corp filed Critical Mazda Motor Corp
Priority to JP2327586A priority Critical patent/JPS62179812A/en
Publication of JPS62179812A publication Critical patent/JPS62179812A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To easily manufacture a composite cylindrical material and to improve its productivity by applying a slurry of a wear resistant metal powder and a resin dissolved in a solvent on a metal sheet, by press-fitting uniformly by a roller and forming into a cylindrical shape to sinter and welding an opening part. CONSTITUTION:A hopper 3 is disposed on the metal sheet 1 on guide rollers 9. The slurry 2 of the wear resistant metal powder of a Fe-Cu-Sn-C system metal powder, e.g., and organic resin of phenolic resin, etc., dissolved in the alcoholic solvent in the hopper 3 flowing out from a gap 8a with a movement of the metal sheet 1 is applied on said metal sheet 1. The metal sheet 1 press- fitted with said applying material of equal thickness by the press-fitting rollers 4, 5 is bent cylindrically by the guide roller 6 and cut in a prescribed size to form the cylinder 10. Then, the applying material is brazed by preliminary sintering and regular sintering. Further, the opening part 10a is welded by an electron beam, etc., to form the composite cylindrical material. In this way, the composite cylindrical material is easily formed to improve the productive efficiency.

Description

【発明の詳細な説明】 (産業上の利用分野) この発明は、複合筒部材製造方法、詳しくは、自動車エ
ンジンなどのシリンダライチ内壁に用いられる複合筒部
材の製造方法にI′i、lするもので゛あ(従来技術) 従来から、シリンンダライナ内壁を#摩耗性の優れた素
材と塑性変形能に優れた素材との複合素材で形成するこ
とは知られており、その製造方法として、たとえば特開
昭57−148043号公+gに記載のものがある。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a method for manufacturing a composite cylindrical member, specifically, a method for manufacturing a composite cylindrical member used for the inner wall of a cylinder lychee of an automobile engine, etc. It has been known for a long time that the inner wall of the cylinder liner is made of a composite material of a material with excellent wear resistance and a material with excellent plastic deformability. For example, there is one described in JP-A-57-148043+g.

上記従来の製造方法は、まず、第4図(A)に示すよう
に、耐摩耗性に優れた素材Aと塑性変形能に優れた素材
Bとから成る積層円板スラグMを、ポンチ20.ダイ2
1.ストリッパ22によって構成される金型内に、素材
Aがポンチ20側に位置するように装入し、スラグMを
ポンチ20によって加圧して鍛造する。これによって、
ポンチ20とダイ21との隙間23に第4図(B)に示
すように、スラグMが押し出される。このとき、スラグ
Mを構成する素材A、Hの塑性変形によって、第5図(
A)に示されるような容器粗材Pが成形される。その後
、容器粗材Pを金型内から取出して、′:tS5図(B
)に示すように、その底壁24を打抜き、円筒状の複合
シリンダライチ粗材を得るものである。
In the conventional manufacturing method described above, first, as shown in FIG. die 2
1. The material A is placed in a mold formed by the stripper 22 so as to be located on the punch 20 side, and the slag M is pressurized by the punch 20 and forged. by this,
The slug M is pushed out into the gap 23 between the punch 20 and the die 21, as shown in FIG. 4(B). At this time, due to plastic deformation of the materials A and H constituting the slag M, as shown in Fig. 5 (
A container material P as shown in A) is formed. After that, the container raw material P is taken out from inside the mold, and
), the bottom wall 24 is punched out to obtain a cylindrical composite cylinder lychee raw material.

しかし、上記容器素材Pは、素材A、Hの塑性変形によ
る圧着だけで接合されているため、素材A、B間の接合
強度が低い、しかも、素材AがA交−3n系合金である
場合、その表面にA立置化膜が形成されやすく、この酸
化膜によって素材Aと素材Bの接合強度が一層低下する
However, since the container material P is joined only by pressure bonding due to plastic deformation of materials A and H, the bonding strength between materials A and B is low.Moreover, when material A is an A-3N alloy, , an A-standing film is likely to be formed on the surface thereof, and this oxide film further reduces the bonding strength between the material A and the material B.

また、積層円板スラグMの鍛造加工や、底壁の打ち抜き
加工などの複雑な筒状加工に手間がかかり、このため生
産効率が低下する。
Further, complicated cylindrical processing such as forging the laminated disk slug M and punching the bottom wall takes time, which reduces production efficiency.

(発明の目的) この発明は、上記従来の問題を解決するためになされた
もので、素材間の接合強度を増大し、かつ、生産効率を
向上させることができる複合f、1 m材の製造方法を
提供することを目的とする。
(Purpose of the Invention) This invention was made to solve the above-mentioned conventional problems, and is capable of manufacturing a composite f, 1 m material that can increase the bonding strength between materials and improve production efficiency. The purpose is to provide a method.

(発明の構成) 上記目的を達成するため、この発明は、まず、#摩耗性
金属粉末に有機溶媒および有機溶媒溶解性樹脂を混合し
てスラリー状の粉末合金素材を生成し、その粉末合金素
材を金属板に塗布し、・っぎに、粉末合金素材と金属板
とをローラの加圧によって均一な厚さの積層板に成形す
るとともに、内側が一ヒ記lf1庁耗性金属扮末となる
筒状に成形し、筒状の積層板を焼結して上記耐摩耗性金
属粉末を」、記金属板に焼結結合させ、その後、焼結結
合された上記筒状積層板の開口部を溶接するものである
(Structure of the Invention) In order to achieve the above object, this invention first mixes an abrasive metal powder with an organic solvent and an organic solvent-soluble resin to generate a slurry powder alloy material, and is applied to the metal plate, and then the powder alloy material and the metal plate are formed into a laminate of uniform thickness by the pressure of a roller, and the inside is coated with the wearable metal powder. The cylindrical laminate is molded into a cylindrical shape, the cylindrical laminate is sintered, the wear-resistant metal powder is sintered and bonded to the metal plate, and the opening of the sintered cylindrical laminate is then sintered. It is used for welding.

耐摩耗性金属粉末と金属板とは焼結の際に接合されるの
で、その接合強度が増大し、粉末合金素材が金属板から
分離することが防がれる。また、ローンの加圧によって
積層板を筒状に成形するようにしたので、筒状加工に手
間がかからず、製造1−程が著しく簡略化される (実施例) 以下、この発明の実施例を図面にしたがって説明する。
Since the wear-resistant metal powder and the metal plate are bonded during sintering, the bond strength is increased and separation of the powder alloy material from the metal plate is prevented. In addition, since the laminated plate is formed into a cylindrical shape by applying pressure with a loan, it does not take much time to process the cylindrical shape, and the manufacturing step 1 is significantly simplified (Example). An example will be explained according to the drawings.

第1図は複合筒部材の製造工程図であり、図において、
スラリー状の粉末合金素材2は、ホッパ3内に投入され
、ホッパ3の下方には金属板1が配置され、金属板lの
矢印Aで示す移動方向下流側には、上下一対の圧着ロー
ラ4,5が配置される。
FIG. 1 is a manufacturing process diagram of a composite cylindrical member, and in the figure,
A slurry-like powder alloy material 2 is put into a hopper 3, a metal plate 1 is arranged below the hopper 3, and a pair of upper and lower pressure rollers 4 are placed on the downstream side of the metal plate 1 in the moving direction indicated by arrow A. , 5 are arranged.

ホッパ3は、粉末合金素材2を投入するための投入口3
aと、粉末合金素材2を金属板l上に供給するための供
給口3bとを有する。供給口3bの第1図の紙面に対し
て垂直方向の幅は、金属板lの幅と等しく選ばれている
。したがって、金属板lの全表面に1夏って粉末合金素
材2を塗布することがきる。
The hopper 3 has an input port 3 for inputting the powder alloy material 2.
a, and a supply port 3b for supplying the powder alloy material 2 onto the metal plate l. The width of the supply port 3b in the direction perpendicular to the plane of FIG. 1 is selected to be equal to the width of the metal plate l. Therefore, the powder alloy material 2 can be applied to the entire surface of the metal plate 1 in one summer.

粉末合金素材2は、#摩耗性の金属粉末に有機溶媒およ
び、有機溶媒溶解性の樹脂を混合してスラリー状に生成
したものである。
The powder alloy material 2 is produced in the form of a slurry by mixing abrasive metal powder with an organic solvent and an organic solvent-soluble resin.

耐摩耗性の金1ぶ粉末としては、たとえばFe−Cu−
3n−C系粉末が用いられ、その成分比はFe : 5
7.5〜95.2%、Cu:3〜30%、 S n :
 1〜l 0%、 C: 0 、8〜2 。
Examples of wear-resistant gold powder include Fe-Cu-
3n-C type powder is used, and its component ratio is Fe: 5
7.5-95.2%, Cu: 3-30%, Sn:
1-10%, C: 0, 8-2.

5%に選ばれる。Cu 、 S n粉末は、後述する焼
結峙において溶融して、金属板lと金属粉末とをろう付
けする役割を果たし、また、C粉末は、焼結体の耐厚耗
特性および、焼結体自体のIa度を持だせる役割を果た
す。
Selected by 5%. The Cu, Sn powders are melted in the sintering process described later and play the role of brazing the metal plate l and the metal powder, and the C powder improves the wear resistance properties of the sintered body and the sintering process. It plays a role in raising the Ia degree of the body itself.

また、有機溶媒としては、たとえば上記金属粉末に対し
て16〜30331%%のアルコール類が用いられる。
Further, as the organic solvent, for example, alcohols are used in an amount of 16 to 30331% relative to the metal powder.

この有機溶媒は、粉末合金素材2をスラリーユに生成す
るために用いられるものであり、16重量%未満である
と粉末合金素材2がスラリー状とならず、また、30重
量%を超えると過流動性となって金属板l上に塗布した
際に流れ出て金属板l上に保持することが困難となる。
This organic solvent is used to form the powder alloy material 2 into a slurry, and if it is less than 16% by weight, the powder alloy material 2 will not become slurry, and if it exceeds 30% by weight, it will not flow. When it is coated on the metal plate 1, it flows out and it becomes difficult to hold it on the metal plate 1.

したがって、」:記範囲に限定する。Therefore, the scope shall be limited to the following.

また、有機溶媒溶解性の樹脂としては、たとえばL−記
金属粉末に対して1−151星%のフェノール樹脂が用
いられる。この樹脂は、上記粉末のバインダ(結合剤)
としての役割を果たす。
Further, as the organic solvent-soluble resin, for example, a phenol resin is used in an amount of 1 to 151% based on the L-group metal powder. This resin is the binder for the above powder.
fulfill the role of

金属板lの材料としては、たとえば冷間圧延鋼(SPC
C)、熱間圧延n4(SPHC)、 ステ7レス鋼など
が用いられる。この金属板lは、ホッパ3の背面部7の
ド端部7aに密着し、かつホッパ3の1■j面部8の下
端部8aと一定の間隔DIをあけた状!詣で、送りロー
ン9a〜9fヒに支持されている、したがって、送りロ
ーラ9a〜9fの回転駆動によって金属板1が矢印Aで
示す方向(第1図の右方)に移動したとき、」−2間隔
D1と等しい厚みでホッパ3内のスラリー状の粉末合金
素材2を金属板1.ヒに連続的に塗1a することがで
きる。粉末合金素材2の厚みは、上記間隔D1を変える
ことによって、任意に設定することができる。
The material of the metal plate l is, for example, cold rolled steel (SPC).
C), hot-rolled N4 (SPHC), ST7less steel, etc. are used. This metal plate 1 is in close contact with the do end 7a of the back surface 7 of the hopper 3, and is spaced a certain distance DI from the lower end 8a of the 1J surface 8 of the hopper 3! Therefore, when the metal plate 1 moves in the direction indicated by arrow A (to the right in FIG. 1) by the rotational drive of the feed rollers 9a to 9f, the metal plate 1 is supported by the feed rollers 9a to 9f. The slurry-like powder alloy material 2 in the hopper 3 is spread onto the metal plate 1. with a thickness equal to the distance D1. It can be applied continuously. The thickness of the powder alloy material 2 can be arbitrarily set by changing the distance D1.

第2図において、粉末合金素材2が塗布された金属板l
の前記移動方向Aの下Ii側には、北下−勾の異径の圧
着ローラ4,5が配置されている。
In FIG. 2, a metal plate l coated with powder alloy material 2 is shown.
Pressing rollers 4 and 5 having different diameters with a north-down slope are arranged on the lower Ii side in the moving direction A.

圧着ローラ4,5は、相互に平行な回転軸線を有する。The pressure rollers 4 and 5 have rotation axes that are parallel to each other.

粉末合金素材z側の圧着ローラ4は、モータ(図示せず
)によって反時計方向に回転駆動され、金属板2側の圧
着ローラ5は、モータ(図示せず)によって時計方向に
回転駆動される。また、圧着ローラ4,5の間隔D2は
、金属板lの厚みをdiとし、粉末合金素材2の厚みを
d2とすると、D2=dl+n11d2 (0,35≦
n≦0.50)となるように選ばれている。したがつて
、金属板1と粉末合金素材2とが挟圧され、粉末合金、
に材2が圧密化されて、均一な厚さの高強iIl!1′
な粉末成形体2aを得ることができる。
The pressure roller 4 on the powder alloy material z side is driven to rotate counterclockwise by a motor (not shown), and the pressure roller 5 on the metal plate 2 side is driven to rotate clockwise by a motor (not shown). . Further, the distance D2 between the pressure rollers 4 and 5 is as follows: D2=dl+n11d2 (0,35≦
n≦0.50). Therefore, the metal plate 1 and the powder alloy material 2 are pressed together, and the powder alloy,
Material 2 is consolidated to form a high-strength material with uniform thickness! 1′
A compact powder compact 2a can be obtained.

また、正着ローラ4の経文1は、圧着ローラ5の1:¥
22よりも小さく選ばれている。したがって、圧着ロー
、y4,5の回転速度を等しく設定することによって、
圧着ローシロの周速度が圧着ローラ4の周速度よりも大
となる。このため、圧、tiローラ4,5から排出され
る金属板lと粉末成形体2aとの積層板lOは、粉末成
形体2aを内側にして1白状に弯曲した状態となる。こ
の積層板10の筒形状は、ガイドローラ6によって保持
される。積層板10は、筒状に成形されi;のち、予め
定めた切断線11に沿って切断される。
Also, the sutra 1 of the correct roller 4 is 1 of the pressure roller 5: ¥
It is chosen to be smaller than 22. Therefore, by setting the rotational speeds of crimping rows and y4 and 5 to be equal,
The circumferential speed of the crimping roller is greater than the circumferential speed of the crimping roller 4. Therefore, the laminated plate 10 of the metal plate 1 and the powder compact 2a discharged from the pressure rollers 4 and 5 is curved into a white shape with the powder compact 2a inside. The cylindrical shape of this laminated plate 10 is maintained by guide rollers 6. The laminated plate 10 is formed into a cylindrical shape and then cut along a predetermined cutting line 11.

第3図において1円筒状に湾曲した積層板lOを、N2
ガス雰囲気中で500℃・−800℃で30分間予備焼
結して、樹脂を飛ばした後、900℃〜1200℃で3
0分間〜2時間焼結を行なう、この焼結によって粉末成
形体za内のCu、Sn粉が溶融する。これによって、
耐摩耗性金属粉末と金属板lとがろう付けされ、粉末成
形体2aと金属板lとの接合強度を増大させることがで
きる。また、焼結を行なうことによって粉末成形体za
自体の強度を増大させることができる。
In Fig. 3, a cylindrical curved laminated plate lO is heated with N2
After pre-sintering at 500°C/-800°C for 30 minutes in a gas atmosphere to remove the resin, sintering at 900°C to 1200°C for 30 minutes.
Sintering is performed for 0 minutes to 2 hours, and the Cu and Sn powders in the powder compact za are melted by this sintering. by this,
The wear-resistant metal powder and the metal plate l are brazed, and the bonding strength between the powder compact 2a and the metal plate l can be increased. In addition, by performing sintering, powder compacts za
It can increase its own strength.

焼結後の積層板10の開口部10aは、レーザ溶接ある
いは電子ビーム溶接などによって溶接される。これによ
って、切れ目のない円筒形の複合筒部材を得ることがで
きる。
The opening 10a of the sintered laminate 10 is welded by laser welding, electron beam welding, or the like. As a result, a seamless cylindrical composite tube member can be obtained.

このように、積層板10から複合筒部材を作るにあたっ
て、従来のような鍛造加工や底壁の打抜き加工が不要で
あるから、それだけ製造が容易になる。この複合筒部材
は、その後、仕上げ加工。
In this way, when making a composite cylindrical member from the laminated plate 10, there is no need for conventional forging or punching of the bottom wall, which makes manufacturing easier. This composite cylindrical member is then subjected to finishing processing.

鋳ぐるみを経て、Alシリンダブロック(図示せず)内
に埋め込まれ、シリンダライチ内壁としての機能を果た
すこととなる。
After being cast, it is embedded in an Al cylinder block (not shown) and functions as the inner wall of the cylinder litchi.

つぎの第1表および第1図を参照して、この発明をさら
に具体的に説明する。
This invention will be explained in more detail with reference to the following Table 1 and FIG.

第1表 り2第1表に掲げるスラリー状の粉末合金素材2をホッ
パ3内に投入し、ホッパ3の前面部8の下端部8aの間
隔Diを2 、8mm 〜2 、9mmに設定するとと
もに、圧着ローラ4.5間の間隔D2を4.35mmに
設定し、上側の圧着ローラ4の径Mlを70■、下側の
圧着ローラ5の径す2を200mmとし1両ローラ4,
5の回転数を5ORPM、O−ラ間の荷重を600tf
としたところ、ト記第1表に掲げる金属板l上に厚み1
.0amの粉末成形体2aを形慮中るこ、I−バで身た
。つぎに、その積層板10(第3図)をN2ガス雰囲気
中においてa o o ’cで30分間予備焼結させた
後、1150°Cで1時間焼結を行なったところ、粉末
成形体2aと金属板lとの接合強度が大である複合筒部
材を製造することができた。
Table 1 2 The slurry powder alloy material 2 listed in Table 1 is put into the hopper 3, and the interval Di between the lower ends 8a of the front surface 8 of the hopper 3 is set to 2.8 mm to 2.9 mm. , the distance D2 between the pressure rollers 4.5 is set to 4.35 mm, the diameter Ml of the upper pressure roller 4 is 70 mm, the diameter 2 of the lower pressure roller 5 is 200 mm, and one roller 4,
5 rotation speed is 5ORPM, load between O-ra is 600tf
Then, on the metal plate l listed in Table 1, a thickness of 1
.. While considering the powder compact 2a of 0 am, I tried it on I-bar. Next, the laminate 10 (FIG. 3) was pre-sintered for 30 minutes at a o o 'c in a N2 gas atmosphere, and then sintered at 1150°C for 1 hour, resulting in a powder compact 2a. It was possible to manufacture a composite cylindrical member with high bonding strength between the metal plate 1 and the metal plate 1.

上記実施例において、r#摩耗性金属粉末には、F e
−Cu−3n−C系合金粉末に代えて、鋳鉄粉末、たと
えばねずみ鋳鉄9合金鋳鉄9球状黒鉛鋳鉄を用いるよう
にしてもよい。
In the above examples, the r# abrasive metal powder includes F e
-Cu-3n-C alloy powder may be replaced with cast iron powder, such as gray cast iron 9 alloy cast iron 9 spheroidal graphite cast iron.

(発明の効果) 以上説明したように、この発明によれば、耐摩耗性金属
粉末と金属板とが圧着後、焼結結合されるため、その接
合強度が増大を図ることができるとともに、鍛造加工や
打抜き加工が不要になるので、筒状加工に手間がかから
ず生産効率の向上を図ることができる。
(Effects of the Invention) As explained above, according to the present invention, the wear-resistant metal powder and the metal plate are sintered and bonded after being crimped, so that the bonding strength can be increased, and the forging Since machining and punching are no longer required, production efficiency can be improved without the hassle of cylindrical machining.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明に係る複合筒部材の製造過程を示す縦
断面図、第2図は圧着ローラ付近の拡大断面図、第3図
は積層板の斜視図、第4図および第5図は従来の製造方
法を示す工程図である。 l・・・金属板、2・・・粉末合金素材、3・・・ホッ
パ、4.5・・・圧着ローラ、10・・・積層板、io
a・・・開口部。 特許出願人     マツダ株式会社 代理人 弁理士   難波国英(外1名)□−1、ノI 第1図 5:ホッパ       10:積層板帛4囚 ’□’ 3.”    < A)、、   < s>;
Iへ5l−1 (A)          (B) i
Fig. 1 is a longitudinal sectional view showing the manufacturing process of the composite cylindrical member according to the present invention, Fig. 2 is an enlarged sectional view of the vicinity of the pressure roller, Fig. 3 is a perspective view of the laminate, and Figs. 4 and 5 are FIG. 2 is a process diagram showing a conventional manufacturing method. l... Metal plate, 2... Powder alloy material, 3... Hopper, 4.5... Pressure roller, 10... Laminate plate, io
a...Opening. Patent applicant Mazda Motor Corporation agent Patent attorney Kunihide Namba (1 other person) □-1, No.I Figure 1 5: Hopper 10: Laminated board 4 prisoners '□' 3. ” <A),, <s>;
5l-1 to I (A) (B) i

Claims (1)

【特許請求の範囲】[Claims] 耐摩耗性金属粉末に有機溶媒および有機溶媒溶解性樹脂
を混合してスラリー状の粉末合金素材を生成し、その粉
末合金素材を金属板に塗布し、その粉末合金素材と金属
板とをローラーの加圧により均一な厚さの積層板に成形
するとともに内側が上記耐摩耗性金属粉末となる筒状に
成形した後、その筒状の積層板を焼結して上記耐摩耗性
金属粉末を上記金属板に焼結結合させ、焼結結合された
上記筒状の積層板の開口部を溶接することを特徴とする
複合筒部材の製造方法。
A slurry-like powder alloy material is produced by mixing wear-resistant metal powder with an organic solvent and an organic solvent-soluble resin, the powder alloy material is applied to a metal plate, and the powder alloy material and the metal plate are passed through a roller. The laminate is pressurized to form a laminate of uniform thickness and formed into a cylinder with the wear-resistant metal powder on the inside.The cylindrical laminate is then sintered and the wear-resistant metal powder is coated with the wear-resistant metal powder. 1. A method for manufacturing a composite cylindrical member, which comprises sinter-bonding the composite cylindrical member to a metal plate, and welding the opening of the sinter-bonded cylindrical laminate.
JP2327586A 1986-02-05 1986-02-05 Manufacture of composite cylindrical material Pending JPS62179812A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2327586A JPS62179812A (en) 1986-02-05 1986-02-05 Manufacture of composite cylindrical material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2327586A JPS62179812A (en) 1986-02-05 1986-02-05 Manufacture of composite cylindrical material

Publications (1)

Publication Number Publication Date
JPS62179812A true JPS62179812A (en) 1987-08-07

Family

ID=12106050

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2327586A Pending JPS62179812A (en) 1986-02-05 1986-02-05 Manufacture of composite cylindrical material

Country Status (1)

Country Link
JP (1) JPS62179812A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100928230B1 (en) * 2007-11-15 2009-11-24 정창선 Double pipe manufacturing method
JP2016084713A (en) * 2014-10-23 2016-05-19 マツダ株式会社 Heat insulation layer formation method of cylindrical hole inner peripheral surface, heat insulation layer formation structure, and engine including heat insulation layer formation structure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100928230B1 (en) * 2007-11-15 2009-11-24 정창선 Double pipe manufacturing method
JP2016084713A (en) * 2014-10-23 2016-05-19 マツダ株式会社 Heat insulation layer formation method of cylindrical hole inner peripheral surface, heat insulation layer formation structure, and engine including heat insulation layer formation structure

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