JPS62178239A - Silver halide color photographic sensitive material - Google Patents
Silver halide color photographic sensitive materialInfo
- Publication number
- JPS62178239A JPS62178239A JP2060186A JP2060186A JPS62178239A JP S62178239 A JPS62178239 A JP S62178239A JP 2060186 A JP2060186 A JP 2060186A JP 2060186 A JP2060186 A JP 2060186A JP S62178239 A JPS62178239 A JP S62178239A
- Authority
- JP
- Japan
- Prior art keywords
- group
- atom
- formulas
- general formula
- silver halide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 Silver halide Chemical class 0.000 title claims abstract 7
- 229910052709 silver Inorganic materials 0.000 title claims abstract 7
- 239000004332 silver Substances 0.000 title claims abstract 7
- 239000000463 material Substances 0.000 title claims abstract 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract 9
- 125000003277 amino group Chemical group 0.000 claims abstract 7
- 239000000839 emulsion Substances 0.000 claims abstract 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract 4
- 125000004434 sulfur atom Chemical group 0.000 claims abstract 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract 3
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000003342 alkenyl group Chemical group 0.000 claims abstract 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052737 gold Inorganic materials 0.000 claims abstract 3
- 239000010931 gold Substances 0.000 claims abstract 3
- 125000005843 halogen group Chemical group 0.000 claims abstract 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract 3
- 239000011593 sulfur Substances 0.000 claims abstract 3
- 125000003118 aryl group Chemical group 0.000 claims 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims 6
- 239000000126 substance Substances 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 3
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 125000003396 thiol group Chemical group [H]S* 0.000 claims 2
- 125000001960 7 membered carbocyclic group Chemical group 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
- G03C2001/091—Gold
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
- G03C2001/095—Disulfide or dichalcogenide compound
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
- G03C2001/348—Tetrazaindene
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/40—Mercapto compound
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
PURPOSE:To obtain a photosensitive material which permits quick processing and has an excellent fogging-sensitivity relation by providing >=1 layers of emulsion layers contg. substantially silver chlorobromide particles chemically sensitized by a sulfur sensitizer and gold sensitizer and contg. a specific compd. CONSTITUTION:The silver halide emulsion consisting of the silver chlorobromide chemically sensitized by the sulfur sensitizer and gold sensitizer is incorporated into at least on layer of the emulsion layers and at least on kind of the compds. expressed by formula I- formula VI is incorporated therein. R1, R2, R3 are an H atom, halogen atom, amino group, etc., R5 is an H atom, alkyl group. X is formula V is the monovalent group excluding one H atom from the compds. expressed by formula I- formula IV, J is a divalent combination group. X in formula VI is an H atom, amino group, etc. Z is an N atom, S atom, O atom, n is 1, 0 when Z is the N atom or 0 when Z is the S atom. R6-R0 are an alkyl group, alkenyl group, etc.
Description
【発明の詳細な説明】 ６、ＮＩｔ正の内容 別紙のとおり[Detailed description of the invention] 6. NIT positive content As per attached sheet
Claims (1)
化銀カラー写真感光材料において感光性ハロゲン化銀乳
剤層の少なくとも一層が少なくともイオウ増感剤および
金増感剤を用いて化学増感された実質的に塩臭化銀から
なるハロゲン化銀乳剤を含みかつ下記一般式（１）〜（
６）で示される化合物の少なくとも一種を含むことを特
徴とするハロゲン化銀カラー写真感光材料。 一般式（１）▲数式、化学式、表等があります▼一般式
（２）▲数式、化学式、表等があります▼ 一般式（３）▲数式、化学式、表等があります▼一般式
（４）▲数式、化学式、表等があります▼ 一般式（５）▲数式、化学式、表等があります▼一般式
（６）▲数式、化学式、表等があります▼ 一般式（１）〜（５）式中、Ｒ＿１、Ｒ＿２およびＲ＿
３は同じでも異なっていてもよく、各々水素原子、ハロ
ゲン原子、アミノ基、アミノ基の誘導体、アルキル基、
アルキル基の誘導体、アリール基、アリール基の誘導体
、シクロアルキル基、シクロアルキル基の誘導体、メル
カプト基、メルカプト基の誘導体または−ＣＯＮＨ−Ｒ
＿４（Ｒ＿４は水素原子、アルキル基、アミノ基、アル
キル基の誘導体、アミノ基の誘導体、ハロゲン原子、シ
クロアルキル基、シクロアルキル基の誘導体、アリール
基またはアリール基の誘導体を表わす。）を表わし、Ｒ
＿５は水素原子またはアルキル基を表し、Ｒ＿１とＲ＿
２は結合して環（例えば、５〜７員の炭素環、複素環）
を形成してもよく、Ｘは一般式（１）、（２）、（３）
または（４）で表わされる化合物から水素原子１箇を除
いた１価の基（例えば前記一般式（１）ないし（４）に
おけるＲ＿１〜Ｒ＿３またはＯＨ部分から水素原子１箇
を除いたもの）を表わし、Ｊは２価の連結基を表わす。 一般式（６）Ｘは水素原子、アミノ基、ヒドロキシル基
、メルカプト基、ヒドラジノ基、アルキル基、アルケニ
ル基、シクロアルキル基、アリール基、−ＮＨＣＯＲ＿
６基、−ＮＨＳＯ＿２Ｒ＿６基又は−ＳＲ＿７基を表わ
しＹは水素元素、アミノ基、アルキル基、アルケニル基
、シクロアルキル基、アリール基、−ＣＯＮＨＲ＿６基
、−ＣＯＲ＿９基、−ＮＨＣＯＲ＿１＿０基又は−ＮＨ
ＳＯ＿２Ｒ＿１＿０基を表わす。Ｚは窒素原子、硫黄原
子又は酸素原子を表わす。ｎはＺが窒素原子の場合１を
表わし、Ｚが酸素原子又たは硫黄原子の場合０を表わす
。 Ｒ＿６、Ｒ＿７、Ｒ＿８、Ｒ＿９及びＲ＿１＿０はそれ
ぞれアルキル基、アルケニル基、シクロアルキル基又は
アリール基を表わす。[Claims] In a silver halide color photographic light-sensitive material having a light-sensitive silver halide layer on a reflective support, at least one of the light-sensitive silver halide emulsion layers contains at least a sulfur sensitizer and a gold sensitizer. contains a silver halide emulsion substantially consisting of silver chlorobromide which has been chemically sensitized by the following general formulas (1) to (
6) A silver halide color photographic material containing at least one of the compounds shown in (6). General formula (1) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (2) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (3) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (4) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (5) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formula (6) ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ General formulas (1) to (5) Medium, R_1, R_2 and R_
3 may be the same or different, and each represents a hydrogen atom, a halogen atom, an amino group, a derivative of an amino group, an alkyl group,
Derivatives of alkyl groups, aryl groups, derivatives of aryl groups, cycloalkyl groups, derivatives of cycloalkyl groups, mercapto groups, derivatives of mercapto groups or -CONH-R
_4 (R_4 represents a hydrogen atom, an alkyl group, an amino group, a derivative of an alkyl group, a derivative of an amino group, a halogen atom, a cycloalkyl group, a derivative of a cycloalkyl group, an aryl group or a derivative of an aryl group), R
_5 represents a hydrogen atom or an alkyl group, and R_1 and R_
2 is bonded to a ring (e.g., 5- to 7-membered carbocycle, heterocycle)
may be formed, and X is the general formula (1), (2), (3)
Or a monovalent group obtained by removing one hydrogen atom from the compound represented by (4) (for example, a compound obtained by removing one hydrogen atom from R_1 to R_3 or the OH moiety in the above general formulas (1) to (4)). where J represents a divalent linking group. General formula (6)
6 group, -NHSO_2R_6 group, or -SR_7 group, and Y is a hydrogen element, an amino group, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, -CONHR_6 group, -COR_9 group, -NHCOR_1_0 group, or -NH
Represents SO_2R_1_0 group. Z represents a nitrogen atom, a sulfur atom or an oxygen atom. n represents 1 when Z is a nitrogen atom, and represents 0 when Z is an oxygen atom or a sulfur atom. R_6, R_7, R_8, R_9 and R_1_0 each represent an alkyl group, an alkenyl group, a cycloalkyl group or an aryl group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2060186A JPS62178239A (en) | 1986-01-31 | 1986-01-31 | Silver halide color photographic sensitive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2060186A JPS62178239A (en) | 1986-01-31 | 1986-01-31 | Silver halide color photographic sensitive material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62178239A true JPS62178239A (en) | 1987-08-05 |
Family
ID=12031783
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2060186A Pending JPS62178239A (en) | 1986-01-31 | 1986-01-31 | Silver halide color photographic sensitive material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62178239A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5071320A (en) * | 1973-10-25 | 1975-06-13 | ||
| JPS54119917A (en) * | 1978-03-10 | 1979-09-18 | Konishiroku Photo Ind Co Ltd | Photosensitive material of silver halide for photography |
| JPS58126526A (en) * | 1981-12-19 | 1983-07-28 | Konishiroku Photo Ind Co Ltd | Manufacture of silver halide emulsion, and photosensitive silver halide material |
| JPS58215644A (en) * | 1982-06-10 | 1983-12-15 | Konishiroku Photo Ind Co Ltd | Preparation of silver halide photographic emulsion |
-
1986
- 1986-01-31 JP JP2060186A patent/JPS62178239A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5071320A (en) * | 1973-10-25 | 1975-06-13 | ||
| JPS54119917A (en) * | 1978-03-10 | 1979-09-18 | Konishiroku Photo Ind Co Ltd | Photosensitive material of silver halide for photography |
| JPS58126526A (en) * | 1981-12-19 | 1983-07-28 | Konishiroku Photo Ind Co Ltd | Manufacture of silver halide emulsion, and photosensitive silver halide material |
| JPS58215644A (en) * | 1982-06-10 | 1983-12-15 | Konishiroku Photo Ind Co Ltd | Preparation of silver halide photographic emulsion |
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