JPS62177076A - Aqueous printing ink composition for preventing copying - Google Patents
Aqueous printing ink composition for preventing copyingInfo
- Publication number
- JPS62177076A JPS62177076A JP61018212A JP1821286A JPS62177076A JP S62177076 A JPS62177076 A JP S62177076A JP 61018212 A JP61018212 A JP 61018212A JP 1821286 A JP1821286 A JP 1821286A JP S62177076 A JPS62177076 A JP S62177076A
- Authority
- JP
- Japan
- Prior art keywords
- pigment
- water
- ink composition
- printing
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000011230 binding agent Substances 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 238000010521 absorption reaction Methods 0.000 claims abstract description 6
- 239000011256 inorganic filler Substances 0.000 claims abstract description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- 229910052711 selenium Inorganic materials 0.000 abstract description 4
- 239000011669 selenium Substances 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005018 casein Substances 0.000 abstract description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract description 2
- 235000021240 caseins Nutrition 0.000 abstract description 2
- 239000001023 inorganic pigment Substances 0.000 abstract description 2
- 150000002688 maleic acid derivatives Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 abstract description 2
- 239000012860 organic pigment Substances 0.000 abstract description 2
- 230000035699 permeability Effects 0.000 abstract description 2
- -1 polyazo Polymers 0.000 abstract description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 27
- 238000000034 method Methods 0.000 description 8
- 108091008695 photoreceptors Proteins 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QLNFINLXAKOTJB-UHFFFAOYSA-N [As].[Se] Chemical compound [As].[Se] QLNFINLXAKOTJB-UHFFFAOYSA-N 0.000 description 2
- YQRYRVCUJXRYIF-UHFFFAOYSA-N [Se].[Sb].[As] Chemical compound [Se].[Sb].[As] YQRYRVCUJXRYIF-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- OQRNKLRIQBVZHK-UHFFFAOYSA-N selanylideneantimony Chemical compound [Sb]=[Se] OQRNKLRIQBVZHK-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 239000003232 water-soluble binding agent Substances 0.000 description 2
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000007647 flexography Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔発明の目的〕
（産業上の利用分野）
本発明は、電子写真方式の複写機、とりわけセレン、セ
レン−ひ素、セレン−アンチモン、セレン−テルル、よ
う素ドープされたセレン−ひ素−アンチモンなどのセレ
ン系感光体やフタロシアニン系感光体を用いた電子写真
方式の複写機による複写の防止のための水性印刷インキ
組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Object of the invention] (Industrial field of application) The present invention relates to an electrophotographic copying machine, particularly a selenium-doped, selenium-arsenic, selenium-antimony, selenium-tellurium, iodine-doped copying machine. The present invention relates to an aqueous printing ink composition for preventing copying by an electrophotographic copying machine using a selenium-based photoreceptor such as selenium-arsenic-antimony or a phthalocyanine-based photoreceptor.
（従来の技術）
電子写真方式の複写機は、近年型々普及しつつあるが、
これに伴って秘密文書などの漏洩、あるいは紙幣、証券
などの偽造、変造などが容易になされることが弊害とな
ってきている。(Prior art) Electrophotographic copying machines have become increasingly popular in recent years, but
Along with this, it has become a problem that confidential documents can be leaked or banknotes, securities, etc. can be easily forged or altered.
これらの弊害を除去するためには、■可視光線に対して
は透明であり、複写機の光によって発色する成分を用い
る方法２例えばロイコ体、フォトクロミック物質などを
含浸あるいはこれらの物質を含むコーティング組成物を
塗布する方法、■メタメリー（条件等色）効果を利用す
る方法、■螢光染料を使用する方法などが知られている
。しかしながら、ロイコ体、螢光染料などは耐候性に乏
しく経時により劣化するという欠点があり、また、他の
方法にしても白い紙に濃色の印刷がされている通常の印
刷物の複写を完全に防止することのできるシステムは開
発されていなかった。In order to eliminate these harmful effects, there are two methods: 1. Using a component that is transparent to visible light and colored by the light of a copying machine 2. For example, impregnation with leuco bodies, photochromic substances, etc., or coating compositions containing these substances. The following methods are known: 1. Using metamery (conditional color matching) effect, and 2. Using fluorescent dye. However, leuco bodies, fluorescent dyes, etc. have the disadvantage of poor weather resistance and deteriorate over time, and even if other methods are used, it is impossible to completely copy normal printed matter that is printed in dark colors on white paper. No system had been developed that could prevent it.
これらの欠点を改良するものとして、油性の結着剤に顔
料を分散したオフセントインキを地紋状にオフセント印
刷して複写を防止する方法が提案された。In order to improve these drawbacks, a method has been proposed in which copying is prevented by using offset ink in which a pigment is dispersed in an oil-based binder to perform offset printing in the form of a tint pattern.
しかしながら、この方法では油性の結着剤が用いいられ
ているため、この複写防止法を施した印刷文書または用
紙に、鉛筆、油性筆記インキ、水性筆記インキなどの筆
記具、とりわけ水性筆記インキで書込みなどをしようと
しても、ばしいて字が途切れたりして十分筆記できない
という欠点があった。However, since this method uses an oil-based binder, it is difficult to write on printed documents or paper coated with this anti-copying method with writing instruments such as pencils, oil-based writing inks, water-based writing inks, and especially water-based writing inks. Even if you tried to write something like this, the problem was that the characters would break off and you wouldn't be able to write them properly.
（発明が解決しようとする問題点）
本発明は、上記の欠点を改良し、汎用されている各種の
電子写真方式の複写機による複写を実用上はぼ完全に防
止でき、それを印刷した上に鉛筆、油性筆記インキのみ
ならず水性筆記インキでも十分筆記しうる複写防止用水
性印刷インキ組成物を提供するものである。(Problems to be Solved by the Invention) The present invention improves the above-mentioned drawbacks, practically completely prevents copying by various commonly used electrophotographic copying machines, and prints To provide a water-based printing ink composition for preventing copying which can be sufficiently written on with not only pencils and oil-based writing inks but also water-based writing inks.
（問題点を解決するための手段）
本発明は、５００〜７００ ｎｍの範囲に最大吸収波長
を有する顔料、水性結着剤、および必要に応じて無機充
填剤を含んでなる複写防止用水性印刷インキ組成物であ
る。(Means for Solving the Problems) The present invention provides a water-based printing for preventing copying, which comprises a pigment having a maximum absorption wavelength in the range of 500 to 700 nm, an aqueous binder, and, if necessary, an inorganic filler. It is an ink composition.
本発明において、５００〜７００ ｎｍの範囲に最大吸
収波長を有する顔料としては、５００〜７００ ｎｍの
範囲に最大吸収波長を有する溶性アヅ、不溶性アブ、フ
タロシアニンブルー、モノアゾ、ポリアブなどの有機顔
料、酸化鉄などの無機顔料、あるいはこれらの混合物が
あるが２文書の印刷文字や筆記した文字が黒の場合には
、原本の判読し易さの面から朱。In the present invention, pigments having a maximum absorption wavelength in the range of 500 to 700 nm include organic pigments such as soluble azu, insoluble ab, phthalocyanine blue, monoazo, and polyab, which have a maximum absorption wavelength in the range of 500 to 700 nm; If there is an inorganic pigment such as iron or a mixture of these, but the printed or written characters on the two documents are black, red is used to make the original easier to read.
赤あるいは茶の色相を有する顔料あるいは顔料混合物を
選択することが好ましい。Preference is given to selecting pigments or pigment mixtures with a red or brown hue.
本発明において、水性結着剤としては、水溶型のもの、
水分散型のもの、あるいはこれらの中間のいわゆるハイ
ドロゾル型のものがあるが、顔料の分散性１紙への転移
性あるいは印刷適性の面からハイドロゾル型のものを用
いることが好ましい。これらの結着剤には、シェラツク
、カゼインなどの天然樹脂。In the present invention, the water-based binder includes water-soluble binders,
There are water-dispersible types and so-called hydrosol types intermediate between these types, but it is preferable to use hydrosol types from the viewpoint of pigment dispersibility, transferability to paper, and printability. These binders include natural resins such as shellac and casein.
ロジン変性マレイン酸樹脂、 （メタ）アクリル酸エス
テル−（メタ）アクリル酸共重合樹脂またはこれらのア
ルカリ中和物、スチレン−（メタ）アクリル酸共重合樹
脂またはこれらのアルカリ中和物、スチレン−マレイン
酸共重合樹脂またはこれらのアルカリ中和物などがある
。Rosin-modified maleic acid resin, (meth)acrylic ester-(meth)acrylic acid copolymer resin or alkali neutralized product thereof, styrene-(meth)acrylic acid copolymer resin or alkali neutralized product thereof, styrene-malein Examples include acid copolymer resins and alkali neutralized products thereof.
本発明において、鉛筆、油性筆記インキ、水性筆記イン
キなどの筆記具、とりわけ水性筆記インキの筆記性をよ
り高めるために、さらに無機充堤剤を用いることが好ま
しく、このような無機充填剤としては、シリカ、炭酸マ
グネシウム、炭酸カルシウム。In the present invention, in order to further improve the writing properties of writing implements such as pencils, oil-based writing inks, and water-based writing inks, especially water-based writing inks, it is preferable to further use an inorganic filler, and such inorganic fillers include: Silica, magnesium carbonate, calcium carbonate.
硫酸バリウム、クレーなどを用いることができるが。Barium sulfate, clay, etc. can be used.
筆記性の面からは多孔質で水浸透性の高いシリカを用い
ることが好ましい。From the viewpoint of writability, it is preferable to use silica which is porous and has high water permeability.
文字・図などの印刷または筆記を施したまたは施さない
紙、プラスチック、アルミ箔などの基材に。For base materials such as paper, plastic, aluminum foil, etc. with or without printing or writing such as letters and figures.
本発明の複写防止用水性印刷インキ組成物を用いて。Using the aqueous printing ink composition for preventing copying of the present invention.
全面または部分にベタ刷りまたは適宜模様状に印刷を行
ない、さらに必要に応じて文字・図などの印刷が施され
る。本発明の複写防止用水性印刷インキ組成物の印刷の
方法としては特に制限はなく、グラビア印刷、フレキソ
印刷、ロールコートなどが可能であるが９版深で印刷及
膜厚を調節できるグラビア印刷による方法が便利である
。Solid printing or appropriate pattern printing is performed on the entire surface or part, and furthermore, characters, figures, etc. are printed as necessary. There are no particular limitations on the printing method of the water-based printing ink composition for preventing copying of the present invention, and gravure printing, flexographic printing, roll coating, etc. are possible, but gravure printing is used, which allows printing and film thickness to be adjusted at a depth of 9 plates. The method is convenient.
（作 用）
このようにして得られた印刷物には、鉛筆や油性筆記イ
ンキのみならず、水性筆記インキなどでもはじくことな
く筆記が可能である。(Function) It is possible to write on the thus obtained printed matter not only with a pencil or oil-based writing ink, but also with water-based writing ink without repelling it.
また、筆記または印刷された文字や図は、原本では十分
明瞭に判読できるのに対して、複写物では全く判読でき
ず、十分な複写防止効果を有するものである。In addition, written or printed characters and figures can be clearly read in the original, but cannot be read at all in the copy, and have a sufficient effect of preventing copying.
（実 施 例）
以下、実施例により本発明を説明する。例中１部とは重
量部を１％とは重量％を表わす。(Examples) The present invention will be explained below with reference to Examples. In the examples, 1 part means part by weight, and 1% means % by weight.
実施例１
スチレン含有量５０％のスチレン−アクリル酸共重合体
をアンモニア水で中和率１００％となるように中和して
固形分３０％、溶剤組成水９３％、イソプロピルアルコ
ール７％の水溶性結着剤を得た。得られた水溶性結着剤
１３３部および酸化鉄「戸田カラーＫＮＯＪ （戸田
工業＠製）６０部を練肉し、水性印刷インキ組成物を得
た。得られた水性印刷インキ組成物を用い、墨インキで
文字印刷を施した秤量６０ ｇ／ｍの上質紙上へ版深３
０μｍのグラビア版によるグラビア印刷（全面ベタ刷り
）を行い、乾燥し、その上に「水性サインペン黒」 （
ペンチル＠製）および黒色鉛筆「ユニ」 （硬度Ｂ、三
菱鉛筆＠製）を用いて文字を筆記した。Example 1 A styrene-acrylic acid copolymer with a styrene content of 50% was neutralized with aqueous ammonia to give a neutralization rate of 100%, and the solid content was 30%, the solvent composition was 93% water, and 7% isopropyl alcohol. A binding agent was obtained. 133 parts of the obtained water-soluble binder and 60 parts of iron oxide "Toda Color KNOJ (manufactured by Toda Kogyo@) were kneaded to obtain a water-based printing ink composition. Using the obtained water-based printing ink composition, Plate depth 3 on high-quality paper with a weight of 60 g/m printed with black ink.
Gravure printing (solid printing on the entire surface) is performed using a 0μm gravure plate, dried, and then "water-based felt-tip pen black" (
The letters were written using a black pencil "Uni" (hardness B, manufactured by Mitsubishi Pencil@) and a black pencil "Uni" (hardness B, manufactured by Mitsubishi Pencil@).
筆記された文字ははじくことなく連続した線となり、筆
記適性は良好であった。また、印刷文字および筆記文字
は明瞭に読みとることができた。The written characters formed a continuous line without flickering, and the writing aptitude was good. In addition, printed and written characters could be clearly read.
このようにして得られた印刷文字および筆記文字を有す
る印刷物からｒＦＵＪＩ ＸＥＲＯＸ ＦＸ−３８
９０Ｊ （富士ゼロックス側製）により複写したとこ
ろ、全面黒色の複写物が得られ、いずれの文字も読みと
ることばできなかった。From the printed matter having printed characters and written characters obtained in this way
90J (manufactured by Fuji Xerox), a completely black copy was obtained, and none of the characters could be read or spoken.
実施例２
固形分３０％のスチレン−アクリル酸系ハイドロゾル型
水性結着剤「リオクリルＡＰ−２Ｊ （東洋インキ製
造＠製）１００部に、「リオノールイエローＧＧＴＮＪ
３０％、 「ブライトレッドＧ Ｉ−ナー」６０％お
よび［リオノールブルーＦＧ−７３３０Ｊ １０％から
なる顔料混合物（いずれも東洋インキ製造■製）３０部
および微粉シリカ「エロジル２００」（日本アエロジル
■製）２．６部を加え、練肉し水性印刷インキ組成物を
得た。１１られた水性印刷インキ組成物を用い、秤量５
５ ｇ／ｌｒｉの中質紙へ乾燥印刷皮模厚２ｇ／％とな
るようにフレキソ印刷でランダム掌紋印刷を施し、乾燥
し、その上に水性ペン「Ｐｉｎ極細黒」 （三菱鉛筆＠
１ ！ｌ！ ）を用いて文字を筆記した。Example 2 100 parts of a styrene-acrylic acid hydrosol-type aqueous binder with a solid content of 30% "Lyocryl AP-2J (manufactured by Toyo Ink Mfg.
30 parts of a pigment mixture consisting of 30% "Bright Red G I-ner" and 10% Lionor Blue FG-7330J (all manufactured by Toyo Ink Mfg. ■) and fine powder silica "Erosil 200" (manufactured by Nippon Aerosil ■). ) was added and kneaded to obtain a water-based printing ink composition. Using a water-based printing ink composition prepared by
5 g/lri medium-quality paper with a dry printing surface thickness of 2 g/%, a random palm print is printed using flexography, dried, and then water-based pen ``Pin Extra Fine Black'' (Mitsubishi Pencil @
1! l! ) was used to write the letters.
筆記された文字ははじくことなく連続した線となり、筆
記適性は良好であった。また、筆記された文字は明瞭に
読み取ることができた。The written characters formed a continuous line without flickering, and the writing aptitude was good. In addition, written characters could be clearly read.
このようにして得られた筆記文字を有する印刷物からｒ
ＦＵＪＩ ＸＥＲＯＸ ＦＸ−３８９０Ｊにより複
写したところ、得られた複写物では筆記文字の判読が不
可能であった。From printed matter with written characters obtained in this way r
When a copy was made using FUJI XEROX FX-3890J, it was impossible to read the written characters in the resulting copy.
実施例３ 実施例２で用いた水性印刷インキ組成物を用い。Example 3 The aqueous printing ink composition used in Example 2 was used.
秤量５５ｇ／％の上質紙・＼版深３０μｍのグラビア版
によりランダム斜線印刷を施し乾燥した。得られた印刷
物の印刷面に、「水性サインペン黒」を用いて文字を筆
記した。Random diagonal printing was applied using a gravure plate with a plate depth of 30 μm on high-quality paper with a weight of 55 g/% and dried. Characters were written on the printed surface of the obtained printed matter using a "water-based felt-tip pen black."
筆記された文字ははじくことなく連続した線となり、筆
記適性は良好であった。また、筆記された文字は明瞭に
読み取ることができた。The written characters formed a continuous line without flickering, and the writing aptitude was good. In addition, written characters could be clearly read.
このようにして得られた筆記文字を有する印刷物からｒ
ＦＵＪＩ ＸＥＲＯＸ ＦＸ−３８９０Ｊにより複
写したところ、得られた複写物では筆記文字の判読が不
可能であった。From printed matter with written characters obtained in this way r
When a copy was made using FUJI XEROX FX-3890J, it was impossible to read the written characters in the resulting copy.
比較例
秤量５５ｇ／ｎｒの上質紙に油溶性オフセットインキｒ
ＴＫニューブライトＧｊ （東洋インキ製造＠製）に
より乾燥印刷皮膜厚１．５ｇ／ｍとなるようにオフセッ
トのベク印刷で複写防止印刷を施した。Comparative example: Oil-soluble offset ink on high-quality paper with a weight of 55 g/nr.
Copy prevention printing was performed using offset vector printing using TK New Bright Gj (manufactured by Toyo Ink Seisaku@) so that the dry printed film thickness was 1.5 g/m.
得られた印刷物の印刷面に黒色鉛筆「ユニ」 （硬度Ｂ
）「水性サインペン黒」および「Ｐｉｎ極細」で筆記し
た。「ユニ」で筆記された文字は、線がとぎれることな
く明瞭に筆記することができたが、これに対して「水性
サインペン黒」およびｒＰｉｎ極細」で筆記された文字
ははじいて線がとぎれ簡単にこすれおちるものであった
。Black pencil “UNI” (hardness B
) Written with "Water-based felt-tip pen black" and "Pin extra fine". Characters written with "Uni" were able to be written clearly without any line breakage, but on the other hand, characters written with "Water-based felt-tip pen black" and rPin ultra-fine "repelled easily and the lines were easily broken." It was something that rubbed off on me.
このようにして得られた黒色鉛筆「ユニ」 （硬度Ｂ）
による筆記文字を有する印刷物からｒＦＵＪＩＸＥＲＯ
Ｘ ＦＸ−３８９０Ｊにより複写したところ、得られ
た複写物では、全面が黒色となり、黒色鉛筆による筆記
文字の判読が不可能であった。Black pencil “Uni” obtained in this way (hardness B)
rFUJIXERO from prints with written characters by
When a copy was made using X FX-3890J, the entire surface of the resulting copy was black, making it impossible to read the characters written with a black pencil.
本発明により、汎用されている各種の電子写真方式の複
写機、とりわけセレン、セレン−ひ素、セレン−アンチ
モン、セレン−テルル、よう素ドープされたセレン−ひ
素−アンチモンなどのセレン系感光体やフタロシアニン
系感光体を用いた複写機による複写を実用上はぼ完全に
防止でき、それを印刷した上に鉛筆、油性筆記インキの
みならず水性筆記インキでも十分筆記しうる複写防止用
水性印刷インキ組放物が得られるようになった。According to the present invention, various commonly used electrophotographic copying machines, particularly selenium-based photoreceptors such as selenium, selenium-arsenic, selenium-antimony, selenium-tellurium, and iodine-doped selenium-arsenic-antimony, and phthalocyanin A water-based printing ink composition for preventing copying, which practically completely prevents copying by a copying machine using a photoreceptor, and which can be sufficiently written on with a pencil or oil-based writing ink as well as water-based writing ink. I can now get things.
本発明の複写防止用水性印刷インキ組成物は、小切手用
紙、為替用紙、証券用紙、印鑑証明用紙１機密メモ用紙
など書込みがなされる複写防止用紙の印刷に有用である
。The aqueous printing ink composition for preventing copying of the present invention is useful for printing on copy-preventing paper on which writing is written, such as check paper, money order paper, securities paper, seal certificate paper 1 confidential memo paper, etc.
Claims (1)
、水性結着剤、および必要に応じて無機充填剤を含んで
なる複写防止用水性印刷インキ組成物。A water-based printing ink composition for preventing copying, comprising a pigment having a maximum absorption wavelength in the range of 500 to 700 nm, an aqueous binder, and, if necessary, an inorganic filler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018212A JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018212A JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62177076A true JPS62177076A (en) | 1987-08-03 |
| JPH0569146B2 JPH0569146B2 (en) | 1993-09-30 |
Family
ID=11965339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61018212A Granted JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62177076A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004035699A1 (en) * | 2002-10-12 | 2004-04-29 | Avecia Limited | Ink comprising casein |
| GB2413558A (en) * | 2002-10-12 | 2005-11-02 | Avecia Inkjet Ltd | Use of casein for improving ozone fastness of a colorant |
| CN108003703A (en) * | 2017-12-22 | 2018-05-08 | 许宏元 | A kind of binder for water-based ink and corresponding water-based ink |
-
1986
- 1986-01-31 JP JP61018212A patent/JPS62177076A/en active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004035699A1 (en) * | 2002-10-12 | 2004-04-29 | Avecia Limited | Ink comprising casein |
| GB2408743A (en) * | 2002-10-12 | 2005-06-08 | Avecia Ltd | Ink comprising casein |
| GB2413558A (en) * | 2002-10-12 | 2005-11-02 | Avecia Inkjet Ltd | Use of casein for improving ozone fastness of a colorant |
| GB2408743B (en) * | 2002-10-12 | 2006-01-11 | Avecia Ltd | Process for improving ozone fastness |
| CN108003703A (en) * | 2017-12-22 | 2018-05-08 | 许宏元 | A kind of binder for water-based ink and corresponding water-based ink |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0569146B2 (en) | 1993-09-30 |
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| LAPS | Cancellation because of no payment of annual fees |