JPH0569146B2 - - Google Patents
Info
- Publication number
- JPH0569146B2 JPH0569146B2 JP1821286A JP1821286A JPH0569146B2 JP H0569146 B2 JPH0569146 B2 JP H0569146B2 JP 1821286 A JP1821286 A JP 1821286A JP 1821286 A JP1821286 A JP 1821286A JP H0569146 B2 JPH0569146 B2 JP H0569146B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- written
- printing
- printed
- writing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007639 printing Methods 0.000 claims description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000049 pigment Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 239000011256 inorganic filler Substances 0.000 claims description 4
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 229910052570 clay Inorganic materials 0.000 claims description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
- 239000001095 magnesium carbonate Substances 0.000 claims description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 2
- 239000000976 ink Substances 0.000 description 28
- 238000000034 method Methods 0.000 description 11
- 108091008695 photoreceptors Proteins 0.000 description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 3
- QLNFINLXAKOTJB-UHFFFAOYSA-N [As].[Se] Chemical compound [As].[Se] QLNFINLXAKOTJB-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229910052711 selenium Inorganic materials 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 235000010724 Wisteria floribunda Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- OQRNKLRIQBVZHK-UHFFFAOYSA-N selanylideneantimony Chemical compound [Sb]=[Se] OQRNKLRIQBVZHK-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- YQRYRVCUJXRYIF-UHFFFAOYSA-N [Se].[Sb].[As] Chemical compound [Se].[Sb].[As] YQRYRVCUJXRYIF-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- BNZLJNRQXPJPJY-UHFFFAOYSA-L barium(2+) 4-[(5-chloro-4-methyl-2-sulfophenyl)diazenyl]-3-oxidonaphthalene-2-carboxylate Chemical compound CC1=CC(=C(C=C1Cl)N=NC2=C(C(=CC3=CC=CC=C32)C(=O)[O-])[O-])S(=O)(=O)O.[Ba+2] BNZLJNRQXPJPJY-UHFFFAOYSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- -1 polyazo Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
【発明の詳細な説明】
〔発明の目的〕
（産業上の利用分野）
本発明は、電子写真方式の複写機、とりわけセ
レン、セレン−ひ素、セレン−アンチモン、セレ
ン−テルル、よう素ドープされたセレン−ひ素−
アンチモンなどのセレン系感光体やフタロシアニ
ン系感光体を用いた電子写真方式の複写機による
複写の防止のための水性印刷インキ組成物に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Object of the Invention] (Industrial Field of Application) The present invention relates to an electrophotographic copying machine, particularly a selenium-doped, selenium-arsenic, selenium-antimony, selenium-tellurium, iodine-doped copying machine. Selenium - arsenic -
The present invention relates to a water-based printing ink composition for preventing copying by an electrophotographic copying machine using a selenium-based photoreceptor such as antimony or a phthalocyanine-based photoreceptor.
（従来の技術）
電子写真方式の複写機は、近年益々普及しつつ
あるが、これに伴つて秘密文書などの漏洩、ある
いは紙幣、証券などの偽造、変造などが容易にな
されることが弊害となつてきている。(Prior Art) Electrophotographic copying machines have become more and more popular in recent years, but with this comes the disadvantage that confidential documents can be leaked, and banknotes and securities can be easily forged or altered. I'm getting used to it.
これらの弊害を除去するためには、可視光線
に対しては透明であり、複写機の光によつて発色
する成分を用いる方法、例えばロイコ体、フオト
クロミツク物質などを含浸あるいはこれらの物質
を含むコーテイング組成物を塗布する方法、メ
タメリー（条件等色）効果を利用する方法、螢
光染料を使用する方法などが知られている。しか
しながら、ロイコ体、螢光染料などは耐候性に乏
しく経時により劣化するという欠点があり、ま
た、他の方法にしても白い紙に濃色の印刷がされ
ている通常の印刷物の複写を完全に防止すること
のできるシステムは開発されていなかつた。 In order to eliminate these harmful effects, methods using components that are transparent to visible light and develop color when exposed to light from a copying machine, such as impregnation with leuco bodies, photochromic substances, etc., or coatings containing these substances, are recommended. A method of applying a composition, a method of utilizing a metamery effect, a method of using a fluorescent dye, etc. are known. However, leuco bodies, fluorescent dyes, etc. have the disadvantage of poor weather resistance and deteriorate over time, and even if other methods are used, it is impossible to completely copy normal printed matter that is printed in dark colors on white paper. No system had been developed that could prevent it.
これらの欠点を改良するものとして、油性の結
着剤に顔料を分散したオフセツトインキを地紋状
にオフセツト印刷して複写を防止する方法が提案
された。 In order to improve these drawbacks, a method has been proposed in which copying is prevented by offset printing in the form of a background pattern using an offset ink containing a pigment dispersed in an oil-based binder.
しかしながら、この方法では油性の結着剤が用
いいられているため、この複写防止法を施した印
刷文書または用紙に、鉛筆、油性筆記インキ、水
性筆記インキなどの筆記具、とりわけ水性筆記イ
ンキで書込みなどをしようとしても、はじいて字
が途切れたりして十分筆記できないという欠点が
あつた。 However, since this method uses an oil-based binder, it is difficult to write on printed documents or paper coated with this anti-copying method with writing instruments such as pencils, oil-based writing inks, water-based writing inks, and especially water-based writing inks. Even when I tried to write something like this, the problem was that I couldn't write properly because the letters would break off when I flicked them.
（発明が解決しようとする問題点）
本発明は、上記の欠点を改良し、汎用されてい
る各種の電子写真方式の複写機による複写を実用
上ほぼ完全に防止でき、それを印刷した上に鉛
筆、油性筆記インキのみならず水性筆記インキで
も十分筆記しうる複写防止用水性印刷インキ組成
物を提供するものである。(Problems to be Solved by the Invention) The present invention improves the above-mentioned drawbacks, practically completely prevents copying by various widely used electrophotographic copying machines, and prints and To provide a water-based printing ink composition for preventing copying which can be sufficiently written with not only pencil and oil-based writing ink but also water-based writing ink.
（問題点を解決するための手段）
本発明は、500〜700nｍの範囲に最大吸収波長
を有する顔料、水性結着剤、およびシリカ、炭酸
マグネシウム、炭酸カルシウム、硫酸バリウムお
よびクレーから選ばれる無機充填剤を含んでなる
印刷インキであり、該インキを基材に印刷した上
に筆記インキで筆記しうることを特徴とする複写
防止用水性印刷インキ組成物である。
(Means for Solving the Problems) The present invention comprises a pigment having a maximum absorption wavelength in the range of 500 to 700 nm, an aqueous binder, and an inorganic filler selected from silica, magnesium carbonate, calcium carbonate, barium sulfate, and clay. This is an aqueous printing ink composition for preventing copying, which is a printing ink comprising an agent, and can be printed on a substrate with the ink and written on with a writing ink.
本発明において、500〜700nｍの範囲に最大吸
収波長を有する顔料としては、500〜700nｍの範
囲に最大吸収波長を有する溶性アゾ、不溶性ア
ゾ、フタロシアニンブルー、モノアゾ、ポリアゾ
などの有機顔料、酸化鉄などの無機顔料、あるい
はこれらの混合物があるが、文書の印刷文字や筆
記した文字が黒の場合には、原本の判読し易さの
面から朱、赤あるいは茶の色相を有する顔料ある
いは顔料混合物を選択することが好ましい。 In the present invention, examples of pigments having a maximum absorption wavelength in the range of 500 to 700 nm include organic pigments such as soluble azo, insoluble azo, phthalocyanine blue, monoazo, and polyazo, and iron oxide, which have a maximum absorption wavelength in the range of 500 to 700 nm. However, if the printed or written characters on a document are black, it is recommended to use pigments or pigment mixtures with a vermilion, red, or brown hue in order to make the original easier to read. It is preferable to select.
本発明において、水性粘着剤としては、水溶性
のもの、水分散性のもの、あるいはこれらの中間
のいわゆるハイドロゾル型のものがあるが、顔料
の分散性、紙への転移性あるいは印刷適性の面か
らハイドロゾル型のものを用いることが好まし
い。これらの結着剤には、シエラツク、カゼイン
などの天然樹脂、ロジン変性マレイン酸樹脂、
（メタ）アクリル酸エステル−（メタ）アクリル酸
共重合樹脂またはこれらのアルカリ中和物、スチ
レン−（メタ）アクリル酸共重合樹脂またはこれ
らのアルカリ中和物、スチレン−マレイン酸共重
合樹脂またはこれらのアルカリ中和物などがあ
る。 In the present invention, water-based adhesives include water-soluble ones, water-dispersible ones, and so-called hydrosol-type ones in between, but there are some problems in terms of pigment dispersibility, transferability to paper, and printability. It is preferable to use a hydrosol type. These binders include natural resins such as silica and casein, rosin-modified maleic resins,
(meth)acrylic acid ester-(meth)acrylic acid copolymer resin or alkali neutralized product thereof, styrene-(meth)acrylic acid copolymer resin or alkali neutralized product thereof, styrene-maleic acid copolymer resin or these There are also alkaline neutralized products.
本発明において、鉛筆、油性筆記インキ、水性
筆記インキなどの筆記具、とりわけ水性筆記イン
キの筆記性をより高めるために、さらに無機充填
剤を用いる。このような無機充填剤としては、シ
リカ、炭酸マグネシウム、炭酸カルシウム、硫酸
バリウム、クレーなどを用いることができるが、
筆記性の面からは多孔質で水浸透性の高いシリカ
を用いることが好ましい。 In the present invention, an inorganic filler is further used in order to further improve the writing properties of writing implements such as pencils, oil-based writing inks, and water-based writing inks, especially of water-based writing inks. As such inorganic fillers, silica, magnesium carbonate, calcium carbonate, barium sulfate, clay, etc. can be used.
From the viewpoint of writability, it is preferable to use silica which is porous and has high water permeability.
文字・図などの印刷または筆記を施したまたは
施さない紙、プラスチツク、アルミ箔などの基材
に、本発明の複写防止用水性印刷インキ組成物を
用いて、全面または部分にベタ刷りまたは適宜模
様状に印刷を行ない、さらに必要に応じて文字・
図などの印刷が施される。本発明の複写防止用水
性印刷インキ組成別の印刷の方法としては特に制
限はなく、グラビア印刷、フレキソ印刷、ロール
コートなどが可能であるが、版深で印刷皮膜厚を
調節できるグラビア印刷による方法が便利であ
る。 The water-based printing ink composition for preventing copying of the present invention can be used to print solid or appropriate patterns on the entire surface or part of a base material such as paper, plastic, aluminum foil, etc., which has or has not been printed or written with characters or figures, using the water-based printing ink composition for preventing copying of the present invention. It is printed in a shape, and if necessary, characters and
Printing of figures, etc. is performed. The printing method according to the composition of the water-based printing ink for preventing copying of the present invention is not particularly limited, and gravure printing, flexographic printing, roll coating, etc. are possible, but methods using gravure printing, in which the printing film thickness can be adjusted by plate depth, are possible. is convenient.
（作用）
このようにして得られた印刷物には、鉛筆や油
性筆記インキのみならず、水性筆記インキなどで
もはじくことなく筆記が可能である。(Function) It is possible to write on the thus obtained printed matter not only with a pencil or oil-based writing ink, but also with water-based writing ink without repelling it.
また、筆記または印刷された文字や図は、原本
では十分明瞭に判読できるのに対して、複写物で
は全く判読できず、十分な複写防止効果を有する
ものである。 In addition, written or printed characters and figures can be clearly read in the original, but cannot be read at all in the copy, and have a sufficient effect of preventing copying.
（実施例）
以下、実施例により本発明を説明する。例中、
部とは重量部を、％とは重量％を表わす。(Example) The present invention will be explained below with reference to Examples. In the example,
Parts refer to parts by weight, and % refers to % by weight.
実施例 １
固形分30％のスチレン−アクリル酸系ハイドロ
ゾル型水性結着剤「リオクリルAP−２」（東洋イ
ンキ製造(株)製）100部に、「リオノールイエロー
GGTN」30％、「ブライトレツドＧトナー」60％
および「リオノールブルーFG−7330」10％から
なる顔料混合物（いずれも東洋インキ製造(株)製）
30部および微粉シリカ「エロジル200」（日本アエ
ロジル(株)製）2.6部を加え、練肉し水性印刷イン
キ組成物を得た。得られた水性印刷インキ組成物
を用い、秤量55ｇ／m2の中質紙へ乾燥印刷皮膜厚
２ｇ／m2となるようにフレキソ印刷でランダム字
紋字印刷を施し、乾燥し、その上に水性ペン
「Pin極細黒」（三菱鉛筆(株)製）を用いて文字を筆
記した。Example 1 100 parts of styrene-acrylic acid hydrosol-type aqueous binder "Liocryl AP-2" (manufactured by Toyo Ink Mfg. Co., Ltd.) with a solid content of 30% was mixed with "Lionol Yellow".
GGTN” 30%, “Bright Red G Toner” 60%
and 10% "Lionol Blue FG-7330" (all manufactured by Toyo Ink Manufacturing Co., Ltd.)
30 parts and 2.6 parts of fine powder silica "Erosil 200" (manufactured by Nippon Aerosil Co., Ltd.) were added and kneaded to obtain a water-based printing ink composition. Using the obtained aqueous printing ink composition, random characters were printed by flexo printing on medium-quality paper weighing 55 g/m 2 to a dry printing film thickness of 2 g/m 2 , dried, and printed on the paper. Letters were written using a water-based pen "Pin Extra Fine Black" (manufactured by Mitsubishi Pencil Co., Ltd.).
筆記された文字ははじくことなく連続した線と
なり、筆記適性は良好であつた。また、筆記され
た文字は明瞭に読み取ることができた。 The written characters formed a continuous line without flickering, and the writing aptitude was good. In addition, written characters could be clearly read.
このようにして得られた筆記文字を有する印刷
物から「FUJI XEROX FX−3890」により複写
したところ、得られた複写物では筆記文字の判読
が不可能であつた。 When the printed matter having the written characters thus obtained was copied using "FUJI XEROX FX-3890", the written characters could not be read in the resulting copy.
実施例 ２
実施例２で用いた水性印刷インキ組成物を用
い、秤量55ｇ／m2の上質紙へ版深30μｍのグラド
ア版によりランダム斜線印刷を施し乾燥した。得
られた印刷物の印刷面に、「水性サインペン黒」
を用いて文字を筆記した。Example 2 Using the aqueous printing ink composition used in Example 2, random diagonal printing was performed on high-quality paper weighing 55 g/m 2 using a Grado plate with a plate depth of 30 μm, followed by drying. "Water-based felt-tip pen black" is applied to the printed surface of the resulting printed matter.
The letters were written using.
筆記された文字ははじくことなく連続した線と
なり、筆記適性は良好であつた。また、筆記され
た文字は明瞭に読み取ることができた。 The written characters formed a continuous line without flickering, and the writing aptitude was good. In addition, written characters could be clearly read.
このようにして得られた筆記文字を有する印刷
物から「FUJI XEROX FX−3890」により複写
したところ、得られた複写物では筆記文字の判読
が不可能であつた。 When the printed matter having the written characters thus obtained was copied using "FUJI XEROX FX-3890", the written characters could not be read in the resulting copy.
比較例
秤量55ｇ／m2の上質紙に油溶性オフセツトイン
キ「TKニユーブライトＧ」（東洋インキ製造(株)
製）により乾燥印刷皮膜厚1.5ｇ／m2となるよう
にオフセツトのベタ印刷で複写防止印刷を施し
た。Comparative example Oil-soluble offset ink "TK New Bright G" (Toyo Ink Manufacturing Co., Ltd.) on high-quality paper with a weight of 55 g/ m2
Anti-copy printing was applied using offset solid printing to give a dry printed film thickness of 1.5 g/m 2 using a commercially available printing method (manufactured by M. Co., Ltd.).
得られた印刷物の印刷面に黒色鉛筆「ユニ」
（硬度Ｂ）「水性サインペン黒」および「Pin極
細」で筆記した。「ユニ」で筆記された文字は、
線がとぎれることなく明瞭に筆記することができ
たが、これに対して「水性サインペン黒」および
「Pin極細」で筆記された文字ははじいて線がと
ぎれ簡単にこすれおちるものであつた。 Black pencil "UNI" on the printed surface of the resulting printed matter
(Hardness B) Written with "water-based felt-tip pen black" and "Pin extra fine". The characters written in "uni" are
I was able to write clearly without any breaks in the lines, but on the other hand, letters written with the "water-based felt-tip pen black" and "Pin ultra-fine" were repelled, the lines were broken, and they easily rubbed off.
このようして得られた黒色鉛筆「ユニ」（硬度
Ｂ）による筆記文字を有する印刷物から「FUJI
XEROX FX−3890」により複写したところ、得
られた複写物では、全面が黒色となり、黒色鉛筆
による筆記文字の判読が不可能であつた。 From the printed matter with written characters written using the black pencil ``UNI'' (hardness B) obtained in this way, ``FUJI''
When a copy was made using "XEROX FX-3890", the entire surface of the resulting copy was black, and the handwritten characters written with a black pencil were impossible to read.
本発明により、汎用されている各種の電子写真
方式の複写機、とりわけセレン、セレン−ひ素、
セレン−アンチモン、セレン−テルル、よう素ド
ープされたセレン−ひ素−アンチモンなどのセレ
ン系感光体やフタロシアニン系感光体を用いた複
写機による複写を実用上ほぼ完全に防止でき、そ
れを印刷した上に鉛筆、油性筆記インキのみなら
ず水性筆記インキでも十分筆記しうる複写防止用
水性印刷インキ組成物が得られるようになつた。
According to the present invention, various widely used electrophotographic copying machines, particularly selenium, selenium-arsenic,
Copying by a copying machine using a selenium-based photoreceptor or a phthalocyanine-based photoreceptor such as selenium-antimony, selenium-tellurium, or iodine-doped selenium-arsenic-antimony can be practically completely prevented, and printing It has now become possible to obtain a water-based printing ink composition for preventing copying that can be sufficiently written on with not only pencils and oil-based writing inks but also water-based writing inks.
本発明の複写防止用水性印刷インキ組成物は、
小切手用紙、為替用紙、証券用紙、印鑑証明用
紙、機密メモ用紙など書込みがなされる複写防止
用紙の印刷に有用である。 The aqueous printing ink composition for preventing copying of the present invention includes:
It is useful for printing copy-protected paper on which writing is written, such as check paper, money order paper, securities paper, seal certificate paper, confidential memo paper, etc.
Claims (1)
顔料、水性結着剤、およびシリカ、炭酸マグネシ
ウム、炭酸カルシウム、硫酸バリウムおよびクレ
ーから選ばれる無機充填剤を含んでなる印刷イン
キであり、該インキを基材に印刷した上に筆記イ
ンキで筆記しうることを特徴とする複写防止用水
性印刷インキ組成物。1 A printing ink comprising a pigment having a maximum absorption wavelength in the range of 500 to 700 nm, an aqueous binder, and an inorganic filler selected from silica, magnesium carbonate, calcium carbonate, barium sulfate, and clay. A water-based printing ink composition for preventing copying, which can be printed on a substrate and written on with writing ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018212A JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61018212A JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62177076A JPS62177076A (en) | 1987-08-03 |
| JPH0569146B2 true JPH0569146B2 (en) | 1993-09-30 |
Family
ID=11965339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61018212A Granted JPS62177076A (en) | 1986-01-31 | 1986-01-31 | Aqueous printing ink composition for preventing copying |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62177076A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2413558A (en) * | 2002-10-12 | 2005-11-02 | Avecia Inkjet Ltd | Use of casein for improving ozone fastness of a colorant |
| GB0223824D0 (en) * | 2002-10-12 | 2002-11-20 | Avecia Ltd | Process for improving ozone fastness |
| CN108003703A (en) * | 2017-12-22 | 2018-05-08 | 许宏元 | A kind of binder for water-based ink and corresponding water-based ink |
-
1986
- 1986-01-31 JP JP61018212A patent/JPS62177076A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62177076A (en) | 1987-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5510199A (en) | Photocopy resistant document and method of making same | |
| US5290068A (en) | Document security method and system | |
| US5427415A (en) | Heat sensitive system and use thereof | |
| US5523167A (en) | Indelible magnetic transfer film | |
| GB2159097A (en) | Tamper resistant documents | |
| US4614367A (en) | Tamper-resisting multipart negotiable instruments | |
| WO2005037905A1 (en) | Invisible ink | |
| JPH0569146B2 (en) | ||
| JP6836754B2 (en) | Scratch ink and scratch printed matter | |
| JPS6155549B2 (en) | ||
| JP2001019887A (en) | Ink for forgery prevention and thermal ribbon | |
| JP3131358U (en) | Pressure sensitive correction tape | |
| JPS6135985A (en) | Preparation of printed matter | |
| GB2060491A (en) | Security Document | |
| JPS5931187A (en) | Composite pressure sensitive copy sheet | |
| DE3810015A1 (en) | Application of a sheet-like information medium and its design | |
| JPS63254482A (en) | Copying preventive coating agent and copying preventive sheet | |
| JP2803557B2 (en) | Report | |
| JP2740765B2 (en) | Wet paper print, manufacturing method thereof and wet paper printing apparatus | |
| CA2149947C (en) | Heat sensitive system and use thereof | |
| JPS6311160B2 (en) | ||
| JP2925557B2 (en) | Recording film | |
| JP2002144695A (en) | Forgery preventive printed matter | |
| JP2021059024A (en) | Printing medium | |
| JP2001341406A (en) | Printing method using water absorptive plate material and copy preventive printed product formed by using water absorptive plate material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |