JPS619579A - Corrosion protecting method of steel structure - Google Patents

Corrosion protecting method of steel structure

Info

Publication number
JPS619579A
JPS619579A JP13040084A JP13040084A JPS619579A JP S619579 A JPS619579 A JP S619579A JP 13040084 A JP13040084 A JP 13040084A JP 13040084 A JP13040084 A JP 13040084A JP S619579 A JPS619579 A JP S619579A
Authority
JP
Japan
Prior art keywords
rust
paint
steel structure
phosphates
pressure water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP13040084A
Other languages
Japanese (ja)
Other versions
JPS633024B2 (en
Inventor
Kazumi Daitoku
一美 大徳
Hiroyasu Murakami
村上 弘保
Toshiaki Hodate
甫立 敏昭
Mikitomo Ikeda
幹友 池田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DAIKI KOGYO KK
Nippon Steel Corp
Original Assignee
DAIKI KOGYO KK
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DAIKI KOGYO KK, Nippon Steel Corp filed Critical DAIKI KOGYO KK
Priority to JP13040084A priority Critical patent/JPS619579A/en
Publication of JPS619579A publication Critical patent/JPS619579A/en
Publication of JPS633024B2 publication Critical patent/JPS633024B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/76Applying the liquid by spraying

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Working Measures On Existing Buildindgs (AREA)
  • Laminated Bodies (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

PURPOSE:To remove completely old coated films and rust and simultaneously to carry out undercoating with phosphates, etc. by jetting high-pressure water added with a conversion coating treating agent such as phosphates when a steel structure is repainted. CONSTITUTION:The painting on the surface of an outdoor steel structure deteriorates with age, and the stripping off of coated films and rusting are caused. In this case, high-pressure water contg. 4-6% phosphates or 0.1-4.0% amine rust preventive or <=1.0% nitrite rust preventive is jetted. By said jetting, old paints and rust on the extremely minute rugged parts are completely striped off and removed, and the undercoating of the steel surface or the formation of phosphate films for improving corrosion resistance is simultaneously carried out. A corrosion protecting paint is successively coated only once, and the steel structure is easily coated again with a corrosion protecting paint.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、例えば製鉄工場の原料ヤードなどに設けられ
た粉粒体搬送用のベルトコンベア設備など宏大な開放空
間に存する屋外鉄鋼構造物等の防食工法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention is applicable to outdoor steel structures, etc. that exist in vast open spaces, such as belt conveyor equipment for transporting powder and granules installed in raw material yards of steel factories, etc. Regarding anti-corrosion construction methods.

(従来技術〕 一般に、屋外構造物は、据付は以後長年にわたり風雨に
曝されたり、あるいは工場立地の観点から海に臨ませて
設けられる場合が多く必然的に塩害を被るなどの弱点を
抱えており、従って、該鉄鋼構造物における新装時塗装
の経年劣化は避けられず、そのままでは発錆、設備老朽
化が避けられない状況にあった。
(Prior art) In general, outdoor structures have weaknesses such as being exposed to wind and rain for many years after installation, or being built facing the sea due to factory location, and inevitably suffering from salt damage. Therefore, deterioration over time of the paint applied to the new steel structure cannot be avoided, and if left as it is, rusting and deterioration of the equipment are unavoidable.

従うて鉄鋼構造物の保全、寿命延長等のために適宜時期
に再塗装を行なうのが一般的である口ところで従来の再
塗装法では、その下地処理手段とシテハンマー、ワイヤ
ーブラシ、あるいは動カニ具を用いて作業者による個別
処理を行なっていた為きわめて長期間を要し、シ必も上
記方法では、構造物の被塗装面即ち素地凹部の除錆が充
分に行なえず、この結果素地凸部と凹部の錆の残置状態
にバラツキを生じ、このような素地上に被覆防食を行な
ったとしても発錆欠陥を抑止し得なかった。
Therefore, it is common practice to repaint steel structures from time to time in order to preserve them and extend their service life.However, in the conventional repainting method, it is necessary to use a ground preparation method and a shite hammer, wire brush, or moving crab. Since the treatment was carried out individually by workers using tools, it took a very long time, and the above method was not able to sufficiently remove rust from the surface to be painted of the structure, that is, the concave parts of the substrate, resulting in convexities on the substrate. There were variations in the state of remaining rust between the parts and the recesses, and even if such a substrate was coated with corrosion protection, rust defects could not be suppressed.

一方いわゆる下地処理を完全に行なおうとすればサンド
ブラスト、酸洗等の手段があるが砂、劇薬類を用いるこ
とから取扱いにあたり高度の安全防護対策を必要とする
はホ高額の出費が避けられず甚だ実用的な方法とは云い
難いものである。
On the other hand, if you want to complete the so-called surface treatment, there are methods such as sandblasting and pickling, but since sand and powerful chemicals are used, high safety measures are required when handling them, and high costs are unavoidable. This is hardly a practical method.

(発明の目的) 本発明は鉄鋼構造物の再塗装にあたシ、被塗装面の下地
処理をムラなく行なうと共にこの下地処理の際、同時に
、被塗装面に化成被膜を形成させ発錆の抑止とともに、
防食塗料の付着性を良好ならしめ、且つ、さび止顔料を
加えた防食塗料を1回塗りすることで一連の再塗装処理
を簡便、かつ、きわめて効果的に行なうことが出来る鉄
鋼構造物の防食工法を提供するにちる。
(Purpose of the Invention) The present invention is used for repainting steel structures, and performs surface treatment evenly on the surface to be painted, and at the same time forms a chemical conversion film on the surface to be painted, thereby preventing rust. Along with deterrence,
Corrosion protection for steel structures that improves the adhesion of anticorrosive paint and allows a series of repainting treatments to be performed easily and extremely effectively by applying a single coat of anticorrosive paint containing anticorrosion pigments. Nichiru provides construction methods.

(発明の構成・作用) 本発明者等は、本発明の完成に先立ち種々検討を重ねた
結果以下の知見を得た。
(Structure and operation of the invention) The present inventors have obtained the following knowledge as a result of various studies conducted prior to completing the present invention.

先ず、■下地処理として被塗装面即ち素地に除錆不良部
分のない除錆手段を採用すること。■素地面の発錆全抑
止するために除錆後化成被膜を形成すること。■従来の
防食塗料の多数目塗シを改善し、さび止顔料を加えた防
食塗料fi−1’回塗シすることで、鉄鋼構造物の延命
保全を可能とするとともに、塗装工程の簡略化、作業性
の向上、塗料の節減等をはかることにあシ、その特徴と
するところは、燐酸塩若しくは同効薬剤添加高圧水を構
造物部材に噴射させて前回塗装被膜の剥離除去を行なう
と同時に、該被塗装面に化成被膜を形成させ、次いで、
さび止顔料を加えて成る防食塗料を1回塗シする鉄鋼構
造物の防食工法にある。
First of all, ① adopt a rust removal method that does not leave any rust-removal defects on the surface to be painted, that is, the substrate. ■Formation of a chemical conversion film after rust removal to completely prevent rust on the base surface. ■By improving the multiple coatings of conventional anti-corrosion paints and applying the anti-corrosion paint fi-1' with anti-rust pigments, it is possible to prolong the life of steel structures and simplify the painting process. The purpose of this method is to improve workability and save on paint, and its feature is that high-pressure water containing phosphate or the same effective agent is sprayed onto structural members to remove the previously painted film. At the same time, a chemical conversion film is formed on the surface to be painted, and then,
A method for preventing corrosion of steel structures by applying one coat of anti-corrosion paint containing anti-rust pigments.

さて、本発明者等は、鉄鋼構造物の前回塗装被膜剥離、
及び被塗装面、即ち、素地の極微凹凸部に対しても完全
に除錆を行なえる手段として高圧水のジェット噴射を採
用し、且つ、この高圧水に燐酸塩等の化成被膜処理剤を
添加することで、前回塗布した塗料被膜の剥離と素地面
の除錆を行なうと同時に、被塗装面即ち素地面への燐酸
被膜形成を可能とし効果的な下地処理を一挙に実現した
のである。高圧水に添加する化成被膜処理剤としては、
燐酸塩として例えばトリオナ505..(ミ・リオン化
学株式会社)、MP−7(ダイラ工業株式会社)等を用
いるかあjるいはくアミン系防錆剤、亜硝酸塩系防錆剤
等が好ましい。
Now, the present inventors have discovered that the previous paint film peeling of steel structures,
A jet spray of high-pressure water is used as a means to completely remove rust from the surface to be painted, that is, even the minute irregularities of the substrate, and a chemical conversion coating treatment agent such as phosphate is added to this high-pressure water. By doing so, it was possible to peel off the previously applied paint film and remove rust from the base surface, while at the same time forming a phosphoric acid film on the surface to be painted, that is, the base surface, achieving effective base treatment all at once. As a chemical conversion coating treatment agent added to high-pressure water,
As a phosphate, for example, Triona 505. .. (Million Chemical Co., Ltd.), MP-7 (Daira Kogyo Co., Ltd.) and the like are preferably used as amine-based rust preventive agents, nitrite-based rust preventive agents, and the like.

また従来用いられていた塗料としては、下塗塗料、中塗
塗料、上塗塗料等があシ、下塗塗料はさび止顔料を用い
ビヒクルには、素地との密着性が良好なものを選定して
いること、中塗塗料は、さび止顔料を使用しても下塗塗
料よシも少ないか、あるいは全く使用せず、ビヒクルは
下塗りにも中塗りにも密着性が良く膜厚の大きいものが
使世されているのが実状である。さらに上塗塗料は、さ
び止顔料は使用せず暴露環境に耐えうるようなビヒクル
と顔料を選定し必要な発色を具備するものを添加してお
り、各塗料それぞれの特性を有し下・中塗りに上塗りを
合せ施工して始めて効果的な防錆が図れるものである。
In addition, conventionally used paints include base coat paint, intermediate coat paint, and top coat paint, etc., but the base coat paint uses rust-preventing pigments, and the vehicle is selected to have good adhesion to the substrate. Even if rust-preventing pigments are used as intermediate coatings, there is little or no scratching compared to the primer coating, and vehicles with good adhesion and a large film thickness have been used for both the primer and intermediate coatings. The reality is that there are. Furthermore, the topcoat paints do not use anti-rust pigments, but instead select vehicles and pigments that can withstand exposure environments, and add those that provide the necessary color development. Effective rust prevention can only be achieved by applying a top coat to the surface.

本発明方法で用いるHD塗料は、これらの性能を一つに
兼ねそなえたものであって、−回塗りで充分な防食美装
効果を発揮するものであり、例えば、上塗塗料として用
いられている油性フタル酸樹脂塗料(タイコ−マリン(
犬日本塗料株式会社)、ORペイント(日本ペイント株
式会社)、SDマリンペイント(関西ペイント株式会社
))などの中に、さび止顔料である例えが亜鉛末、シン
クロメート、シアナミド鉛などを適量に添加して下塗、
上塗効果を同時に持たせている、また、ビヒクルとして
は、例えば塩ゴム系塗料、エポキシ樹脂塗料、ポリウレ
タン樹脂塗料、シリコンアルキッド樹脂塗料などが望ま
しい。
The HD paint used in the method of the present invention has all of these properties, and exhibits sufficient anti-corrosion and aesthetic effects when coated in multiple coats, and is used, for example, as a top coat. Oil-based phthalate resin paint (Tyco Marine)
Inu Nippon Paint Co., Ltd.), OR Paint (Nippon Paint Co., Ltd.), SD Marine Paint (Kansai Paint Co., Ltd.), etc., contain appropriate amounts of rust-preventing pigments such as zinc powder, synchromate, cyanamide lead, etc. Add and undercoat,
Desirable vehicles that simultaneously provide a top coating effect include salt rubber paints, epoxy resin paints, polyurethane resin paints, and silicone alkyd resin paints.

さらにまた、本発明による化成被膜処理剤を用いること
によp1塗装体の表面に空気侵入(酸素源の侵入)等に
よる錆の抑制効果が発現するとともに、上塗シの塗料と
の密着性の極めて良好なものが得られる。このように、
錆の抑制と上塗り塗料の相互の効果を得るには、例えば
リン酸塩の場合は、高圧水中に4〜16%添加し、アミ
ン系防錆剤の場合は、0.1〜4.0係亜硝酸塩系防錆
剤の場合は、1.0φ以下が望ましい。これは、化成被
膜処理剤の含有量が多すぎると高圧の洗滌水の−の変動
、上塗り塗料と該処理剤との作用により錆の抑止効果が
低下するとともに処理剤の高濃度添加は処理コストの上
昇を招く。一方、処理剤の含有量が低くいと塗装体の表
面の防錆被膜の形成効果がなくなシ防錆効果が大巾に低
下する。
Furthermore, by using the chemical conversion coating treatment agent of the present invention, the effect of suppressing rust due to air intrusion (intrusion of oxygen source) etc. on the surface of the P1 coated body is expressed, and the adhesion with the top coat paint is extremely improved. You can get something good. in this way,
To obtain the mutual effect of rust suppression and topcoat, for example, in the case of phosphates, add 4 to 16% in high pressure water, and in the case of amine rust preventives, add 0.1 to 4.0%. In the case of a nitrite-based rust preventive agent, the diameter is preferably 1.0φ or less. This is because if the content of the chemical conversion coating treatment agent is too high, the rust suppression effect will decrease due to fluctuations in the high-pressure cleaning water and the interaction between the top coat and the treatment agent, and the addition of a high concentration of the treatment agent will increase the processing cost. leading to an increase in On the other hand, if the content of the treatment agent is low, the effect of forming a rust preventive film on the surface of the painted body is lost and the rust preventive effect is significantly reduced.

なお、必要があれば、即ちとくに落ち難い強固な錆、汚
れ若しくは付着物が存在する場合には硅砂、鉄粉若しく
はコークス粉等の研磨剤を高圧水中に適宜添加混入する
ことで容易に除去することが出来る。
If necessary, especially if there is strong rust, dirt, or deposits that are difficult to remove, they can be easily removed by adding abrasives such as silica sand, iron powder, or coke powder to the high-pressure water. I can do it.

(実施例及び効果) 次に、本発明による防食施工法の効果を確認するために
適宜大きさの鋼板を化成被膜処理剤を添加した高圧洗滌
水にて除錆して後に、従来の上塗シ塗料にさび止顔料お
よびビヒクルを添加したものを一回塗シした本発明方法
と、単に、水圧除錆のみで従来通カ3回塗シ、あるいは
ディスクサングー処理して後に、1回、もしくは3目塗
シした場合を従来法として比較した。これは、経年劣化
を予想するために、通常用いられる塩水噴霧試験方法を
用いて行なったものであるが、明らかに本発明方法が防
錆効果およびコストの面で優れていることがわかる。
(Example and Effects) Next, in order to confirm the effects of the anti-corrosion construction method according to the present invention, a steel plate of an appropriate size was derusted using high-pressure washing water to which a chemical conversion coating treatment agent was added, and then a conventional top coat was applied. The method of the present invention involves applying one coat of paint with anti-corrosion pigment and vehicle added, and the method of the present invention, which involves applying a single coat of paint with anti-rust pigment and vehicle applied, and the conventional method of applying three coats using only hydraulic rust removal, or one coat after disk sangu treatment, or A comparison was made between the conventional method and the case of applying 3 coats. This was carried out using a commonly used salt spray test method in order to predict aging deterioration, and it is clear that the method of the present invention is superior in terms of rust prevention effect and cost.

さらにこの結果を基にして、製鉄所内の海岸に近接した
コークス工場の全長200mのベルトコンベアーの支柱
に、前記表−1の内水法としてテストAI’に約100
m、残!1100mを従来法としてテス) A 8 =
 & 9 t−防食施工したが、本発明方法による高圧
水の洗滌は、脱スケールが良好でちゃ、塗装仕上9も従
来と何んら変りなく第1図に示す如き好結果が得られた
Furthermore, based on this result, approximately 100% of the test AI' was applied to the support of a belt conveyor with a total length of 200m in a coke factory near the coast within a steelworks using the inland water method in Table 1 above.
m, left! 1100m as conventional method) A 8 =
& 9 T-Anti-corrosion construction was carried out, but the cleaning with high pressure water according to the method of the present invention yielded good results as shown in FIG. 1, with good descaling and the paint finish 9 was no different from that of the conventional method.

【図面の簡単な説明】[Brief explanation of drawings]

第i図H、コークス工場の200m+ベルトコンベアの
塗り分はテスト結果を示す回である。 新部興治(。 □二二二) 第1図 其目 聞 Q手〕
Figure i H shows the test results for the 200m+ belt conveyor coating in the coke factory. Koji Shinbe (. □222) Figure 1 Part 1 Q-hand]

Claims (1)

【特許請求の範囲】[Claims] 燐酸塩、若しくは同効薬剤添加高圧水を構造物部材に噴
射させて前回塗装被膜の剥離除去を行なうと同時に、該
被塗装面に化成被膜を形成させ、次いで、さび止顔料を
加えて成る防食塗料を1回塗りすることを特徴とする鉄
鋼構造物の防食工法。
Corrosion prevention by spraying high-pressure water containing phosphate or the same effective agent onto structural members to peel off and remove the previously painted film, at the same time forming a chemical conversion film on the surface to be painted, and then adding a rust-inhibiting pigment. A corrosion prevention method for steel structures that involves applying one coat of paint.
JP13040084A 1984-06-25 1984-06-25 Corrosion protecting method of steel structure Granted JPS619579A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13040084A JPS619579A (en) 1984-06-25 1984-06-25 Corrosion protecting method of steel structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13040084A JPS619579A (en) 1984-06-25 1984-06-25 Corrosion protecting method of steel structure

Publications (2)

Publication Number Publication Date
JPS619579A true JPS619579A (en) 1986-01-17
JPS633024B2 JPS633024B2 (en) 1988-01-21

Family

ID=15033387

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13040084A Granted JPS619579A (en) 1984-06-25 1984-06-25 Corrosion protecting method of steel structure

Country Status (1)

Country Link
JP (1) JPS619579A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000020658A1 (en) * 1998-10-02 2000-04-13 Abb Flexible Automation Spa Method for pretreating metal sheets to be painted
US6734102B2 (en) 1998-11-17 2004-05-11 Applied Materials Inc. Plasma treatment for copper oxide reduction
US6946401B2 (en) 1998-11-17 2005-09-20 Applied Materials, Inc. Plasma treatment for copper oxide reduction
CN109735885A (en) * 2019-03-12 2019-05-10 珠海市玛斯特锌镍加工有限公司 Anti-corrosive technology before a kind of plating of steel-iron components

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50103436A (en) * 1974-01-16 1975-08-15

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50103436A (en) * 1974-01-16 1975-08-15

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000020658A1 (en) * 1998-10-02 2000-04-13 Abb Flexible Automation Spa Method for pretreating metal sheets to be painted
US6734102B2 (en) 1998-11-17 2004-05-11 Applied Materials Inc. Plasma treatment for copper oxide reduction
US6946401B2 (en) 1998-11-17 2005-09-20 Applied Materials, Inc. Plasma treatment for copper oxide reduction
US8183150B2 (en) 1998-11-17 2012-05-22 Applied Materials, Inc. Semiconductor device having silicon carbide and conductive pathway interface
CN109735885A (en) * 2019-03-12 2019-05-10 珠海市玛斯特锌镍加工有限公司 Anti-corrosive technology before a kind of plating of steel-iron components

Also Published As

Publication number Publication date
JPS633024B2 (en) 1988-01-21

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