JPS6177683A - Manufacture of lightweight foamed body - Google Patents

Manufacture of lightweight foamed body

Info

Publication number
JPS6177683A
JPS6177683A JP19922684A JP19922684A JPS6177683A JP S6177683 A JPS6177683 A JP S6177683A JP 19922684 A JP19922684 A JP 19922684A JP 19922684 A JP19922684 A JP 19922684A JP S6177683 A JPS6177683 A JP S6177683A
Authority
JP
Japan
Prior art keywords
clay
foam
lightweight
plastic foam
shape
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19922684A
Other languages
Japanese (ja)
Inventor
隆一 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Technical Research Inc
Original Assignee
IG Technical Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Technical Research Inc filed Critical IG Technical Research Inc
Priority to JP19922684A priority Critical patent/JPS6177683A/en
Publication of JPS6177683A publication Critical patent/JPS6177683A/en
Pending legal-status Critical Current

Links

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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はフィルタ、土壌改良材、骨材として有用な軽量
発泡体の製造方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for producing lightweight foams useful as filters, soil conditioners, and aggregates.

特に、耐火性があり、任意形状に成形が可能で、しかも
再生が容易な軽量発泡体の製造方法に係る。
In particular, the present invention relates to a method for producing a lightweight foam that is fire resistant, can be molded into any shape, and is easily recyclable.

(従来の技術) 多孔質の軽量発泡体を製造する方法には、■無機物質に
おがくず、コークスのような可燃性物質を混合し、これ
を燃焼させて空隙を形成する方法、■膨張蛭石、パーラ
イト粒のような軽量粒を無機材でバインダする方法、■
粘土、その他の耐火組成物粉末の泥漿中に化学的に泡を
発生させ、これを焼成する方法、■予め起泡剤を無機組
成物に添加する方法、■無機組成物にナフタリンのよう
な昇華性固体粒を配合し、加熱によりこれを発揮させて
多孔質の軽量発泡体とする方法などが知られている。
(Prior art) Methods for producing porous lightweight foam include: - Mixing flammable substances such as sawdust and coke with inorganic substances and burning them to form voids; - Expanded vermiculite. , A method of binding lightweight grains such as pearlite grains with inorganic materials,■
A method in which bubbles are chemically generated in a slurry of clay or other refractory composition powder and then fired; ■ A method in which a foaming agent is added to an inorganic composition in advance; ■ A method in which a foaming agent such as naphthalene is sublimated to an inorganic composition. A method is known in which a porous, lightweight foam is produced by blending solid particles with a porous material and heating them to exhibit their properties.

(発明が解決しようとする問題点) 前記した多孔質の軽量発泡体の製造方法において、■で
は可燃物を無機組成物の中に均一に混合することができ
ず、所定の多孔質、形状の板体等を製造しにくいし、形
くずれが多い。■では連通気孔とならないし、適当なバ
インダーがない。■では焼成すると亀裂が入り、破壊す
ることが多い。
(Problems to be Solved by the Invention) In the above-mentioned method for producing a porous lightweight foam, the combustible material cannot be uniformly mixed into the inorganic composition in (2), It is difficult to manufacture plates, etc., and they often lose their shape. With ■, there are no continuous holes and there is no suitable binder. In the case of ■, cracks appear when fired and often result in destruction.

■、■では形状に制限がある。などの欠点があった。そ
して、この種方法では形状を型材によって成形するため
、製造が大がかりとなり、かつ、保形性の関係から長時
間を要する不利があった。(問題点を解決するための手
段) 本発明は泥奨状の粘土を保形性のあるプラスチック製連
通気泡発泡体の気泡内に任意量を含浸させて保形性をよ
り強化し、その形状下でプラスチ・7り成分を焼却して
粘度のみからなる連通気泡組織の軽量発泡体を製造する
ことである。
■ and ■ have restrictions on the shape. There were drawbacks such as. In this type of method, since the shape is formed using a mold material, the manufacturing process is large-scale, and there are disadvantages in that it requires a long time due to shape retention. (Means for Solving the Problems) The present invention impregnates an arbitrary amount of clay in the shape of a clay into the cells of a plastic open-cell foam that has shape-retaining properties to further strengthen its shape-retaining properties. The purpose is to incinerate the plasti components at the bottom to produce a lightweight foam with an open cell structure consisting only of viscosity.

(作 用) 本発明ではプラスチック製連通気泡発泡体の気泡の大き
さ、密度が発泡体形成時に任意に選択できると共に、形
状も最終製品形状を形成することができ、しかも粘土の
含浸割合、硬さ、粒度、泥奨状態によって軽量発泡体の
高密度をも選択できるものである。
(Function) In the present invention, the size and density of the cells in the plastic open-cell foam can be arbitrarily selected at the time of forming the foam, and the shape can be formed into the final product shape. The density of the lightweight foam can be selected depending on the size, grain size, and soil conditions.

(実施例) 以下に、図面を用いて本発明に係る軽量発泡体に係る製
造方法について詳細に説明する。すなわち、本発明は連
通気泡発泡組織のプラスチックフオーム内に泥奨状の粘
土を含浸し、粘土を予備乾燥すると共に、プラスチック
フオームを焼却し・次に粘土を焼成して軽量発泡体を製
造する方法である。さらに説明すると、本発明で使用す
るプラスチックフオームlは例えば第1図(al〜te
lに示すような形状に成形したものであり、主に形状形
成材、保形材、含浸用材として機能するものである。
(Example) Below, the manufacturing method of the lightweight foam according to the present invention will be described in detail using the drawings. That is, the present invention provides a method for producing a lightweight foam by impregnating clay in the form of clay into a plastic foam having an open-cell foam structure, pre-drying the clay, incinerating the plastic foam, and then firing the clay. It is. To explain further, the plastic foam l used in the present invention is illustrated in FIG.
It is molded into the shape shown in 1, and mainly functions as a shape forming material, shape retaining material, and impregnating material.

また、プラスチックフオーム1は第2図に示すように粘
土3を気泡2の中に含浸できるものであり、連通気泡組
織に形成したものである。その気泡2の大きさ、膜厚、
気泡の分布度合はプラスチックフオームエ形成時に任意
に設定することができるものである。換言すれば、軽量
発泡体の物性、形状はプラスチックフオームlによって
殆んどが決定されるものである。また、本発明で使用す
る粘土は陶器、磁器を製造できる素材であればよく、例
えば木節粘土、蛙目粘土、陶石、蝋石、信楽木粘土等、
および各地で産出される粘土の1種、もしくは2種以上
を混合したものからなるものである。なお、粘土の粒子
径は0.01m以下であり、プラスチックフオーム1に
含浸するには泥奨状態にする。そこで、製造工程を説明
すると、まず第1図(a)に示すような軟質ポリウレタ
ンフォームからなるプラスチックフオーム1 (厚さ5
mm)、長さ10cm X fociの板体で気泡の直
径1龍の連通気泡組織からなるものに泥奨を含浸させる
。この場合、プラスチックフオーム1は可撓性、クッシ
ョン性があるもので、プラスチックフオーム1を泥奨の
中で揉むことによって含浸するものである。勿論、揉む
回数によって粘土3の含浸量が異なり、焼成後の嵩比重
も含浸量に対応した数値となる。なお、プラスチックフ
オーム1の気泡2に泥奨を含浸した状態ではプラスチッ
クフオーム■が復帰しうる程度の含浸量である。次に、
この泥奨を含浸したプラスチックフオームlを電子レン
ジで5〜10分間強制的に加熱して粘土3を含むプラス
チックフオーム1を乾燥する。なお、この場合の急激な
加熱でもポーラスな粘土板体は亀裂、破壊が見られなか
った。次に、粘土板体を200〜350℃に加熱してプ
ラスチックフオームlを焼却し、その後1000〜12
00℃の温度で30分間焼成し、これを徐冷して軽量発
泡体とするものである。このように形成した軽量発泡体
はプラスチックフオーム1と同じ形状で、連通気泡の無
機質多孔体となっており、しかも硬く亀裂、破損のない
硬化体となるものである。
Furthermore, the plastic foam 1 is capable of impregnating clay 3 into the cells 2, and is formed into an open cell structure, as shown in FIG. The size of the bubble 2, the film thickness,
The degree of distribution of air bubbles can be arbitrarily set at the time of forming the plastic foam. In other words, the physical properties and shape of the lightweight foam are mostly determined by the plastic foam l. The clay used in the present invention may be any material that can be used to make pottery or porcelain, such as Kibushi clay, Frogme clay, pottery stone, Rouseki, Shigaraki clay, etc.
It is made of one type of clay produced in various places, or a mixture of two or more types. The particle size of the clay is 0.01 m or less, and the clay is in a muddy state to be impregnated into the plastic foam 1. Therefore, to explain the manufacturing process, first, as shown in Fig. 1(a), plastic foam 1 (thickness 5
A plate with a length of 10 cm x foci and an open cell structure with a bubble diameter of 1 mm was impregnated with mud. In this case, the plastic foam 1 has flexibility and cushioning properties, and is impregnated by rubbing the plastic foam 1 in mud. Of course, the amount of clay 3 impregnated varies depending on the number of times of rolling, and the bulk specific gravity after firing also corresponds to the amount of impregnation. Note that when the bubbles 2 of the plastic foam 1 are impregnated with mud, the amount of impregnation is such that the plastic foam (2) can recover. next,
The plastic foam 1 impregnated with this clay is forcibly heated in a microwave oven for 5 to 10 minutes to dry the plastic foam 1 containing the clay 3. In this case, even with rapid heating, no cracks or destruction were observed in the porous clay plate. Next, the clay plate is heated to 200-350°C to incinerate the plastic foam, and then heated to 1000-120°C.
It is baked at a temperature of 00°C for 30 minutes, and then slowly cooled to form a lightweight foam. The lightweight foam thus formed has the same shape as the plastic foam 1, is an inorganic porous body with open cells, and is hard and cured without cracks or damage.

以上説明したのは本発明に係る軽量発泡体の製造方法の
一実施例にすぎず、粘土3に珪酸質、アルミナ質、有機
高分子(CMC、MC)等を泥奨時に添加して、粘土の
粘性を強化し、保形性、成形性を改善したり、より多孔
体の軽量体とすることもできる。その他、軽量発泡体を
撲水剤で処理して吸油性のフィルタとすることもできる
What has been described above is only one example of the method for producing a lightweight foam according to the present invention, and the clay is made by adding silicic acid, alumina, organic polymers (CMC, MC), etc. It is also possible to strengthen the viscosity of the material, improve shape retention and moldability, and make it more porous and lightweight. Alternatively, the lightweight foam can be treated with a dehydrating agent to make an oil-absorbing filter.

(発明の効果) このような工程で軽量発泡体を製造すると、成形、加工
容易なプラスチックフオームで外形を形成できるため、
筒体、球体、ハニカム、ネット状物、角柱、柱体等のよ
うに任意形状の軽量発泡体を製造できる特徴がある。ま
た、粘土の含浸は連通気泡の組織内に泥奨状体で行なう
ため、極めて容易である特徴がある。さらに、粘土を含
浸したプラスチックフオームを乾燥する際に電子レンジ
で強制的に行なってもプラスチックフオーム自体で連通
気泡のため粘土自体に亀裂、破壊もなく短時間で乾燥で
きる特徴がある。また、粘土の含浸量はプラスチックフ
オームの気泡の大きさ、密度と含浸工程によって任意に
選択できるため、任意の嵩密度、硬度の軽量発泡体を容
易に製造できる特徴がある。
(Effect of the invention) When a lightweight foam is manufactured through such a process, the outer shape can be formed using a plastic foam that is easy to mold and process.
It is characterized by the ability to produce lightweight foams of arbitrary shapes such as cylinders, spheres, honeycombs, net-like objects, prisms, columns, etc. In addition, since the clay is impregnated into the open cell structure in the form of a slurry, it is extremely easy to impregnate the clay. Furthermore, even if the clay-impregnated plastic foam is forcibly dried in a microwave oven, the clay itself can be dried in a short time without cracking or breaking because the plastic foam itself has open air bubbles. In addition, since the amount of clay impregnated can be arbitrarily selected depending on the size and density of the cells in the plastic foam and the impregnation process, it is possible to easily produce lightweight foams with arbitrary bulk density and hardness.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a)〜(e)は本発明で使用するプラスチ・ツ
クフオームの形状の一例を示す説明図、第2図はプラス
チックフオームに粘土を含浸した状態の一部を拡大して
示す説明図、第3図は本発明に係る軽量発泡体の製造方
法を示す工程図である。 1・・・プラスチックフオーム、2・・・気泡、3・・
・粘土。
Figures 1 (a) to (e) are explanatory diagrams showing an example of the shape of the plastic foam used in the present invention, and Figure 2 is an explanatory diagram showing an enlarged part of the plastic foam impregnated with clay. , FIG. 3 is a process diagram showing a method for manufacturing a lightweight foam according to the present invention. 1...Plastic foam, 2...Bubble, 3...
·clay.

Claims (1)

【特許請求の範囲】[Claims] (1)連通気泡発泡組織のプラスチックフォームに粘土
の泥奨を含浸させ、次に高周波加熱によりこのフォーム
の粘土分を乾燥し、その後で上記フォームを200〜4
00℃に加熱してプラスチックフォーム成分を焼却した
後に粘土分を800〜1200℃で焼成することを特徴
とする軽量発泡体の製造方法。
(1) A plastic foam with an open-cell foam structure is impregnated with clay slurry, and then the clay content of this foam is dried by high-frequency heating.
1. A method for producing a lightweight foam, which comprises heating the plastic foam component to 00°C to incinerate the plastic foam component, and then firing the clay component at 800 to 1200°C.
JP19922684A 1984-09-22 1984-09-22 Manufacture of lightweight foamed body Pending JPS6177683A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19922684A JPS6177683A (en) 1984-09-22 1984-09-22 Manufacture of lightweight foamed body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19922684A JPS6177683A (en) 1984-09-22 1984-09-22 Manufacture of lightweight foamed body

Publications (1)

Publication Number Publication Date
JPS6177683A true JPS6177683A (en) 1986-04-21

Family

ID=16404241

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19922684A Pending JPS6177683A (en) 1984-09-22 1984-09-22 Manufacture of lightweight foamed body

Country Status (1)

Country Link
JP (1) JPS6177683A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04175276A (en) * 1990-11-08 1992-06-23 Kamiyama:Kk Porous ceramic plate
JPH04175275A (en) * 1990-11-08 1992-06-23 Kamiyama:Kk Production of porous ceramic plate

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58176161A (en) * 1982-04-09 1983-10-15 初鹿野 清 Refractory heat-resistant brick

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58176161A (en) * 1982-04-09 1983-10-15 初鹿野 清 Refractory heat-resistant brick

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04175276A (en) * 1990-11-08 1992-06-23 Kamiyama:Kk Porous ceramic plate
JPH04175275A (en) * 1990-11-08 1992-06-23 Kamiyama:Kk Production of porous ceramic plate

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