JPS6168206A - Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like - Google Patents

Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like

Info

Publication number
JPS6168206A
JPS6168206A JP59191379A JP19137984A JPS6168206A JP S6168206 A JPS6168206 A JP S6168206A JP 59191379 A JP59191379 A JP 59191379A JP 19137984 A JP19137984 A JP 19137984A JP S6168206 A JPS6168206 A JP S6168206A
Authority
JP
Japan
Prior art keywords
prepreg
whisker
impregnated
synthetic resin
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59191379A
Other languages
Japanese (ja)
Inventor
Sho Aoyama
青山 捷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Globeride Inc
Original Assignee
Daiwa Seiko Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiwa Seiko Co Ltd filed Critical Daiwa Seiko Co Ltd
Priority to JP59191379A priority Critical patent/JPS6168206A/en
Publication of JPS6168206A publication Critical patent/JPS6168206A/en
Pending legal-status Critical Current

Links

Landscapes

  • Fishing Rods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

PURPOSE:To prevent a whisker layer from breaking and twisting in a manufacturing process by a method wherein the whisker layer is laid on a thin fabric before it is impregnated with thermoplastic synthetic resin. CONSTITUTION:When prepregs of high strength fiber are manufactured and these prepregs are polymerized to manufacture a tubular substance such as a fishing rod, etc., long whisker fibers of 3-8m/m are scattered uniformly in the solution of low viscosity, the whisker layer is made on the thin fabric and impregnated with thermosetting synthetic resin to obtain a prepreg sheet. A fabric of glass fibers, etc. is about 0.02m/m in thickness and epoxy resin liquid or phenol resin liquid with 20-40wt% is used as thermosetting synthetic resin to be impregnated. A prepreg sheet composed of a prepreg and a sheet impregnated with resin is wound around a core bar to obtain a tubular product.

Description

【発明の詳細な説明】 発明の目的 本発明は釣竿等の管状体を製造するためのプリプレグに
併用するウィスカー長繊維を使用したプリプレグを製造
することを目的とする。
DETAILED DESCRIPTION OF THE INVENTION Object of the Invention The object of the present invention is to manufacture a prepreg using whisker long fibers, which is used in conjunction with a prepreg for manufacturing tubular bodies such as fishing rods.

従来の技術 高強度、高弾性のウィスカーをプリプレグに補強材とし
て混合し釣竿等の管状体の強度、弾性を向上する。:と
が、特9fJna58−211442号公報で知られて
いる。
Conventional Technology High strength and high elasticity whiskers are mixed into prepreg as a reinforcing material to improve the strength and elasticity of tubular bodies such as fishing rods. : is known from Japanese Patent No. 9fJna58-211442.

しかしながら従来の方法は、ウィスカーが50〜200
μの短Jamであるためこれをプリプレグを形成する熱
硬化性合成樹脂中に直接混合しても比較的均等にプリプ
レグに分散混入させることができるが、ウィスカーが3
〜8m/mもの長繊維となると粘度の高い熱硬化性合成
樹脂中に均等に分散混合することが極めて困難であると
共に混合攪拌によってウィスカーの折損も生じウィスカ
ー自体の高強度、高弾性の特性を充分に管状体に発揮さ
せることができない欠陥がある。
However, in the conventional method, the number of whiskers is 50 to 200.
Since it has a short Jam of μ, even if it is directly mixed into the thermosetting synthetic resin that forms the prepreg, it can be dispersed relatively evenly into the prepreg, but the whisker
When the fibers are as long as ~8m/m, it is extremely difficult to evenly disperse and mix them in a thermosetting synthetic resin with high viscosity, and the whiskers also break during mixing and agitation, resulting in the high strength and high elasticity characteristics of the whiskers themselves. There is a defect in the tubular body that cannot be fully utilized.

発明の構成 そこでこれらの欠陥を改善するために高強度繊維のプリ
プレグとは別個にウィスカー長繊維のプリプレグを製造
し、これらのプリプレグを重合して釣竿等の管状体を製
造することを開発し、本発明はこの場合において品質の
良い前記ウィスカー長繊維のプリプレグを製造するよう
にしたもので、3〜8yXlのウィスカー長繊維を粘度
の低い溶液に帖均−に分散させて薄い織布上に漉き取っ
て薄い織布上にウィスカー層を形成した後、これに熱硬
化性合成樹脂を含浸せしめてプリプレグシー1−をkl
 34することを要旨とするものである。
Structure of the Invention In order to improve these defects, we developed a method of manufacturing whisker long fiber prepregs separately from high-strength fiber prepregs and polymerizing these prepregs to manufacture tubular bodies such as fishing rods. In this case, the present invention is designed to produce a prepreg of high quality whisker long fibers, by uniformly dispersing whisker long fibers of 3 to 8 y After forming a whisker layer on a thin woven fabric, this is impregnated with a thermosetting synthetic resin to form prepreg sheet 1-.
The main purpose of this document is to do 34 things.

本発明の詳細な説明すると、水、メタノール、トルエン
、アセトン等の有機溶剤、又はこれら有機溶剤で熱硬化
性合成樹脂を稀釈した粘性の低い液体を収容した槽内に
、炭化珪素、窒化珪素等の3〜8m/mのウィスカー長
繊維を混合攪拌して均等に分散させた後、該槽内に厚さ
0.02yXn程度の薄いガラス繊維等の織布(スクリ
ムシート)を展張しながら入れてウィスカー長繊維を漉
き取り、その−側にウィスカー長繊維の0.02〜0.
03%の薄い層を形成する。
To explain the present invention in detail, silicon carbide, silicon nitride, etc. After mixing and stirring the whisker long fibers of 3 to 8 m/m to uniformly disperse them, a thin woven cloth (scrim sheet) such as glass fiber with a thickness of about 0.02yXn is placed in the tank while being stretched. Strain out the long whisker fibers, and add 0.02 to 0.0% of the long whisker fibers to the minus side.
Form a thin layer of 0.03%.

次いでこれにエポキシ樹脂、フェノール樹脂等の熱硬化
性合成樹脂を20〜40重量%含浸せしめてウィスカー
長繊維のプリプレグを製造する。
Next, this is impregnated with 20 to 40% by weight of a thermosetting synthetic resin such as an epoxy resin or a phenol resin to produce a prepreg of whisker long fibers.

前記ウィスカー長繊維の長さは5%程度が好ましく、ま
た分散溶液には含浸合成樹脂を溶剤で5〜6%溶かした
ものを使用するとウィスカーが織布上に仮固定されるの
で好適である。
The length of the long whisker fibers is preferably about 5%, and it is preferable to use a dispersion solution in which 5 to 6% of the impregnating synthetic resin is dissolved in a solvent because the whiskers are temporarily fixed on the woven fabric.

しかしてこのウィスカー長繊維のプリプレグを使用して
釣竿等の管状体を製造するには、このプリプレグと、ガ
ラス繊維、炭素繊維の織布、又は引揃シートに熱硬化性
合成樹脂を含浸して形成したプリプレグシートとを重合
して芯金に捲着した後、常法の如くテープによる緊縛、
熱硬化処理、芯金抜去、テープ剥離、研磨等を行って管
状体を製造するものである。
However, in order to manufacture tubular bodies such as fishing rods using whisker long fiber prepreg, this prepreg and glass fiber, carbon fiber woven fabric, or pulling sheet are impregnated with a thermosetting synthetic resin. After polymerizing the formed prepreg sheet and wrapping it around the core metal, it is bound with tape as usual.
A tubular body is manufactured by performing heat curing treatment, core bar removal, tape peeling, polishing, etc.

発明の効果 本発明はウィスカー長繊維が薄い織布上で絡み合って均
一な薄い層状に漉き取られ、熱硬化性合成樹脂で薄い織
布に一体的に結合されるので、ウィスカー自体の高強度
、高弾性の特性によりプリプレグ全面が均等に補強され
、高強度繊維のプリプレグシートとの併用によって製造
される管状体の強度及び弾性を向上することができる。
Effects of the Invention In the present invention, long whisker fibers are intertwined on a thin woven fabric, skived to form a uniform thin layer, and integrally bonded to the thin woven fabric with a thermosetting synthetic resin. Due to its high elasticity, the entire surface of the prepreg is uniformly reinforced, and the strength and elasticity of the tubular body produced can be improved by using it in combination with a prepreg sheet made of high-strength fibers.

また本発明のウィスカー長繊維は薄い織布で裏打されて
いるので、樹脂含浸工程、裁断工程、高強度繊維のプリ
プレグシートとの重合及び捲回工程等においてもウィス
カー層が破れたり撚られたりすることもなく、安定した
ウィスカー長繊維のプリプレグを製造することができる
Furthermore, since the whisker long fibers of the present invention are lined with a thin woven fabric, the whisker layer will not be torn or twisted during the resin impregnation process, cutting process, polymerization with high-strength fiber prepreg sheet, winding process, etc. A stable prepreg of whisker long fibers can be produced without any problems.

Claims (1)

【特許請求の範囲】[Claims] 3〜8m/mのウィスカー長繊維を粘度の低い溶液に略
均一に分散させて薄い織布上に漉き取って薄い織布上に
ウィスカー層を形成した後、これに熱硬化性合成樹脂を
含浸せしめてプリプレグシートを製造することを特徴と
する釣竿等の管状体製造用プリプレグの製造法。
After whisker long fibers of 3 to 8 m/m are almost uniformly dispersed in a low viscosity solution and strained onto a thin woven fabric to form a whisker layer on the thin woven fabric, this is impregnated with a thermosetting synthetic resin. A method for manufacturing prepreg for manufacturing tubular bodies such as fishing rods, which comprises at least manufacturing a prepreg sheet.
JP59191379A 1984-09-12 1984-09-12 Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like Pending JPS6168206A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59191379A JPS6168206A (en) 1984-09-12 1984-09-12 Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59191379A JPS6168206A (en) 1984-09-12 1984-09-12 Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like

Publications (1)

Publication Number Publication Date
JPS6168206A true JPS6168206A (en) 1986-04-08

Family

ID=16273612

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59191379A Pending JPS6168206A (en) 1984-09-12 1984-09-12 Manufacture of prepreg for manufacturing tubular product such as fishing rod and the like

Country Status (1)

Country Link
JP (1) JPS6168206A (en)

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