JPS6166707A - 新規アクリルアミド系共重合体及びその製造方法 - Google Patents
新規アクリルアミド系共重合体及びその製造方法Info
- Publication number
- JPS6166707A JPS6166707A JP18859784A JP18859784A JPS6166707A JP S6166707 A JPS6166707 A JP S6166707A JP 18859784 A JP18859784 A JP 18859784A JP 18859784 A JP18859784 A JP 18859784A JP S6166707 A JPS6166707 A JP S6166707A
- Authority
- JP
- Japan
- Prior art keywords
- methylolacrylamide
- copolymer
- formula
- reaction
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 14
- 229920000642 polymer Polymers 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 230000002441 reversible effect Effects 0.000 title description 3
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims abstract description 25
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 claims abstract 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract description 17
- 238000010438 heat treatment Methods 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 6
- 239000012528 membrane Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 238000012216 screening Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 239000000243 solution Substances 0.000 description 25
- 230000007704 transition Effects 0.000 description 22
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 15
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 10
- 238000002474 experimental method Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- YQIGLEFUZMIVHU-UHFFFAOYSA-N 2-methyl-n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C(C)=C YQIGLEFUZMIVHU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AJFDBNQQDYLMJN-UHFFFAOYSA-N n,n-diethylacetamide Chemical compound CCN(CC)C(C)=O AJFDBNQQDYLMJN-UHFFFAOYSA-N 0.000 description 1
- WDFKEEALECCKTJ-UHFFFAOYSA-N n-propylprop-2-enamide Chemical compound CCCNC(=O)C=C WDFKEEALECCKTJ-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18859784A JPS6166707A (ja) | 1984-09-08 | 1984-09-08 | 新規アクリルアミド系共重合体及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18859784A JPS6166707A (ja) | 1984-09-08 | 1984-09-08 | 新規アクリルアミド系共重合体及びその製造方法 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13223286A Division JPS61287931A (ja) | 1986-06-07 | 1986-06-07 | 熱可逆性高分子架橋成形体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6166707A true JPS6166707A (ja) | 1986-04-05 |
| JPS6215565B2 JPS6215565B2 (enrdf_load_stackoverflow) | 1987-04-08 |
Family
ID=16226438
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18859784A Granted JPS6166707A (ja) | 1984-09-08 | 1984-09-08 | 新規アクリルアミド系共重合体及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6166707A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63278502A (ja) * | 1987-05-08 | 1988-11-16 | Mitsui Toatsu Chem Inc | 分離膜 |
| US5104954A (en) * | 1987-10-05 | 1992-04-14 | Ciba-Geigy Corporation | Thermostropic biphilic hydrogels and hydroplastics |
| US6974660B2 (en) | 2002-03-15 | 2005-12-13 | Penn State Research Foundation | Method for control of temperature-sensitivity of polymers in solution |
-
1984
- 1984-09-08 JP JP18859784A patent/JPS6166707A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63278502A (ja) * | 1987-05-08 | 1988-11-16 | Mitsui Toatsu Chem Inc | 分離膜 |
| US5104954A (en) * | 1987-10-05 | 1992-04-14 | Ciba-Geigy Corporation | Thermostropic biphilic hydrogels and hydroplastics |
| US6974660B2 (en) | 2002-03-15 | 2005-12-13 | Penn State Research Foundation | Method for control of temperature-sensitivity of polymers in solution |
| US7011930B2 (en) | 2002-03-15 | 2006-03-14 | The Penn State Research Foundation | Method for control of temperature-sensitivity of polymers in solution |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6215565B2 (enrdf_load_stackoverflow) | 1987-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kröger et al. | Light controlled solubility change of polymers: Copolymers of N, N‐dimethylacrylamide and 4‐phenylazophenyl acrylate | |
| Dunn et al. | The synthesis of block copolymers of styrene and methyl methacrylate | |
| Liu et al. | Thermophilic films and fibers from photo cross-linkable UCST-type polymers | |
| US3575946A (en) | Method of preparing soluble polymers of ethylene glycol | |
| Yamamoto et al. | Synthesis and Thermosensitive Properties of Poly [(N‐vinylamide)‐co‐(vinyl acetate)] s and Their Hydrogels | |
| Tanaka et al. | Synthesis and thermal, mechanical, and optical properties of A–B–A or A–B block copolymers containing poly (norbornene‐co‐1‐octene) | |
| CagriAta et al. | Synthesis and characterization of polyvinyl alcohol-g-polystyrene copolymers via MADIX polymerization technique | |
| Wei et al. | Preparation of thermosensitive hydrogels by means of tandem physical and chemical crosslinking | |
| US3663650A (en) | Substantially transparent polydimethylsiloxane - polyalkylmethacrylate compositions and method for making same | |
| Veen et al. | Photoregulation of polymer conformation by photochromic moieties–II. Cationic and neutral moieties on an anionic polymer | |
| Shi et al. | Chiral pH‐Responsive Amphiphilic Polymer Co‐networks: Preparation, Chiral Recognition, and Release Abilities | |
| Biswas et al. | Synthesis and characterization of stereoregular poly (N-ethylacrylamide) hydrogel by using Y (OTf) 3 Lewis acid | |
| Allen et al. | Composites formed by interstitial polymerization of vinyl monomers in polyurethane elastomers: 4. Preparation, properties and structure of acrylonitrile and styrene based composites | |
| JPS6166707A (ja) | 新規アクリルアミド系共重合体及びその製造方法 | |
| US5483005A (en) | Preparation of polymers with NLO-active side groups and the use thereof | |
| Xiang et al. | Preparation and characterization of alkali soluble polyacrylamide-g-polyaniline | |
| Boudevska et al. | The influence of molecular interaction on polymerization, 10. On the copolymerization of methacrylic acid with styrene | |
| US2469295A (en) | Synthetic resins and method for producing same | |
| US3634370A (en) | Acrylonitrile polymerization in the presence of sulfuric acid followed by a neutralization step | |
| JPH0219166A (ja) | 酸素透過性成形物 | |
| JPS61287931A (ja) | 熱可逆性高分子架橋成形体の製造方法 | |
| US3828015A (en) | Method for preparing branched copolymers of ethylene with vinyl organosilicon monomers | |
| JPS61197615A (ja) | 新規な架橋性熱可逆高分子化合物の製造方法 | |
| KR102705506B1 (ko) | 극성 작용기를 포함하는 광학 필름용 그라디언트 공중합체 및 이의 제조방법 | |
| JPH1017622A (ja) | 新規共重合高分子化合物およびその製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |