JPS615196A - Crushing method of fragile substance - Google Patents

Crushing method of fragile substance

Info

Publication number
JPS615196A
JPS615196A JP12712684A JP12712684A JPS615196A JP S615196 A JPS615196 A JP S615196A JP 12712684 A JP12712684 A JP 12712684A JP 12712684 A JP12712684 A JP 12712684A JP S615196 A JPS615196 A JP S615196A
Authority
JP
Japan
Prior art keywords
agent
crushing
combustion
airway
expandable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP12712684A
Other languages
Japanese (ja)
Other versions
JPS6334280B2 (en
Inventor
孝夫 斉藤
吉山 達夫
辻 進三
康夫 石井
坂野 良一
飯島 健一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taisei Corp
Nichiyu Giken Kogyo Co Ltd
NOF Corp
Original Assignee
Taisei Corp
Nichiyu Giken Kogyo Co Ltd
NOF Corp
Nippon Oil and Fats Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taisei Corp, Nichiyu Giken Kogyo Co Ltd, NOF Corp, Nippon Oil and Fats Co Ltd filed Critical Taisei Corp
Priority to JP12712684A priority Critical patent/JPS615196A/en
Publication of JPS615196A publication Critical patent/JPS615196A/en
Publication of JPS6334280B2 publication Critical patent/JPS6334280B2/ja
Granted legal-status Critical Current

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  • Drilling And Exploitation, And Mining Machines And Methods (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、岩石やコンクリート構造物等の脆性物を破砕
する工法に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method for crushing brittle materials such as rocks and concrete structures.

〈従来の技術〉 従来、岩石やコンクリート構造物等の脆性物を膨張性破
砕剤により破砕する場合、熱を供給することによって、
水利反応が促進される石灰系ケイ酸塩を主成分とする膨
張性破砕剤を含水状態にして、燃焼剤とともに、あらか
じめ被破砕物に穿孔した孔内に装填しておき、適宜手段
により燃焼剤に着火して燃焼させ、その時の燃焼熱によ
り、膨張性破砕剤の水和反応による膨張圧の発現を促進
するとともに、燃焼剤周辺部の水等をガス化して、この
ガス圧をも利用して被破砕物を破砕する工法がある。(
特公昭54−38412号公報)〈発明が解決しようと
する問題点〉 ところが、この方法の場合、封塞剤として使用する急硬
性モルタル等が硬化する時以前、又は膨張性破砕剤が膨
張固化して封塞効果を示す時以前に、燃焼剤を燃焼させ
ると、燃焼時に発生する水蒸気等のガス圧によって、燃
焼剤の位置より孔口側に装填した封塞剤又は膨張性破砕
剤が孔口から噴出し、破砕効果を著しく損なうばかりで
なく、噴出物が周囲に危害を及ぼす場合もあった。かか
る不具合を回避するため、従来の工法では、封塞剤とし
て急硬性モルタル等を使用する場合でも30分以上、膨
張性破砕剤のみを使用して封塞効果を発揮させる場合に
は2時間以上も待ってから、燃焼剤を燃焼させる必要が
あったので、早急に破砕を必要とする破砕工事には不適
格であった。
<Conventional technology> Conventionally, when crushing brittle materials such as rocks or concrete structures using an expansive crushing agent, by supplying heat,
An expansible crushing agent mainly composed of lime-based silicate, which promotes water utilization reactions, is brought into a hydrated state and loaded together with a combustion agent into holes drilled in the object to be crushed in advance. is ignited and combusted, and the combustion heat at that time promotes the development of expansion pressure due to the hydration reaction of the expandable crushing agent, and also gasifies water etc. around the combustion agent and utilizes this gas pressure. There is a method of crushing the material to be crushed. (
(Japanese Patent Publication No. 54-38412) (Problems to be Solved by the Invention) However, in the case of this method, the problem occurs before the rapidly hardening mortar used as the sealant hardens or when the expandable crushing agent expands and solidifies. If the combustion agent is burned before it exhibits a sealing effect, the pressure of gas such as water vapor generated during combustion will cause the sealant or expandable crushing agent loaded closer to the hole opening than the position of the combustion agent to burst into the hole. In some cases, the ejected material not only significantly impairs the crushing effect, but also poses a hazard to the surrounding area. In order to avoid such problems, in conventional construction methods, it takes at least 30 minutes even when using rapidly hardening mortar etc. as a sealing agent, and for at least 2 hours when using only an expanding crushing agent to achieve a sealing effect. Because it was necessary to wait for a long time before burning the combustible material, the method was unsuitable for crushing work that required immediate crushing.

く問題点を解決するための手段〉 本発明の目的は、従来の上述の欠点を解消して、急硬性
モルタル等の、膨張性破砕剤以外の封塞剤を使用するこ
となく、また、噴出の危険性もなく、しかも、短時間で
破砕を完了し得る破砕工法を提供することにある。
Means for Solving the Problems> An object of the present invention is to solve the above-mentioned drawbacks of the conventional technology, and to eliminate the need for a sealant other than an expandable crushing agent such as a rapidly hardening mortar, To provide a crushing method that can complete crushing in a short time without the risk of.

すなわち、本発明の破砕工法は、燃焼剤と点火部とを収
納した燃焼剤容器と、その容器の外壁に一端を固定した
線状体とからなる加熱具を、含水状態にある例えば石灰
系ケイ酸塩を主成分とする膨張性破砕剤とともに、あら
かじめ被破砕物の所定の位置に設けた孔の中に、加熱具
が膨張性破砕剤中に埋設するように装填し、膨張性破砕
剤が固化する以前に、上記線状体を引き抜いて気道を作
り、燃焼剤を適宜手段によって燃焼させ、その時に発生
するガス圧を気道を通じて孔口から孔外に放散させるこ
とによって、膨張性破砕剤の孔]」からの噴出を防ぎ、
さらに、燃焼剤の燃焼熱を反応過程にある膨張性破砕剤
に伝達して、破砕時間の短縮をはかることを特徴とする
破砕工法である。
That is, in the crushing method of the present invention, a heating tool consisting of a combustion agent container containing a combustion agent and an ignition part, and a linear body with one end fixed to the outer wall of the container is used to crush, for example, lime-based silica in a water-containing state. A heating tool is embedded in the expandable crushing agent together with an expandable crushing agent whose main component is an acid salt, and the heating tool is inserted into a hole prepared in advance at a predetermined position of the object to be crushed, and the expandable crushing agent is Before it solidifies, the linear body is pulled out to create an airway, the combustion agent is combusted by an appropriate means, and the gas pressure generated at that time is radiated out of the hole through the airway, thereby releasing the expandable crushing agent. Prevents eruption from the hole]
Furthermore, this crushing method is characterized by transmitting the combustion heat of the combustion agent to the expandable crushing agent in the reaction process to shorten the crushing time.

以下、本発明の破砕工法を図によって説明する。Hereinafter, the crushing method of the present invention will be explained with reference to the drawings.

第1図は、本発明の一実施態様を示す縦断面図で、1は
岩石やコンクリート構造物等の脆性被破砕物であり、2
は脆性被破砕物1の所定の位置に穿孔された孔である。
FIG. 1 is a longitudinal sectional view showing one embodiment of the present invention, in which 1 is a brittle object such as a rock or a concrete structure, and 2 is a brittle object to be crushed.
is a hole drilled at a predetermined position in the brittle material 1 to be crushed.

3は加熱することにより、水和反応が増進する膨張性破
砕剤で、例えば、石灰系ケイ酸塩を主成分とする膨張性
破砕剤等である。
3 is an expansible crushing agent whose hydration reaction is promoted by heating, such as an expansible crushing agent whose main component is lime-based silicate.

4は燃焼剤容器であり、この燃焼剤容器4の外壁には、
引き抜くことによって容易に離脱するように、線状体5
の一端が適宜手段例えば粘着テープ等(図示しない)に
よって固定されており、その他端は孔2の孔口から孔外
に出るように装填される。燃焼剤容器4は水[こ対して
不透過性のプラスチック又は金属製の容器で、内部には
金属酸化物と金属還元剤との混合物からなる燃焼剤6と
、通電することによって灼熱するニクロム線等の抵抗線
からなる点火部7とが収納されている。点火部7には導
線8a、8bが接続され、その他端は孔2の孔口から孔
外に導かれる。
4 is a combustion agent container, and on the outer wall of this combustion agent container 4,
The linear body 5 is arranged so that it can be easily detached by pulling it out.
One end is fixed with appropriate means such as adhesive tape (not shown), and the other end is loaded so as to come out of the hole 2. The combustion agent container 4 is a water-impermeable plastic or metal container, and inside contains a combustion agent 6 consisting of a mixture of metal oxide and metal reducing agent, and a nichrome wire that becomes scorching hot when energized. An ignition section 7 made of resistance wires such as the above is housed. Conductive wires 8a and 8b are connected to the ignition part 7, and the other ends are guided out of the hole from the opening of the hole 2.

図のように装填したのち、膨張性破砕剤3が固化するま
での間に、孔2の孔口から出ている加熱具の線状体5を
引き抜くと、燃焼剤容器4の外壁に固定された線状体5
の一端が離脱して、線状体5は孔外に抜け、膨張性破砕
剤3の中に、燃焼剤容器4の近傍から孔口まで連通する
気道が形成される。 次いで、導線8a、8bに電流を
通じて点火部7を灼熱せしめ燃焼剤6を燃焼させると、
燃焼剤6の燃焼によって生じたガスや、燃焼熱によって
気化した水蒸気は、孔口まで連通した」−記気道を通じ
て孔2の孔口から孔外へ逸散する。従って、孔2内には
ガス圧の蓄積が生じないため、膨張性破砕剤3を一気に
孔2から吐出するいわゆる噴出力は生じない。
After loading as shown in the figure, if the linear body 5 of the heating tool protruding from the hole 2 is pulled out before the expandable crushing agent 3 solidifies, it will be fixed to the outer wall of the combustion agent container 4. Linear body 5
One end separates, and the linear body 5 comes out of the hole, forming an airway in the expandable crushing agent 3 that communicates from the vicinity of the combustion agent container 4 to the hole opening. Next, when electric current is passed through the conductors 8a and 8b to scorch the ignition part 7 and burn the combustion agent 6,
The gas generated by the combustion of the combustion agent 6 and the water vapor vaporized by the heat of combustion escape from the hole of the hole 2 through the airway that communicates with the hole. Therefore, since no gas pressure is accumulated in the holes 2, so-called ejection force for discharging the expandable crushing agent 3 from the holes 2 at once does not occur.

また、燃焼剤6の燃焼熱は、燃焼剤容器4の周辺と前記
気道に近接した膨張性破砕剤3に伝達され、膨張性破砕
剤3の水和反応は急速に促進される。しかも、例えば、
石灰系ケイ酸塩を主成分とする膨張性破砕剤3の水和反
応は発熱反応であるので、急速に反応した一部の膨張性
破砕剤3から発生する熱量で、さらにその周囲の膨張性
破砕剤3が加熱され、反応が促進される。このようにし
て孔2内全域の膨張性破砕剤3に急速な水和反応が進行
し、この膨張圧力によって脆性被破砕物1は短時間で破
砕される。
Further, the combustion heat of the combustion agent 6 is transferred to the expandable crushing agent 3 near the combustible agent container 4 and the airway, and the hydration reaction of the expandable crushing agent 3 is rapidly promoted. Moreover, for example,
The hydration reaction of the expandable crushing agent 3 whose main component is lime-based silicate is an exothermic reaction. The crushing agent 3 is heated to accelerate the reaction. In this way, a rapid hydration reaction progresses in the expandable crushing agent 3 throughout the interior of the hole 2, and the brittle object 1 to be crushed is crushed in a short time by this expansion pressure.

なお、本発明に使用される線状体は、脆性被破砕物に穿
孔された孔の大きさによって、その材質、太さ、本数等
が決められる。通常用いられる直径34〜40mmの孔
に対しては、取り扱いが容易であることから、材質とし
ては可撓性のひも、針金又は電線等が好ましく、太さは
直径1mmから10 m +u、好ましくは1mmから
5mmである。直径が11III11未満であると、線
状体を引き抜いたあとに形成される気道の直径が小さい
ので、膨張性破砕剤によってff11+まってしまうこ
とがあり、ガス抜けを阻害するおそれがある。また、直
径が1.ommを超えると、気道の容積が大きくなりす
ぎ、相対的に膨張性破砕剤の装填密度が低くなるので、
破砕に至るまでの時間が長くなるという欠点がある。
The material, thickness, number, etc. of the linear bodies used in the present invention are determined by the size of the holes drilled in the brittle object to be crushed. For the commonly used holes with a diameter of 34 to 40 mm, the material is preferably a flexible string, wire, or electric wire, since it is easy to handle, and the thickness is from 1 mm to 10 m + u, preferably. It is 1 mm to 5 mm. If the diameter is less than 11III11, the diameter of the airway formed after the filament is pulled out is small, so the expandable crushing agent may cause the airway to become ff11+, which may impede gas release. Also, the diameter is 1. If it exceeds omm, the volume of the airway becomes too large and the loading density of the expandable disrupting agent becomes relatively low.
The disadvantage is that it takes a long time to crush.

さらに、線状体の本数は、1本であっても複数本であっ
ても差し支えないが、複数本の場合は、気道全部の合泪
容積が、直径10mmの1木の線状体を用いたときの容
積より大きくなることは、上に述べた理由から好ましく
ない。
Furthermore, the number of linear bodies may be one or more, but in the case of multiple linear bodies, the combined volume of the entire airway can be reduced by using one wooden linear body with a diameter of 10 mm. For the reasons stated above, it is not preferable for the volume to be larger than the original volume.

以」−1気道を形成する方法として、可撓性を有する線
状体を例として説明してきたが、この線状体に代えて線
状体と同寸法の鉄棒、プラスチック棒等の棒状体もしく
は金属管、プラスチック管等の管状体も、十分使用し得
ることはいうまでもない。特に、管状体の場合は、線状
体と同様に引き抜いて気道を形成してもよいし、あるい
は、引き抜かずにそのまま膨張性破砕剤中に残留させて
、気道として使用してもよい。
Hereinafter, the method for forming an airway has been explained using a flexible linear body as an example, but instead of this linear body, a rod-shaped body such as an iron rod or a plastic rod of the same size as the linear body, or It goes without saying that tubular bodies such as metal tubes and plastic tubes can also be used satisfactorily. In particular, in the case of a tubular body, it may be pulled out to form an airway in the same way as a linear body, or it may be left in the expandable crushing agent without being pulled out and used as an airway.

また、これら線状体を引き抜いて気道を形成する代わり
に、始めに線状体を有しない加熱具を装填しておき、燃
焼剤を燃焼させる前に、線状体と同寸法の棒状体を加熱
具の近傍に押し込み、次いで引き抜いて気道を形成する
方法も、十分実用に供し得る。
In addition, instead of pulling out these linear bodies to form an airway, it is possible to first load a heating tool that does not have a linear body, and before burning the combustion agent, a rod-shaped body of the same size as the linear body is inserted. A method in which the airway is formed by pushing the airway into the vicinity of the heating tool and then pulling it out can also be put to practical use.

本発明の方法に用いられる加熱具の燃焼剤は、金属酸化
物と金属還元剤との混合物からなる組成物で、金属酸化
物としては、酸化鉄、酸化銅、酸化ニッケル等が、金属
還元剤としては、アルミニウム、マグネシウム、ケイ素
等が、それぞれ、1種又は2種以」二の混合物として使
用される。
The combustion agent of the heating tool used in the method of the present invention is a composition consisting of a mixture of a metal oxide and a metal reducing agent. Examples of the metal oxide include iron oxide, copper oxide, nickel oxide, etc. As the material, aluminum, magnesium, silicon, etc. are each used singly or as a mixture of two or more.

〈実施例及び比較例〉 次に、実施例及び比較例によって、本発明をさらに詳細
に説明する。
<Examples and Comparative Examples> Next, the present invention will be explained in more detail with reference to Examples and Comparative Examples.

実施例1〜4、比較例1〜4 縦50cm、横50cm、高さ50cmの無筋コンクリ
ートの中央に、直径38mm、深さ35cmの孔を穿孔
し、別に、外径30mm、高さ35mmのプラスチック
製の燃焼剤容器に、主成分がFe2O3である酸化鉄7
5重量部とアルミニウム粉末25市川部−7= との混合粉末20gからなる燃焼剤と、ニクロム線から
なる点火部とを収納し、その燃焼剤容器の外壁に、線状
体として外径1.25mmのビニル被覆電線の一端をビ
ニルテープで固定してなる加熱具を用意し、この加熱具
の燃焼剤容器の上面が孔口から25cmの位置に埋設さ
れるように、加熱具の周囲に膨張性破砕剤(商品名カー
ムマイト、日油技研工業(株)製)を装填した。以上の
ように装填して、装填から線状体を引き抜くまでの時間
(引抜時間)及び装填から燃焼開始までの時間(燃焼時
間)を変化させて、膨張性破砕剤噴出の有無と装填から
破砕に至るまでの時間(破砕時間)とを調べた。なお、
比較例として線状体を使用しない場合についても実施例
に準じて実施した。結果を第1表に示した。
Examples 1 to 4, Comparative Examples 1 to 4 A hole with a diameter of 38 mm and a depth of 35 cm was drilled in the center of plain concrete measuring 50 cm in length, 50 cm in width, and 50 cm in height. Iron oxide 7, the main component of which is Fe2O3, is placed in a plastic combustion agent container.
A combustion agent consisting of 20g of a mixed powder of 5 parts by weight of aluminum powder and 25 parts by weight of aluminum powder and an ignition part consisting of a nichrome wire are stored, and a linear body with an outer diameter of 1.5 parts is placed on the outer wall of the combustion agent container. Prepare a heating tool made by fixing one end of a 25 mm vinyl-covered electric wire with vinyl tape, and expand around the heating tool so that the top surface of the combustion agent container of this heating tool is buried 25 cm from the hole opening. A crushing agent (trade name: CALMITE, manufactured by NOYU Giken Kogyo Co., Ltd.) was loaded. After loading as described above, the time from loading to pulling out the linear body (pulling time) and the time from loading to the start of combustion (combustion time) were varied to determine whether or not the expansible crushing agent was ejected and from loading to crushing. The time required to achieve this (crushing time) was investigated. In addition,
As a comparative example, a case in which no linear body was used was also carried out according to the example. The results are shown in Table 1.

第1表実施例1の結果から明らかなように、本発明の破
砕工法によれば、膨張性破砕剤と加熱具との装填後3分
間で燃焼剤を燃焼させても、膨張性破砕剤の噴出は起こ
らず、しかも、装填後15分間でコンクリ−1へが破砕
されることが分かる。
As is clear from the results of Example 1 in Table 1, according to the crushing method of the present invention, even if the combustion agent is burned for 3 minutes after loading the expandable crushing agent and the heating tool, the expandable crushing agent is It can be seen that no eruption occurred and, moreover, the concrete 1 was crushed within 15 minutes after loading.

実施例5〜23、比較例5〜7 実施例1〜4と同様なコンクリート及び加熱具(気道を
棒状体の押し込みによって形成するときは燃焼剤容器)
を使用し、引抜時間(押し込みによって気道を形成する
ときは押込時間)を2分、燃焼時間を5分と定め、線状
体、棒状体、管状体の種類、外径、本数及びそれらによ
る気道形成方法の区分を第2表に示すとおりとして、実
施例1〜4に準じて膨張性破砕剤噴出の有無及び破砕時
間を調べた。結果を第2表に示した。
Examples 5 to 23, Comparative Examples 5 to 7 Concrete and heating tool similar to Examples 1 to 4 (combustion agent container when airway is formed by pushing a rod)
The extraction time (the pushing time when forming an airway by pushing) was set at 2 minutes, the combustion time was set at 5 minutes, and the type, outer diameter, number of linear bodies, rod-shaped bodies, and tubular bodies, and the airways formed by them were determined. The classification of the formation method was as shown in Table 2, and the presence or absence of extrusion of the expandable crushing agent and the crushing time were investigated according to Examples 1 to 4. The results are shown in Table 2.

第2表に示されるとおり、本発明の破砕工法は、気道形
成に線状体、棒状体、管状体のいずれを用いても、また
、気道形成をそれらの引き抜き、押し込みあるいは残留
のいずれによって行なっても、形成された気道全部の合
計容積が一定範囲内にある限り、常に膨張性破砕剤の噴
出がなく、破砕時間も十分実用の範囲内にあることは明
らかである。
As shown in Table 2, the crushing method of the present invention can be used to form airways regardless of whether linear bodies, rod-shaped bodies, or tubular bodies are used, and whether the airways can be formed by pulling them out, pushing them in, or leaving them behind. However, it is clear that as long as the total volume of all the airways formed is within a certain range, there is no ejection of the expandable crushing agent and the crushing time is well within a practical range.

〈発明の効果〉 以上の記載から明らかなように、本発明の破砕工法、す
なわち含水状態にある膨張性破砕剤中に加熱具等を埋設
するように装填し、加熱具等の周辺に気道を形成する破
砕工法は、膨張性破砕剤の噴出を防止して、しかも、装
填後燃焼剤を燃焼させるまでの待時間を極端に短縮する
ことができる産業上利用価値の高い発明である。
<Effects of the Invention> As is clear from the above description, the crushing method of the present invention, that is, a heating tool, etc. is buried in an expandable crushing agent in a water-containing state, and airways are created around the heating tool, etc. The resulting crushing method is an industrially valuable invention that prevents the expulsion of the expandable crushing agent and can extremely shorten the waiting time until the combustible agent is combusted after loading.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施態様を示す縦断面図である。 1:脆性被破砕物 2:孔 3:膨張性破砕剤 4:燃焼剤容器 5:線状体 6:燃焼剤 7:点火部 8a、8b:導線 特許出願人  日油技研工業株式会社 大成建設株式会社 日本油脂株式会社 FIG. 1 is a longitudinal sectional view showing one embodiment of the present invention. 1: Brittle object to be crushed 2: Hole 3: Expandable crushing agent 4: Combustion agent container 5: Linear body 6: Combustion agent 7: Ignition part 8a, 8b: Conductor wire Patent applicant: NOYU Giken Kogyo Co., Ltd. Taisei Construction Co., Ltd. Nihon Yushi Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 水和反応によって体積膨張する膨張性破砕剤と燃焼剤と
を用いて、岩石やコンクリート構造物等の脆性物を破砕
する工法において、脆性物に穿孔した孔内に、燃焼剤と
点火部とを収納した燃焼剤容器と燃焼剤容器の外壁に一
端を固定した線状体とからなる加熱具を、上記膨張性破
砕剤とともにその中に埋設するように装填したのち、上
記線状体を引き抜いて気道を形成し、燃焼剤の燃焼熱に
よって発生するガスを気道を通じて、孔外へ放散させる
ことを特徴とする破砕工法
In a method of crushing brittle materials such as rocks and concrete structures using an expansible crushing agent that expands in volume through a hydration reaction and a combustion agent, the combustion agent and ignition part are placed in a hole drilled in the brittle material. A heating tool consisting of a stored combustion agent container and a linear body with one end fixed to the outer wall of the combustion agent container is buried therein together with the expandable crushing agent, and then the linear body is pulled out. A crushing method characterized by forming an airway and dissipating gas generated by the heat of combustion of a combustion agent out of the hole through the airway.
JP12712684A 1984-06-20 1984-06-20 Crushing method of fragile substance Granted JPS615196A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12712684A JPS615196A (en) 1984-06-20 1984-06-20 Crushing method of fragile substance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12712684A JPS615196A (en) 1984-06-20 1984-06-20 Crushing method of fragile substance

Publications (2)

Publication Number Publication Date
JPS615196A true JPS615196A (en) 1986-01-10
JPS6334280B2 JPS6334280B2 (en) 1988-07-08

Family

ID=14952250

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12712684A Granted JPS615196A (en) 1984-06-20 1984-06-20 Crushing method of fragile substance

Country Status (1)

Country Link
JP (1) JPS615196A (en)

Also Published As

Publication number Publication date
JPS6334280B2 (en) 1988-07-08

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