JPS6141559B2 - - Google Patents

Info

Publication number

JPS6141559B2

JPS6141559B2 JP2451579A JP2451579A JPS6141559B2 JP S6141559 B2 JPS6141559 B2 JP S6141559B2 JP 2451579 A JP2451579 A JP 2451579A JP 2451579 A JP2451579 A JP 2451579A JP S6141559 B2 JPS6141559 B2 JP S6141559B2

Authority

JP

Japan

Prior art keywords

fructose

glucose

solution

tank

liquid

Prior art date

1979-03-05

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

• Espacenet
• Global Dossier
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• 239000005715 Fructose Substances 0.000 claims description 144
• 229930091371 Fructose Natural products 0.000 claims description 144
• RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 144
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 111
• 239000008103 glucose Substances 0.000 claims description 111
• 239000007788 liquid Substances 0.000 claims description 86
• 239000000243 solution Substances 0.000 claims description 84
• 238000000034 method Methods 0.000 claims description 44
• 239000011550 stock solution Substances 0.000 claims description 41
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 34
• WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 31
• 238000001179 sorption measurement Methods 0.000 claims description 25
• 230000008569 process Effects 0.000 claims description 21
• NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 14
• 239000003729 cation exchange resin Substances 0.000 claims description 14
• 239000000203 mixture Substances 0.000 claims description 13
• 230000002378 acidificating effect Effects 0.000 claims description 11
• 239000012530 fluid Substances 0.000 claims description 6
• 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims description 6
• 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
• 150000001342 alkaline earth metals Chemical class 0.000 claims description 5
• GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 21
• 239000011347 resin Substances 0.000 description 21
• 229920005989 resin Polymers 0.000 description 21
• 235000000346 sugar Nutrition 0.000 description 17
• 238000000926 separation method Methods 0.000 description 11
• 239000000463 material Substances 0.000 description 7
• 238000000605 extraction Methods 0.000 description 5
• 150000008163 sugars Chemical class 0.000 description 5
• BJHIKXHVCXFQLS-UYFOZJQFSA-N fructose group Chemical group OCC(=O)[C@@H](O)[C@H](O)[C@H](O)CO BJHIKXHVCXFQLS-UYFOZJQFSA-N 0.000 description 4
• 238000002347 injection Methods 0.000 description 4
• 239000007924 injection Substances 0.000 description 4
• 238000010586 diagram Methods 0.000 description 3
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
• UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
• 230000008859 change Effects 0.000 description 2
• 230000007423 decrease Effects 0.000 description 2
• 230000000694 effects Effects 0.000 description 2
• 230000006872 improvement Effects 0.000 description 2
• 239000011259 mixed solution Substances 0.000 description 2
• 239000002245 particle Substances 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• 229930006000 Sucrose Natural products 0.000 description 1
• CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
• 229910021536 Zeolite Inorganic materials 0.000 description 1
• 239000003463 adsorbent Substances 0.000 description 1
• LKDRXBCSQODPBY-ZXXMMSQZSA-N alpha-D-fructopyranose Chemical compound OC[C@]1(O)OC[C@@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-ZXXMMSQZSA-N 0.000 description 1
• 230000008901 benefit Effects 0.000 description 1
• 229910001628 calcium chloride Inorganic materials 0.000 description 1
• 239000001110 calcium chloride Substances 0.000 description 1
• 229940023913 cation exchange resins Drugs 0.000 description 1
• 238000013375 chromatographic separation Methods 0.000 description 1
• 238000004440 column chromatography Methods 0.000 description 1
• 238000011109 contamination Methods 0.000 description 1
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
• 230000004941 influx Effects 0.000 description 1
• 229960004903 invert sugar Drugs 0.000 description 1
• 239000003456 ion exchange resin Substances 0.000 description 1
• 229920003303 ion-exchange polymer Polymers 0.000 description 1
• 238000006317 isomerization reaction Methods 0.000 description 1
• 230000000813 microbial effect Effects 0.000 description 1
• 230000002265 prevention Effects 0.000 description 1
• 238000004064 recycling Methods 0.000 description 1
• 150000003839 salts Chemical class 0.000 description 1
• 239000012086 standard solution Substances 0.000 description 1
• 239000005720 sucrose Substances 0.000 description 1
• 239000010457 zeolite Substances 0.000 description 1